Sec: SR.

IIT_*CO-SC(MODEL-A,B&C) GTM-1 Date: 21-02-23

Time: 3 HRS JEE-MAIN Max. Marks: 300
KEY SHEET
PHYSICS
1 C 2 A 3 B 4 C 5 A
6 C 7 C 8 D 9 B 10 D
11 D 12 A 13 A 14 A 15 B
16 D 17 D 18 C 19 A 20 B
21 28 22 25 23 9 24 27 25 296
26 160 27 5 28 3 29 20 30 110

CHEMISTRY
31 C 32 C 33 C 34 B 35 B
36 B 37 A 38 D 39 B 40 A
41 B 42 C 43 A 44 A 45 D
46 D 47 A 48 B 49 A 50 B
51 2 52 7 53 50 54 4 55 73
56 62 57 7 58 8 59 2 60 5

MATHEMATICS
61 C 62 C 63 B 64 A 65 C
66 D 67 B 68 C 69 B 70 A
71 C 72 A 73 C 74 D 75 B
76 D 77 D 78 D 79 B 80 D
81 21 82 351 83 11 84 3 85 0
86 37 87 25 88 2 89 –3 90 16

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SOLUTIONS
PHYSICS

v p0 

1. Let OP = r. Angular speed about the origin =  =  , where vp0 = The component of
r 

velocity of P w.r.t. O perpendicular to OP.

v sin
  where r = b cosec 
r
v sin2

b
2. Time taken in moving distance S along smooth inclined surface with inclination  is 2S
ts 
g sin 
And time taken in moving distance S along smooth inclined surface with inclination
 is t  2S
 n ts
g  sin    cos  
r

Using the expression obtained above

1 1  1
 1   cot  cot  = 1 - 2  =  1   tanθ .
 n  n2 
3. The velocity of both the bodies m & M are equal. If the block M sticks to the wall, the block m
will continue to move which compresses the spring through x. The K.E. of the block m will be
converted into the potential energy of the spring as it compresses the spring.
Conservation of energy yields
1 2 1 2 m
mv  kx  x  v
2 2 k
1
where  M  m  v 2  E
2
2E 2mE
 v  x 
 M  m  M  m k
4. by conservation of linear momentum along the line of collision (along the line joining the centers of
two spheres), m1u sin   m2 v

v2  v1
Since, Coefficient of restitution for oblique collision, e  
u2  u1 along the line of collision

v m 2
e  1 
u sin  m2 3
5.
or …(i)

Here,
Substituting in Eq. (i), we have

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6. The gravitational potential at a point Q (OQ  x) is given by :
  3 1 x2  
 s  
 g R 2 
, when x <R 
V(x)  
 2 2 R  

 R 
 g s R   , when x >R 
 x 
The energy required to project the body, to a maximum altitude of 3R from its surface, is :
  9
m  VB R  VP   mg s R .
 x  8
 2 x  4R 

2T cos  hr  g h
7. h T  or T 
r g 2 cos  cos 
TW h cos  2 1
 1 
THg h2 cos 1  2
Putting the values, we obtain 1 : 6.5
8.

.
9. When two gases are mixed together then
Heat lost by the Helium gas = Heat gained by the Nitrogen gas

Box A Box B

1 mole N 2 1 mole He
Temperature = T 0 Temperature = 7 T 0
3

By solving we get
2
10. Potential energy of the particle U  k (1  e  x )

Force on particle F  dU

2
 k [e  x  (2 x )]
dx
2  x4 
F   2kxe  x  2kx 1  x 2   ...... 
 2 ! 
For small displacement F  2kx
 F   x i.e. motion is simple harmonic motion
11.   x, y, z   ax 2

E  2ax i
 

  2aLi L i  2aL
E.ds 2

3

s
x  L  
    
E.ds   2a(L  i  . L2 i  2aL3
s
x  L 

 E.ds = 0

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each of the other faces
  q
  E.ds  4aL3 
0
 q  4a 0 L3
12.

Solving, we get
Charge flown through
.
13. Here, both Assertion and Reason are correct, and reason is the correct explanation of assertion.
14. .
15.
i i
C C
L 2L 2L L

16. Z  (R ) 2  ( X L  X C ) 2 ;

R  10 , X L  L  2000  5  10 3  10 
1 1
XC    10  i.e . Z  10 
C
2000  50  10 6
V
Maximum current i0  0  20  2 A
Z 10
2
Hence irms   1 .4 A
2
and Vrms  4  1 .41  5.64 V
17. The equation of electric field occurring in -direction

Therefore, for the magnetic field in -direction

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D
18.    for  max , ' d ' will be min  2d 0  d 0  d 0
d
And for  min , ' d ' will be max  2d 0  d 0  3d 0
D D
  max  and  min 
d0 3d 0
D  1   2 D 
  max   min  1     
d0  3   3d 0 
19. Conceptual
20. Young’s modulus

Further,

Or
21. and R=ma  T=4ma

.
Hence acceleration of B w.r.t. ground is 2 2 m/s2.
22.

 M  L   M 4L 
( M  0)       
 4 3   4 6  L
x 
M 4
23. Let the frictional force be in the forward direction, then

and
and
For pure rolling,

For pure rolling, 𝑓𝐿=𝜇𝑀g
𝜇𝑀g⇒𝑎 3𝜇g amax  9m / s 2
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24. Slope of line
i.e., (i)
Similarly, for line
(ii)
Dividing Eq.(i) by Eq.(ii),
(iii)
From Eq.(iii),
25. As the tension in string Y is increased hence it’s frequency will increase. But as given, beat
frequency is decreased so , in the beginning nX  nY  4  300  nY  4  nY  296 Hz
26. The given circuit can be redrawn as follows
3
X
i

10
20 30 60

A
i
6
24 8 48 V

B
Y
1 i

24  8
Resistance between A and B  6
32
48
Current between A and B = Current between X and Y  i   8A
6
Resistance between X and Y  (3  10  6  1)  20 
 Potential difference between X and Y = 8  20 = 160 V.
1 1 1 1 (1  )  2  (1  4)  2  31  4
27. = +  = R  = R  =
f eq f1 f2 f1    4   2R
   2   
=   2   =  3 2 
1
f2    R   2R 
1 3(1   2 ) 2R R 20 5
= 1 – 2 = = = =
24 2R 24  3 12  3 36 9
28. As the current depends on the number of photons incident. Now by inverse square law,

or .
29. Current in R1=5/500=10mA and current in R2=10/1500=20/3 mA , hence the current in Zener
Diode=10/3 mA
30. Since there is no shunt resistance , I  9  60 A
6 1000
  540  106  G 
11000  G 9
RS 1000 11000 S
Since for half deflection , G     S  110
RS 9 11000  S

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CHEMISTRY
1

1 hc hc  2hc   0     2
31. mv 2max    v max   
2  0  m   0 
32. TI3 is T  I3
CSI3 is Cs  I3
Thallium shows T  state due to inert pair effect.
33. Conceptual
5 / 60
34. f  K f .m  0.2  1.86 
m Solvent
 M Solvent  0.775Kg
 Mass of water separate as ice = 1  0.775  0.225Kg
35. FeCl3  NH 4OH  Fe  OH 3  excess  inso lub le
NH OH 4

 Brown ppt.

36. A   2B  C
t=0 P0 0 0
t=t P0  x 2x x
t  0 2P0 P0
From question : P  2P0  P0
P
 P0  
3
and P   P0  x   2x  x
P  P0 3P  P
x 
2 6
1 P 1 o
P0
Now, K  .In A  .In
t PA t P0  x
1 P / 3
 .In
t P 3P  P

3 6
1 2P
 .In
t 3  P  P 
37. Fe has less positive value of E oM3 / M2 since Fe3  3d 5  is more stable than Fe 2  3d 6  . Also, the order
is Co (1.97) >Mn (1.57) > Fe (0.77).
50. Eu 2 :  Xe 4f 7 ;Ce3 :  Xe  4f 1
51. Conceptual
52. 
Ag 2CO3  s   C2 O 24  Ag 2C 2O 4  s   CO3
2

0.15
Initial  1000 0
500
 0.3M
0.035
Final 0.3  x x  1000
500
 0.23M  0.07 M

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K sp  Ag 2 CO 3 
2
 CO3   Ag 2 

Now, K eq    
K sp  Ag 2 C 2 O 4 
2
C 2 O 4   Ag  
2

0.07 K sp  Ag 2 CO3 
Or, 
0.23 2.3  10 11
 K sp  Ag 2CO3   7  1012
53. M.eq. of K 2 Cr2 O 7  M. eq. of FeC2 O 4
FeC 2 O 4  Cr2 O 72  
 Fe3  CO 2  Cr 3
0.288
V  0.02  6   3  1000
144
V = 50 mL.
54.  o eq NH OH    o eq NH Cl   o eq  NaOH    o eq NaCl
4 4

129.8  217.4  108.9  238.3ohm 1cm 2 mol 1

 9.532
Now,   eqo   0.04  4%
 eq 238.3
56. Given n = 3
T1  300;T2  1000
C p  23  0.01T
The relation between H and C p is
T2

H   nC p dT ….. (i)
T1

After putting all variable values in eq. (i)

1000

H 
300
  23  0.01T  dT
1000
 0.01T 2 
 3  23T 
 2  300
= 3 [16100+ 4550] = 3  20650 = 61950 J
= 61.95 kJ
= 62 kJ
60. O 2 ;O 2 ; O 2 ; N 2 ; N 22 
MATHS
61. Centre of the circle z  2  2 i.e., 2 lie on z 1  i   z 1  i   4 ,
Hence given line z 1  i   z 1  i   4 pass through the centre of circle i.e., intersect at two points.
 Number of solutions = 2.
62. A  A2  A 3  ....... and B  B 2  B 3  ..........

A 
2020
 A  B 
2019 2020
 B 2019

 A  B 3  2  A  B  A  B   22  A  B 

 A  B 2020  22019  A  B 

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2 3 4
1 1 1 1
63. p  q    r    s   t  
x x x x
3 1 3
1 1 1
x x x
1 2 3
 1 2 1 1 
x x x
3 4
1 2 1 3
x x
as x   , we get
1 1 1
p  1 1 1  4 .
1 1 3

64. 2    2  0 ………1

So,

6  3  2 2    

6 2  2  1 
5
  3  3   4 3 2
 2
 3 2
 3  3  1 
6    1
2
6 6
   3
 2
   1 3
   2
2

65.

2  a x 1 b x 1 
lim  
x 0 x  2 
66. e 
 e ln ab  ab  6
a,b   1,6 ,  6,1 ,  2,3 3,2
4 1
 P E   
36 9
x
1
67. Let P(X = x) =    , x  0
5
We have
4

5
68. a 1  7
a 8
"
69. f x  0
 f ' isinc.fn
To find : where g is nec. Inc
g is inc  g '  0

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1
 
2 1 2
 
 .f ' 2x  1  4x   f 1  x  2x   0
4 2
 x f '  2x  1  f ' 1  x   0
2 2

Case 1 : x  0  1 f '  2x  1  f ' 1  x 

2 2

2 2
 2x  1  1  x
 2  2 
 x   ,     ,     2
 3   3 
 2 
1   2  x   ,   ……….(3)
 3 


Case II : x  0   3 f ' 2x  1  f ' 1  x
2
  2

2 2
 2x  1  1  x
 2 2
 x   ,    4
 3 3
 2 
 3   4     ,0    6 
 3 
 g is inc in x   5    6 
 2   2 
 x    ,0    ,  
 3   3 
    
70. Let the angle between a and b is  /and a  b andc is 

a  b  .c  6  sin  cos   1
  
So  a , b , c are mutually perpendicular
 2 2
Req  a  c d  9

71. Let L1 , L2 , L3 be the mutually perpendicular lines and P  x0 , y0 , z0  be their point of concurrence. If
L1 cuts the x-axis at A(a, 0, 0), L2 meets the y-axis at B(0, b, 0) and C(0, 0, c)  L3 , then
x0  x0  a   y0  y0  b   z02  0

x02   y0  b  y0  z0  z0  c   0 
x0  x0  a   y02  z0  z0  c   0
Eliminating a and b from the equations, we get
x02  y02  z02  2cz0  0
72. t1t2  1
25
 t1  t2 
2

4
1
t1  , t2  2
2

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73.

74. We have,
f(x) = max{x2, (1 – x2), 2x(1 – x)}

 1  x  2 , for 0  x 1/ 3

f(x) = 2x 1  x  , for 1 / 3  x  2 / 3
 2
 x , for 2 / 3  x 1
Hence the area bounded by the curve y = f(x); x–axis and the lines x = 0 and x = 1 is given by
1 2
3 3 1

 1  x  dx   2x 1  x  dx    x dx
2
= 2

0 1 2
3 3

17
= sq. unit.
27
A 17
   A = 34 Sq. unit.
54 27

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75.

76.

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77.

  3
 
2
78. LHS = 3 sin 550  3 sin50  3 cos 2 250  1  cos 500
2
3
a  b 
2
79. f  0    2; g  2    3
80.

adjA
81. B=adj(A)  B  A  B  A A 1
A
1
B  3A 1, B 1  A
3
f x  
3

1 3
x  6 x 2  9x  9 
f '  x   x 2  4x  3
1
Global maximum at x = 6   72  72  54  9   21
3
82. A  1, 2,3, 4,5,5,7
Case I: All elements of set A satisfy f  x   x
In this case number of functions =1
Case II: 4 elements of set A satisfy f  x 
Total number of functions 7 C4 .2  7

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e.g ,: f  4   4, f  5  5, f  6   6, f  7   7
Now for elements 1, 2,3 we have two options mapping
Case III: 1 elements of set A satisfy f  x   x
For remaining six elements make groups of  3,3
6!
Hence, total functions 7 C1   2  2  280
3!.3!.2!
Hence, total functions are 351.
83.    
L1 : r  2i  6 j  34k  t 2i  3 j  10k , t  R
L : r   6i  7 j  7k     4i  3 j  2k  ,   R
2

P is a point on L1 and Q is a point on L2

PQ.L1  0
PQ.L2  0
3x 2dx
1
1
84. I2   , put t  x 3
 
x 3 3
3 0 e 2x
1
1 dt
 
3 0 e 2  t 
t

1
1 dt I
 
3 0 e 2  t 
t  1  3e
I2
PA 2 PB 2 PC 2
85.  ;  ; 
QA 3 QB 3 QC 3
 12 12  12
 A, B, C lies on circle with diameter ends  ,  ;  12, 12  , this circle radius is 13
 5 5 5
4
Required circle radius is 13
5
86.

87.

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88.

89. Let Y : y1 , y2 , y3 ,..., yn , W : w1 , w 2 , w 3 ,..., w n

Given, W  Y  k
Use  2  W    2 2  Y  ,   W     Y   k
90. f '  x   3x 2
1 1
f '  8   192 and g '  8   
f '  2 12

 f ' 8  f   '  8   192  12

1 1
 16

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