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Spectroscopy and Structural Elucidation Practical(ASAC3206P)

SEMESTER I, 2023-2024
WORK SHEET – 5 Marks:20

Word Problems related to NMR Spectroscopy

Name: ID: Date: ……
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b)
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d)

Problem #1:

An unknown compound C8H8O2 shows the IR spectrum 1710cm-1. Following are details
from NMR spectrum

0.95δ (6H) doublet.

2.43δ (1H) multiplet
2.1 δ (3H) singlet
Problem #2
Determine the structural formula from the following H-NMR. IR shows C=O (Ketone)
and molecular form is C6H12O:

Integration: 0.7:1.8: 0.7: 0.7:1.8

Problem #3:
Interpret the following spectrum of IR, MS and NMR respectively and arrive at correct
structural formula of the compound. Show all values and calculations involved in
various steps.