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Midterm examination CHM61-104E©

1. Element X in group 7A has the highest electronegativity. What is the electron configuration
of X?
1. 1s2 2s2 2p6 3s2 3p1 2. 1s2 2s2 2p6 3s2 3p6 4s2 3d9
3. 1s2 2s2 2p5 4. 1s2 2s2 2p6

2. Electron configuration at ground state of an atom of an element Y is 1s2 2s22p6 3s23p6 4s2
3d10 4p5 . Which of the following statement is false?
1. Y is in the 4th period. 2. Cation derived from its isotope is 2+
3. It has 7 valence electrons. 4. The 1st ionization energy of Y is higher
than I atom.

3. Which is the characteristic of an orbital? If electron quantum numbers n = 3, l = 2, ml =

−1, and ms = +1/2.

1. 3s1 2. 3d1
3. 3p1 4. 3f1

4. Given that five elements have atomic numbers as 3, 4, 5, 11, and 19. Arrange these five
elements in order of decreasing size.
1. 3 < 4 < 5 < 11 < 19 2. 19 < 11< 5 < 4 < 3
3. 19 < 11 < 3 < 4 < 5 4. 5 < 4 < 3 < 11 < 19

5. Comparison of Rb, Si, and Cl is below, which of following statement is correct?

1. Atomic radius: Rb > Si > Cl 2. Electronegativity: Cl > Si > Rb
3. Ionization energy: Cl > Si > Rb 4. All of above.
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6. Atomic number of elements A, B, C, and D, are 7, 11, 17, and 20, respectively. Which ions
and chemical formula are correct?
Cation Anion Chemical formula
1 D2+ A3¯ D3A2
2 C3+ B2¯ C2B3
3 B+ A¯ BA
4 A+ C¯ AC

7. What are the chemical formulas of calcium phosphate, nitrogen trichloride, hydrogen
peroxide, and cobalt(II) sulphide, respectively?
1. Ca3(PO4)2 N3Cl HO2 CoS
2. Ca3(PO4)2 NCl3 H 2O 2 CoS
3. CaPO4 NCl3 HO2 CoS2
4. CaPO4 N3Cl H 2O 2 CoS
8. Arrange these following compounds in order of increasing of angle between hydrogen
bonds.
1. CH4 < NH3 < H2O
2. H2O < CH4 < NH3
3. NH3 < CH4 < H2O
4. H2O < NH3 < CH4 Example of bond angle

9. Which of the following covalent molecules are all polar molecules?

1. H2O and CO2
2. H2O and CaCl2
3. BF3O and HF
4. NH3 and CHCl3
10. Refer to Lewis structure below, what is formal charges of O?
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1. -1
2. +1
3. 0
4. -3
11. Which of the following statement about 100 grams of adrenaline (C9H13NO3) is incorrect?
(Given that atomic mass of C = 12.01, H = 1.01, N = 14.01 and O = 15.99) (13%)
a. It consists of 0.64 moles
b. It consists of 2.79 x 1023 molecules
c. It contains 8.38 x 1023 oxygen atoms
d. Its molar mass is 183.20 g/mol

12. What is the mass in gram of nitrogen (N) in 145 grams of Cr(NO3)3∙9H2O? (Given that
atomic mass of Cr = 52, H = 1.01, N = 14.01 และ O = 15.99) (13%)
a. 15.22 g
b. 18.85 g
c. 36.25 g
d. 45.00 g
13. Which of the following statements is incorrect? (13%)
a. All gases become more soluble when the temperature is decreased.
b. Sodium chloride has a small increase in solubility with pressure.
c. Not all solutes in solid state can dissolve more when temperature is increased.
d. Given that the solubility of KClO3 is 13.21g/ 100 mL of water at 40 ℃, when dissolving 26
g of KClO3 200 mL of water, supersaturated solution is achieved.
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14. All of these are the concentration of the solution made from dissolving NaOCl 7.10 g in
2 2 5 mL of water, except ( Given that atomic mass of Na = 22.99, O = 15.99 and Cl = 35.5,
dH2O = 0.997 g/mL) (13%)
a. 3.16 %wt/v
b. 3.06 %wt/wt
c. 0.42 M
d. 0.41 m

15. What is the volume in mL of acetic acid (CH3COOH) in 80 mL of 3 6 %v/v acetic acid
solution? (Given that atomic mass of C = 12.01, H = 1.01, และ O = 15.99, dCH3COOH = 1.05
g/mL) (13%)
a. 28.80 mL
b. 30.24 mL
c. 45.00 mL
d. 60.04 mL

16. What is the mass in gram of acetic acid (CH3COOH) in 80 mL of 36 %v/v acetic acid solution?
(Given that atomic mass of C = 12.01, H = 1.01, และ O = 15.99, dCH3COOH = 1.05 g/mL) (13%)
a. 28.80 g
b. 30.24 g
c. 45.00 g
d. 60.04 g
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17. What is the mole of acetic acid (CH3COOH) in 80 mL of 36 %v/v acetic acid solution? (Given
that atomic mass of C = 12.01, H = 1.01, และ O = 15.99, dCH3COOH = 1.05 g/mL) (13%)
ก. 0.60 mol
ข. 0.48 mol
ค. 0.63 mol
ง. 0.50 mol
18. What is the molality of the concentration, if 2 0 0 mL of water is added into 80 mL of 3 6
%v/v acetic acid solution? ( Given that atomic mass of C = 1 2 . 0 1 , H = 1.01, แ ล ะ O = 15.99,
dCH3COOH = 1.05 g/mL, dH2O = 0.997 g/mL) (13%)
a. 1.78 m
b. 2.00 m
c. 2.05 m
d. 2.52 m
19. World Health Organization (WHO) designates that for a safe drinking water, the
concentration of chloride ion must be in between 1-16 mg/L. If water purified by one factory
is found to contain 50 microgram of chloride ion in 0.2 L of sample water. What is the
concentration of the purified water in ppm? and is this water suitable for drinking? (13%)
a. 2.8 x 10-3 ppm, yes
b. 0.28 ppm, yes
c. 2.8 ppm, yes
d. 2.8 x 103 ppm, no
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20. Chompoonoot needs to prepare a solution for her stock solution, a 100 mL of 8 M nitric
acid. How should Chompoonoot prepare her 250 mL nitric solution with the concentration of
25 %wt/v? (Given that the atomic mass of N = 14.01, H = 1.01, และ O = 15.99 dHNO3 = 1.51
g/mL, dH2O 0.997 g/mL) (13%)
a. pipette 187.3 mL of the stock solution, then add 250 mL of water and mix well.
b. pipette 187.3 mL of the stock solution, add water and adjust the solution volume to 250
mL
c. pipette 124.00 mL of the stock solution, then add 250 mL of water and mix well.
d. pipette 124.00 mL of the stock solution, add water and adjust the solution volume to 250
mL
21. Which mixture of water and H2SO4 represents a solution with a concentration that is closet
to 30% by mass H2SO4? (25%)
a. 30 g H2SO4 + 100 g H2O
b. 1 mol H2SO + 200 g H2O
c. 30 mol H2SO4 + 0.7 kg H2O
d. 0.30 mol H2SO4 + 0.70 mol H2O
22. What is the mole fraction of CH3OH in an aqueous solution that is 12.0 m in CH3OH? (25%)
a. 0.178
b. 2.16
c.0.400
d. 0.667
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23. What is the final [Na+] in a solution prepared by mixing 70.0 mL of 3.00 M Na2SO4 with 30.0
mL of 1.00 M NaCl? (25%)
a. 2.00 M
b. 2.40 M
c. 4.00 M
d. 4.50 M

24. From the following reaction: Na2 SO3(aq) + HCl(aq) → H2 O(l) + SO2(g) + ....A....
Which statement is incorrect about A
Given that Mw Na = 23.0 g/mol; S = 32.0 g/mol; O = 16.0 g/mol; H = 1.0 g/mol; Cl= 35.5 g/mol
(0.5 %)
a. The amount of A is 2 mol
b. A is NaCl
c. Molar mass of A is 58.5 g/mol
d. A is insoluble in water

25. Which of the following equation is acid-base neutralization (0.5 %)

a. 2H2(g) + O2(g) → 2H2 O(l)
b. CaBr2(aq) + H2 SO4(aq) → CaSO4(s) + 2HBr(aq)
c. 2HNO3(aq) + Ba(OH)2(aq) → Ba(NO3 )2(aq) + 2H2 O(l)
d. Cl2(g) + 2NaOH(aq) → NaCl(g) + NaOCl(aq) + H2 O(l)

26. Which of the following is correct for the conversion of 50.0 g of K2S to the amount of
potassium ion? Given that Mw K = 39.1 g/mol; S = 32.0 g/mol (0.5 %)
1 mol K2 S 6.02 × 1023 atom K+
a. 50.0 g K2 S × ×
110.0 g K2 S 1 mol K+
1 mol K2 S 2 mol K+
b. 50.0 g K2 S × ×
110.0 g K2 S 1 mol K2 S
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1 mol K2 S 1 mol K+ 6.02 × 1023 atom K+

c. 50.0 g K2 S × × ×
110.0 g K2 S 1 mol K2 S 1 mol K+
1 mol K2 S 2 mol K+ 6.02 × 1023 atom K+
d. 50.0 g K2 S × × ×
110.0 g K2 S 1 mol K2 S 1 mol K+

27. The chemical reaction 2Al(s) + 6HCl(aq) → 2AlCl3(aq) + 3H2(g)

If 160 g of aluminium is reacted with an excess amount of hydrochloric acid, how many grams
of hydrogen gas is forming? Given that Mw Al = 27.0 g/mol; Cl = 35.5 g/mol; H = 1.0 g/mol
(0.5 %)
a. 17.78 g
b. 8.89 g
c. 3.56 g
d. 1.19 g

28. The chemical reaction 2Al(s) + 6HCl(aq) → 2AlCl3(aq) + 3H2(g)

How many grams of hydrochloric acid will be needed to react with 160 g of aluminium? Given
that Mw Al = 27.0 g/mol; Cl = 35.5 g/mol; H = 1.0 g/mol (0.5 %)
a. 72.1 g
b. 175.2 g
c. 216.3 g
d. 648.9 g

29. The chemical reaction 2C4H10(g) + 13O2(g) ⟶ 8CO2(g) + 10H2O(g)

If 1.25 g of C4H10 is reacted with 2.25 g of oxygen, determine the limiting agent. Given that Mw
C = 12.0 g/mol; H = 1.0 g/mol; O = 16.0 g/mol (0.5 %)
a. O2
b. C4H10
c. H2O
d. CO2
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30. From question 29, how many grams of carbon dioxide will be formed? (0.5 %)
a. 1.90 g
b. 5.00 g
c. 12.8 g
d. 44.0 g

31. From question 29 and 30, it was found that 1.00 gram of CO2 was formed. Calculate the
percent yield of this reaction. (0.5%)
a. 52.52
b. 69.20
c. 144.5
d. 19.47

32. Reaction between CH3NO2 and oxygen yielding CO2, H2O and N2 as products. Which of the
following statement is incorrect?
Given that Mw C = 12.0 g/mol; H = 1.00 g/mol; N = 14.0 g/mol; O = 16.0 g/mol (1.0%)
a. If 1.0 mole of CH3NO2 reacts with 1.00 mole of oxygen, CH3NO2 is limiting agent.
b. CH3NO2 0.5 mole will react with 32.0 g of oxygen.
c. If 0.5 mole of CH3NO2 reacts with an excess amount of oxygen, the total mole of gas
product is 1.5 moles.
d. The chemical reaction is 4CH3 NO2(g) + 3O2(g) → 4CO2(g) + 6H2 O(g) + 2N2(g)

33. The chemical reaction Fe2(SO4)3(aq) + 6KOH(aq) → 3K2SO4(aq) + 2Fe(OH)3(aq)

When 50 mL of 0.25 M of Fe2(SO4)3 reacts with 4.0 g of KOH, percent yield of 50 is achieved.
How many grams of Fe(OH)3 is formed?
Given that Mw KOH 56.1 g/mol; K2SO4 = 174.2 g/mol; Fe(OH)3 = 106.85 g/mol; Fe2(SO4)3 =
399.70 g/mol (1.5%)
a. 2.84 g
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b. 4.49 g
c. 5.70 g
d. 1.27 g

34. From the following chemical reaction: Fe2(SO4)3(aq) + KOH(aq) → K2SO4(aq) + Fe(OH)3(s)
If 25.00 mL of 0.50 M iron sulfate (Fe2(SO4)3) reacts with 25.00 mL of 1.25 M of potassium
hydroxide (KOH), what is the concentration of potassium sulfate (K2SO4) after the reaction is
completed? (Molar mass of KOH 56.1 g/mol; K2SO4 = 174.2 g/mol; Fe(OH)3 = 106.85 g/mol;
Fe2(SO4)3 = 399.70 g/mol (50%)
a. 0.31 M
b. 0.62 M
c. 0.75 M
d. 1.50 M

35. The formulas and boiling points of three compounds are given in this table.
Formula CH3CH2CH3 CH3OCH3 CH3CHO
Boiling point (K) 231 250 294
The trend in boiling points is best attributed to variations in (25%)
a. Covalent bonding
b. Dipole forces
c. Dispersion forces
d. Hydrogen bonding
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36.
The phase diagram for compound X is shown above. Which statement about this diagram is
incorrect? (25%)
a. The critical point is above 304.25 C and 73 atm.
b. The triple points is at 216.6 C and 5.2 atm.
c. This compound is in gas form at room temperature.
d. This compound does not melt at room temperature.
37. Which samples of the following exhibit hydrogen bonding? (25%)
I CH3CH2OH II. CH3F III. CH3CH2CN
a. I only
b. I and II only
c. II and III only
d. I, II, and III
38. In a glass tube column of water and mercury appear as shown.

Which of the following statement is incorrect? (25%)

a. It relates to surface tension.
b. In case of mercury, cohesive force is larger than adhesive force.
c. In case of water, cohesive force is larger than adhesive force.
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d. This is known as capillary effect.

39. How would the freezing point depression of a 0.05 m MgF2 solution compare with that of
a LiF solution? It would be (13%)
a. a. less than that for a 0.10 m LiF solution
b. b. between that for a 0.10 m LiF solution and a 0.20 m LiF solution.
c. c. between that for a 0.20 m LiF solution and a 0.30 m LiF solution.
d. d. greater than that for a 0.30 m LiF solution.

40. Which aqueous solution freezes at the highest temperature? (13%)

a. 0.30 m C2H5OH
b. 0.25 m KNO3
c. 0.20 m CaBr2
d. 0.10 m FeCl3

41. 40 g of a solute (non-electrolyte) is dissolved in a 700 mL of water. If the freezing point of

the solution is -0.56 oC. What is the molar mass of solute? (Kf of water = 1.86 °C/m) (25%)
a. 76.80 g/mol
b. 132.86 g/mol
c. 189.80g/mol
d. 265.73 g/mol
42. 40 g of CaCl2 is dissolved in a solvent to give a solution with a volume of 520 mL. The
obtained solution has a density of 1.10 g/mL. What is the boiling point elevation? (Kb of water
= 0.512 °C/m, molar mass of Ca = 40, Cl = 35.5) (25%)
a. 0.09
b. 0.28
c. 0.35
d. 1.04
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O
43. 40 g of KNO3 is dissolved in a solvent to give a solution with a volume of 405 mL. What is
the osmotic pressure of the solution at 30 °C? (Given that R = 0.08206 L atm mol-1 K-1, molar
mass of K = 39, N = 14, O = 16) (25%)
a. 0.025 atm
b. 24.31 atm
c. 48.65 atm
d. 2461.8 atm
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43. 40 g of KNO3 is dissolved in a solvent to give a solution with a volume of 405 mL. What is
the osmotic pressure of the solution at 30 °C? (Given that R = 0.08206 L atm mol-1 K-1, molar
mass of K = 39, N = 14, O = 16) (25%)
a. 0.025 atm
b. 24.31 atm
c. 48.65 atm
d. 2461.8 atm