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Dense Phase Transmission of Natural Gas, King and Katz
Dense Phase Transmission of Natural Gas, King and Katz
reduced pipe size and pumping installa- ated closer to atmospheric temperatures. PIPELINE EQUATIONS
tions. Disadvantages are low operating 2) The refrigeration requirements to prepare
temperatures requiring refrigeration and natural gas for transportation in a dense
Flow Equation (Conservation of Momentum)
exotic metallurgy. Economic trade-off phase system, and to maintain it in that
between reduced size and increased com- condition in the pipeline, are only one third dP + dz + 2fv2 dx = 0
gD
plexity, in comparison to a conventional the refrigeration requirements for LNG.
where,
pipeline, is investigated. 3) The metallurgical difficulties for a dense
iTTE -
phase pipeline are less severe than for 3.7 D Re > Ncrit
'Dense Phase -14ismiss than that of LNG and greater flow efficiency
can therefore be obtained.
Temperature Profile Equation (Conservation of Energy)
dH + dz = dq
g
5) The transportation of heavy hydrocarbons where.
{1n(2ti/D+1) cosh-1(2h/D)1-1
dq
system suffers from solid formation prob- g Ki 2n K (T-Tg)dx
lems.
Chilled conventional pipelines also exhibit many STATION EQUATIONS
of these advantages over both dense phase and Compressor Horsepower Equation (Conservation of Momentum)
PIPELINE SCRENATIC
ratures below 32°F and permanently maintain the
A conventional gas pipeline which is operated used in this paper are intended to reflect general frozen ground around the pipeline. The LNG, dense
at temperatures below 32°F is referred to here as Arctic conditions and apply to pipelines that trans- phase and chilled conventional systems are all
a "chilled conventional" pipeline. The chilled con- port gas from a gathering point in the Arctic to a Ictuat
losieltietation 0 0
3astlicattan
responses to these needs in that they all operate
ventional example transports gas v.-ith a density of distribution point in southern Canada. ataeltbe at temperatures below 32°F and achieve favourable
about 10 lb/cu. ft. at temperatures in the range of
Segment
economics at large flowing volumes such as are
0°F to 15°F. ADVANTAGES OF DENSE PHASE contemplated for Arctic gas pipelines.
PIPELINE SEGOENT SCHEMATIC
•
in the Arctic has stimulated the search for the least system compared with an LNG system result from lark a00ea ment comprises a pipeline section, a device for add-
by Turbine
mally thought of as a compressor for the chilled tion to cool the gas to the required flowing tempera- tinctions between the three systems in the calcula- VISCOSITY OF METHANE
(DATA OF KOWA ET AL)
conventional pipeline and a pump for dense phase ture of the pipeline. The gas is treated before it tion of friction, work to overcome friction and heat 1300
and LNG pipelines. Since present concepts for rais- enters the pipeline to reduce water vapour, carbon exchange between the system and the environment. 1100
ing the pressure are generally limited to centrifugal dioxide and other impurities to required levels. It Accordingly, the same basic equations are used for
units with turbine prime movers, the units which is assumed for the purposes of this study that this each of the three systems. The equations are given
,
impart work to the flowing fluid to overcome friction initial treatment plant produces gas at 15°F and in Figure 2. 1000 N.
are similar in character for the three cases, and therefore only the dense phase and LNG systems 5
7ao
vary only by degree depending upon the density require further initial refrigeration. 2i.
.
.0
and the compressibility of the flowing fluid. I `, 0 a
'411144441141
The device for removing heat from the flowing assumed to be transferred to conventional vapour
PROPERTIES OF FLUIDS ,.f. 300
cp-
00„
l ,4
fluid is also similar in each of the three examples phase pipelines and some form of regasification Fluids under pressure in pipelines have properties 200
except that the LNG system requires three refrigera- is required. This is no special problem for the chilled which are not easily visualized. The combined effect 150 1 1 09
I 0 ,, ,
tion stages, the dense phase system at the tempera- conventional pipeline where the absence of refrige- of low temperature and high pressure on the density - II ......-....---..
oo _
ture level studied requires two stages and the chilled ration at several compressor stations is sufficient of a real gas may not be familiar to those who think so
to
bT1 p714
conventional system only one. Mixed refrigerant to raise the temperature to conventional levels. in terms of what can be seen at atmospheric condi- 70
130
__—.2
1 5V-
cycles could also be utilized. The pipeline sections However, both the dense phase and LNG pipelines tions and the ideal gas laws. Natural gas can be 50 '''.
—300 —200 —150 —100 — so 0 so
are similar in all cases except for the metallurgy require some form of regasification plant. The alter- compressed from normal atmospheric pressure and TEMPERATURE('F )
and that both the dense phase system and the LNG native of allowing the temperature to rise naturally temperature, cooled and then decompressed until
system are insulated to reduce the heat load on over a long length of pipeline is not considered it reaches a liquid condition at atmospheric pres-
the refrigeration cycles. here and is outside the scope of this paper. sure and -260°F without changing phase.
available for predicting these phase relationships,
The thermodynamic properties of the gas during but with certain complex mixtures it may be desir-
this process, change in a continuous fashion and able to take physical measurements of specific sys-
no sudden break between gas and liquid states is tems.
observed. During this cooling process in the single
One advantage of the dense phase system is that
1
O ETOPIF
1500
',' o temperatures is the phenomenon which changes CH LLED CON
", 4', • YE iT I ON, 1
id 1500
.* .,,, the relationship between the pipe diameter and flow OPilikill(G
CT:LE
%,,),
rate among the systems under consideration. 1400
TWO PHASE
REDIOR
That is, they are operated at pressures and tempera- 1200
--..
r., tures such that vapour and liquid cannot exist at 1100
25':'
the same time. The terminology implies that gas
000 gyp`
in the chilled conventional pipeline would not be ,.,
E:ANPLI
DI DEN: E
i
BILLED
CANYENT I ON A L
permitted to reach its dew point to form condensate 200 PT AGE
VERA( MG
i(
REGION of either hydrocarbon or water. The dense phase sac,
CfCLE
/ 74
M
and LNG systems are operated such that the pres- 700
7,
sure does not fall below the bubble point where i f.
M
500
vapour would form in the system. E AMPL
0 LNG
-................ 500
,...1........
—.......
The addition of other hydrocarbqns such as C CLE i
ti
400
...."----"--"'"---.----__,_12LJsia ethane, propane, butane, etc., to methane, causes
the system to take on the two-phase envelope as 300 4.
-"----......,..., 400 As ia
indicated in Figure 5. The conventional or chilled 200 4
..---T 100 psia
conventional systems are operated at temperatures 100
\
I,
..240 -220 --200 -180 -160 -140 -120 -100 -SO 60 -40 -20 0 20 40 60 80 100 120 140
above the dew point line while the dense phase
TEMPERATURE( ° F )
and LNG systems operate at temperatures and pres-
' —1— ' I_._.L._1 .- ---..
TEMPERATURE (4 F)
sures above the bubble point curve. Procedures are
1500
... I •
c.#
cAn
I
,-- —
tion. This energy must be removed at the end of
I 1 1
0
co
each segment of the pipeline. In addition, the heat
6. 1:1
. .4.- 0
0
UP
0
-t 4
0
equivalent of the work of the compressor along with
/-' L. 0 ......
...
.-
1. 0 0 -4 the compressor inefficiency must be removed.
0 0 C5
''
41 C,
C7 C, CV i
These two sources of energy input between the inlet
1000 of a segment and the outlet, must be removed in
..,
..c
the station refrigeration unit. The air coolers, accor-
c,,
."
u,
.
I
dingly, must be designed to handle the heat which
cc
cu
ll
is absorbed from the ground and the work input
of the gas compressor, as well as the heat equivalent
TWO POSE
500
of the work done on the refrigeration system by
. RFR IN
its own compressors.
2600
parisons given in this paper, that the gas available transfer at both ends of the cycle, and this must INSULATION
from the Arctic is not rich in intermediate and heavy be taken into account when using the minimum
1\1
\
Insulation is desirable in order to reduce the heat
". 2600
molecular weight hydrocarbons and that the three work equation. flow between the pipe and the ground, especially
systems carry the same gas. The potential advan- The work required in a real refrigeration cycle
,C 2400
for LNG pipelines. The refrigeration stations of the
tage of the dense phase system to carry inter- is some factor higher than the minimum work. LNG pipeline are three times larger than for a dense
22 00
mediate and heavy molecular weight hydrocarbons Figure 8 shows several refrigeration cycles such
F:
t phase pipeline, and hence any reduction in the
c2
is therefore not considered. as might be used for the initial refrigeration of the
ID 2000
amount of heat transfer between the ground and
7-- leo°
A pressure-enthalpy diagram representing the gas and for cooling the gas along the pipeline route. the pipe achieves greater savings in the size and
gas properties which were actually used in the cal- For the chilled conventional system with discharge cost of the LNG refrigeration stations. Calculations
; 1000
-
...J g
,
culations is shown in Figure 6. temperatures of 15°F, a propane refrigeration cycle have been performed which show that the optimum
'100 E is sufficient. For the dense phase system at tempera- insulation thickness for a dense phase system is
2
1200
":,
y
REFRIGERATION tures of -115°F, an ethane refrigeration system can about four inches and is zero for the chilled conven-
All three systems make important use of refrigera- be used with the ethane being condensed by a prop- tional case. The result appears to be relatively insen-
1000
tion, both at the entrance to the pipeline and for ane cycle. This dual-cycle type of refrigeration unit sitive to most parameters and is affected principally
800 the after-cooling following pumping at the pipeline lowers the overall efficiency as indicated on Figure by the flowing temperature. The optimum thickness
stations. In the design of a refrigeration system, it 8. for an LNG line is about eight inches.
BOO APRON ROTORS.
1.1111101 THORETICAL HORSEPOWER is important to understand that there is a minimum It should be noted from Figure 7 that the refrigera- Problems associated with application of the insu-
HORSEPOWER
400
amount of work required to remove heat energy tion for LNG at -258°F requires more than three lation, the use of vapour barriers, weighting of an
200 at some low temperature and exhaust it to the envi- times as much horsepower to remove a million btu's insulated pipeline to stop it floating, crushing of
I ronment at some higher temperature. than the dense phase refrigeration cycle. In addi- the insulation during cool-down and by ground
0
410 •380 -010 -280 -210 -160 -1 0 -80 -10 40 90 t40
The formula for minimum work is given in Equa- tion, the heat to be removed in cooling the fluid movements have not been fully investigated at this
CHiLliMG IENPCRATORE.( 'F)
tion 9 in Figure 2, if the efficiency (Er) is set equal from dense phase temperatures to LNG tempera- time. These special problems have not been taken
An ENERGY PROCESSING/CANADA—November-December, 1973 ENERGY PROCESSING/CANADA—November-December, 1973 41
into account in the installation cost data shown in The wall thickness of the LNG system is limited For all systems, an average daily flow of 4.5 Bcfd station suction piping, the gas chillers and the sta-
Table 3. by construction difficulties which arise with thin was assumed to be available at a temperature of tion discharge piping.
wall pipes. For a pipe diameter of 36 inches, the 15°F and at the maximum line pressure of the sys- The results of the design calculations are given
METALLURGY minimum wall thickness has been set at 0.281 tem. For both the LNG and dense phase systems, in Table 2. The comparison shows the principal fea-
inches for this study. This wall thickness for the an initial refrigeration system is installed at the Arc-
Because it is necessary to avoid brittle fracture tures of each system. Both the dense phase and
36-inch LNG pipe is therefore greater than is dic- tic gathering point to reduce the temperature to chilled conventional systems use similar total horse-
phenomena, the metallurgy of the pipeline and
tated by the internal pressure. Shrinkage problems -250°F and -115°F, respectively. The fuel used by power, although the dense phase system has less
pump or compressor station depends upon the low-
associated with the initial cool-down of the LNG the initial refrigeration station is subtracted from
est expected operating temperature in the system. pumping horsepower. This is because of the larger
pipe have not been allowed for in the examples the assumed 4.5 Bcfd flow available at the gathering
In general the lower the transition temperature is refrigeration horsepower requirement of the dense
presented here. Stress analysis calculations show point before the gas enters the pipeline. A constant
set, the more expensive the steel becomes. For the phase system compared with the chilled conven-
chilled conventional system the pipe would have that some form of expansion loop design will be load factor of 93 per cent was used in the design tional system. The difference between the dense
necessary for LNG pipelines. Our calculations show of the three systems. phase system and the chilled conventional system
a specification below 0°F, whereas the dense phase
that the dense phase system does not require
system requires a specification of around -125°F lies principally in the metallurgy.
expansion loops.
and the LNG system requires a specification of Table 1 summarizes the physical parameters of The LNG system requires about three times the
about -260°F. MECHANICAL DESIGN refrigeration horsepower and twice the amount of
each system. Each LNG and dense phase pumping
In general, the three and one half percent nickel The three pipeline systems were designed using station is powered by an 8,750 horsepower (ISO) insulation as the dense phase system for the cases
class of steel is expected to be satisfactory at the a computer program which utilizes the equations gas turbine and the chilled conventional compres- studied. It is therefore obvious that such a system
dense phase conditions reported in this paper, but given in Figure 2. The pipeline route under conside- sor stations are powered by 30,000 horsepower is not desirable because its only advantage, namely
more advanced technology may be available using ration runs for 1300 miles from the Arctic to a point (ISO) units. The power output of all turbine units that it uses less steel, cannot be realized because
quenched steels with special metallurgical compo- in southern Canada where it is assumed to connect is adjusted for station elevation and ambient tempe- of the minimum wall thickness limitation that is
nents which will reduce the cost of steel for dense with conventional pipeline systems. Simulated rature. The flow program spaces the stations so imposed by construction considerations. This
phase systems considerably and make them more elevation, air temperature and ground temperature minimum wall thickness for the LNG system is set
that all the available pumping or compressor horse-
competitive. For the LNG case it is expected that profiles were used for the three cases. Each pipeline at 0.281 inches for a 36-inch pipe.
power can be utilized at each station when all
a five percent plus nickel class of steel would be was assumed to be buried six feet to centreline the units are running. The three systems are there- Except for the initial refrigeration, both the dense
suitable. below the ground surface. fore well balanced hydraulically, make equally phase and chilled conventional systems use similar
efficient use of their installed horsepower and quantities of fuel because they have similar total
hence can be compared on an equal basis. Station installed horsepower. The LNG system uses con-
TABLE 1—SYSTEM PARAMETERS losses of 15 psi were allowed for in each system. siderably more fuel than either of the other two sys-
This loss is made up of pressure losses through tems.
Liquid Dense Ll-AGied
Natural Phase Conventional
Units Gas Gas Gas
Parameter
1,300 1,300
Length of Pipeline miles 1,300
42 48
From
inches 36
Pipe Outside Diameter
inches .281 .404 .720 these few components,
Pipe Wall Thickness
4
Insulation Thickness inches
72 72
we build words
inches 72
Depth to Pipe Centre
to sell you,
1,2A7 2,540
Total Weight of Steel lb x 106 743 your product,
ft3 x 106 47 25
Total Volume of Insulation
lb x 106 130 68 your community.
Total Weight of Insulation
We will write,
inches .0003 .0003 .0003
Roughness Projections
Steel Yield Strength psi 65,000 65,000 70,000 edit, design,
Percent Nickel % Ni 5 3 print and
% SMYS 80 80
i3 UsEIGHILML/In&AMISnA4i
Sanford Evans Services Ltd. !
Design Factor
psig 600 1,000 1,680 'XY mail your 1077 ST. JAMES STREET, P.O. BOX 6900
Maximum Line Pressure WINNIPEG, CANADA R3C 3B1
650 1,150
Minimum Pressure psia company or PHONE (204) 775-0201
50
Total Horsepower HP 110,900 34,500 45,000 Base Cost $/ft. 50 50
0.35
Materials $/lb. 1.50 1.00
Propane/Air Heat Exchange tons 25,000 9,000 11,300 Insulation VI b. 1.00 1.00
30
Ethylene or gas/Propane Exch. tons 15,600 5,650 8,000 Installation $/ft. 25* 27.5*
Methane or gas/Ethylene Exch. tons 8,500 3,600
2. Pump or Compressor Stations
Gas/Methane Exchange tons 3,400
31 3. Refrigeration Stations
Number of Stations 33 33
Gas Pumps or Compressors 33 33 31
2,000
Gas Horsepower HPx 103 290 290 930 Turbine-Compressor Base Cost $000/unit 2,000 2,000
85
Horsepower $/HP 85 85
400
Refrigeration Compressors 132 66 31 Propane/Air Exchangers $/ton 400 400
200
Propane Horsepower HPx 103 1,470 530 460 Ethylene or Gas/Propane Exch. $/ton 200 200
Ethylene Horsepower HPx 103 1,110 320 Methane or Gas/Ethylene Exch. $/ton 550 550
Methane Horsepower HP x 103 790 Gas/Methane Exchangers $/ton 870
Total Refrigeration Horsepower HP x 103 3,370 850 460
4. Initial Refrigeration $000,000 2,100 650
Total Horsepower HPx 103 3,660 1,140 1,400
5. Regasification Vton 800 800
Propane/Air Heat Exchange tons x 103 820 300 350
6. Indirect Costs 25% of Items 1-5
Ethylene or Gas/Propane Exch. tons x 103 510 190 250
Methane or Gas/Ethylene Exch. tons x 103 280 120
7. Total Annual Cost 15% of Items 1-6
Gas/Methane Exchange tons x 103 110
600 0.30
Total Heat Exchange tons x 103 1,720 610 8. Well Head Gas $/Mscf 0.30 0.30
4,500 25
Average System Supply MMscfd 4,500 4,500 9. Escalation (for 5 years) 25 25
Initial Refrigeration H.P. HPx 103 1,730 875
Average Pipeline Supply MMscfd 4,170 4,330 4,500 Note: These costs are intended to reflect average Arctic conditions for
Average Pipeline Delivery MMscfd 3,580 4,130 4,270 a pipeline that transports gas from a gathering point in the Arctic
Regasification Heat Exchange tons x 103 190 120 to a distribution point in southern Canada.
Average System Delivery MMscfd 3,500 4,080 4,270
1. Pipeline
Bose Cost $ 343 $ 343 $ 343
Now
Materials 1,115 1,247 889
Insulation 130 68
Installation 172 189 206
Available!
Fixed Costs $ 280 $ 280 $ 264
Turbine/Pumps Base Cost 66 66 62
Horsepower 25 25 79
3. Refrigeration Stations
•
Turbine/Compressor Base
Horsepower
Propane/Air Exchangers
$ 264
286
328
$ 132
72
120
62
39
140
San lord Evans' Direct Mail
Ethylene or Gas/Propane Exchangers
Methane or Gas/Ethylene Exchangers
103
156
39
66
50
LIS CATALOGUE 1974.
Gos/Metha ne Exchangers 96
Direct Mail properly used, is a powerful Write in for your free copy of Canada's
Subtotal, Refrigeration Stations $1,233 $ 429 $ 291
and effective advertising medium. Di- most complete Direct Mail List
rect Mail programs are only as good Catalogue (includes the largest listings
Subtotal, Pumps and Refrigeration $1,604 $ 800 $ 696
as the mailing lists used and Sanford of mail order buyers available in
4. Initial Refrigeration $2,100 $ 650
Evans' lists are the best available! Canada)—the Sanford Evans Gold Book
of Mailing Lists!
5. Regasification 150 95