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Class Xii Final Papers (All)
Class Xii Final Papers (All)
SECTION A
This section contains 16 multiple-choice questions with only one correct answer. Each question of the section
carries 1 mark. There is no internal choice in this section.
2. The following cell is found to have the standard cell potential of 2.36 V. What will be standard
reduction potential value of magnesium electrode? 1
3. The molecularity of an elementary reaction cannot have which of the following values according to the
collision theory? 1
(a) 2.5 (b) 1
(c) 2 (d) 3
4. The rate law for the reaction, A + B → Products is: Rate = k [A] [B]2. The rate of this reaction at 298 K
is found to be 0.25 mol L−1 s−1. What is the rate constant of the reaction if [A] = 1 mol L−1 and [B] = 0.2
mol L−1? 1
2 −2 −1 2 −2 −1
(a) 6.25 L mol s (b) 0.16 L mol s
(c) 100 L2 mol−2 s−1 (d) 16 L2 mol−2 s−1
7. Which of the following elements can stabilize the higher oxidation states like +6, +7 and +8 of
transition metals to the greatest extent? 1
(a) Nitrogen (b) Fluorine
(c) Chlorine (d) Oxygen
8. How many moles of AgCl will be obtained when CoCl3.4NH3 is treated with excess
AgNO3 solution? 1
(a) 1 (b) 2
(c) 3 (d) 0
10. Name the main product obtained when an alkyl halide is reacted with silver cyanide. 1
(a) Alkyl cyanide (b) Alkyl isocyanide
(c) Aliphatic amide (d) Carboxylic acid
11. For the best yield of ether from Williamson’s synthesis, the alkyl halide should
preferable be: 1
(a) Primary (b) Secondary
(c) Tertiary (d) Acidified
12. The esterification of alcohols involves the breaking of which bond in alcohols? 1
(a) Carbon-oxygen (b) Oxygen-hydrogen
(c) Carbon-hydrogen (d) Carbon-carbon
For Questions 13 to 16, two statements are given – one labelled Assertion (A) and the other
labelled Reason (R). Select the correct answers to these questions from (i), (ii), (iii), and (iv) as
given below: 1×4=4
(i) Both Assertion (A) and Reason (R) are correct statements, and the Reason
(R) is the correct explanation of the Assertion (A).
(ii) Both Assertion (A) and Reason (R) are correct statements, but the Reason
(R) is not the correct explanation of the Assertion (A).
(iii) Assertion (A) is correct, but Reason (R) is an incorrect statement.
(iv) Assertion (A) is incorrect, but Reason (R) is a correct statement.
13. Assertion (A) : During the nitration of aniline, 47% of the product formed is
meta-substituted.
Reason (R) : During the nitration of aniline, anilinium ion is formed that has the
meta-directing —NH+ group.
14. Assertion (A) : Benzene diazonium chloride reacts with phenol in alkaline
medium to form a coloured dye.
Reason (R) : Benzene diazonium chloride is resonance stabilized.
15. Assertion (A) : Primary amines cannot form intermolecular hydrogen bonds.
Reason (R) : In primary amines, the nitrogen atom is directly bonded to two
hydrogen atoms.
SECTION B
This section contains 7 very-short-answer questions with internal choice in two questions. Each
question of the section carries 2 marks.
17. State Kohlrausch’s law of independent migration of ions and give its mathematical expression.
2
OR
The graph shows the variation of molar conductivities of two electrolytes, A and B with
concentration. Identify the weak electrolyte and explain what accounts for its increase in molar
conductivity as the concentration of its solution approaches zero. 2
19. A first order reaction takes 69.3 minutes for 50% completion. How much time will it take for
80% completion? (log 2 = 0.3010, log 5 = 0.6990, log 8 = 0.9030) 2
20. What type of structural isomerism is exhibited by the following compounds? 1+1=2
(a) [Cr(NH3)5Cl]SO4
(b)[Cr(NH3)6][Co(CN)6]
SECTION C
This section contains 5 short-answer questions with internal choice in two questions. Each question of
the section carries 3 marks.
22. How many grams of ascorbic acid (vitamin C, C6H8O6) must be dissolved in 75 g of acetic acid
to lower its melting point by 1.5ºC. The Kf for acetic acid is 3.9 K kg mol−1 and the atomic masses
are C = 12 u, H = 1 u, O = 16 u. 3
23. Write the IUPAC name of [Ni(CN)4]2− complex and explain why the complex is (Any two): 3
(a) Square planer in shape
(b) Diamagnetic in nature
(c) Homoleptic.
25. Write the reaction mechanism of acid-catalysed dehydration of ethanol to form ethene. What
product is formed when ethanol is heated with conc. H2SO4 at 413 K? 3
26. Write the chemical equations for the following reactions: 1×3=3
(a) Gabriel phthalimide synthesis
(b) Hoffmann bromamide degradation
(c) Isocyanide test
OR
Answer the following questions: 1×3=3
(a) The pKb values of CH3NH2, C6H5NH2, and C6H5CH2NH2 are 3.38, 9.38, and 4.70
respectively. Arrange these amines in the increasing order of their basic strength.
(b) Write the IUPAC name of the compound:
(c) How would you explain aniline‟s inability to give Friedel-Craft reactions?
SECTION D
This section contains 2 case-based questions with internal choice in one of the sub-questions that follow
the passages. Each question of the section carries 4 marks.
29. The four colligative properties of the dilute solutions help in calculating the molecular mass of the
solute which is often called observed molecular mass. It may be same as the theoretical molecular mass
(calculated from the molecular formula) if the solute behaves normally in solution. In case, it undergoes
association or dissociation, the observed molar mass gives different results. The nature of the solute in
solution is expressed in terms of van’t Hoff factor (i) which may be 1 (if the solute behaves normally),
less than 1 (if the solute associates) and more than 1 (if the solute dissociates). The extent of association
or dissociation is represented by : (n=no of particles after dissociation/before association)
OR
What will be the van’t Hoff factor if the solute A+B-is 40% dissociated?
30. The communication between different cells in our body is established by certain chemicals called
hormones, which act as chemical messengers. Hormones are a group of biomolecules which are produced
in the endocrine or ductless glands and are carried to different parts of the body by the blood stream
where they control various metabolic processes or show physiological activity. They are required only
in very small amounts. Like fats and carbohydrates, they are not stored in the body but continuously
being produced.
In mammals, the secretion of hormones is controlled by the pituitary gland located at the
base of the brain. A general classification of hormones is given below.
OR
Which gland controls the secretion of hormones in humans? 1
d. By reading the above passage, differentiate between steroids and non-steroids
hormone. 1
SECTION E
This section contains 3 long-answer questions with internal choice in two of them. Each question of
the section carries 5 marks.
31. Answer any five from the following cell: 3+2=5
Sn | Sn2+ (0.02 M) || Ag+ (0.1 M) | Ag
Given: E° Sn2+ / Sn = −0.136 V and E° Ag+ /Ag = 0.799 V
a) Write cell reaction.
b) Between Sn and Ag which one is more reducing?
c) Calculate E°cell.
d) Write one use of salt bridge.
e) Predict whether the reaction is spontaneous or not?
f) Can we store Ag in tin container? Give reason for your answer.
g) Calculate Ecell for the above.
32. Give reasons: 1×5=5
2+
a) The compounds of Zn are colorless.
b) Among the first transition series, chromium is the hardest metal.
c) Scandium does not show variable oxidation states.
c) Transition elements form interstitial compounds.
d) Zinc, cadmium, and mercury are not considered as transitions elements.
OR
Answer the following questions: 3+1+1=5
(a) What is lanthanide contraction? Mention its cause and any two consequences.
(b) Cerium, in its +4-oxidation state, is oxidizing in nature. Why?
(c) Write the balanced ionic equation for the oxidation of iodide in the presence of
alkaline potassium permanganate.
OR
Write the main product of the following reactions: 3+2=5
MARKING SCHEME
Questi
on Value Points Mark
s
No.
SECTION A
1. (b) H2 at cathode, Cl2 at anode 1
2. (d) −2.36 V 1
3. (a) 2.5 1
8. (a) 1 1
(i) Both Assertion (A) and Reason (R) are correct statements, and 1
13
the Reason (R) is the correct explanation of the Assertion (A).
(ii) Both Assertion (A) and Reason (R) are correct statements, but 1
14.
the Reason (R) is not the correct explanation of the Assertion (A).
(iv) Assertion (A) is incorrect, but Reason (R) is a correct 1
15.
statement.
(iii) Assertion (A) is correct, but Reason (R) is an incorrect 1
16.
statement.
SECTION B
● At infinite dilution, when dissociation of electrolyte is complete,
each ion makes a definite contribution of its own towards the
17. molar conductivity of electrolyte, irrespective of
the nature of the other ion with which it is associated. 1
● Ωo = ν+ λ˚+ + ν– λ˚– 1
m
OR
● B 1
● Dilution causes the degree of dissociation/ionization of B to
increase, resulting in greater number of ions. 1
● The reactions which have actual order higher than 1, but
18. under certain conditions behave like a first order reactions. 1
● Acidic hydrolysis of ethyl acetate or sucrose. 1
For a first order reaction, k = 0.693 = = 0.693 = 0.01 min−1 ½
t0.5 69.3
½
t = 2.303 log
R0
k R
½
19. = 2.303 log
100
0.01 20
= 2.303 log 5
0.01 ½
= 230.3 × 0.6990
t = 160.9 min
(Half mark to be deducted for not writing or writhing wrong unit)
(a) Ionization isomerism 1
20
(b) Coordination isomerism 1
An optically inactive mixture of two enantiomers in equal
(a) 1
proportions.
(b) A carbon atom attached to four different atoms or group of atoms. 1
OR
21 (a) The boiling points of isomeric alkyl halides decrease with
branching because of the weakened van der Waal’s forces. 1
It is because para-isomers fit in the crystal lattice better than
(b) 1
ortho- and meta-isomers.
SECTION C
MB of solute, C6H8O6 = (6×12) + (8×1) + (6×16) ½
= 176 g mol−1
WB = ∆Tf × MB × WA ½
22. Kf × 1000
( 1
a
)
½
(
24. b ½
)
( 1
c
)
● Mechanism of dehydration of ethanol: H2SO4 →
H+ + HSO4− ½
2
5 ½
½
1
26
a)
b) 1
R—CONH2 + Br2 + 4NaOH → R—NH2 + Na2CO3 + 2NaBr + 2H2O
Amide 1º amine
c) 1
R—NH2 + CHCl3 + 3KOH → R—NC + 3KCl + 3 H2O
31 a) Correct reaction.
b) Sn
c) E˚ = E˚ – E˚ = 0.799 − (−0.136) = 0.935 V
cell cathode anode
c d
C6H5COCl
d) By Tollens test
e) By Iodorm reaction
KENDRIYA VIDYALAYA SANGATHAN
(IN-SERVICE COURSE 2023-24, AHMEDABAD REGION)
CLASS XII- SESSION ENDING EXAMINATION (SEE)
CHEMISTRY THEORY (043)
BLUE-PRINT
CHEMISTRY (043)
Class: XII
S.No Chapters MCQ VSA SA Case LAQ Total
A/R study Marks
question
1 1 2 3 4 marks 5 70
Mark Mark Marks Marks MARKS
1 SOLUTIONS 2(2) 1(3) 7
SECTION A
The following questions are multiple -choice questions with one correct answer. Each
question carries 1 mark. There is no internal choice in this section.
S.N. QUESTIONS: MARKS
1. Which of the following solutions of KCl will have the highest value of 1
conductivity?
a) 0.5 M b) 0.01M c) 0.1M d) 1.0 M
2. 1
Above shown Acetal is formed by the reaction between A &B in the presence of
dry HCl. Identify A and B.
SECTION: B
This section contains 5 questions with internal choice in one question. The
following questions are very short answer type and carry 2 marks each.
17. (i) Gas (A) is more soluble in water than Gas (B) at the same temperature. Which 1
one of the two gases will have the higher value of KH (Henry’s constant) and
why?
(ii) In non-ideal solution, what type of deviation shows the formation of
maximum boiling azeotropes? 1
18. Calculate the mass of ascorbic acid (vitamin C, C6H8O6) to be dissolved in 2
75 g of acetic acid to lower its melting point by 1·5°C.
(Kf for CH3COOH) = 3·9 K kg mol-1, molar mass of C6H8O6 is 176 g/mol )
19. a) Arrange the following compounds in order of increasing boiling point. 1
Bromomethane, bromoform, chloromethane, dibromomethane
b) The treatment of alkyl chloride with aq. KOH leads to formation of alcohol but
in presence of alcoholic KOH, alkenes are the major products. Explain why? 1
20. a) Propanone is less reactive than ethanal towards addition of HCN. Why? 1
b) Write the structure of product will be formed on reaction of propanal with
2-methylpropanal in the presence of NaOH? 1
(OR)
a) Convert Ethylbenzene into benzoic acid 1
b) Convert Acetophenone into benzoic acid 1
21. How are the following conversions carried out : 1
(a) Aniline to p-hydroxyazobenzene
(b) Ethanoyl chloride to Ethanenitrile. 1
SECTION: C
This section contains 7 questions with internal choice in one question. The
following questions are short answer type and carry 3 marks each.
22. Answer any three? 1
a) Write the formula for the following coordination compound:
Amminebromidochloridonitrito-N- platinate(II)
b) FeSO4 solution mixed with (NH4)2SO4 solution in 1:1 molar ratio gives the test
of Fe3+ but CuSO4 solution mixed with aqueous ammonia in 1:4 ratio does not 1
give test of Cu2+ ion. Explain why?
c) Define Ambidentate ligand with suitable example?
d) [NiCl4]2- is paramagnetic, while [NiCO4] is diamagnetic though both are 1
tetrahedral. Why?
28 (i) On mixing liquid X and liquid Y, volume of the resulting solution decreases. 2
What type of deviation from Raoult’s law is shown by the resulting solution?
What change in temperature would you observe after mixing liquids X and Y?
(ii) What happens when we place the blood cell in water (hypotonic solution)? 1
Give reason.
SECTION: D
The following questions are case -based questions. Each question has an
internal choice and carries 4 (1+1+2) marks each. Read the passage carefully
and answer the questions that follow.
29. The stability of complex in solution refers to degree of association between the two
species involved in the state of equilibrium. The magnitude of the equilibrium constant
(stability or formation) for the association, quantitatively expresses the stability. If
complex is formed in steps, then the stepwise and overall stability constant is related as
follows—
The addition of four amine groups to copper shows a pattern found for most formation
constants, in which the successive stability constant decreases. The instability constant
or the dissociation constant of coordination compound is defined as reciprocal of
formation constant β 4.
30. The standard electrode potentials are very important and we can extract a lot of
useful information from them. If the standard electrode potential of an electrode is
greater than zero then its reduced form is more stable compared to hydrogen gas.
Similarly, if the standard electrode potential is negative then hydrogen gas is more
stable than the reduced form of the species. It can be seen that the standard
electrode potential for fluorine is the highest in the electrochemical series
indicating that fluorine gas (F2) has the maximum tendency to get reduced to
fluoride ions (F–) and therefore fluorine gas is the strongest oxidising agent and
fluoride ion is the weakest reducing agent. Lithium has the lowest electrode
potential indicating that lithium ion is the weakest oxidising agent while lithium
metal is the most powerful reducing agent in an aqueous solution. It may be seen
that as we go from top to bottom in in electrochemical series the standard
electrode potential decreases and with this, decreases the oxidising power of the
species on the left and increases the reducing power of the species on the right-
hand side of the reaction.
(a) Write cell reaction of Zn and Cu cell. 1
(b) E0 reduction of three metals A, B, C are respectively + 0.5 V, - 3.0 V, -1.2 V
write the decreasing order of reducing power of these metals. 1
(c) A student prepared 1 molar aqueous solution of silver nitrate and stirred the
solution with copper spoon. Point out if he has committed any mistake.
2
(OR)
Silver articles gets tarnished gradually due to the formation of Ag2S layer. In
order to remove the tarnish a student placed the silverware in aqueous solution of
sodium chloride taken in aluminum vessel. Will he succeed or not? Justify.
E0 Al+3/Al = - 1.66 V and E0 Ag2S(s)/Ag(s) = - 0.71 V
SECTION: E
The following questions are long answer type and carry 5 marks each. All
questions have an internal choice.
31. ATTEMPT ANY FIVE OF THE FOLLOWING:
1X5=5
(a) Of the d4 species, Cr2+ is strongly reducing whereas manganese (III) is
strongly oxidising. Why?
(b) How do you prepare K2MnO4 from MnO2?
(c) Complete the following chemical equation: Cr2O72– + 6Fe2+ + 14H+ →
(d) How would you account for the following: Zr (Z = 40) and Hf (Z = 72) have
almost identical radii.
(e) What are different oxidation states exhibited by lanthanoids?
(f) Which of following cations are colored in aqueous solutions and why?
Sc3+, V3+, Ti4+, Mn2+ (At. No. Sc = 21, V = 23, Ti = 22, Mn = 25)
(g) State reasons for the Cu (I) ion is not stable in an aqueous solution.
32. (a) Explain the following terms:
(i) Rate of a reaction 1
(ii) Activation energy of a reaction
(b) The decomposition of phosphine, PH3, proceeds according to the following 1
equation:
4 PH3 (g) → P4 (g) + 6 H2 (g)
It is found that the reaction follows the following rate equation : 3
Rate = K [PH3].
The half-life of PH3 is 37.9 s at 120° C.
(i) How much time is required for 3/4th of PH3 to decompose?
(it) What fraction of the original sample of PH3 remains behind after 1 minute?
OR
(a) Explain the following terms : 2
(i) Order of a reaction
(ii) Molecularity of a reaction
(b) The rate of a reaction increases four times when the temperature changes from
300 K to 320 K. Calculate the energy of activation of the reaction, assuming that 3
it does not change with temperature. (R = 8.314 J K-1 mol-1)
33. (a) Why water-soluble vitamins must be supplied regularly in the diet? Give one
example of it. 2
(b) Differentiate between the following: 2
(i) Essential and non-essential amino acids.
(ii) Fibrous and globular proteins. 1
(c) Which one of the following is a polysaccharide:
Starch, Maltose, Fructose, Glucose
OR
(a) What one difference between a-helix and P-pleated sheet structure of protein. 1
(b) Write the name of the disease caused by the deficiency of Vitamin B12. 1
(c) Deficiency of which vitamin causes scurvy? 1
(d) What type of linkage is responsible for the formation of proteins?
1
(e) Write the product formed when glucose is treated with HI.
1
KENDRIYA VIDYALAYA SANGATHAN
(IN-SERVICE COURSE 2023-24, AHMEDABAD REGION)
CLASS XII
CHEMISTRY THEORY (043)
GROUP -4 (James Chadwick) QP-2
CLASS: XII
MARKING SCHEME
SECTION A
S.N. QUESTIONS: MARKS
1. D 1
2. D 1
3. B 1
4. B 1
5. B 1
6. A 1
7. C 1
8. B 1
9 A 1
10. A 1
11. A 1
12. C 1
13. B 1
14. B 1
15. C 1
16 A 1
17. i) B 1
ii) large negative deviation. 1
18. ½
1
19. a) bromoform >dibromethane > bromomethane > chloromethane (Decreasing order)
b) Alcoholic solution of KOH contains alkoxide ion which being stronger base eliminates 1
a molecule of HCl from alkyl halide to form alkene. ( Any suitable explanation)
1
20. a) Due to steric and electronic reasons 1
b) 2,4-Dimethylpent-2-en-al 1
OR
a) OR
b)
𝛬mº (CaCl2) = [119.0 + 152.6] S cm2 mol-1 ,𝛬mº (CaCl2) = 271.6 S cm2 mol-1
25. 3
26. (a)Correct order. 1
(b) Azo dye test 1
(c )Azo dye test 1
Thus, CN– ion is an ambident nucleophile. Therefore, it can attack the “carbon atom of
C-Br bond in n-BuBr either through C or N. Since C – C bond is stronger than C – N
bond, therefore, attack occurs through C to form n-butyl cyanide.
SECTION: D
29. a) strong ligand
b) No 9
c) i)+3 oxidation state more stable than +2
ii) correct answer
30. (a) Zn + Cu+2 → Zn+2 + Cu 1
(b) B > C> A 1
(c) It is not safe to stir AgNO3 solution with copper spoon because reduction of Ag+ by Cu 2
is a feasible process.
(OR)
As E0cell is positive the reaction is feasible and he will succeed to get rid of tarnish from
silver ware.
SECTION: E
31. (a) Cr is reducing as its configuration changes from d4 to d3 , having a half-filled t2g
2+
level. On the other hand, the change from Mn3+ to Mn2+ results in the half-filled (d5 ) Any five
answers
configuration which has extra stability. 1 mark
(b) 2MnO2 + 4KOH + O2 → 2K2MnO4 + 2H2O each
(c) Cr2O72– + 14 H+ + 6 Fe2+ → 2 Cr3+ + 6 Fe3+ + 7 H2O
(d) due to lanthanoid contraction 4d to 5d size decreases
(e) +2, +3, +4
(f) V3+, Mn2+ presence of unpaired electrons.
(g) because hydration enthalpy of Cu2+ is higher than that of Cu+ . It compensates the second
ionisation enthalpy of Cu involved in the formation of Cu2+ ions.
33 a) It excreted through urine. Vit-C
b) i)Essential amino acids are not made by the human body and must instead be acquired
from our diet. Non-essential amino acids, by contrast, are synthesized by the human
body.
ii) Fibrous proteins are generally composed of long and narrow strands and have structural
role Globular proteins generally have a more compact and rounded shape and have
functional roles
c) Starch
KENDRIYA VIDYALAYA SANGATHAN
(IN-SERVICE COURSE 2023-24, AHMEDABAD REGION)
CLASS XII- SESSION ENDING EXAMINATION (SEE)
SAMPLE PAPER - 03
CHEMISTRY THEORY (043)
BLUE PRINT
General Instructions:
(a) There are 33 questions in this question paper with internal choice.
(a) There are 33 questions in this question paper with internal choice.
(b) SECTION A consists of 16 multiple –choice questions carrying1mark each.
(c) SECTION B consists of 5 short answer questions carrying 2 marks each.
(d) SECTION C consists of 7short answer questions carrying 3 marks each.
(e) SECTION D consists of 2case-based questions carrying 4marks each.
(f) SECTION E consists of 3 long answer questions carrying 5 marks each.
(g) All questions are compulsory.
(h) Use of log tables and calculators is not allowed.
SECTION-A
The following questions are multiple –choice questions with one correct answer. Each question
carries 1 mark. There is no internal choice in this section.
1 Solubility of gases in liquids decreases with rise in temperature because dissolution [1]
is an:
(a) Endothermic and reversible process.
(b) Exothermic and reversible process.
(c) Endothermic and irreversible process.
(d) Exothermic and irreversible process.
2 Which of the following is a non-reducing sugar ? [1]
(a)Glucose (b)Sucrose (c)Maltose (d)Lactose
3 The atomic number of the element having magnetic momentum is equal to1.7B [1]
Minits+2 oxidation state is:
(a) 24 (b)25 (c)26 (d) 29
4 For a reaction ,the energy of activation is zero. The value of rate constant at 300K, [1]
if k = 1.6×106s−1at 280 K is:
(a)zero (b)6.4×106s−1
(c)1.6×106s−1 (d)3.2×106s−1
5 Which of the following shows structure of allylic alcohol? [1]
(i)CH2=CH-CH2OH (ii)CH2=CH-OH
(iii)CH2=CH-CH(CH3)-OH (iv)CH2=CH-C(CH3)2-OH
(a)(i),(iii)and(iv) (b)(i),(ii)and(iv)
(c)(ii),(iii)and(iv) (d)(i),(ii),(iii)and(iv)
6 Arrange the following compounds in decreasing order of pKb values: [1]
C2H5NH2,(C2H5)2NH,C6H5NHCH3,C6H5NH2
(a) C2H5NH2 >(C2H5)2NH >C6H5NH2 >C6H5NHCH3
(b) C6H5NHCH3 >C6H5NH2 >(C2H5)2NH>C2H5NH2
(c) C6H5NH2 >C6H5NHCH3 >C2H5NH2>(C2H5)2NH
(d) (C2H5)2NH> C2H5NH2>C6H5NHCH3>C6H5NH2
7 How many moles of AgCl will be precipitated when an excess of AgNO3 is added to [1]
a molar solution of [CrCl(H2O)5]Cl2?
(a) 6moles (b) 8moles (c) 3 moles (d) 2moles
8 Choose the correct IUPAC name for [1]
(a)3-Bromo-2-methylpropene (b)1-Bromo-2-methylbut-2-ene
(c)4-Bromo-3-methylpent-2-ene (d)3-Bromo-2-methylbut-1-ene
9 Thevariationofmolarconductivitywithconcentrationofanelectrolyte(X)inaqueous [1]
solution is shown in the given figure
(c)cis-pent-2-ene (d)trans-pent-2-ene
12 Study the given reaction and identify the process which is carried out.. [1]
Or
Name the reagents used in the following reactions:
(i) Bromination of phenol to2,4,6-tribromo phenol
(ii) Butan-2-one to Butan-2-ol
(iii) Friedel–Crafts alkylation of anisole
(iv) Oxidation of primary alcohol to carboxylic acid.
20 Account for the following: [2]
(i)
(ii)
SECTION- C
This section contains 7questions with internal choice in one question. The following
questions are short answer type and carry 3 marks each.
26 (a)Write the name of two monosaccharides obtained on hydrolys is of lactose sugar. [3]
(b)Name any one fat soluble vitamin,its sources and the diseases caused due to
its deficiency in diet.
27 (a)Which of the following isomers is more volatile: [3]
o-nitrophenol or p-nitrophenol?
(b)How would you obtained
(i) Picric acid (2,4,6-trinitro phenol)from phenol.
(ii) 2-Methyl propenefrom2-methylpropanol?
28 (a) What is the structural difference between a nucleoside and a nucleotide? [3]
(b) What happens when D-glucose is treated with HI?
(c) Give two examples of globular proteins.
SECTION-D
The following questions are case –based questions .Each question has an
Internal choice and carries 4(1+1+2) marks each .Read the passage carefully
and answer the questions that follow.
29 Electrochemistry playsa very importantpart in ourdaily life. Electrochemical cell [4]
converts chemical energy of redox reaction into electricity. Mercury cell, Drycells
are primary cells whereas Ni—Cd cell, lead storage battery are secondary
Cells..A 38% solution of sulphuric and is used in lead storage batter..Its density is
1.30gmL–1.The battery holds 3.5L of the acid. During the discharge of the battery, the
density of H2SO4 falls to 1.14 g mL–1 (20% solution by mass) (Molar mass of H2SO4 is
98 g mol–1).
(i) Which type of cell is Mercury cell ?
(ii) How much electricity in Faraday is required to carry out the reduction of one mole
of PbO2?
(iii) Write the reactions taking place at cathode and anode in lead storage battery
when the battery is in use. What happens on charging the battery?
Or
(iii)Mention the reactions occurring at (i) anode, (ii) cathode,during working of a
Mercury cell. Why does the voltage of a mercury cell remain constant during ts
operation?
30 As in case of organic compounds, coordination compounds also show two types of [4]
isomerism viz. structural isomerism and stereo isomerism. There are four types of
structural isomerism shown by coordination compounds viz. ionization isomerism,
hydrate isomerism, linkage isomerism and coordination isomerism. Similarly, there
are two types of stereo isomerism viz. geometrical isomerism and optical isomerism.
Geometrical isomerism is shown by square planar as well as octahedral complexes
whereas optical isomerism is shown by octahedral complexes.
33 (i) Calculate the amount of KCl which must be added to1kg of water so that the [5]
freezing point is depressed by 2 K (the Kffor water = 1.86 K kg mol–1).
(ii) Define azeotropes. What type of azeotrope is formed by negative deviation from
Raoult’s law? Give an example.
Or
(i) A solution containing15gurea(molarmass= 60gmol–1) per litre of solutionin
water has the same osmotic pressure (isotonic)as a solution of glucose(molar
mass = 180 g mol–1) in water. Calculate the mass of glucose present in one
litre of its solution.
(ii) Define the term ‘osmotic pressure’. What is the advantage of using osmotic
pressure as compared to other colligative properties for the determination of
Molar masses of solutes in solutions?
KENDRIYA VIDYALAYA SANGATHAN
(IN-SERVICE COURSE 2023-24, AHMEDABAD REGION)
CLASS XII- SESSION ENDING EXAMINATION (SEE)
SAMPLE PAPER - 03
CHEMISTRY THEORY (043)
SAMPLE PAPER 2023-24
CLASS-XII CHEMISTRY MARKING SCHEME
Q.No VALUE POINTS MARKS
1 (b) exothermic and reversible process 1
2 (b) Sucrose 1
3 (d) 29 1
4 (c) 1.6×106 s−1 1
5 (a) (i), (iii) and (iv) 1
6 (c) C6H5NH2 > C6H5NHCH3 > C2H5NH2 > (C2H5)2NH 1
7 (d) 2 moles 1
8 (b) 1-Bromo-2-methylbut-2-ene 1
9 (d) CH3COOH 1
10 (b) 524 × 10–4 1
11 (d) trans-pent-2-ene 1
12 (a) It is used for purification of aldehydes and ketones. 1
13 (c) A is true but R is false. 1
14 (c) A is true but R is false. 1
15 (d) A is false but R is true. 1
16 (b) Both A and R are true but R is not the correct explanation of A. 1
17 A=[Ni(H2O)6]2+ B=[Ni(H2O)4(en)]2+ ½ x4=2
C=[Ni(H2O)2(en)2]2+ D=[Ni(en)3]2+
Or
½
(i) Bromine water, (Br2(aq)) ½
(ii) Lithium aluminium hydride, (LiAlH4) or H2/Ni
(iii) Alkyl halide in the presence of anhydrous aluminium chloride, CH3Cl and ½
AlCl3 (anhy.)
½
(iv) Acidified potassium permanganate
(i) 20 Although amino group is o, p- directing in aromatic electrophilic substitution 1
reactions, aniline on nitration gives a substantial amount of m-nitroaniline.
Nitration is carried out in an acidic medium. In an acidic medium, aniline is
protonated to give anilinium ion (which is meta- directing). For this reason,
aniline on nitration gives a substantial amount of m-nitroaniline.
(ii) It is because aniline is basic, can form adduct salt with AlCl3 due to
which it deactivates and electrophile cannot be generated
1
21 (i) 1
(ii)
1
22 1
1
23 (a) 1
(b)
1
(c) p-Dichlorobenzene has higher melting point than those of o-and m- isomers
because it is more symmetrical and packing is better in solid form. Hence, it has 1
stronger intermolecular force of attraction than o-and
m-isomers
1 +1+1
24
25 1
1
26 Lactose on hydrolysis gives -D-glucose and -D-galactose.
(a) 1
(b) Examples of fat-soluble vitamins are vitamin A and D (any one).
1+1
(i) 27 o-nitrophenol 1
(ii) (a) 1
(b)
(a)
28 Nucleoside contains pentose sugar, and base whereas nucleotide contains 1
pentose sugar, base as well as phosphate group.
Nucleoside = Base + Sugar
Nucleotide = Base + Sugar + Phosphate.
(b) 1
Or
1+1
The cell potential remains constant during its life as the overall reaction does not
involve any ion in solution whose concentration can change during its use.
30 (i) [Pt(NH3)4] [CuCl4] 1
(ii) pentaaquasulphatochromium(III) bromide 1
(ii) (a) Linkage isomerism
(b) Optical isomerism 1 +1
Or
1 +1
(a) (b)
31 (i) (a) 4-Methoxybenzoic acid < Benzoic acid < 4-Nitrobenzoic acid 1+1
< 3,4-Dinitrobenzoic acid
(b) Ethanal < Propanal < Propanone < Butanone
(ii)(a) Cannizzaro’s reaction : Aldehydes which do not contain α -H atom undergo
disproportionation when heated with concentrated
(50 %) NaOH.
(b) Hell Volhard Zelinsky reaction: Carboxylic acids react with chlorine or
bromine in the presence of phosphorous to
give compounds in which α-hydrogen atom is replaced by halogen atom.
(iii) The negative charge rests on the electronegative O atom in carboxylate ion. The
presence of negative charge on an electronegative atom makes the ion more stable.
For the same reason RCOO– is more stable than the phenoxide ion where the
carbon has negative charge on it. For the above two reasons carboxylate ion is
more stable and has higher acidity than phenol.
Or
(i) Conversion:
(a)
(b)
(c)
(ii) (a) Propanal and propanone can be distinguished by their reactions with Tollens’
eagent. Propanal will form the silver mirror, but propanone does not react. Or any
other test – Iodoform/ Fehling test
(b) Benzaldehyde will form silver mirror, on treatment with Tollens’ reagent whereas
acetophenone will not show Tollens’ Test. Or any other test – Iodoform test
(i)
32(a) Manganese can form p𝜋 - d𝜋 bond with oxygen by utilising 2p-orbital of oxygen and 1
3d-orbital of manganese due to which it can show highest
oxidation state of +7. While with fluorine it cannot form such p𝜋 - d𝜋 bond thus, it can
show a maximum of +4 oxidation state.
(b) Zn2+has 3d10 configuration and no unpaired electrons, hence it is colourless.
Whereas in Cu2+state which has 3d93d9 configuration there is one unpaired electron
and it undergoes d-d transitions emiting colour so Cu2+ salts are blue in colour. 1
(c) Actinides exhibit larger oxidation states than lanthanides, because of the very
small energy gap between 5f, 6d and 7s subshells. Thus, the outermost electrons
get easily excited to the higher energy levels, giving variable oxidation states.
(d) Cr2+ has the configuration 3d4. It can lose electron to form 3d3 which has stable 1
configuration (as it has half -filled t2g level). Hence, it is reducing. On the other hand,
Mn3+ also has 3d4. configuration but it can gain electron to form
1 +1
Mn2+ which has stable 3d5 configuration.
(e) Their ability to adopt multiple oxidation states, ability to adsorb the reactant(s) and
ability to form complexes.
Or
(i) Copper exhibits +1 oxidation state in its compounds. Electronic configuration of Cu ½ +½
in the ground state is 3d10 4s1. So, Cu can easily lose 4s1electron to
give a stable 3d10 configuration. Thus it shows +1 oxidation state.
(ii)
1+1
(iii)
(a)
(b)
1+1
33 ( 3 +2
i
)
(ii) Azeotropes are the binary mixtures of solutions that have the same composition in
liquid and vapour phases and that have constant boiling points. A maximum
boiling azeotrope is formed by solutions showing a large negative deviation from
Raoult’s law at a specific compostion. For example Chloroform – acetone mixture.
Or
(i) .
(ii) Osmotic Pressure : The minimum excess pressure that has to be applied
on the solution to prevent the passage of solvent
molecules into it through semipermeable membrane is called osmotic pressure.
The osmotic pressure method has the advantage over other methods because
(i) osmotic pressure can be measured at room temperature and the molarity of the
solution is used instead of molality.
(ii) its magnitude is large as compared to other colligative properties even for very
dilute solutions.
KENDRIYA VIDYALAYA SANGATHAN
(IN-SERVICE COURSE 2023-24, AHMEDABAD REGION)
CLASS XII- SESSION ENDING EXAMINATION (SEE)
BLUE PRINT 04
CLASS -XII SUBJECT- CHEMISTRY (043)
MAXIMUM MARKS:70 TIME: 3HRS
UNIT TOTAL
CHAPTER MCQ A/R VSA SA CASE-BASED LONG ANS TYPE
NO. MARKS
5 Marks each with
4 marks each (1+1+2). internal choice in two
2 Marks each 3 Marks each with
1 1 No MCQ, internal questions and one
with internal internal choice in one
Mark Mark choice in one question has the
choice in one question like attempt any
each each question in a sub part choice like attempt
question two out of three parts
of two marks any five parts out of
given 7 parts
CLASS - XII
(a) III > IV > I > II (b) I > IV > III > II
(c) II > I > III > IV (d) IV > III > I > II
9. Methyl ketones are usually characterised through 1
(a) Tollen’s reagent (b) Iodoform test
(c) Schiff’stest (d) Benedict solution test
10 Imine derivatives of aldehyde and ketone is called as 1
(a) Schiff’s reagent (b) Fehling’s reagent (c) Schiff’s base (d) Schiff’s acid.
11. Amine that cannot be prepared by Gabricl-Phthalmidie synthesis is 1
(a) aniline (b) benzyl amine (c) methyl amine (d) iso-butylamine
12. Which of the following Amino acid is optically inactive? 1
(a) Glycine (b) Valine
(c) Alanine (d) Phenyl alanine
For the Questions from Q No 13 to 16, select the most appropriate answer from the options
given below:
A. Both A and R are true and R is the correct explanation of A
B. Both A and R are true but R is not the correct explanation of A.
C. A is true but R is false.
D. A is false but R is true.
13. Assertion (A): For complex reaction, the order of overall reaction is equal to the molecularity of 1
the slowest step of the reaction.
Reason (R): The overall rate of the complex reaction is controlled by the slowest step of the
reaction
14. Assertion -Compounds containing —CHO group are easily oxidised to corresponding 1
carboxylic acids.
Reason: Carboxylic acids can be reduced to alcohols by treatment with LiAlH4
15. Assertion: Ethers behave as bases in the presence of mineral acids. 1
Reason: Due to the presence of lone pairs of electrons on oxygen.
16. Assertion: Conductivity of an electrolyte increases with decrease in concentration. 1
Reason: Number of ions per unit volume decreases on dilution.
SECTION B
17. Explain why: 2
(a) The dipole moment of chlorobenzene is lower than that of cyclohexyl chloride.
(b) Alkyl halides, though polar, are immiscible with water
18. A reaction is first order with respect to A & second order with respect to B 2
(i)How is the rate affected on increasing Concentration of B three times.
(ii)How is the rate affected when concentration of A is reduced to half & that of B is doubled.
19. (i) Mention the condition when Raoult’s law becomes special case of Henry’s law 2
(ii) At the same temperature, H2 is more soluble in water than He, which of them will have
higher KH value and why?
20. Explain the following 2
(i) Cl-CH2COOH has lower Pka than CH3COOH.
(ii) There are two –NH2 groups in semicarbazide, only one is involved in the formation of
semicabazone
OR
(ii) Illustrate the following name reactions giving a chemical equation in each case-
(i) HVZ reaction (ii) Clemmensen’s reduction
21. Differentiate between 2
(i) Nucleotides and nucleosides (ii) Peptide and glycosidic linkage
22. Calculate e.m.f. of the following cell at 298 K : 3
2Cr(s) + 3Fe2+ (0.1M) → 2Cr3+ (0.01M) + 3Fe(s)
E°(Cr3+ | Cr) = – 0.74 E° (Fe2+ | Fe) = – 0.44 V
23. The half-life for radioactive decay of C-14 isotope is 5730 years. An archaeological artefact 3
containing wood had only 80% of the C-14 found in a living tree. Estimate the age of the
sample. ( log 2= 0.3010)
24. a) Explain on the basis of valence bond theory that [Ni(CN)4] 2- ion with square planar structure 3
is diamagnetic and [NiCl4] 2- ion with tetrahedral geometry is paramagnetic.
b) FeSO4 solution mixed with (NH4)2SO4 solution in 1: 1 molar ratio gives the test of Fe2+ ion
but CuSO4 solution mixed with aqueous ammonia in 1:4 molar ratio does not give the test of
Cu2+ ion. Explain why?
25. (a) Which one of the following compounds will undergo faster hydrolysis reaction by SN1 3
mechanism? Justify your answer. C6H5CH2Cl or CH3CH2CH2Cl
(b) What happens when chlorobenzene reacts with Sodium hydroxide at 623K and 300 atm
pressure?
26. Give equations of the following reactions: 3
(i) Oxidation of propan-1-ol with alkaline KMnO4 solution.
(ii) Conc. HNO3 with phenol.
(iii) Treating phenol with chloroform in the presence of aqueous NaOH.
27. Do any two parts 3
(i) Arrange the following in the increasing order of their reactivity towards nucleophillic
reaction C6H5COCH3 ,CH3CHO, CH3COCH3
(ii) How will you distinguish between acetophenone and benzophenone (iii) Complete the
following
carbon of
cyclohexyl chloride
29 a) The current flows from cathode to anode 4
b) Zn rod acts as anode and Cu rod acts as cathode
c) At Zero emf, the cell reaction attains equilibrium
The electrochemical cell stops working after some time
because the electrode potential of both electrodes become
equal.
OR
c) Two functions of salt bridge are:
I. It maintains electrical neutrality in both compartments
II.It completes the circuit.
30 a) Elements from group 3 – 11 are called transition elements. 4
b) (n-2) f1-14 (n-1)d0-1 ns2
c) Because upto Cr the number of unpaired electrons increases
and then decreases.
OR
Size of lanthanoid ion decreases from La3+ to Lu3+, tendency
to give hydroxyl ion decreases so basic strength decreases.
KENDRIYA VIDYALAYA SANGTHAN
IN-SERVICE COURSE 2023-24, AHMEDABAD REGION
CLASS XII SESSION ENDING EXAMINATION(BOARD)
CHEMISTRY THEORY (043)
SAMPLE PAPER-05
BLUE PRINT
S.NO. Name of Unit Objective type Very short Short answer Case based Long answer Total
Questions (1) answer question Question (3) Question (4) Questions (5) marks
(2)
SECTION -A
The following questions are multiple-choice questions with one correct answer. Each question
carries 1 mark. There is no internal choice in this section.
1 On electrolysis of dilute sulphuric acid using platinum electrode, the product 1
obtained at anode will be?
(a)Hydrogen
(b)Sulphur dioxide
(c)Hydrogen sulphide
(d)Oxygen
2 Pyrimidine base present in RNA is- 1
(a)Uracil (b)Thymine
(c)Cytosine (d)Guanine
3 Which of the following alcohol reacts fastest with conc. HCl and anhydrous 1
ZnCl2 is
(a)butanol-1 (b)Butanol-2
(c)2-Methylbutanol-1 (d)2-Methylpentanol-2
4 How much coulomb/ charge is required for the reduction of one mol MnO4 - into 1
Mn 2+ ?
(a)96500 C (b)289500 C
(c)482500 C (d)868500 C
5 Compounds of transition metals are coloured due to- 1
(a)their similar atomic size
(b)their incomplete (n-1) d orbital
(c)their reducing property
(d)their variable oxidation state
6 The synthesis of alkyl iodide is best accomplished by- 1
(a)Finkelstein reaction (b)Swarts reaction
(c)Balz-Schiemann reaction (d)Sandmeyer’s reaction
7 Which of the following cannot be made by using Willamson synthesis? 1
(a)Methoxy benzene (b)tert.- butylmethyl ether
(c)Di-tert-butylether (d)Methyl ethyl ether
8 When a catalyst increases the rate of a chemical reaction, the rate constant 1
(a) remains constant (b) increases
(c) decreases (d) may increase or decrease
9 Which of the following disaccharide gives two aldose molecules on hydrolysis? 1
(a)Maltose (b)Sucrose
(c)Lactose (d)All of these
10 The reagent used for differentiation of acetaldehyde and acetophenone is 1
(a)NaHSO 3 (b)NH 2OH
(c) I2 and NaOH (d)C6 H5 NHNH 2
11 Which of the following is more acidic? 1
(a)Benzoic acid (b)p-Nitrobenzoic acid
(c)Ethanoic acid (d)4-Methoxy benzoic acid
12 Which of the following gives yellow precipitate of Iodoform on adding 1
Iodine and aq. NaOH?
(a)Methanol (b)2-Methylpropan-2-ol
(c)Propanol-2 (d)Butanol-1
13 Given below are two statements labelled as Assertion (A) and Reason (R) 1
ASSERTION: Order of reaction can be fractional but molecularity is never be
fractional.
REASON: Order of reaction does not depend upon the stoichiometric
coefficients of the balanced equation.
Select the most appropriate answer from the options given below:
a. Both A and R are true and R is the correct explanation of A
b. Both A and R are true but R is not the correct explanation of A.
c. A is true but R is false.
d. A is false but R is true.
14 Given below are two statements labelled as Assertion (A) and Reason (R) 1
ASSERTION: Mn atom loses ns electrons first during ionization as
compared to (n-1) d electrons.
REASON: The effective nuclear charge experienced by (n-1) d electron
is greater than that by ns electrons.
Select the most appropriate answer from the options given below:
a. Both A and R are true and R is the correct explanation of A
b. Both A and R are true but R is not the correct explanation of A.
c. A is true but R is false.
d. A is false but R is true.
15 Given below are two statements labelled as Assertion (A) and Reason (R) 1
ASSERTION- Both aliphatic and aromatic 1o amine give carbylamine test.
REASON- In carbylamine reaction, a mixture of 1o amine and carbon
tetrachloride is heated in presence of alcoholic KOH.
Select the most appropriate answer from the options given below:
a. Both A and R are true and R is the correct explanation of A
b. Both A and R are true but R is not the correct explanation of A.
c. A is true but R is false.
d. A is false but R is true.
16 Given below are two statements labelled as Assertion (A) and Reason (R) 1
ASSERTION- Ketones can easily give nucleophilic addition reaction than
aldehydes.
REASON: Ketones have more steric hinderance on -CO- group.
Select the most appropriate answer from the options given below:
a. Both A and R are true and R is the correct explanation of A
b. Both A and R are true but R is not the correct explanation of A.
c. A is true but R is false.
d. A is false but R is true.
SECTION -B
This section contains 5 questions with internal choice in one question. The following
Questions are very short answer type and carry 2 marks each.
17 A solution of urea in water has a boiling point of 100.128 0 C. Calculate the 2
freezing point of the same solution. (K f and K b are 1.86 and 0.52 K/m)
18 A chemical reaction, 2X → 4Y + Z, in gas phase occurs in closed vessel. The 2
concentration of Y is found to be increased by 5 x 10 -3 mol /L in 10 minutes.
Calculate the rate of disappearance of X.
19 (a)Name the products obtained on hydrolysis of nucleotide having uracil. 2
(b)Which structure remains intact during denaturation of protein?
20 (a) Write the IUPAC name of DDT. 2
(b)Arrange the following in increasing order of reactivity towards SN 1 reaction
1-Chlorobutane, 1-Chloro-2,2-dimethylpropane,
1-Chloro-2-methylbutane, 1-Chloro-3-methylbutane
21 Give reason why- 2
(a)Palladium is poisoned with BaSO4 during the formation of aldehyde from
acid chloride?
(b)Arrange the following in increasing order of reactivity-
Acetophenone, Benzaldehyde, Benzophenone
OR
(i)How can you convert ethanal into butan-2-ol. Write equation.
(ii)What happens when calcium ethanoate is dry distilled? Write equation.
SECTION-C
This section contains 7 questions with internal choice in one question. The following
questions are short answer type and carry 3 marks each.
22 (a)A coordination compound with molecular formula CrCl 3.5H2O 3
precipitate one moles of AgCl with AgNO3 solution. Write its structural
formula.
(b) Arrange the following in correct order of absorption of wavelength
of light in the visible region.
[Ni(NH3)6]2+ , [Ni(en)3]2+ , [Ni(H2O)6]2+
(c)Draw the labelled crystal field splitting diagram for an octahedral
complex having d6 electrons if Δ 0 < P.
23 (a) Which carbon atom have different configuration in anomers of glucose? 3
(b) What is the difference between two types of secondary structure of
protein?
(c)Write the equation of glucose with bromine water.
24 (a)Calculate the Λ m o of Al2 (SO 4) 3 if the molar conductivities at infinite 3
dilution of AlCl3, HCl and H2 SO 4 are 130, 426 and 860 S cm 2 mol -1
respectively.
27 The following data were obtained during the first order thermal decomposition of 3
SO2 Cl 2 at constant volume. Calculate the rate constant.
SO2 Cl 2 (g) → SO2 (g) + Cl 2 (g)
SECTION-E
31 Answer any five of the following questions- 5
(a)Why pKb value of aniline is more than ethylamine.
(b)Why meta product is formed along with ortho and para product during
direct nitration of aniline?
(c)Write an equation for the formation of azo dye. ( write equation)
(d) How can you convert Benzoic acid into aniline?
(e) Arrange the following in increasing order of boiling point.
C2H5OH,(CH3)2 NH, C2H5NH2
(f) Can aniline be prepared by Gabriel phthalimide reaction? Give reason in
favour of your statement.
(g)Why N,N-diethylbenzenesulphonamide is insoluble in alkali?
32 Answer the following questions: 5
(a)Calculate the ‘spin only’ magnetic moment of a divalent ion of a metal M
in aqueous solution. The atomic number of the metal M is 28.
(b) How does acidified potassium permanganate solution react with oxalate
ions? Write balanced ionic equation.
(c) Write an alloy of lanthanoid along with its composition.
(d) Out of [Sc (H2O) 6] 3+ and [Ti (H2O) 6] 3+ ions which one is coloured and
Why?
(e) Name an element of 3d series having maximum oxidation state.
OR
(i) Why actinoids shows large number of oxidation state than lanthanoides?
(ii) Which is a stronger reducing agent Cr 2+ or Fe 2+ and why?
(iii) How does acidified potassium dichromate solution react with iodide
ions? Write balanced ionic equation.
(iv)Write a disproportionation reaction shown by a transition element.
(v)Why is it difficult to separate Nb and Ta?
33 (a) The average osmotic pressure of human blood is 7.7 atm at 40 0 C. 5
Assuming the concentration to be essentially the same as the molality,
find the freezing point of blood (K f for water=1.86 K/m)
(c) 1
23 (a)C-1 1
(b)α – helix structure – intramolecular hydrogen bond
Β- pleated sheet structure – intermolecular hydrogen bond 1
(c) CHO-(CHOH)4 - CH2OH + Br 2 → OHC- (CHOH4 - COOH
Gluconic acid 1
24 (a)Λ m Al2 (SO4) 3 = 2(Λ m AlCl3 ) + 3(Λ m H2 SO 4 )- 6(Λ m o HCl)
o o o
½
Λ m o Al2 (SO4) 3 = 2x 130 + 3 x 860 – 6 x 426 ½
Λ m o Al2 (SO4) 3 = 260 + 2580 – 2556 = 284 S cm 2 mol -1 1
(b)E cell = E o cell – 2.303RT log [Al 3+] 2
nF [Fe 2+ ] 3 1
25 A= acetophenone, C6 H5 COCH 3 ½+1/2
B = Benzoic acid, C6 H5 COOH ½+1/2
(d)
1
1
1
(d) C6H5 COOH + NH3 → C6H5 CO NH2
C6H5 CO NH2 +Br 2 + 4KOH→ C6H5NH2 + 2KBr + K2 CO3 1
(e) (CH3) 2 NH < C2 H5 NH 2 < C2 H5 OH
(f)Aniline cannot be prepared by Gabriel phthalimide reaction because aryl 1
halide do not undergo nucleophilic substitution reaction.
(g) Because N,N-diethylbenzenesulphonamide does not contain any
hydrogen atom attached to N atom, so it is not acidic and insoluble in alkali.
32 (a)M 2+ =[Ar]. 3d8, No. of unpaired electrons = 2 1
Magnetic moment= √n(n+2) = √8 BM= 2.82 BM
(b) 2MnO 4 - + 5 C2O4 2- + 16 H + → 2 Mn 2+ + 10 CO 2 + 8 H2O 1
(c) Misch metall, It contains 95 % lanthanoid 5% Fe and trace of C, S, Ca 1
and Al
(d) [Ti (H2O) 6] 3+ is coloured due to d-d transition /have one unpaired 1
electron
(e)Mn 1
OR
(i) Actinoides shows large number of oxidation state due to very small energy 1
gap between 5f, 6d and 7s.
(ii) Cr 2+ is stronger reducing agent than Fe 2+ because E 0 Cr 3+/ Cr 2+ value 1
is -ve while E 0 Fe 3+/ Fe 2+ is +ve
(iii) Cr2 O7 2- + 6 I - + 14 H + → 2 Cr 3+ + 3I 2 + 7 H2O 1
+6 +7 +4
2- + -
(iv) 3 MnO 4 + 4 H → 2 MnO 4 + MnO 2 + 2 H2O 1
(v)Nb and Ta have same atomic radii due to lanthanoides contraction 1
33 (a) π= CRT 1/2
C = π / RT ½
C = 7.7 / 0.0831b x 313 = 0.296 ½
ΔT f = k f m 1
ΔT f = 1.86 x 0.296 = 0.55 ½
Freezing point = 0 o - 0.55 = - 0.55 o C
(b)Negative deviation, 1/2
Ex. Acetone and chloroform (or any other correct answer) ½
1
OR
o
(i ) P – P = n = w/m
P o N W/M 1
0.850- 0.845 = 0.5 / m 1
0.850 39/ 78
M = 170 g/mol 1
(ii)RBC shrink 1
(iii) due to osmosis 1
SAMPLE PAPER-6
CHEMISTRY XII
BLUE PRINT
S.NO. Name of Unit Objective Very short Short Case based Long Total
type answer answer Question answer marks
Questions question Question (4) Questions
(1) (2) (3) (5)
SAMPLE PAPER-6
CHEMISTRY THEORY (043)
Max. Marks:70 Time: 3 hours
General Instructions:
Read the following instructions carefully
(a) There are 33 questions in this question paper with internal choice
(b) SECTION A consists of 16 multiple -choice questions carrying 1 mark each.
(c) SECTION B consists of 5 short answer questions carrying 2 marks each.
(d) SECTION C consists of 7 short answer questions carrying 3 marks each.
(e) SECTION D consists of 2 case - based questions carrying 4 marks each
(f) SECTION E consists of 3 long answer questions carrying 5 marks each.
(g) All questions are compulsory
(h) Use of log tables and calculators is not allowed
SECTION A
The following questions are multiple -choice questions with one correct answer. Each
question carries 1 mark. There is no internal choice in this section.
1 . The cell constant of a conductivity cell _____________. 1
(a) changes with change of electrolyte.
(b) changes with change of concentration of electrolyte.
(c) changes with temperature of electrolyte.
(d) remains constant for a cell
2 −𝐸𝑎
1
According to Arrhenius equation rate constant k is equals to k= A 𝑒 𝑅𝑇 . which of the
𝟏
following options represents the graph of ln k vs 𝑻
Based On the graph above, find the element with a melting point lower than 2000K
a) Y
b) X
c) Z
d) None of the above
7 The correct order of acid strength of the following compounds is 1
(i) Phenol (ii) p-Cresol (iii) m-Nitrophenol (iv) p-Nitro phenol
a) iii > ii > i > iv
b) iv> iii > I > ii
c) ii > iv > I > iii
d) I > ii > iv > iii
8 Which of the following reactions will not result in the formation of carbon-carbon bond? 1
a) Reimer-Tiemann reaction b) Friedal craft’s acylation
c)Wurtz reaction d) Cannizaro reaction
9 1
24 An organic compound A with the molecular formula (+)C 4H9Br undergoes hydrolysis to form 3
( )C4H9OH. Give the structure of A and write the mechanism of the reaction.
b)Give the chemical tests to distinguish between the following pairs of compounds:
Methylamine and Dimethylamine
c) How are the following conversions carried out
Ethanoyl chloride to Ethanenitrile
SECTION D 3
The following questions are case -based questions. Each question has an internal choice
and carries 4 (1+1+2) marks each. Read the passage carefully and answer the questions
that follow.
29 Read the passage and find the answer 4
Khoulrauschs law states that molar conductivity of any electrolyte is equal to sum of the
molar conductivity of individual ions. For finding molar conductivity of any weak
electrolyte graphical method is not suitable and the same can be find out by molar
conductivity value of corresponding strong salts.
Weak electrolytes have lower molar conductivities and lower degree of dissociation
at higher concentrations. The graph plotted between molar conductivity and c1/2 (where c
is the concentration) is not a straight line for weak electrolytes. The molar conductivity of
weak electrolyte increases steeply at lower concentrations. Therefore, limiting molar
conductivity, ʎom cannot be obtained by extrapolation of molar conductivity to zero
concentration. Hence, we use the Kohlrausch law of independent migration of ions for the
determination of limiting molar conductivity, ʎom for weak electrolytes.
a) This is true that 𝛬mº for CH3COOH cannot be determined experimentally? Support this
statement
b) Suppose you are the teacher teaching about khoulrauschs law and one student asked a
question that why weak electrolytes have higher molar conductivities at lower
concentrations, write your answer
c) The 𝛬mº for sodium iodide, sodium acetate, and magnesium acetate solution are 12.69,
9.10 and 18.78 S cm2 mol-1, respectively, at 298 K. Calculate 𝛬mº for magnesium iodide.
OR
d) The resistance and conductivity of a cell containing 0.001 M KCl solution at 298 K are
1500 Ω and 1.46 X 10−4 S cm−1, respectively. What is the cell constant of the cell?
30 Read the passage given below and answer the following questions 4
Arrangement of ligands in the order of their ability to cause splitting (Δ) is called spectrochemical
series. Ligands which cause large splitting (large Δ) are called strong field ligands while those
which cause small splitting (small Δ)are called weak field ligands. When strong field ligands like
CN-approach metal atom/ion, the value of Δo is large, so that electrons are forced to get paired up
in lower energy t2g orbitals. Hence, a low spin complex is resulted from strong field ligand. When
weak field ligands like halogens approach the metal atom/ion. The value of Δo is small, so that
electrons enter high energy eg orbitals rather than pairing in low energy t2g orbitals.Hence, a high
spin complex is resulted from weak field ligands. Strong field ligands have a tendency to form
inner orbital complexes by forcing the electrons to pair up. Whereas weak field ligands have
tendency to form outer orbital complex because inner electrons generally do not pair up.For
getting colour the central atom in a complex must contain unpaired electrons.
a) In an octahedral complex the central atom is in d4 configuration state, it came to
know that the ligand is cyanide ion, comment on coloring state of complex
b) Cyanide usually gives inner orbit complex, what nature makes cyanide to give
inner orbit complex
c) While analysing complexess you will observe that Ti4+ forms colourless
complexess even with weak ligands,if this statement is correct then support it with
suitable value points.
OR
Write the correct relation between Δo and Δt, where Δo denotes crystal field
splitting in octahedral complexes and Δt denotes crystal field splitting in tetrahedral
c
SECTION E
The following questions are long answer type and carry 5 marks each. All questions
have an internal choice
31 When a chromite ore (A) is fused with sodium carbonate in free excess of air and the 5
product is dissolved in water, a yellow solution of compound (B) is obtained. After
treatment of this yellow solution with sulphuric acid, compound (C) can be crystallised
from the solution. When compound (C) is treated with KCI, orange crystals of compound
(D) crystallise out. Identify A to D and also explain the reactions.
OR
a) Give reason
i) Transition metals have high melting points.
ii) The highest oxidation state of a transition metal exhibited in its oxide or
fluoride only.
b) What is meant by ‘lanthanoid contraction’?
c) Complete the following chemical equations:
(i) MnO4-(aq) + S2O32- (aq) + H2O (1) →
(ii) Cr2O72- (aq) + Fe2+ (aq) + H+ (aq) →
32 a) A reaction is of first order in reactant A and of second order in reactant B. How is 5
the rate of this reaction affected when the concentrations of A as well as B are
doubled? (1)
b) Distinguish between ‘rate expression’ and ‘rate constant’ of a reaction. (1)
c) The value of rate constant k of a reaction depends on temperature. From the values
of k at two different temperatures, the Arrhenius parameters Ea and A can be calculated.
The rate constants of a reaction at 1000K and 1060K are 0.01M-1S -1 and 0.10M-1S -1
respectively. Find the values of Ea and log A .
(3)
OR
a) Draw the plot of t1/2 Vs initial concentration [A0] for a first order Reaction.
1
b) Differentiate Order and molecularity of a reaction.( any two points).
2
c) The rate of a first order reaction is 0.04 molL-1s-1 after 10 mins and 0.03molL-1s-1
2
after 20 mins of initiation. What is the half life of the reaction?
3 a) 10 -4 mol-1l-1S-1 1
4 (c) 0.85 Å 1
5 2 1
√𝑛(𝑛 + 2)
6 c) Z 1
7 b) iv> iii > I > ii 1
Electron withdrawing groups increases acid strength and electron releasing groups
decreases acidic strength
8 d) Cannizaro reaction 1
9 1
10 c) (CH3)3CCOOH 1
11 (d) CH3CH2NH2 1
12 c)Galactose 1
13 (d) A is false but R is true 1
14 b) Both A and R are true but R is not the correct explanation of A. 1
15 (a) Both A and R are true and R is the correct explanation of A 1
16 d) A is false but R is true 1
17 a) Gas (A) will have lower value of KH (Henry’s constant) than Gas (B at the same 1
temperature because lesser the solubility of a gas in a given solvent, higher will be
the value of KH for a gas.
p=KH x
b) 2M glucose will have a higher boiling point than 1M glucose because elevation in 1
boiling point is a colligative property which depends upon the number of particles in
the solution which is more in the case of 2M glucose solution
18 Van’t Hoff factor: It is defined as the ratio of the experimental value of the colligative 1+
1
property to the calculated value of the colligative property.
i) If there is dissociation of the solute in the solution, the Van’t Hoff factor will be greater
than one i.e., i > 1.
(ii) If there is association of solute in the solution, the Van’t Hoff factor ‘f’ will be less than
one i.e., i < 1.
1
25 1
b)By Carbylamine test: Methylamine being a primary amine gives this test but
Dimethylamine being a secondary amine does not.
1
c) 1
26 a) Statement 1
b)
½
½
OR
SECTION D
29 a) The plot of molar conductivity versus square root is a steep curve which can't be 1
extrapolated to get the value of molar conductivity at infinite dilution. Also, the ionization is 1
increased with dilution which leads to increase in molar conductivity as infinite dilution can't
reached.
b) Molar conductivity is the property of conductance of a solution containing an electrolyte 1
mole or is a function of the ionic resistance of a solution or concentration of salt
c)According to Kohlrausch’s law
𝛬mº (MgI2) = 𝛬mº [CH3(COO)]2Mg + 2 𝛬mº (NaI) – 2 𝛬mº (CH3COONa)
𝛬mº (MgI2) = (18.78 + 2 X 12.69 – 2 X 9.10) S cm2 mol-1 1
𝛬mº (MgI2) = (18.78 + 25.38 – 18.20) S cm2 mol-1
𝛬mº (MgI2) = (44.16 – 18.20) S cm2 mol-1
𝛬mº (MgI2) = 25.96 S cm2 mol-1
OR
c)Conductivity = Cell constant / Resistance 1
1.46 X 10−4 S cm−1 = Cell constant / 1500 Ω
Cell constant = 1.46 X 10−4 S cm−1 X 1500 Ω 1
Cell constant = 0.219 cm -1
30 a)
The magnitude of Δ0 decides the actual configuration of d-orbitals with the help of 1
mean pairing energy. If P < Δ0, then pairing of electrons occurs within the same set
and forms low spin complexes due to strong-field ligands. Therefore, it becomes
more energetically favourable for the fourth electron to occupy a t2g orbital with
configuration t2g4 eg0
b) The colour of the complex is due to d-d transition . [Ti(H2O)6]Cl3 on heating 1
becomes colourless because water is removed on heating [Ti(H2O)6]Cl3 molecule
and in the absence of ligand, crystal field splitting does not occur and hence
substance is colourless 1+
c) 1
OR
c) i) When ligand approaches a transition metal ion, the d− orbitals split into two
sets, one with lower energy and the other with higher energy. The difference of
energy between the two sets of orbitals is known as crystal field splitting energy.
ii)Δt = -4/9Δo
31 Compound A to D are,
A = FeCr2O4 B = Na2CrO4 C = Na2Cr2O7.2H2O D = K2Cr2O7 2
1
4FeCr2O4 + 8Na2CO3 + 7O2 → 8Na2CrO4 + 2Fe2O3 + 8CO2 1
2Na2CrO4 + 2H+ → Na2Cr2O7 + 2Na+ + H2O 1
Na2Cr2O7 + 2KCl → K2Cr2O7 + 2NaCl
OR 1
a) (i) In transition metals besides ns electrons, (n-1)d electrons can also participate in
bonding making stronger metallic bonds. This increases their melting points. 1
ii) Both oxide and fluoride ions are highly electronegative and have a very small size.
Due to these properties, they are able to oxidize the metal to its highest oxidation 1
state.
b) i) The steady decrease in the ionic radius from La3+ to Lu3+ is termed as lanthanoid
contraction. 1+
c) 1
c. log 𝑘2 = 𝐸𝑎 [𝑇2−𝑇1] ½
𝑘 2.303 𝑅 𝑇 𝑇
1 1 2
0.1 𝐸𝑎 [1060−1000]
log 0.01 = ½
2.303 𝑋 8.314𝑋1000𝑋1060
OR
½+
½
a)
1
b)Any two difference
c) Let the rate =k[A]
At t=10 seconds 1
0.04=k[A1]
At t=20 seconds 1
0.03=k[A2]
∴, in 10 seconds concentration of A decreases by 0.01k[M]
Using first order kinetics equation,
10×k=ln(0.04/k0.03/k)
10×k=0.028
k=0.028
Half life of first order reaction =ln 2k
t1/2=ln 20.028=24.1 seconds
33.