Sec: SR.

IIT_*CO-SC(MODEL-A,B&C) GTM-2 Date: 24-02-23

Time: 3 HRS JEE-MAIN Max. Marks: 300
KEY SHEET
PHYSICS
1 B 2 B 3 D 4 A 5 A
6 D 7 D 8 B 9 C 10 A
11 A 12 C 13 B 14 A 15 C
16 B 17 B 18 B 19 A 20 C
21 15 22 3 23 2 24 3 25 3
26 2 27 4 28 3 29 8 30 0

CHEMISTRY
31 B 32 D 33 A 34 A 35 D
36 D 37 D 38 D 39 A 40 C
41 D 42 A 43 D 44 C 45 C
46 D 47 A 48 B 49 D 50 A
51 3 52 4 53 5 54 1 55 5
56 9 57 8 58 9 59 6 60 6

MATHEMATICS
61 B 62 A 63 A 64 C 65 B
66 B 67 B 68 D 69 C 70 C
71 B 72 A 73 C 74 A 75 B
76 C 77 C 78 B 79 B 80 B
81 5 82 11 83 2 84 0 85 90
86 2 87 540 88 3 89 18 90 1

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 Narayana IIT Academy 24-12-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-2_KEY&SOL
SOLUTIONS
PHYSICS
1. Given velocity in x-direction
vx  2 m / s
Acceleration
E   e  8m   e  
a     . j  8 jm / s 2
m e m
d 1
 time, t   s
vx 2
1
Now y  .a y t 2
2
vy  u y  ayt
1
v y  0  8   4m / s
2
v y 4m / s
Now tan    2
vx 2 m / s
  tan 1  2
2. In the diagram balance all the forces

3.

0i
B
2 d


 4 107   100 
2  3.14  4
B  5  106 T (Southwards)
4.   MB  cos2  cos 1 
MB
  MB  cos 600  cos 00  
2
Torque  MB sin 60  2.sin 600
0

 3

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5.

3L
   B xdx
2L

5
  .Bl 2
2
6.  0  283v,   320 s 1
z  R2   X L  X C 
2

 7
 X L  XC 
  tan 1    45
0

 R 
7. Conceptual
 
2
I max  I1  I 2
8.
 
2
I min I1  I 2
Simplifying the required answer will be 2
9. Using
z2
En  13.6 2 ev
n
 3
2

E1  13.6 2 ev  122.4 ev
1
 3
2

E3  13.6 2 ev  13.6 ev
 3
E  108.8 ev
10. Conceptual
11. Vernier constant = Least count
1 MSD
= ,  10

1cm
1 MSD 
20
u2
12. H max   10m....... 1
2g
u2
Rmax   20m,   450  angle of projection 
g
13. I  I com  md 2
2
mL2  L 
  m 
6  2
2
I  ml 2
3

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14. Energy   TE 3R   TE 2 R
GmM  GmM 
  
3R  2R 
GmM
Energy 
6R
DV
15. P   B.
V
 6  108 N / m2
16. Alongbc w  0
Q  V  60 J
Along ab u  180  60  120 J
also Q  250 J
So
w  250  120  130 J
Hence wab  wbc  130  0  130 J
fR
17. CV 
2
CP  CV  R
fR  f 
CP  R  CV  R   R 1  
2  2
CP

CV
18.

2
T ,   3 

19.

1 mm 1
  v  0   kx 2
2
.
2 2m 2
20. Energy lost = Energy utilised for rise in temperature.
21.

F
ac 
z
F
FBD of 1Kg f  1
3

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f
 110    f  15 N
z
3R
22. x
8
23.

24. PT 2  C
 RT 2
.T  C
V
T 3V 1  C
Differentiating
1 dV 3
. 
V dT 1
y  y 
25. find &    2 fy0
t  t max
wave velocity  f 
26. Find equivalent resistance then distribute current.
 Am 
sin  
27. Use m   2 
sin  A / 2 
m  4
h
28. 
2mav
P m q
  82 2 3
 mP q P
29.

1 2 F
S at , a 
2 m
T  4t
K dv K
30. U  2 ,F    3
2r dr r
2
mv K K
 3  mv 2  2
r r r
Total energy = KE + PE = 0
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CHEMISTRY
31. Conceptual
Z
32. Vn 
n
n2
rn 
Z
Z2
En 
n2
33. PCl5  PCl3  Cl2
1 0 0
(1   )  
Law of conservation of mass
WPCl5  Weq m
M PCl5  (1   ) M eq
M PCl5 D
(1   )  
M eq d
pKa1  pKa2
34. ( pH )i  9
2
( pH ) f  3  2 log 3
 pH  6  2 log 3
CP , m
35. CP 
M
R
 CP , m 
(  1)
R
CP 
M (1)
36. According to slow step
r (t )  K 2  N 2O2  H 2 

Where K1 
 N 2O2 
 NO 
2

 N 2O2   K1  NO 
2

So, r (t )  K 2 K1  NO   H 2 
2

So, r (t )  K 2 K1  NO   H 2  K
2

1 d H2  1 d [ NO] d[ N 2 ]
    K [ NO]2 [ H 2 ]
2 dt 2 dt dt
Where K  K1 K 2
37. K GC*
C*  70
2 70
m    5  104
280 1000  0.5

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38. Leaving group ability  its stability
Weak base are good leaving group
39. Conceptual
40. d xy , d yz , d zx are also known as non-axial d-orbitals
41. (A) 3 p  3 p  3 p  3d  3d  3d (  bond strength)
(B) Ethanol  C2 H 5OH  < ethylene glycol
 CH 2  CH 2 
 
 | |   Glycerol
 OH OH 

 CH 2  CH  CH 2 
 
 | | |  (Viscosity)
 OH OH OH 

(C) XeO3 F2  XeF4  XeF2 (All have zero dipole moment)
(D) more electro positive element in 13th group is Al
42. Conceptual
43. Conceptual
44. dien is tridentate
w
45. 0.05  0.92   0.0821  300
28
w  0.0522
w%  17.46
46. ror  stability of C 
47. Conceptual
48. Conceptual
49. SN 2
50. Cannizaro followed by esterification
moles of NaOH
51. 
2
moles of NaOH
WH 2 SO4   98
2
(0.75  98)
 3
25
1 1000 4.9
52. 0.19   
75 86 x
x4
53. Conceptual
54.

55. Both 2nd and 4th group cations are precipitated in the presence of H 2 S  NH 4OH

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56. Mono halo product =1
Di halo products =2
Tri halo products=2
Tetra halo products=2
Penta and hexa are each one  total =9
57.

58. Conceptual
59.
OH

HO O
O

OH OH
Ascorbic acid
60. Conceptual

MATHS
61. f ( x)  x  3ax  3  a  1 x  1
3 2 2

f  ( x)  3x 2  6ax  3  a 2  1
 3( x - (a  1))( x - (a -1))
So f  ( x)  0  x  a  1 or a  1
 a  1 (2,4) if a  (3,3)
And a  1 (2,4) if a  (1,5)
 a  (1,3)
62. Apply by parts
 tan 4 x

 4  tan 3 x 
;0  x 
 3  2

 
63. f ( x )  b  2; x 
 2
 a
|tan x| 
(1 | cos x |)
b
;  x 
 2

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tan 4 x tan 4 h

4 tan 3 x 4 (  cos 3 h )
lim f ( x)  lim f    lim  
x

x
 3  
h 0 3
2 2
So, =1=b+2
B=-1
a
|tan x|
lim f ( x)  lim (1 | cos x |) b
 
x x
2 2
a
 |tan x|
lim (1  cos x) b

x
2
a
 cot h
lim(1  sinh) b
h 0
a a
cosh
 lim(1  sinh) b
e b
h0 sinh
a
1 e  b  2
b

a=0, b  1
a+b  1
64. f ( x)   x3   x  (tan x)sgn x
f (- x)  f ( x)
   x3   x  tan x sgn x
  x3   x  (tan x)(sgn x)
 2  x 2    x  0x  R
   0 and   0
 [a]2  5[a ]  4  0
and 6{a}2  5{a}  1  0
 (3{a}  1)(2{a}  1)  0
 [a ]  1,4 and {a}  1 / 3,1 / 2
1 1 1 1
 a  1  ,1  ,4  ,4 
3 2 3 2
35
Sum of value a 
3
dy
65.  1  xe yx
dx
dy
 e y  e y  xe x
dx
dy dt
Let e y  t  e y 
dx dx
dt
  t  xe x
dx
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dt
 t  xe x
dx
 Integrating function  e 
1dx
 ex
 Solution is t  e x    xe x  e x dx
x2
t  ex   C
2
x2
exy    C
2
 y 0  0  C  1
x2  x2 
e xy
1  y  x   x  ln 1  
2  2 
 
66. ‘P’ is orthogonal matrix. i.e., P.P  P .P  I
 
And Q 2023  PAPT PAPT     PAPT   
 PT Q 2023 P  PT  PA2023 P P
T

1 1  1 11 1  1 2 
Similarly A     A 2
  0 1 0 1   0 1 
 0 1     
1 3 
A3   
0 1
 1 2023 
A2023  
0 1 
 1 2023 
 PT Q 2023 P  
0 1 
 1 2023 
The inverse of PT Q 2023 P is 
0 1 
67. For multiple of 3, the sum of all digits should be divisible by 3.
So, number can be formed 0,1,2,3 (sum is 6 which is divisible by 3) or 0,2,3,4 (sum is 9which is
divisible by 3). 0 and 1 cannot be on highest digit in the number. Therefore, number of 4 digit
numbers
 2  3! 3  3!  30
 1  x2 
68. We have f ( x )   sin
1
 
log 4 x  sin  1

 4x 

Clearly domain of f ( x) is x  1 only, so f (1) 
2 
0  sin 1   
4 6
 
Hence range of f ( x)   
6
69. Draw the graph of f  x  .

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x x
70. f ( x)    f (t ) tan tdt   tan(t  x) dt
0 0
x x
f ( x)    f (t ) tan tdt   tan(t )dt
0 0
(Use f (a  x)  f ( x))
x x
f ( x)    f (t ) tan tdt   tan(t )dt
0 0
Differentiating w.r.t x, we have
f  ( x)   f ( x ) tan x  tan x
dy
 (tan x) y  tan x
dx
dy
 (tan x) y   tan x
dx
IF  e 
tan xdx
 elog sec x  sec x

Therefore, solution is y. sec x   secx tan xdx  c
Or y sec x   sec x  c
Or y  c cos x  1
Curve passes through (0,0)
 0  c  1 or c  1
 y  cos x  1
Therefore, the maximum value of y is 0.

71. We have
In S1 units place can have 1 or 3 or 5
4!
In S 2 it is 5C3  3   5C2  9  2  6   600
2!

72. Line passes through the points a1  (3, 2,1) a
 
a2  (3,6,5), b1  2iˆ  3 ˆj  kˆ
  
b1  2iˆ  ˆj  3kˆ, a2  a1  6iˆ  4 ˆj  4kˆ
   

 a2  a1  b1  b2 
SHORTEST DISTANCE   

b1  b2 
iˆ ˆj kˆ
 
b1  b2 2 3 1  10iˆ  8 ˆj  4kˆ
2 1 3
   
 
 a2  a1   b1  b2  60  32  16  108
 
b1  b1  100  64  16  180
108 108 18
S .D   
180 6 5 5

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73. Let the probability of the faces 1,3,5 or 6 p for each face.
Hence the probability of the faces 2 or 4 is 3p. therefore
1
4 p  6 p 1 p 
10
1
P(1)  P(3)  P(5)  P(6) 
10
3
P(2)  P(4) 
10
P( total of 7 with a draw of dice )  P(16,61, 25,52, 43,34)
1 1  3 1  3 1
 2    2    2  
 10 10   10 10   10 10 
2  6  6 14 7
  
100 100 50
74. Apply condition for externally touching circle.
2
 x  2  ( y  2) 2
75. The hyperbola    1
 4  2
3
a  2, b  2, e 
2
If D be the centre, then
DC  ae  6 and DA  a  2
b2
AC  6  2 and BC   1
a
1 3
Now area of ABC  ( AC )( BC )  1
2 2
76. Use r  a  0
r b  0
Where v  xiˆ  yjˆ  zkˆ
And x  iˆ  21
 A  P  A  B 1
77. For option (1) P     PA 
B P  B 3
 A  2
Similarly P    P  A   
 B  3
1 5
A P  
A 1  P   3  6 1
B
P    
 B  1  P  B  5 3
6
 A  P  A   A  B 
P 
 A B P  A  B

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1
PA 3
 
P  A  B 1  1  1
3 6 18
6 3
 
6  3 1 4
1 1

 
2
78. x 2  5 2  (20) 4 x  x 2  5  20 x 2
 x 4  5  2 5 x 2  2 5 x 2  x 4  5  x8  25
So,  8   8  50
79. If we write the elements of A + A, we can certainly find 39 distinct elements as
1  1,1  a 1 ,1  a 2 ,.......1  a 18 ,1  77, a 1  77, a 2  77,....a 18  77, 77  77 .
It means all other sums are already present in these 39 values, which is only possible in case when all
numbers are in A.P.
Let the common difference be ‘d’
77  1  19d  d  4
18
18
So,  a1   2a1  17d   910  68  702
i 1 2
80. PQ is focal chord.
Quadrilateral PTQR is square

PQ  TR
Area  8
2
Given 27 pqr  ( p  q  r )
3
81.
But using AM  GM
pqr
  ( pqr )1/3
3
 p  q  r (using (i) and (ii))
Also, 3 p  4q  5r  12
 sin  3x 2  4x  1 
   3x 2  4x  1  x 2  1
 3x  4x  1 
2

82. lim    2
x 1 2x  7x 2  ax  b
3

3x 2  4x  1  x 2  1
 lim  2
x 1 2x 3  7x 2  ax  1

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2  x  1
2

 lim  2
x 1 2x 3  7x 2  ax  b

So f  x   2x 3  7x 2  ax  b  0 has x  1 as repeated root, therefore f 1  0 and

f  1  0 gives a  b  5 and a  8
So, a  b  11

Let f  x   x  ax  bx  c
3 2
83.
f   x   3x 2  2ax  b  f  1  3  2a  b
f   x   6x  2a  f   2   12  2a
f   x   6  f   3  6
 f  x   x 3  f  1 x 2  f   2  x  f   3
 f  1  a  3  2a  b  a  a  b  3 .......1
 f   2   b  12  2a  b  2a  b  12 ....... 2 
From 1 and  2 
3a  15  a  5  b  2
 f  x   x 3  5x 2  2x  6
 f  2   8  20  4  6  2
84. According to given data
7

 x  62 
2
i
i 1
 20
7
7
   X i  62   140
2

i 1

So for any X i ,  Xi  62   140

2

 X i  50 i  1, 2,3,.....7
So no student is going to score less than 50.
85.

0 0 1
1
Area  x1 99  x1 1
2
x2 99  x2 1
1
  x1  99  x2   x2  99  x1  
2

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1
Area   x1  x2  99 
2
Area is an integer. Then both x1 and x2 are simultaneously either even or odd.
Hence,
10
C2 10 C2  2 10 C2  90
1
log x
86. Area bounded   ex
1/ e

1
1   log x  
2 1
 x2 x2 
    e  log x  
e  2  1  2 4 1
e e

 1 
1 
1 1   2 e2 
     e 2  
e  2   2e 4 

 
1 1 e 1
   
2e 2e 4 4e
e 5
 
4 4e
87. K  3! 3! 1  36
P  6! 3! 6!  6! 7  5040
88. Conceptual
4 4
Vice   10  r    10 
3 3
89.
3 3
dV 4 2 dr
  310  r 
dt 3 dt
2 dr
 4 10  r 
dt
dr
At r  5,50  4  225
dt
dr 50

dt 4  225 
1
 cm/min
18

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90. Let z  iy
 y 4  a1 y 3i  a3 y 2  ia3 y  a4  0
 y 4  a2 y 2  a4  0  1 and  a1 y 3  a3 y  0

 y  0 or y 2  a3   2 
a1
From (1) and (2)
a32 a
2
 a2 3  a4  0
a1 a1
a3 aa
  1 4 1
a1a2 a 2 a3

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