-1- FIRST YEAR MAINS MODEL EX. DT.

18-12-2023 (SET-A) A

INTERNAL TEST
FIRST YEAR 2023-25
JEE MAINS
Syllabus
Mathematics : Complete Three Dimensional Geometry.
Physics : Fluid Dynamics, Viscosity and Surface tension.
Chemistry : Geometrical optical and conformational isomerism (Exclude Cyclohexane)
Time: 3 hours Maximum Marks: 300
INSTRUCTIONS: 18th DEC 2023

Instructions to the Candidates

A. General
1. This booklet is your Question Paper containing 75 questions.
2. Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers and
electronic gadgets in any form are not allowed to be carried inside the examination hall.
B. Question paper format:
3. The question paper consists of 3 parts (Mathematics, Physics and Chemistry). Each part
consists of two sections.
4. Section I contains 20 Multiple Choice questions. Each question has four choices (A), (B),
(C) and (D) out of which ONE is correct.
5. Section II contains 5 questions. Each question is numerical value. Q.No. 21-25, 46-50, 71-75 are
Numerical based questions For each question, enter the correct numerical value (in decimal notation
rounded-off to second decimal place.
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Section-II Bubbling samples
Ans. 1.25 Ans. 5 Ans. 19

Ans. 0.33 Ans. 30.27 Ans. – 127.30

C. Marking Scheme
6. For each question in Section I, you will be awarded 4 marks if you darken ALL the
bubble(s) corresponding to the correct answer(s) ONLY. In all other cases zero (0) marks
will be awarded. –1 negative marks will be awarded for incorrect answers in this section.
7. For each question in Section II, you will be awarded 4 marks if you darken the bubble
corresponding to the correct answer ONLY. In all other cases zero (0) marks will be
awarded. No negative marks will be awarded for incorrect answers in this section.

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-2- FIRST YEAR MAINS MODEL EX. DT. 18-12-2023 (SET-A)
MATHEMATICS

Section-I :: Single Correct Answer Type

x  3 y 1 z  2 
1. The plane containing the line   is rotated through about this line to contain the point
2 4 5 2
(4, 3, 7). The equation of plane before rotation is
(A) 3x  y  2z  6 (B) 2x  y  5 (C) x  2y  2z  1 (D) x  3y  2z  6

2. If (a, b, c) is the solution of the system of linear equations x  8y  7z  0 , 9x  2y  3z  0 , x  y  z  0

such that  a,b,c  lies on the plane x  2y  z  6 then 2a  b  c equals to
(A) 2 (B) 1 (C) 0 (D) –1

3. Equation of plane containing the line 2x  z  4  0 , 2y  z  0 and passing through the point  2,1, 1 is
(A) x  y  z  2  0 (B) 2x  y  0 (C) x  2y  z  3  0 (D) x  y  z  2  0

4. Circumcentre of the triangle formed by  sin10,cos10,3  ,  2 sin 25,2cos 25,0  and

 2 sin 40, 2 cos 40,2 is 

(A)  0,0,0  (B) 1,1,1 (C)  2,2,2  (D) None of these

5. Equation of the bisector of the angle containing the point (1,1,1) of the planes 2x  y  2z  6  0 and
3x  2y  6z  12  0 is
(A) 23x  y  32z  6  0 (B) 5x  13y  4z  78  0
(C) 23x  y  32z  6  0 (D) 5x  13y  4z  78  0

6. If  is the angle between the diagonals of the rectangular parallelepiped whose edges are of lengths 2, 3
and 4, then cos  cannot be equal to
3 21 11 7
(A) (B) (C) (D)
29 29 29 29

1  x 7y  14 z  3 7  7x 5  y 6  z
7. If the lines   and   are orthogonal to each other, then the value
3 2P 2 3P 1 5
of P is
70
(A) 10 (B) (C) 7 (D) 5
11

x 1 y  3 z  5
8. The line which passes through origin and intersects the two lines   ,
2 4 3
x  4 y  3 z  14
  is
2 3 4
x y z x y z x y z x y z
(A)   (B)   (C)   (D)  
1 3 5 1 3 5 1 3 5 1 4 3

9.  
If A 1, 4,5  , B k 2  1,k,k  1 lie on the same side of the plane 3x  y  2z  7  0 then k lies in the interval

(A)  ,   (B)  0, 

 1  73   1  73   1  73 1  73 
(C)  ,    ,  (D)  , 
 6 6   6 6
     

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-3- FIRST YEAR MAINS MODEL EX. DT. 18-12-2023 (SET-A)
10. The distance of the origin from the plane through the lines determined by x  2y  z  3  0  3x  y  2z  1
and 2x  2y  3z  2  0  x  y  z  1 is
1 1 1 1
(A) (B) (C) (D)
2 2 2 3 2 4 2

11. The length of projection of the line segment joining the points (1, –1, 0) and (–1, 0, 1) to the plane
2x  y  6z  1 is
255 237 137 3
(A) (B) (C) (D)
41 41 41 41

x7 y 7 z3 x 1 y 1 z 1
12. Consider two lines L1 :   and L 2 :   . If a line whose direction ratios are
3 2 1 2 4 3
(2, 2, 1) intersects the lines L1 and L 2 at A and B respectively, then the distance AB is
15
(A) 20 (B) 18 (C) 17 (D)
2

13. The shortest distance between any two opposite edges of the tetrahedron formed by the planes y  z  0 ,
z  x  0 , x  y  0 and x  y  z  6 is
(A) 1 (B) 2 (C) 6 (D) 3

14. A line segment OA has length 21 and its direction ratios are proportional to  2, 3,6  . The coordinates of A
(given OA makes acute angle with x-axis and O is origin)
(A) (6, –9, –18) (B) (6, 9, 18) (C) (–6, –9, 18) (D) (6, –9, 18)

15. P  7,12,10  , Q  8,8,1 and R 11,3,9  are three vertices of a cube. Then its surface area is (in sq. units)
(A) 98 (B) 294 (C) 598 (D) Cannot be determined

16. The distance of the point 1, 2,3  from the plane x  y  z  5 measured parallel to the line
x 2y  3 z  5
 
2 6 6
1 3
(A) 1 (B) (C) 2 (D)
2 2

17. The angle between the lines x  3y  4  0  4y  z  5 and x  3y  11  0  2y  z  6

(A) 90 (B) 60 (C) 30 (D) 45

x 1 y 1
18. The coordinates of a point on the line   z at a distance of 4 14 from the point 1, 1,0  which
2 3
is nearer to origin
(A)  7,11, 4  (B)  7,11,4  (C)  7, 11, 4  (D)  7, 11,4 

 17 13 
19. The line passing through the points  5,1,a  and  3,b,1 crosses the yz-plane at the point  0, , .
 2 2 
Then
(A) a  2, b  8 (B) a  4, b  6 (C) a  6, b  4 (D) a  2, b  8

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
20. A   2,3, 1 , B  1, 1,2  , C is a point on y-axis such that ABC  then C =
2
 3   9   9   3 
(A)  0, ,0  (B)  0, ,0  (C)  0,  ,0  (D)  0,  ,0 
 2   4   4   2 

Section-II :: Numerical Based

x y 1 z  2
21. Consider a set of points R in the space which is at a distance of 2 units from the line  
1 1 2
between the planes 2x  y  2z  3  0 and 2x  y  2z  2  0 . If volume of the bounded figure formed by
a a
the set of points R in cubic units is then 
b b

22. 
If 3x  4y  z  5 , where x,y,z   , then minimum value of 26 x 2  y 2  z2 is 
x y 1 z 1
23. Angle between the plane 2x  y  2z  5 and the line   is  then the value of 9 sin  is
2 2 1

24. Two systems of rectangular axes have the same origin. If a plane cuts the axes at 1, 2, 2 and a, b, c from
1 1 1
the origin, then 2  2  2 
a b c

25. Let A(2, 3, 5), B(–1, 3, 2) and C  ,5,   are vertices of a triangle and its median through A is equally
inclined to the positive directions of coordinate axes. The value of 2   is equal to

PHYSICS

Section-I :: Single Correct Answer Type

26. Air is pushed into a soap bubble of radius ‘r’ to double its radius. If the surface tension of the soap solution
is S, the work done in the process is
(A) 8r 2S (B) 12 r 2 S (C) 16 r 2 S (D) 24 r 2S

27. If two soap bubbles of different radii are connected by a tube.

(A) Air flows from bigger bubble to the smaller bubble till the sizes becomes equal
(B) Air flows from the bigger bubble to the smaller bubble till the sizes are interchanges
(C) Air flows from the smaller bubble to the bigger
(D) There is no flow of air

28. Estimate the speed of vertically falling raindrops from the following data. Radius of the drops = 0.02 cm,
viscosity of air = 1.8  10 4 poise, g  10ms 2 and density of water = 1000kgm3 (neglect density of air)
(A) 10 m/s (B) 7 m/s (C) 15 m/s (D) 5ms1

29. A wire forming a loop is dipped into soap solution and taken out so that a film of soap solution is formed. A
loop of 6.28 cm long thread is gently put on the film and the film is pricked with a needle inside the loop.
The thread loop takes the shape of a circle. Find the tension in the thread. Surface tension of
soap solution = 0.030Nm1
(A) 6  104 N (B) 8  104 N (C) 11 10 4 N (D) 15  104 N

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-5- FIRST YEAR MAINS MODEL EX. DT. 18-12-2023 (SET-A)
3
30. A metallic sphere of radius 1.0  10 m and density 1.0  10 4 kg / m3 enters a tank of water after a free fall
through a distance of h in the earth’s gravitational field. If its velocity remains unchanged after entering
water, Determine the value of h.
Given: Coefficient of viscosity of water  1.0  10 3 Ns / m2 , g  10m s1 and density of water
 1.0  103 kg / m3
(A) 20m (B) 10m (C) 15m (D) 5m

31. Find the minimum force required to drag a hard polythene plate of area 2m2 on a thin film of oil of
thickness 0.25 cm and   15 poise . Assume the speed of the plate is 10cms1
(A) 0.12  107 dyne (B) 1.2  107 dyne (C) 2.4  107 dyne (D) 5  107 dyne

32. Two separate air bubbles (radii 0.002 m and 0.004 m) formed of the same liquid (Surface tension 0.07
N/m) come together to form a double bubble. Find the radius and the sense of curvature of the internal film
surface common to both the bubbles
(A) 0.008 m (B) 0.004 m (C) 0.04 m (D) 0.08 m

33. A film of water (which as two surfaces) is formed between two straight parallel wires each 10 cm long and
at separation 0.5 cm. Calculate the work required to increase 1 mm distance between the wires. Surfaces
tension of water  72  103 N/ m
(A) 288  107 J (B) 100  10 7 J (C) 144  10 7 J (D) 169  10 7 J

34. A river 10 m deep is flowing at 5ms1 . The shearing stress between horizontal layers of the river is
(   10 3 SI units)
(A) 10 3 N / m2 (B) 0.8  103 N / m2 (C) 0.5  103 N / m2 (D) 1 N/ m2

35. A sphere of brass released in a long liquid column attains a terminal speed v 0 . If the terminal speed is
attained by a sphere of marble of the same radius and released in the same liquid is nv 0 , then the value of
n will be (Given: The specific gravities of brass, marble and liquid are 8.5,2.5 and 0.8 respectively)
5 17 11 17
(A) (B) (C) (D)
17 77 31 5

36. A film of soap solution is trapped between a vertical frame and a light wire
ab of length 0.1 m. If g  10ms 12 , then the load ‘w’ that should be
suspended from the wire to keep it in equilibrium is ( T  25  10 3 N / m )
(A) 0.2 g (B) 0.3 g
(C) 0.4 g (D) 0.5 g

37. The angle of contact between glass and water is 0 and water (surface tension 70 dyn/cm) rises in a glass
capillary upto 6 cm. Another liquid of surface tension 140 dyn/cm, angle of contact 60 and relative density
2 will rise in the same capillary upto
(A) 12 cm (B) 24 cm (C) 3 cm (D) 6 cm

38. A horizontal pipe line carries water in a streamline flow. At a point along the pipe where the cross –
sectional area is 10 cm2 , the velocity of water is 1 m/s and the pressure is 2000 Pa. What is the pressure
at another section where the cross – sectional area is 5cm2
(A) 500Pa (B) 1000Pa (C) 800Pa (D) 300Pa
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39. Three are two identical small holes, each of area of

cross – section ‘a’ on the opposite sides of a tank
containg liquid of density  . The difference in height
between the holes is ‘h’ tank is resting on a smooth
horizontal surface. Find the horizontal force which will
have to be applied on the tank to keep it in equilibrium
(A) 6agh (B) 8agh
(C) 4agh (D) 2agh

40. A 16 cm3 volume of water flows per second through a capillary tube of radius ‘r’ cm and length 1 cm when
connected to a pressure head of ‘h’ cm of water. If a tube of the same length and radius r/2 is connected to
the same pressure head, find the mass of water flowing per minute through the tube.
(A) 30 g/min (B) 60 g/min (C) 80 g/min (D) 90 g/min

41. Two identical drops of water are falling through air with a steady speed of ‘V’ each. If the drops coalesce to
form a single drop, what is the new terminal velocity ?
(A) V '  22 / 3 v (B) V '  21/ 3 v (C) V '  23 / 2 v (D) V '  2v

42. A vessel fitted with a horizontal capillary tube at its base is first filled with a liquid A, and then with a liquid
B. The specific gravities of the two liquids are 0.6 and 0.8 respectively. If the time taken to empty the
vessel be 1 hr and 2 hr respectively then determine the ratio of their coefficient of viscosities.
(A) 8:5 (B) 5:8 (C) 3:8 (D) 2:7

43. An air bubble of radius 1 cm rises from the bottom portion through a liquid of density 1.5 g/cc at constant
speed of 0.25 cm/sec. If the density of air is neglected then find the coefficient of viscosity of the liquid
(A) 120 Pa.s (B) 130 Pa.s (C) 100 Pa.s (D) 150 Pa.s
44. 1000 drops of liquid each of diameter 4 mm coalesce to form a single large drop. If surface tension of liquid
is 35 dyn cm1 . Calculate the energy evolved by the system in the process.
(A) 1.58  103 J (B) 2.58  103 J (C) 4.58  10 3 J (D) 5.58  10 3 J

45. Figure shows a liquid flowing through a tube at the rate of 0.1 m3 / s . The
tube is branched into two semi circular tubes of cross – sectional area A/3
and 2A/3.The velocity of liquid at Q is (The cross – section of the main tube
is A  102 m2 and VP  20m / s )

(A) 5 m/s (B) 30 m/s (C) 35 m/s (D) None of these

Section-II :: Numerical Based

46. A cylindrical container of radius R and height ‘h’ is completely filled with a
liquid. Two horizontal L – shaped pipes of small cross – sectional area ‘a’
are connected to the cylinder as shown in the figure. Now the two pipes
are opened and fluid starts coming out of the pipes horizontally in
opposite directions. Then the torque due to ejected liquid on the system
is NaghR , then find ‘N’

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47. The surface tension of a liquid is 80 dyne / cm. Its relative density is 0.8. If the angle of contact between
the liquid and glass is 60 , If the height to which the liquid rises is____ cm in a glass capillary tube of
radius 1 mm(Assume g  10ms 2 ),

48. If a soap bubble of radius 3 cm coalesce under isothermal(constant temperature) conditions with another
soap bubble of radius 4 cm. If the radius of the big soap bubble so formed is ‘n’ cm, then find n.

49. The excess pressure inside a spherical drop of water of radius 1mm is n  20 Nm2 (surface tension of
water is 70  10 3 N / m ), then find ‘n’.

50. A drop of water of volume V is pressed between two glass plates

so as to spread to an area A. The normal force required to
nTA 2
separate the glass plates if T is the surface tension is then
V
find ‘n’

CHEMISTRY

Section- I :: Single Correct Answer Type

51. Which of the following compounds will exhibit Cis-Trans isomerism?

(A) 2-butene (B) 2-butyne (C) 2-butanol (D) butanal

52. Which among the following structures represents a ‘Threo’ isomer?

CHO CH3 COOH COOH
H OH Br H H Cl H NH2
(A) (B) (C) (D)
H OH H OH H OH H OH
CH2OH CH3 CH3 CH3

53. The structures shown here are related as

Br
H Br C
H3C H
CH3 C
H 3C
CH3 C H
C
Br H Br
(I) (II)
(A) Conformers (B) Enantiomers (C) Geometrical isomers (D) Diastereoisomers

54. Which of the following structure is different from the other three?
Br Br CH3 H Br
Br
CH3 H3C H3C
H CH2CH3
CH3CH2 H CH3CH2 H CH2CH3

(1) (2) (3) (4)

(A) 2 (B) 1 (C) 3 (D) 4

55. A solution of 0.1 g/mL of a pure R enantiomer in a 1.0 dm (i.e. 10 cm) polarimeter rotates plane
0
polarized light by +4.8 . What is the rotation observed for this solution in a 2 dm polarimeter?
0 0 0 0
(A) +2.4 (B) +9.6 (C) +19 (D) +4.8

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56. The correct IUPAC name of the following compound

is
(A) 2E,4E,6Z  Octa  2,4,6  triene (B) 2E,4E,6E  Octa  2,4,6  triene
(C) 2Z,4E,6Z  Octa  2,4,6  triene (D) 2Z,4Z,6Z  Octa  2,4,6  triene

57. Which among the following structures has high net dipole moment.

Br H Br Br Br H H H

Br H H H H Br H H
(A) (B) (C) (D)

58. Select the optically active compound among the following.

NH H3C COOH H3C CH3

COOH all
HN H3C HOOC COOH

(A) (B) (C) (D)

59. Which of the following pairs cannot be resolved?

(A) (B)

FF FF
a a
b b
(C) (D) C=C=C C=C=C
a a
b b
NO2 NO2 NO2 NO2

60. The absolute configurations at the chiral centres of the following

compound is
(A) 2S, 3R (B) 2S, 3S
(C) 2R, 3S (D) 2R, 3R

61. The compound has

(A) Plane of symmetry
(B) Axis of symmetry
(C) Center of symmetry
(D) No symmetry

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62. Which of the following statements is incorrect?
(A) Penta-2,3-diene shows optical isomerism
(B) Hexa-2,3,4-triene shows geometrical isomerism
(C) Cyclooctene shows geometrical isomerism
(D) 1-Bromo-3-chlorocyclobutane shows both geometrical and optical isomerism

63. The structure of 2R,3S C2H5 CHCH3  CHD CH2D is

(A) (B) (C) (D)

64. The correct set of E/Z configuration for the following structures I-IV respectively is

O Br Cl
CH3 O Me Me
O HC C C H
H O
C C
HOH2C C N S
Me
O Me Et
(I) (II) (III) (IV)
(A) EEZE (B) ZZEZ (C) ZEZE (D) EZEZ

65. For the compound with molecular formula C3H5Br3 the number of optically active stereoisomers and
the total number of isomers are respectively.
(A) 2 and 6 (B) 1 and 5 (C) 2 and 4 (D) 2 and 5

66. In the following structure, the double bonds are marked as I, II, III and IV. Geometrical isomerism is not
possible at site(s)?

(A) III (B) I (C) I and III (D) III and IV

67. The Newman projection of one of the conformer of 2,2-dimethylbutane is depicted as shown below.

Then X and Y can respectively be

(A) H and H (B) C2H5 and C2H5 (C) C2H5 and CH3 (D) CH3 and CH3

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- 10 - FIRST YEAR MAINS MODEL EX. DT. 18-12-2023 (SET-A)
68. The total number of cyclic compounds (including stereoisomers) having the molecular formula C5H10 is
(A) 4 (B) 5 (C) 6 (D) 7

69. The number of isomers of the compound C2FClBrI is

(A) 3 (B) 4 (C) 5 (D) 6

70. The total number of stereo isomers possible for 2-methyl cyclopropane-1-carboxylic acid is _______
(A) 3 (B) 2 (C) 4 (D) 5

Section- II :: Numerical Based

71. Number of possible geometrical isomers of the given

compound are

72. How many chiral centres are present in chlolesterol (below structure) ?

73. The dihedral angle in staggered form of Newman projection of 1,1,1-Trichloroethane is _______ degree.
(Round off to the nearest integer)

74. How many of the following are optically active ?

75. The minimum molar mass of optically active alkene (comprising C and only H) is X. The minimum molar
mass of optically active alkane (comprising C, isotopes of H) is Y. Then X  Y is ________.

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