Introduction to

6 Organic Chemistry
1. How many chain isomers can be obtained from the
6. IUPAC Nomenclature of (DMC 2011)
alkane C6H14? (DMC 2016, LMC 2016)
2. A. 7
B. 6
CH 3 − CH = CH2 CH = CH2 is
–

C. 5 A. 2- pentene
D. 4 B. 1, 4 hexadiene
3. The IUPAC name for the following structure ends in
C. 3 Methyl butane
what suffix? (DMC 2015)
D. 1, 3, 5- heptatriene
E. 1, 3, 6 hexatriene
7. During condensation polymerization, two
monomers may be joined by the removal of a
molecule of: (DMC 2009, LMC 2011))
A. carbon dioxide
B. Nitrogen
C. Hydrogen
D. Oxygen
E. Water
8. The IUPAC name of the given compound is:
A. –ol
B. –one CH3-CH- CH2 -C- (CH3)2
C. –oic acid | |
D. –yne
OH OH
4. Which type of isomerism depends on distribution
of carbon atoms on each side of functional
(LMC 2014)
group? (DMC 2013)
A. 4-Methyl-2, 4-pentane diol
A. Structural isomerism
B. 1, 3, 3-Trimethyl-1, 3-propanediol
B. Functional isomerism
C. 1, 1-Dimethyl-1, 3-butanediol
C. Chain isomerism
D. Metamerism D. 2-Methyl-2, 4-pentane diol
5.
CH3 – CH2 – CH2 – CH3 and CH3 – CH – CH3 9. Chain isomers of C5 H12 will be:
1 propanol | (LMC 2014,NTS 2018)
OH A. 4
2, propanol B. 5
C. 6
D. 7
E. 3
are examples of? (DMC 2012)
A. Chain isomerism
B. Position isomerism
C. Functional group isomerism
D. Metamerism
E. Optical isomerism
1
10.Butane and methyl-propane are isomers which formula is 16. The correct I.U.P.A.С. name of diethyl acetylene is:
different for the two isomers? (LUMHS 2013)
(LMC 2013) A. 1, 2 - diethyl ethyne
A. Empirical formula B. 3 - hexyne
B. General formula C. 2 - hexyne
C. Molecular formula D. 1 – pentyne
D. Structural formula 17. Coke is produced from bituminous coal by:
E. Both General formula and Empirical formula (LUMHS 2010)
11. Alkanes having five to seventeen carbon atoms per A. Cracking
molecule are: (LMC 2013) B. Synthesis
A. liquids C. Substitution
B. Solids D. Destructive distillation
C. gases E. Filtration
D. semi solid wax 18. Which of the following hydrocarbons has the lowest
12.The IUPAC name of the compound is: (LMC 2011) normal boiling point? (LUMHS 2009)
A. Ethane B. Propane
CH3 - CH- CH2- CH3 C. Butane D. Pentane
| E. Hexane
C6H5 19. Cyclo Hexane has the formula: (IBA 2000)
A. C6H14 n B. C6H12
A. 2-cyclohexyl butane C. C6H16 D. C6H6
B. 2-phenyl butane 20. Crude Oil can be separated by fractional distillation
C. 3-cyclohexyl butane because its constituents?
D. 3-phenyl butane (BAHARIA 2003)
E. 4-phenyl butane A. Are compounds
B. Are chemically similar
13.Polyvinyl acetate is the polymer of: (LUMHS 2014) C. Have different boiling points
A. Vinyl chloride D. Have different densities
B. Vinyl acetate 21. Bituminous coal can produce by destructive distillation:
C. Formaldehyde (NTS 2005)
D. Methyl methacrylate A. Coke s
14.An inorganic compound forming an organic substance B. Coal gas
on heating is: (LUMHS 2014) C. Coal tar
A. Ammonium cyanate D. Coal tear
B. Sodamide 22. Which of these is organic: (NTS 2005)
C. Sodalime A. SO2
D. Potassium B. CH4
E. Both A & D C. H2O
15.IUPAC name of the given compound is: D. HCl
23. Which is not a normal cracking phenomenon?
(NTS 2006)
CH3 A. Thermal cracking
| B. Catalytic cracking
H3C− (CH2)4 – CH − C−CH2−CH3 C. Steam cracking
| | D. Normal cracking
CH3 (CH2)2 − CH3 24. What are the raw materials in the formation of urea?
(NTS 2006)
(LUMHS 2014) A. Steam, methane and ammonia
A. 6, 7-Dimethyl-7-n-propy! nonane B. Steam and ammonia
B. 4, 5-Dimethyl-4-ethyl decane C. Methane and steam
C. 3, 4-Dimethyl-3-n-propyl nonane D. None of the above
D. 6, 7-Dimethyl-7-ethyl decane
E. 6, 7-Dimethyl-7-ethyl octane
25. Urea was prepared in the laboratory by Wohler first 32. All amino acids contain the functional group:
time in? (DMC 2007) (NTS 2017)
A. 1918 A. NH2 B. CO2H
B. 1928
1828 C. s2- D. Both A and B
C. 1938
33. Which one of the following is the pure carbon and used
D. 1948 as reducing agent in industries? (NTS 2018)
26. Reforming is a process in: (DMC 2008) A. Coal tar
A. Which smaller compound into large compounds B. Petroleum
B. Straight chain into branches chain C. Coal gas
C. Less volatile compound into high volatile D. Coke
D. Branches chain into cyclic compound IUPAC name of Butyric acid is:
In destructive distillation of coal all of the following
34.
27. A. Methanoic acid
are obtained except: (DMC 2008)
B. Butanoic acid
A. Coal liquor
C. Ethanoic acid
B. Coal tar D. Octadecanoic acid
C. Colle E. Butyric acid is IUPAC name
D. Coal gas 35. Ethers show the phenomenon of (NTS 2019)
28. Catenation is a process in which carbon shows the (A) Position isomerism
properties of: (DMC 2009) (B) Functional group isomerism
A. making single bond (C) Metamerism
B. hybridization (D) Cis-trans isomerism
C. making long chains or rings of carbon atoms 36. Write the chemical name of the given structure (NTS
D. isomerism 2019)
E. breaking of bonds
C2H5
29. The isomers must have the same: (DMC 2013) ▏
A. Physical properties H3C― C ≡ C―CH―C≡ CH
B. Molecular Formula
A. 4-ethyi-2,5-hexadiyne
C. Structural Formula
B. 3-ethyl-1,4-hexadiene
D. Chemical properties
C. 3-ethyl-1,4-hexadiyne
E. Both B and C
D. 3-ethyl-2,5-hexadiyne
30. The Carbon number of gasoline is: (NTS 2019)
CH3CH2CH2COCH3 37.
A. C3 ― C6
is the functional isomer of: (DMC 2016) B. C6 ― C7
A. CH3CH2CH2CH2CHO C. C5 ― C10
B. CH3CH2CH2CH2OH D. C12 ― C15
C. CH3CH2COCH2CH3 38. In t-butyl alcohol, the tertiary carbon is bonded to:
D. CH3-(CH)2COCH2CH3 (NTS 2019)
31. IUPAC name of this is A. No H - a toms B. One H - atoms
C. Three H - atoms D. Four C-atoms
(CH3)2-CH-CH (C2H5)-C(CH3)3 39. Why are large alkane molecules cracked to form
smaller molecules? (LUMHS 2015)
(DMC 2016)
A. Alkanes with large molecules are not useful
A. 3-ethyl-2, 2, 4-trimethyl pentane
B. Small alkane molecules can be polymerized
B. 4-ethyl-2, 2, 4-trimethyl pentane
C. Crude oil does not contain small alkane molecules
C. 5-ethyl-2, 2, 4-trimethyl pentane
D. To meet the demand for small alkane molecules
D. 2-ethyl-2, 2, 4-trimethyl pentane
E. 1-ethyl-2, 2, 4-trimethyl pentane
40. The structures of an acid and an alcohol are shown
(LUMHS 2015) 43.
(i) (i) CH3 -CH2-O-CH2 -CH3
H H O (ii) CH3 -CH2 -CH2- O-CH3
(iii) CH3 -CH- O-CH3
|
H C C C CH3

O H Above given forms are example of: (LMC 2015)

H H A. Functional group isomerism
Acid B. Position isomerism
(ii) C. Skeletal isomerism
H H H H D. Metamerism
44. Percentage of Butane in Sui gas is: (LMC 2015)
A. 94.60 %
H C C C C O H C. 1.05 %
D. O.02 %
E. 0.17 %
H H H H 45. Which of the following is the correct IUPAC name?
Alcohol (LMC 2016)
A. 3-Ethyl-4, 4-dimethylheptane
Acid Alcohol B. 4, 4-Dimethyl-3-ethylheptane
A. ethanoic Butanol C. 5-Ethyl-4, 4-dimethylheptane
B. ethanoic Propanol D. 2, 3-diethylheptane
C. propanoic Propanol
D. propanoi Butanol
41. The structures of two compounds are shown
(LUMHS
2015)
42. (i)
H H H H

H C C C C H

H H H H
H H
H
(ii)

H C C C H
C
H H
H C H

H
the compounds have the same
A. Boiling point
B. Melting point
C. Percentage composition by mass
D. Structural Formula
46. The molecular structure of a hydrocarbon is D.
shown below. (NTS 2017) H H

H C H
H H C H

H C C H
H C C H
H C H
H C HH

H
H
Which structure is an isomer of this
hydrocarbon?
A.
H

H HH C H

H C C C H

H C HH H

H
B.
H H H

H C C C H

H H
H C H

H
C.

H H H H H

H C C C C C H

H H H H H