AITS – 1 CHEMISTRY (PAPER – I)

PART (B) : CHEMISTRY

SECTION I: (SINGLE CHOICE QUESTIONS)

This section contains 06 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLY ONE is correct.

21. Arrange the following compounds in decreasing order of rate of electrophilic aromatic chlorination
with Cl2/FeCl3
O O
H H
N O N
NH
NH
O
(C) (D)
(A) (B)

(A) A  B  D  C (B) B  A  D  C
(C) B  A  C  D (D) B  C  A  D

22. Some quantity of water in a closed container is present. As neon is added to this system at constant
pressure, the amount of liquid water in the vessel
(A) increases (B) decreases (C) remains same (D) changes unpredictably

23. A proportional counter is filled in succession with the same amount of 3 samples of CO2 at a fixed
pressure and the following counts were noted.
i) Dead CO2 from coal : 9000 counts in 900 min.
ii) CO2 from contemporary wood: 22000 counts in 200 min.
iii) CO2 from test sample: 24,000 counts in 400 min.
Then the age of the sample will be (t1/2 of 14C = 5570 years)
(A) 5570 years (B) 4997 years (C) 11140 years (D) 9994 years

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24. Which of the following represents the correct order for the wavelength of absorption in the visible
region for the following
[Ni(NO2 )6 ]4 [NiF6 ]4 [Ni(H 2 O)6 ]2 [Ni(NH3 )6 ]2
(I) (II) (III) (IV)

(A) I  IV  III  II (B) II  IV  III  I

(C) II  III  IV  I (D) I  III  II  IV
OM e
25. OH OH
H
OM e  Product

OEt

The product is
O O
M eO M eO

(A) (B)
OM e OEt

OEt OM e

M eO
OM e OM e
(C) O (D) O
OM e

OEt
OEt

26. O
CHPh2 
H3C O 
H3O
 Products
18
P is
OH
OH
(A)
H3C  Ph 2CH OH
(B) Ph 2 CH
18
OH  H3C
O
O
18
18
OH
OH
(C) (D) H3C  Ph 2CH OH
Ph2 CH OH  H3C
O
O

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SECTION II : (MULTIPLE CHOICE QUESTIONS)

This section contains 08 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE than one is/are correct.

27. Which of the following statements are correct?

(A) Nylon 6 and Nylon 66 are examples of condensation polymerization
(B) D-glucose and D-galactose are epimers
(C) Polyethene is produced via addition polymerization
(D) Teflon has a low coefficient of friction

28. Which of the following statements are incorrect?

(A) Sulfate ion and thiosulphate ion are isostructural
(B) Thiosulphate on reaction with HCl precipitates sulphur along with SO2 evolution
(C) In S2O32 the oxidation states S are zero and 4.
(D) Both SO24 and S2O32 can decolourise I2

29. Which of the following will undergo iodoform test with I2/NaOH
(A) CH3CHO (B) CH3OH (C) (CH3)2CHOH (D) CH3CH2CHO

30. Which of the following are optically active

CH2
(A) H3C C CH3 (B) H3C C
I SO 3 H

C CH3
(C) H3C C (D)
HO3 S I

31. Which of the following pair has identical hybridization of the central atom
(A) S2O82  , SO42  (B) S2O32 , NO3 (C) I3 / BrF5 (D) XeF4 , SF6

32. Which of the following statements are incorrect?

(A) Heat of physisorption is greater than heat of chemisorption
(B) Rate of physisorption increases with increase in pressure
(C) Rate of chemisorption increases with increase in pressure
(D) Rate of chemisorption decreases with increase in temperature

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33. Mg3 N 2 

H2O
 A (g) 
CuO

 B  C(g)  H 2O
C(g) can be obtained by heating
(A) NH4NO3 (B) (NH4)2SO4 (C) NH4ClO4 (D) (NH4)2Cr2O7

34. Which of the following are buffer solutions.

(A) NaOH and NaCl (B) NH4OH and NH4Cl
(C) NaCN and HCN (D) NaCN and NaOH

SECTION III : (INTEGER CORRECT TYPE)

This section contains 06 Questions. The answer to each question is a Single digit integer, ranging
from 0 to 9 (both inclusive)

35. 24 ml of water gas containing only hydrogen and carbon monoxide in equal proportions by volume
are exploded with 80 ml of air, 20% by volume of which is oxygen. If all gaseous volumes are
measured at room temperature and pressure, calculate the volume of unused oxygen in mL?

36. A reaction is carried out at 500 K. If the same reaction is carried out in presence of catalyst at the
same rate the temperature required is 400 K. If the catalyst lowers the energy barrier by 2 KJ mol1
then what is activation energy for catalyzed reaction in KJ mol1 ?

37. Iron (II) oxide crystallizes in cubic lattice with edge length of 5.0 Å. If the density of unit cell is
4 g/cc then effective number of Fe2+ and O2 ions in the unit cell are (round off to nearest integer)

38. The density of an equilibrium mixture of N2O4 and NO2 at 1 atm and 348 K is 1.84 g dm–3. The
equilibrium constant in atm for reaction will approximately be (round off to nearest integer)

39. Chromite FeCr2O4 is the only important ore of chromium and is used in the preparation of K2Cr2O7.
In the first step of preparation the produced ore is heated with molten Na2CO3 in presence of oxygen
to obtain a yellow solution of chromium containing compound (X). The change is oxidation stage of
chromium is

40. In two separate bulbs containing gases A and B, the density of gas A is twice that of gas B while
molecular weight of gas A is half of gas B at same temperature. Their pressure ratio P A/PB will be

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