1. Inthe electrolysis of concentrated aqueous solution of potassium propanoate (A) n-hexane and carbondioxide are formed at anode: potassium hydroxide and hydrogen are formed at cathode (8) n-hexane and hydrogen are formed at anode; carbondioxide and potassium hydroxide are formed at cathode (C) n-butane and carbondioxide are formed at anode; potassium hydroxide and hydrogen are formed at cathode (0) n-butane and hydrogen are formed at cathode; carbondioxide and potassium hydroxide are Tormed at anode ae chectroly wr 2kon LCG, COOK + Myo LOGO ce cu, cy etl + 20m tht ee a gz nt anode At cottroole Cceusplng renin) 20, Which ofthe flowing wal not show tautomerism? 9 e Hae, w is ll eee cts HyC—C—CH, Hee’ co ° o % ia 2 (©) Wc-¢-Ch, -¢-0c,H, GEER Fete, componvicts 21. Which ofthe folowing reactions will give propane withthe best yi? Hae atre one 4-H Aor bautomecomy (A) CH,CH, 14 CH14.Na— 222 (8) CH,CH,COONa + CH,COONa—j, "29 (©) CHCH, + (CH), Ci 22 (0) (CH), CHCOONA 82 cr oy te ree on ee hee é&, Be Gye, 4 (Cty), ri EL, enyen,-H, R at 4 Loy ry + wor © © Gt OS, Hs ya mn ete @ rene i, a ati cH, C4, cap c=cH-e, ee ae a an ee Wy rs a on cn cs 323. Degree of unsaturation (Index of hydrogen deficiency) in product 'Y” CH3 — Cr,0,- Al,O. Hes NAN SDs BPs, 1 product 3 873K (Ay4 (B)3 (C)2 (D)1 Cee ef atkarer ucts omens) fe 1 ( cu, ct = SJ + 34 a x20 AO (BN COs NO os eas ec ‘ Ben, ay 73k. gone CON a cy he ord uf ae ens fou 4 Covings 3A5 24. Which ot the following are correct. () Aromatsaton: n-Hexane 2:28. Benzene (i) Oxidation: CsH, +50, 960, +440 (ii) Substitution Reaction: CH, + Cl, —™—CH,Cl (iv) Reduction: C#,cHO—2*8°_.CHCH, (1a a @umn jum (O)allarecomect aD (creprnl) 25. Mark out the incorrect comparisions. (A) 3°H> 2°H> 1°H(reactivty for bromination) © Noni A~ow CHT © < (stability of carbo cation) oe aon, (heat of hydrogenation) oC26. How many of the following reactions carbon-carbon bond formation is involved (A) Wurtz reaction (8) Sabatier-Sanderen's process (C) Corey-House synthesis (0) Kolbe’s electrolysis etter Fe ep eee Raney Ni ees Re abe ch Rt, ee ’ Lx <*, Aa 8) iC) ee Oe cae W) Cn cleche se RoR + et be 27. From the folowing pair of compound select stronger base (0 (@) p»methoxy aniline & (b) p-cyanoaniine (1) (2) pyridine & (b) pyrrole {il (@) Methane nitrile & (b) propane nitrile Oy Ny CH Nite ‘oH wel Hs - 4 a © 4 ‘ " " eats (wy) mH © ig dete bg nor 2) R- Cooma +H,0 hogea> bette, by (A)I-b, Il-a, Il b, IV-a (B)|-b, —b, Il-b, V-b ()t-ait-b tke, Va (O)t-ata.t-b Vb aD] os ret: oa we Nu) Nit, » 9) ES »° fr ; on ae Ce @e >) = AN ae ore (i) w vn fy (Pyridine) a a 4 CCF as ae “34 Z wi- & DO aauie28. Which of the folowing decreasing order correct regarding stability. & & a 6-6: Hs (Ge) NO, (-€) O- &. : [ae proene datrenee cxnlinrion MOLLLG Y : (er No. ¢-®) SOI (Ces) > (CeHls):CH > (CHa)C > ci, @ @ @ SOY CHs-CHe > CH, > CHy NO ACD *E = 20, How many ofthe following compounds are aromatic in nature according to Huckel rule? Cpmaye en cote cogguiew SS NN ® > OC O i OL (A) oa 2 es ac ce, GOEDE (0) oe le [ 1 (oe ve, (Harte )) ee aaa ‘The monobromo derivatives formed by the alkanes with molecular formula C,H is/are AL ee of ona — oO © wor Ce pe anit = (oe pete pete mee penta i @ om @) The pia mencbrome protuct ave pecs ble 1) n—- peta 30. ay Pas: 31. Select the reactions which can be used to prepare propane with good yield. (B) CH,CH,CH,COONa— “28, cap gerh Hs heat (A) CH,CHI—G— cu, cat, 2 oy PrePame Pre pene (C) CH,CH,COONa—“#oter8s_,_—_* (D) CH,CH = CH, +H, Ramey", Crtgl, Cts 31. ABD N-Bnbane frepans 32, Which of the following methods can be used to prepare methane. (A) AlyCs +H,0 = (B) CH,Mgi—#2_ (C) CHy|+ Zn(Cu) +CH,OH (0) CH,COONa +NaQH— Fo — GaaESD) Conte [Alga ened cece) eters 2) leptte Ayo + 24° al aaa apo! 4 co es, ) Inyo pon Py toy cogent eae @) erent eee a FZ an coo a Hy 020 7 ind cao Che + Naoto, Checnrboty aii ree a =) 4 : 9 f, COOMA Bat33. What will be the major product formed when formed when 2-methyl butane undergoes bromination in presence of light? (i) bomen 2 meth butane (©) 2-bromo-2-methyibutane (C) 1—bromo—2,3—dimethyl—1—propane — (D) none 8 av Aw me CH, 3 Ordag. of TeneBnily 34. The relative reactivity of 1°, 2° and 3° hydrogen in chlorination reaction has been found to be 1:3.8:5 — Suz tH 70 +l, + (CH,),CH CH, -CH,CI + (CH,),CH CHIC) oH, + (CH) CIC CaH, + ® cc o ae o Sa s ‘The ratio of the amount of the product (A), (B), (C) and {D) is expected to be (a) 1:76:25: (8) 1:38:51 76:5:6 (0) 3:76:5:3 no -eg FH» rence Gf U ratio of prectect pot (ey. (AN ene) (8) aap thn enn an Simla, (a) CB): GD 5 00) 35. Wehr cloning compounds er not ia? EG i fee eae pace 2) Cx as hla 6 Ho oy MG on on fe oad :HZOH "7 HyC H é oe “ ® © or 26. Which he folowing pate re dastrorers? no Ho wy HEH ond HOB“) ee es an 7 coon