a A&BYIND GUPTA DAY CENTENARY PUBLIC SCHOOL i CHEMISTRY suajECT- ps CLASS-xit TERM 1- 2! MARKS: 70 \ Time: 3 Hrs. Time: 3 hours Wax. Marks:70 General Instructions: read the following instructions carefully. (a) There are 33 questions in this question paper with internal choice. (b) SECTION A consists of 16 multiple-choice questions carrying 1 mark each. {g) SECTION B consists of § short answer questions carrying 2 marks each. {d) SECTION C consists of 7 short answer questions carrying 3 marks each. {e) SECTION D consists of 2 case- based questions carrying 4 marks each. (f) SECTION E consists of 3 long answer questions carrying 5 marks each. () All questions are compulsory. {h) Use of log tables and calculators is not allowed SECTION A The following questions are multiple -choice questions with one correct answer. Each question carries 1 mark. There is no internal choice in this section. Phenol undergoes bromination with bromine even in the absence of iron (Ill) bromide catalyst A.A: Due to the activation of benzene ring by the hydroxy group. b. Due to the deactivation of benzene ring by the hydroxy group. Ale . Due to the increase in electron density at meta position d. Due to the formation of stable carbocation. 2. Which of the following condition is NOT satisfied by an ideal solution? a. OH mixing = 0 b. AV mixing = 0 c. Raoult’s Law is obeyed At Formation of an azeotropic mixture 3, Reduction of CHsCH:NC with hydrogen in presence of Ni or Pt as catalyst gives 4a. CHCH2NHz —® CHsCH2NHCHs ¢. CHsCH2NHCH2CH:pray ' ae -'B. Chloroform and acetone. " ©. Nitric acid and water. i Phenol and aniline. 'S. Which of the following reagents CANNOT, be used to oxidize Primary alcohols to aldehydes? ACrOs in anhydrous medium b. KMnOs in acidic medium BPrvridinium chlorochromate d. Heat in the presence of Cu at 573K 6.-The following reaction is C2Hscl + CHsON a. Mendius Reduction b. Carbylamine reaction Williamson's synthesis d. Finkelstein reaction ja ~ CoHsOCHs + Nac 7, Molecules whose mirror image is non super imposable over them are known as chiral. Which of the following molecules is chiral in nature? i. 2-Bromobutane b. 1-Bromobutane ©. 2-Bromopropane d. 2-Bromopropan-2-ol “A’ reacts with C2HSI giving ‘8’ and Nal. Here ‘A’ and ‘8 fespectively, are: ‘&. A=CH3COONa, B=CH30CH3 8. A=C2H5ONa, B=C2HSOC2HS ¢. A=C2HSOC2HS, B=C2HSOC2HS d. A=C2HSOH, B=C2HSOC2HS 9. Clemmenson reduction of a ketone is carried out in the presence of which of the following: a. He/Pt b. LIAIHa c. Ethylene glycol/KOH A: 2n-Hg/HC! following solutions will have the highest conductivity at 298 K? 7 _ i ‘ ees© SF a oF 12, The IUPAC name for the following organic compound Is CH - N—CH:CH, 4 he eestlayt Resta N-ethyl, N-methyl benzenamine N-methyl, N ethyl benzenamine ‘N-methyl, N phenyl ethanamine N-ethyl, N -phenyl methanamine ane 13. Assertion (A): During electralysis of aqueous copper sulphate solution using copper electrodes hydrogen gas is released at the cathode, Reason (R): The electrode potential of Cu’ /Cu is greater than that of H TH Given below are two statements labelled as Assertion (A) and Reason (R) ‘Select the most appropriate answer from the options given below a) Both A and R are true and R \s the correct explanation of A ©)Both A and R are true but R is not the correct explanation of A JA is true but R is false. d)A is false but R is true. 14, Assertion (A): The bond angle in alcohols js slightly less than the tetrahedral angle Reason (R): In alcohols, the oxygen of -OH group is attached to sp? hybridized carbon atom. Select the most appropriate answer from the options given below: a) Both A and R are true and R is the correct explanation of A 'b)Both A and R are true but R is not the correct explanation of A. ©) Ais true but R is false. )A |s false but R is true. 15. Assertion (A): When a solution is separated from the pure solvent by semipermeable membrane, the solvent molecules pass through it from pure solvent side to the solution side Reason (R): Diffusion of solvent occurs from a region of high concentration solution to a region of low concentration solution. Select the most appropriate answer from the options given below: a) Both A and R are true and R is the correct explanation of A and R are true but R is not the correct explanation of A.% “9 Renartion (A: Acylation of amines gives a monosubstituted product whereas alkylation of amines gives polysubstituted product. ‘Reason (R): Acyl group sterically hinders the approach of further acyl groups. ‘Select the most appropriate answer from the options given below a)Both A and R are true and R is the correct explanation of A b)Both A and R are true but R is not the correct explanation of A CAIs true but R is false. dD Ais false but R is true SECTION B This section contains § questions with internal choice in one question. The following questions arevery short answer type and carry 2 marks each. 17. A 5% solution of Na2SO4.10H 20 (MW=3 22u) is isotonic with 2% solution of non- 18, Arrange the following carbonyl compounds in increasing order of their reactivity in nucleophilic addition reactions a) Ethanal, propanal, propangne, butanone (b) Benzaldehyde, elastic. INIT ahe neice Rac kege ame 19. Calculate emf of the cell in which the following reaction takes place 2Al(s) + 3Cu*? (0.01M) -------> 2AI+? (0.01M) + 3Cu(s) Given Een = 1.98 V 20. An organic compound A with the molecular formula (+) C4H9Br undergoes hydrolysis to form (+) C4H 9OH. Give the structure of A and write the mechanism of the reaction. OR Write the mechanism for conversion of alkene to alcohol 21. Explain chemical test to distinguish between the following pairs of compounds. a) Pentan-2-one and pentan-3-one conn * b) Benzoic acid and phenol o oO, At er &) Catalytic reduction of buranal a b) Reduction of acetyl chloride in presence of Pd /taSO4 4 { propanone ham bromicbe fothermed ©) Reaction of propanone with methyl magnesium bromide fo wy ore 23, account for the following: a ato @) pKb of aniline is more than that of methylamine. b) Ethylamine is soluble in water whereas aniline is not © Acetylation of aniline reduces its activation effect rae OR pro f pot? P 4) Aniline cannot be prepared by the ammonolysis of chlorobenzene under normal conditions. b) N-ethyl ethanamine boils at 329.3k and butanamine boils at 350.8K, although both are isomeric in nature. ©) Primary aromatic amines cannot be prepared by Gabriel phthalimide synthesis Zs ive reason. a) At high altitude people feel weak and cannot think clearly. 'b) RBC shrink when placed in saline water. ©) An increase in temperature is observed on mixing chloroform and acetone. Fe etree es che contecosr of acetic acid at infinite dilution according to Kohlrausch law. 'b) Calculate the Am for CI- ion from the data given below gPmMach = 258.6 Scm?mol-! and Am Mg?" = 106 Sem2mol~! ‘he cell constant of a conductivity cell is 0.146 cm-!. What is the conductivity of O01 4° Solutionof an electrolyte at 296 K, if the resistance of the cell's 1000 ohm? 26. Calculate Ge and log Ke for the given reaction at 298K Ni(s) + 2Ag* (aq) -------> Niz* (aq) + 2AQ(5) Given E*Ni?+/Ni = -0.25V, E* Ag? /Ag = +0.80V > 27. 3.99 of benzoic acid dissolved in 49g of benzene shows a depression in freezing point of 1.62K Calculate the Van't Hoff factor and predict the nature of solute (Associated r Dissociated). Given molar mass of benzoic acid=122gmol-1, Kf for benzene 6? es adaerasinc nee CH:COOH __NH) A NaOH +8 _,8 CHC! + alc KOH, C \ o® CHgc Moe if got Ro SECTION 0 ¥ K ‘ore cose -based questions. Each question has an internal choice &The boiling point of a liquid is the temperature at which the vapor pressure is equal to atmospheric pressure. On the addition of a non-volatile liquid to a pure solvent, the vapor pressure of a solution decrease. Therefore, to make vapor pressure equal to ‘atmospheric pressure we have to increase the temperature of the solution. The difference in the boiling point of the solution and the boiling point of the pure solvent {s termed as elevation in boiling point. The freezing point of a substance is defined as the temperature at which the vapor pressure of its liquid is equal to the vapor of the corresponding solid. According to Raoult’s law when a non-volatile solid is added to the solvent its vapor pressure decreases and now it would become equal to that of solid solvent at a lower temperature. The difference between the freezing point of the pure solvent and its solution is called depression in freezing point. _-47 When a non-volatile liquid is mixed with water, what will happen to its boiling point and freezing point? pe of the following aqueous solutions should have the highest boiling point and why a Solution A L.0.M Naor Ho, Solution B 1.0-M NaxSOs, *™ Solution C 1.0 MNH«NO; X", 0 Solution D 1.0MKNOs * How does sprinkling of salt help in clearing the snow-covered roads in hilly i : areas? Explain the phenomenon ipvolved in the process. > oR x jevation of boiling point of 1M KCI solution is nearly double than that of Msugar_ + solution. g “What will happen with molal depression constant when molality of a diluted, solution is doubled. ee 30. Read the passage carefully and answer the questions that follow. Primary cells are not rechargeable because the electrode reaction occurs only once and after the Use over a period of time the cell becomes dead and cannot be reused. We commonly use voltaic cell as convenient, portable sources of energy. Flash -lights and radios are examples of devices that are often powered by the zinc-carbon dry cells or Leclanché cell. This voltaic cell has a zine can as the anode, a graphite rod in the center, surrounded by a paste of manganese dioxide ammonium and zinc chloride and carbon black is the cathode. The voltage of this dry cell is 1.5 V, but it decreases as current is drawn off. The voltage also deteriorates -_ A dry cell is not truly ‘dry’, because the electrolyte is an aqueous discharged, the cell is not easily reversed or recharged type of primary cell is Mercury cell. The voltage of this during its life. : after a long time even if it has not been used. ‘constant potential throughout. Give reason©) Write the haif-cell reactions for dry cell at each elect - rode write the half-cell reactions for mercury cell at each electrode. SECTION E The following questions are long answer type and carry 5 marks each. All questions have an internal choice. 31. An organic compound (A) C7HsO has a characteristic odor of bitter almonds. On treatment with conc. NaOH, it forms two compounds (B) and (C). Compound (8) has molecular formula C7Hs0 which on oxidation gives back (A). The compound (C) is a sodium salt of an acid. When (C) is treated with soda lime it yields an aromatic hydrocarbon (D) CeHs. Deduce the structures of (A), (B), (C) and (D) and write the sequence of reactions involved. Also write 2,4 DNP derivative of A. OR (A), (8), (© are three non-cyclic functional isomers of a carbonyl compound with molecular formula C4H8O. Isomers (A) and (C) give positive Tollen’s test whereas Isomers (8) does not give Tollen’s test but gives positive lodoform test. Isomers (A) and (B) on reduction with Zn(Hg)/HC! gives the same product D. Write the strictures of (A), (8), (C) and (0). S Kets WA A, ‘Out of (A), (B), and (C), which one is least reactive towards addition of HCN. 32. Explain: @) Sulphuric acid is not used during the reactions of alcohol with KI b) The treatment of alkyl chlorides with aqueous KOH leads to the formation of alcohols but in presence of alcoholic KGH, alkenes are the major products. ©) Grignard reagent should be prepared under anhydrous conditions. d) Tert-butyl chloride reacts with aq. NaOH by SN! mechanism while n-butyl chloride reacts by SN? mechanism. ©) Alkyl halides though polar are immiscible with water OR How are the following conversions carried out? ) Ethanol to propane nitrile 'b) Aniline to chlorobenzene ) 2-Chloro butane to 3, 4-dimethy! hexane d) 2-Methyl-1-propene to 2-chloro-2-methylpropane e) Ethyl chloride to propanoic acid 33 Write the products in the following reactions =i 2} ees = co cots odb) CBHSOC2HS: Ht mee i pp SOcHCHaON _Foc_, > F fs @CHMRCON Zech) _,g { y Ny = o s @C6HSOH B/C, e 2 & oo oR iN Om 4 explain oo a) The reaction of CHONa with (CHs)sC-Br gives 2-methy! propene and not (CHs)sC-OCH; b) Ortho nitrophenol |s steam volatile while para nitropheno! is not. © Alcohols act both as electrophiles and nucleophiles d) Phenol is more acidic than alcohol e) Propanol has higher boiling point than that of butane. 25.) Aw CHsl00H eee Ant* tb) Won frum ae eae dm My =X am tay e ~9 (toe) Sux* - pp - = R68) 20 1 mal