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Camachem-Sodium Cyanide 98 SDS MSDS
Camachem-Sodium Cyanide 98 SDS MSDS
com
Prevention statement(s)
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin or on clothing.
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a wellventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
Response statement(s)
P301 + P310 IF SWALLOWED: immediately call a POSION CENTER or doctor/physician.
P302 + P350 IF ON SKIN: Gently wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at a rest position comfortable for
breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or a doctor/physician.
P314 Get medical advice/attention if you feel unwell.
P320 Specific treatment is urgent – see first aid instructions.
P330 Rinse mouth.
P332 + P313 If skin irritation occurs: Get medical advice/attention.
P362 Take off contaminated clothing and wash before reuse.
P391 Collect spillage
Storage statement(s)
P403 + P233 Store in a wellventilated place. Keep container tightly closed.
P405 Store locked up.
Disposal statement(s)
P501 Dispose of contents/container in accordance with relevant regulations.
FIRST AID PROCEDURES FOR DEALING WITH THIS PRODUCT AND EXPOSURE TO IT
1. Personal Protection By First Aid Personnel
First aid personnel providing first aid treatment to a patient exposed to sodium cyanide solid should
observe the following precautions for their own personal protection:
Avoid contact with contaminated skin, clothing and equipment by wearing protective gloves;
Wear chemical goggles as a minimum level of eye protection to prevent sodium cyanide dust entering
eyes;
Avoid inhalation of sodium cyanide dust during rescue in contaminate areas by wearing suitable
respiratory protection;
Respiratory protection suggested is: an air supplied breathing apparatus, or positive pressure
selfcontained breathing apparatus.
2. Swallowed
Immediately:
Remove the patient from the source of contamination – to fresh air, if hydrogen cyanide gas (HCN) is
present;
If the patient is not breathing, do not use mouth to mouth, or mouth to nose ventilation, because of the
danger to the rescuer, instead use a resuscitation bag and mask – (OxyViva);
If pulse is absent, start external cardiac massage and follow standard Advanced Cardiovascular Life
Support (ACLS) guidelines;
Give 100% oxygen by mask (OxyViva) if available;
2.Swallowed (cont..)
Remove all contaminated clothing and footwear into a sealable collection bag – launder contaminated
clothing thoroughly and wash the affected areas with soap and copious amounts of water;
Arrange for the urgent transfer of the patient, accompanied by an attendant with the Cyanide Emergency
Kit, to medical professionals;
Those persons designated as competent may open the Cyanide Emergency Kit and commence use of
CAMACHEM (Part of CAMAL Group), 3F Jinlong East Beijing Station Road
Chaoyang District, Beijing, China
www.camachem.com
Contact: sales@camachem.com
any amyl nitrite pearls to treat the effects of cyanide exposure.
Amyl Nitrite should not be used unless the patient is clearly deteriorating, despite oxygen administration,
and there is a reasonable confidence that cyanide intoxication is the cause.
3. Eyes
Persons with potential eye exposure should not wear contact lenses. Immediately irrigate eye with
copious amounts of water, while holding eyelids open, for at least 15 minutes. Seek medical assistance
immediately.
4. Skin
Wash affected area with copious amounts of water for at least 15 minutes. Remove contaminated
clothing and launder before reuse. Seek medical assistance following skin contact.
5. Inhalation
Proceed as for 2. Swallowed above.
Section 5: Fire and Explosion Data
Product flammability
Sodium cyanide solid is not combustible and is not considered a fire risk, but may generate toxic,
flammable, corrosive and explosive hydrogen cyanide gas if in contact with water, CO2 fire extinguishers,
and some foam fire extinguishers if these contain acidic agents.
Hazchem Code
2X
Section 6: Accidental Release Measures
Emergency procedures
The hazardous nature of sodium cyanide, require emergency and spill procedures to be effective to avoid
both human and environmental exposure. Hazardous conditions may result if material is managed
improperly. Make plans in advance to handle possible emergencies, including obtaining stocks of
absorbent materials. Always wear recommended personal protective equipment and respiratory
Engineering controls
Handle sodium cyanide solid within closed systems whenever possible. Provide adequate ventilation at
all times.
Acute: Sodium cyanide solid is a very toxic chemical asphyxiant – may cause death soon after exposure
by all means of entry into the human body. It may cause caustic burns in contact with human flesh.
Cyanide inhibits cytochrome oxidase preventing oxygen utilization leading to cytotoxic anoxia. Acute
effects depend on the degree of cellular hypoxia. Death results from central nervous system failure.
Inhalation which cause weakness, headache, dizziness, shortness of breath, chest pain, confusion,
cyanosis (bluish skin due to deficient oxygenation of the blood), weak and irregular heartbeat, collapse,
unconsciousness, coma and death. Death can be very rapid. Ingestion will cause caustic burns, resulting
in severe gastrointestinal tract irritation with nausea and vomiting, accompanied by severe burning
sensation. Toxic amounts ingested may lead to poisoning symptoms similar for those for inhalation.
Inhalation: Inhalation of sodium cyanide dust, or hydrogen cyanide vapour above the solid, may result in
burns and irritation to the nose and upper respiratory tract, leading to coughing and sore throat. Lesions
of the nasal septum and delayed pulmonary oedema may result. Toxic amounts may be inhaled leading
to poisoning symptoms which include weakness, headache, dizziness, shortness of breath, chest pain,
confusion, cyanosis (bluish skin due to deficient oxygenation of the blood), weak and irregular heartbeat,
collapse, unconsciousness, coma and death. Death can be very rapid. The lethal oral dose of hydrogen
cyanide is estimated to be approximately 50 mg in an adult (Sullivan, J.B. Jr., G.R. Krieger (eds.),
Hazardous Materials ToxicologyClinical Principles of Environmental Health, Baltimore, Williams and
Wilkins, 1992).
Skin: Sodium cyanide solid will cause severe irritation and chemical burns. Sweat increases rate of
absorption into skin. Toxic amounts may be absorbed through the skin, leading to poisoning symptoms
Eye: Sodium cyanide solid will cause severe irritation to the eye, leading to redness, pain and possible
eye burns. May cause chemical conjunctivitis and corneal damage leading to loss of sight. Toxic amounts
may be absorbed through the eye, leading to poisoning symptoms similar to those for inhalation.
Swallowed: Sodium cyanide solid is very toxic and may be fatal if swallowed. It will cause caustic burns,
resulting in severe gastrointestinal tract irritation with nausea and vomiting, accompanied by severe
burning sensation. Toxic amounts ingested may lead to poisoning symptoms similar for those for
inhalation. The mean lethal dose by mouth of cyanide in an 80 kg male human adult is thought to be in
the range of 50 to 200 mg and death is rarely delayed more than one hour (Gosselin et al, Clinical
Toxicology of Commercial Products. 5 th Ed., Baltimore: Williams and Wilkins, 1984). LD50 (Oral, rat) =
6·44 mg/kg.
Chronic: Cyanide may be highly acutely toxic, but it has lower toxicity on a chronic basis. Prolonged or
repeated exposure may cause drying of the skin, dermatitis, ulceration, skin necrosis, loss of appetite,
weight loss, dizziness, shortness of breath, muscle cramps and irritation to upper respiratory tract.
Chronic cyanide intoxication has been associated with extremely rare neurological disorders, renal
disease and isolated small observational studies of reporting effects on thyroid function. (Barnerjee et al,
Evaluation of cyanide exposure and its effect on thyroid function on workers in a cable industry, J Occup
Environ Med., 39(3):258260, Barnerjee et al, Evaluation of cyanide exposure and its effect on thyroid
function on workers in a cable industry, J Occup Environ Med., 39(3):258260, 1997). As acutely toxic as
cyanide is, repeated lowlevel doses of cyanide do not necessarily result in cumulative adverse effects.
Section 12: Ecological Information
Ecotoxicity
Fish and aquatic invertebrates are very sensitive to cyanide exposure. Small concentrations, in the range
of 5 to 20 mg cyanide per litre, causes a reduction in swimming performance, inhibiting reproduction and
altering growth patterns. Increased cyanide concentrations in the range of 30 to 200 mg/L causes the
deaths of many species of fish and invertebrates. Algae and macrophytes can tolerate much higher
environmental concentrations of free cyanide than fish and invertebrates, but cyanide exposures may
leave an aquatic plant community dominated by less sensitive species. Birds and higher mammals are
susceptible to cyanide poisoning and display many symptoms associated with humans exposed to
cyanide. The rapid recovery of some birds to sublethal doses of cyanide may be due to the rapid
metabolism of cyanide to thiocyanate and its subsequent excretion. Cyanide has low persistence and is
not accumulated or stored in any mammal studied.
Bioaccumulative potential
Low potential for human bioaccumulation. Does not bioaccumulate in fish.
Section 13: Disposal Considerations
Disposal methods and containers
Due to its inherent properties, hazardous conditions may result if material is managed improperly.
Dispose of all contained and contaminated spill residue in accordance with the requirements of the
Department of the Environment. Contact CSBP Limited for technical advice on disposal method.
Classifications
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and
Labelling of Chemicals. The classifications and phrases listed below are based on Approved Criteria for
Classifying Hazardous substances [NOHSC: 1008(2004)].
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