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Mock Test # 3 - Chemistry - NCERT Back Exercise

(converted to MCQs) Contact Number: 9667591930 / 8527521718

5.
Chemistry - Section A The products formed after ozonolysis of Pent-2-ene are -
1.
1. Ethanal, Methanal
The concentration of 69% nitric acid (by mass) in a
sample with a density of 1.41 g / mL will be- 2. Ethanal, Propanal
1. 15.44 mol/L 3. Ethanal, Butanal
2. 17.14 mol/L 4. Ethanal, Ethanal
3. 20.06 mol/L
4. 12.26 mol/L 6.

2.
Electrons are emitted with zero velocity from a metal
surface when it is exposed to radiation of wavelength
6800 Å. The work function (W0 ) of the metal is

1. 3.109 x 10-20 J The reason behind higher boiling point of one isomer of
Hex-2-ene is-
2. 2.922 x 10-19 J
1. Cis - less polar than trans
3. 4.031 x 1019 J
2. Trans - more polar than cis
4. 2.319 x 10-18 J
3. Cis - more intermolecular forces
4. Trans - more dipole-dipole interactions
3.
The IUPAC name of p-ClC6H4CH2CH(CH3)2 is -
7.
1. 1−Chloro−4−(2−methylpropyl) benzene The 3° carbon atom in the given structure is
2. 4−Chloro−1−(2−methylpropyl) benzene
3. 1−Chloro−4−(3−methylpropyl) benzene H3 C – CH2 – C(CH3 ) – CH2 – CH3
2

4. 4−Chloro−4−(3−methylpropyl) benzene a b c d e

1. a
4.
2. b
Alkyl groups act as electron donors when attached to a π
system due to 3. c

1) Inductive effect 4. e

2) Mesomeric effect
3) Resonance
4) Hyperconjugation

Page: 1
Mock Test # 3 - Chemistry - NCERT Back Exercise
(converted to MCQs) Contact Number: 9667591930 / 8527521718

8. 12.

The total number and mass of neutrons in 7 mg of 14C Property used by Mendeleev to classify the elements was
-
would be (Assume that mass of a neutron = 1.675 × 10–
27 kg) 1. Brightness

1. 2. 41 × 10
21
, 4. 03 × 10
–6
kg
2. Atomic weight or mass
2. 6. 23 × 10
23
, 1. 67 × 10
−21
kg 3. Number of isotopes
22 6
3. 1. 22 × 10 , 4. 03 × 10 kg
4. Lustre
21 −6
4. 2. 41 × 10 , 4. 03 × 10 g

13.
9. The atomic number of the element present in the 3rd
The wave number of a light whose time period is 2.0 × period and 17th group of the periodic table would be -
10–10 s would be - 1. 18
1. 16.66 m-1 2. 23

2. 1. 66 m-1 3. 24
4. 17
3. 32.34 m-1

4. 12.34 m-1
14.
The explanation for the fact that the first ionization
10. enthalpy of sodium is lower than that of magnesium but
The alkoxy group in aryl alkyl ethers activate the its second ionization enthalpy is higher than that of
benzene ring towards - magnesium would be -

1. Nucleophilic addition reaction 1) pressure and volume

2. Electrophilic addition reaction 2) lustre and brightness

3. Nucleophilic substitution reaction 3) atomic size and effective nuclear charge

4. Electrophilic substitution reaction 4) availability in nature

11.
20 g sugar is dissolved in enough water to make a final
volume of 2L. The concentration of sugar (C12H22O11)
in mol L–1 will be -
1. 0.29 mol/L
2. 0.029 mol/L
3. 0.35 mol/L
4. 0.032 mol/L

Page: 2
Mock Test # 3 - Chemistry - NCERT Back Exercise
(converted to MCQs) Contact Number: 9667591930 / 8527521718

15. 18.

Lewis symbols for the atoms and ions: S and S2–; Al and CH4 does not exhibit square planar geometry because-
Al3+; H and H– respectively would be - 1. An atom of carbon does not have d-orbitals to undergo
sp3 hybridization
.. 2−

1. , [: S , [Al] ,
3+
:] , , 2. An atom of carbon does not have d-orbitals to undergo
..

dsp2 hybridization
.. 2−

2. , [: S :] , , [Al] ,
3+
, 3. An atom of carbon does not have d-orbitals to undergo
..
sp2 hybridization
.. 2− 4. An atom of carbon does not have d-orbitals to undergo
3. [: S , , , [Al] ,
3+
:] , d2sp2 hybridization
..

.. 2−

4. , [: S , , [Al] ,
3+
:] ,
.. 19.
The wavelength of the light emitted when the electron
returns to the ground state in H atom, from n =5 to n =1
16. would be -
The correct relationship between bond strength and bond (The ground-state electron energy is –2.18 × 10-18 ergs)
order is -
1. Bond strength is directly proportional to the bond
order. 1) E = 2.09 x 10-18 Kg, Wavelength = 9.498 x 10-8 km
2. Bond strength is inversely proportional to the bond
2) E = 4.09 x 10-18 J, Wavelength = 12.498 x 10-8 m
order.
3. There is no relationship between these two terms. 3) E = 2.09 x 10-18 J, Wavelength = 9.498 x 10-8 m

4. None of these. 4) E = 3.09 x 10-18 J, Wavelength = 9.498 x 10-8 m

17. 20.
The application of dipole moment is/are -
1. It is used to differentiate polar and non-polar bonds. The correct order of increasing dipole moment is -
2. It is helpful in calculating the percentage ionic 1. CCl 4 < CH Cl3 < CH2 Cl2

character of a molecule.
2. CH Cl 3 < CH2 Cl2 < CCl4

3. Both '1' and '2'


3. CCl 4 < CH2 Cl2 < CH Cl3

4. None of these.
4. CH 2
Cl2 < CCl4 < CH Cl3

Page: 3
Mock Test # 3 - Chemistry - NCERT Back Exercise
(converted to MCQs) Contact Number: 9667591930 / 8527521718

21. 24.
Alcohols are comparatively more soluble in water than The IUPAC name of the following molecule is -
hydrocarbons of comparable molecular masses because -
1. Alcohols form van der waal bonds with water while
hydrocarbons do not
2. Alcohols form covalent bonds with water while
hydrocarbons do not
3. Alcohols form ionic bonds with water while
hydrocarbons do not
4. Alcohols form H-bonds with water while
1. 2-Chloro-4-methylpentane
hydrocarbons do not
2. 4-Chloro-2-methylpentane
3. 4-Chloro-4-methylpentane
22.
4. 2-Chloro-2-methylpentane
A method for the identification of primary, secondary and
tertiary amines is -
1) Azo-dye test
2) Carbylamine test 25.
3) Hinsberg’s test The structure of Hex-2-en-4-ynoic acid is -
4) None of these
O

||

23. 1. H3 C − C ≡ C − CH = CH − C − OH

The number of σ and π bonds in the molecule CH2 Cl2

are CH3 O

| ||

1. 2 = (σ C−Cl
) , 1= (σ C−H
) , and 1= π 2. H3 C − C H − CH2 − C − H

2. 2 = (σ C−Cl ) , 2= (σ C−H ) , and 0= π


3. 2 = (σ C−Cl
) , 1= (σ C−H
) , and 1= π
4. 2 = (σ C−Cl ) , 1= (σ C−H ) , and 1= π

3.

4. All

Page: 4
Mock Test # 3 - Chemistry - NCERT Back Exercise
(converted to MCQs) Contact Number: 9667591930 / 8527521718

26. 29.
O

∣∣
∣∣
∣∣

C H3 — C — C H3
1 2 3

The correct hybridization of carbon atoms are- The IUPAC name of the above compound is-

1. C1= sp , C2= sp3 , C2= sp2


1. 1-Phenylpropan-2-ol
2. C1= sp2 , C2= sp3 , C2= sp3
2. 2-Phenylpropan-2-ol
3. C1= sp3 , C2= sp2 , C2= sp3
3. 1-Phenylpropan-1-ol
4. C1= sp3 , C2= sp3 , C2= sp3 4. 2-Phenylpropan-1-ol

27. 30.

The best substrate for the preparation of 1-iodobutane in The incorrect statement among the following is -
the presence of NaI / dry acetone is - 1. Methylamine in water reacts with ferric chloride to
1. 1-Chlorobutane precipitate hydrated ferric oxide.

2. n-Butane 2. Diazonium salt of aromatic amines is more stable than


those of aliphatic amines.
3. Butanol
3. Both 1 and 2
4. Butyne
4. None of these

28.
The tertiary amine is-
1. (CH3 CH2 ) NCH3
2

2. (CH3 ) NH2
3

3. m − BrC6 H4 NH2

4. None of these

Page: 5
Mock Test # 3 - Chemistry - NCERT Back Exercise
(converted to MCQs) Contact Number: 9667591930 / 8527521718

31. 33.
Propanal and butanal give four possible aldol The correct sequence of reagents used for the preparation
condensation products. The structures of the products of m-Nitrobenzoic acid from benzene is/are
is/are-

1. a = Mg/ Dry ether ; b = Br2 / FeBr3 ; c =


CO2 ; H3O+ ; d = HNO3 + H2SO4

2. a = Br2 / FeBr3 ; b = Mg/ Dry ether ; c =


CO2 ; H3O+ ; d = HNO3 + H2SO4

3. a = CO2 ; H3O+ ; b = Br2 / FeBr3 ; c = Mg/ Dry


ether ; d = HNO3 + H2SO4

4. a = HNO3 + H2SO4 ; b = Br2 / FeBr3 ; c = Mg/ Dry


32. ether ; d = CO2 ; H3O+

The IUPAC name of the following compound is

34.
Chemical test to distinguish between Benzoic acid and
Ethyl benzoate is -
1. Tollen’s test
2. Fehling’s test
1. 1-Cyclohexylpentan-3-ol
3. Iodoform test
2. 3-Cyclohexylpentan-3-ol
4. sodium bicarbonate test.
3. 2-Cyclohexylpentan-1-ol
4. 3-Cyclohexylpentan-1-ol

Page: 6
Mock Test # 3 - Chemistry - NCERT Back Exercise
(converted to MCQs) Contact Number: 9667591930 / 8527521718

35. 38.
Match the following isoelectronic species in column I Phenol is more acidic than ethanol due to -
and column II.
1. Resonance
Column I Column II 2. Phenoxide ions
i. F −
a. Br −

3. Less -I effect
ii. Ar b. Si 2+

iii. Mg c. O 2− 4. More ability to gain a proton


iv. Rb +
d. S2−

1. i = b, ii = c, iii = a, iv = d 39.
2. i = c, ii = b, iii = a, iv = d The energy of an electron in the ground state of the
3. i = c, ii = d, iii = b, iv = a hydrogen atom is – 2. 18 × 10 J . The ionization
−18

enthalpy of atomic hydrogen in terms of J mol is-−1

4. i = b, ii = c, iii = d, iv = a
1. 2.81 × 106 J mol −1

2. 1.31 × 106 J mol −1

Chemistry - Section B 3. 2.31 × 106 J mol −1

36.
4. 1.81 × 106 J mol −1

Difference between electron gain enthalphy and


electronegativity is described by
1) Valence electrons 40.
2) Atomic size The total number of sigma and pi bonds in C2H4 is
3) Atomic radii 1. 6 sigma bonds and 1 pi-bond.
3) Atomic number 2. 3 sigma bonds and 3 pi-bonds.
3. 5 sigma bonds and 1 pi-bond.
37. 4. 2 sigma bonds and 2 pi-bonds.
The effect that can explain the given order of acidity of
the carboxylic acids is:
41.
Cl3CCOOH > Cl2CHCOOH > ClCH2COOH
The bond pairs and lone pairs of electrons are -
1) +I effect
1. Electron pairs that participate in bonding.
2) -I effect
2. Electron pairs that participate in bonding are called
3) +E effect bond pairs and those that do not participate in bonding
are called lone pairs.
4) -E effect
3. Electron pairs that do not participate in bonding.
4. Electron pairs that participate in bonding are called
lone pairs and those that do not participate in bonding are
called bond pairs.

Page: 7
Mock Test # 3 - Chemistry - NCERT Back Exercise
(converted to MCQs) Contact Number: 9667591930 / 8527521718

42. 46.
Out of the following, which orbital is not possible: The following data was obtained when dinitrogen and
dioxygen react together to form different compounds:
1. 6p
2. 2s Mass of dinitrogen Mass of dioxygen
(i) 14 g 16 g
3. 3f
(ii) 14 g 32 g
4. 2p (iii) 28 g 32 g
(iv) 28 g 80 g

The law of chemical combination applicable on the


43.
above experimental data is:
Lewis acid that can be used during ethylation of benzene
1. Law of reciprocal proportions
is -
2. Law of multiple proportions
1. FeCl 3

3. Law of constant composition


2. SnCl 4

4. None of these.
3. BF 3

4. All of the above


47.
(CH3)3CCH2CH(Br)C6H5 is -
44.
A characteristic feature of any form of chromatography is 1. Secondary benzyl halide
the ___ 2. Secondary alkyl halide
1. Use of molecules that are soluble in water. 3. Primary alkyl halide
2. Use of inert carrier gas. 4. Secondary allyl halide
3. Calculation of an Rf value for the molecule separated.
4. Use of a mobile and a stationary phase.
48.
The formula of A and B in the following reaction is -
45. CuCN H2 O /H
+
NH3 ,Δ

C6 H5 N2 Cl −−
−→ C6 H5 CN −−−−→ A −−−→ B

The atomic numbers of elements whose outermost


electrons are represented by 3s1 and 2p5 respectively 1. C6 H5 COOH, and C6 H5 CONH2
are:
2. C6 H5 COOH, and C6 H5 NH2

1. 9, 7 3. C6 H5 CH2 NH2 , and C6 H5 CH2 N = NH

2. 9, 11 4. C6 H5 CH2 NH2 , and C6 H5 CH2 N = NH

3. 11, 5
4. 11, 9

Page: 8
Mock Test # 3 - Chemistry - NCERT Back Exercise
(converted to MCQs) Contact Number: 9667591930 / 8527521718

49.
Pyridine Fill OMR Sheet*
CH3 CH2 OH + CH3 COCl −−−−→ CH3 COOC2 H5 + HCl
Ethanol Acetyl Ethyl acetate

Chloride *If above link doesn't work, please go to test link from
where you got the pdf and fill OMR from there
is an example of-
1. Acetylation
2. Benzoylation
3. Cross aldol condensation
CLICK HERE to get
4. Cross Cannizzaro reaction
FREE ACCESS for 3
50.
days of ANY NEETprep
In Reimer-Tiemann reaction, course

the product will be -


1. ortho-Salicylaldehyde
2. para-Salicylaldehyde
3. meta-Salicylaldehyde
4. all of the above

Page: 9

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