Sec: SR.

IIT_*CO-SC(MODEL-A,B&C) GTM-4 Date: 31-12-23

Time: 3 HRS JEE-MAIN Max. Marks: 300
KEY SHEET
PHYSICS
1 D 2 B 3 B 4 C 5 B
6 B 7 B 8 A 9 B 10 B
11 D 12 A 13 C 14 B 15 D
16 D 17 A 18 A 19 A 20 A
21 4 22 6 23 25 24 141 25 32
26 3 27 2 28 352 29 400 30 125

CHEMISTRY
31 C 32 D 33 A 34 A 35 B
36 B 37 B 38 C 39 B 40 A
41 C 42 B 43 A 44 D 45 C
46 D 47 C 48 D 49 B 50 D
51 5 52 5 53 5 54 44 55 3
56 10 57 6 58 5 59 25 60 3

MATHEMATICS
61 D 62 A 63 C 64 A 65 D
66 B 67 D 68 C 69 A 70 A
71 A 72 A 73 B 74 A 75 D
76 C 77 C 78 D 79 B 80 B
81 3 82 3 83 4 84 5 85 6
86 2 87 3 88 3 89 26 90 68

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 Narayana IIT Academy 31-12-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-4_KEY&SOL
SOLUTIONS
PHYSICS
V  VG 10  1
1. IG   100  104   R  900 
R R
R
2. m    . 4 r 2 dr   KR 4
0

GM G   KR 4  KR3G
V0   
r 2R 2

3. a m / s2
2
Velocity after t  2
v  m/ s
V2 2
Then aN  
R 1
aN   m / s
2 2

2
 
So net according aT      2 
2

2
2
aT   4
4

aT  1  4 2
2
So N = 4
1
T Vrms T' M
4. Vrms  ,   2
M Vrms T M'
1  2  1 1  1.25  1.5   1 1 
5.    1      1   
f  1  R1 R2  100  1   20 40 
1.5 1 1.5 7 1.5  6 9
 1     1   .
1 6 1 6 7 7
6. An   r 2
An    r0 n 2 
2

An   r02 n 4
A
So n n  4 n n
A1
7. No.of divisions = 50
Pitch = 0.5 mm
0.5 mm
Least count   10  m
50
1
8. 
LC
 LC 1
 
0 8L 2C 4

 0 .
4
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 Narayana IIT Academy 31-12-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-4_KEY&SOL
V V V
9.  6  6
2 4 4
V V V
   3
4 8 8
  
10. For stable equilibrium, m is parallel to B (i.e.,   00 ) and for unstable equilibrium, m is

antiparallel to B (i.e,   1800 ).
 
PE in the unstable equilibrium, U 2  m.B  m B cos 00  m B
 (0.40 J / T )  0.16T   0.064 J
Amount of work done to displace the solenoid from its stable to unstable orientation, i.e.,
U 2  U f  0.064 J   0.064 J   0.128 J
K A2  x 2 1  1/ n 2
11.  2
 2
 n2  1
U x 1/ n
12. Vrel  VF   VB
4
 9  3  VB
3
 VB  4.5 m / s
KQ
13. A) V  3R 2  r 2 
3 
2R
R KQ  2 R 2  11KQ 11V
At r  , V   3R   
2 2R 3  4  8R 8
KQ V
B) V  
2R 2
KQ R KQ V
C) E  3  
R 2 2R 2 2
KQ V
D) E  
4R 2 4
14. Here the diode is in forward bias. So we replace it by a connecting wire,

30  VA 0  VA 0  VA
  0
10 10 10
3V
3 A
10
VA  10 V
15. In photoelectric experiment, speed of fastest emitted electron is given by
1 2 hc
mvmax  w
2 
1 hc
Case-I : mv 2  w ……… (i)
2 
1 hc
Case-II : mv '2  w
2 3 / 4
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1 4hc
mv '2  w ……. (ii)
2 3
From eqn. (i) & (ii)
4 w
v '2  v 2 
3 3
4
Hence v '  v
3
16. If the insect is not sliding, mg sin   f

mg sin    mg cos 
3
 tan    
4

The height h from the bottom

h  R  R cos 
4 R
h  R  R     0.20 m .
5 5
3
17.  U  nCv  T  1   8.314  100  1247.1 J
2
18. Conceptual
19. In x direction : Applying conservation of momentum
mu  2mv cos 30
u u
v 0

2 cos 30 3
v u 2
Also e  0
 
u cos 30 3u 3
2
 e
3

d d
20. 
s u  10
u  10  s  u  1 s m / s
4
I0 I 1 I
cos 2 60  0     0
4
21. I
2 2  4  512
1 CC 
22. Loss   1 2  V 2
2  C1  C2 
1
  30  1012  (20) 2  6  109 J
2

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 Narayana IIT Academy 31-12-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-4_KEY&SOL
23. Conservation of linear momentum, pi  pf
2  4  2  1  m2  v2
m2 v2  6 ….. (1)
v v
The coefficient of restitution, e  2 1
u1  u2
v v
1  2 1  v2  5 ms 1
u1  u2
By (1), m2  5  6
 m2  1.2 kg
m v  m2 v2 2  1  1.2  5 8 25
vcm  1 1   
m1  m2 2  1.2 3.2 10
x  25
24. VL  VC  0
200
VR 
2
3
 4T  3  4T   r 
25.  P1   r   P2   
 r   r/22
 4T  8T
  P1   8  P2 
 r  r
T
 P2  8P1  24
r
v v
26. up  rel and down  rel
2R 2R

U ˆ U ˆ
27. F  i j  6iˆ  8 ˆj
dx dy
 a  3iˆ  4 ˆj
 ax  3
s x  6
2 6
t  2s
3
2
1 1  4 
28. u  0 Erms2
  8.8  1012     352  1013
2 2  2
29. Conceptual
hc
30. By photoelectric equation,    K max
2
1240
K max   1.25  1.25
500
2mK
r
eB
2mK
B  125  107 T .
er

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 Narayana IIT Academy 31-12-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-4_KEY&SOL
CHEMISTRY
31. Highest amount of heat will be released when equivalents of acid and base are equal i.e., complete
neutralization takes place.
1
32. For second order reactions t1/ 2 
K[A]0
 Half-life decrease with increase in concentration of reactants.
ln 2
For 1st order, t1/ 2  and is independent of concentration
k
dx
For zero order,  K (both are same)
dt
10 10 10
 P  100   P  200  P  10000
33.  0   10 180 ;  0   10 180 ;  0   10 180
 P A   P B   P C 
100 18 200 18 10000 18
 P   P   P 
 0   0   0 
 P  A  P  B  P C
P
Relative lowering of V.P. = 0  Xsolute .
P
35. (KE)1  hv1  hv0
(KE)2  hv 2  hv0
As (KE)1  2  (KE)2
 hv1  hv0  2(hv2  hv0 )
or hv0  2hv2  hv1
or v0  2v1  v1 .
= 2  (2  1016 )  (3.2  1016 ) = 0.8 1016 Hz  8 1015 Hz .
36. Number of milli equivalents of
MnO 4  0.02  3  250  15
Number of milli equivalent of
I2  0.11 250  25
Thus, here MnO 4 is limiting reagent
 Number of milli equivalents of I 2 formed = Number of milli equivalent of MnO 4
15
= 15 or number of equivalent of I 2 formed =  0.015
1000
0.015
 Number of moles of I 2 formed =  0.0075 .
2
38. Statement-I is correct: Pure aniline is colourless liquid
Statement-II is incorrect: Aniline becomes dark brown due to action of air and light (oxidation)
39. Cross Cannizzaro is simply redox process.
41.

5-amino-4-hydroxymethyl-2-nitrobenzaldehyde

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 Narayana IIT Academy 31-12-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-4_KEY&SOL
 2
43. 2Cu  Cu  Cu
The stability of Cu 2 (aq) rather than Cu  (aq) , is due to the much more negative  hyd H of
Cu 2 (aq) then Cu  (aq) , which more than compensates for the second ionization enthalpy of Cu.
48. During electrolysis of CuSO4 solution using Cu electrodes, the cell reaction is
 Cu   2e
Anode: Cu(S) 
Cathode: Cu  (aq)  2e   Cu(s)
The loss in weight of anode is equal to gain in weight of cathode.
50. Pentaamine chloride cobalt (III) chloride
[Co(NH 3 )5 Cl]Cl 2 [Co(NH3 )5 5Cl  ]2  2Cl 
Gives 3 ions in aqueous solution.
51. Given compound undergoes free radical bromination under given conditions, replacing H by Br.
C is chiral carbon.

(III) has two chiral centres and can have two structures.

(IV) has also two chiral centres and can have two structures.

It has plane of symmetry thus, achiral,

Thus, chiral compounds are five, I, IIIA, IIIB, IVB and V

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 Narayana IIT Academy 31-12-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-4_KEY&SOL
54. Weight of C in 0.792 gm CO2
12
=  0.792  0.216 .
44
0.216
% of C in compound = 100  43.90%  44 .
0.492
56. G 0  H0  TS0  54.07  103 J  298 10 J = 57.05 103 J
Also, G 0  2.303RT log K .
G 0 57.05 103
 log K  =  10 .
2.303 RT 5705
57. A decapeptide has nine peptide (amide) linkage as

Therefore, on hydrolysis, it will absorb nine water molecules.

Hence, total mass of hydrolysis product = 796  18  9  958
958  47
 Mass of glycine in hydrolysis product =  450 .
100
450
 Number of glycine molecule in one molecule of decapeptide=  6.
75
58.

59.
AB2  AB(g)  B(g)
500  
500  x x x
Require = 600 torr = 500 – x + x + x, x = 100 torr
P  P 100 100
K p  AB B   25 torr .
PAB2 400
60.

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 Narayana IIT Academy 31-12-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-4_KEY&SOL
MATHS
1
x 2 sin    2 x
 x x
61. lim .
1  x   e
1/ x
x 0 x
 1  x  2 4
 lim  x sin    2    0  2     
x 0
  x   e 1  x  11 x 2  ....  e  e e
 2 24 
62.

Median CD = 3r
1
2  3   2  4    2r 
2 2 2
3r 
2
36 r 2  18  32  4 r 2  40 r 2  50
5 5
r2  r
4 2
Diameter AB = 2r  5

2 x 1  sin x 
63. I  dx

1  cos 2 x

2 x 1  sin x   2   x 1  sin x  
x sin x
Using King and add 2I  

1  cos x 2
dx  4 

1  cos 2 x
dx
 
x sin x
I  2  f  x dx  I  4 dx
 0
1  cos 2
x

sin x
Using Kind and add 2 I  4  dx
0
1  cos 2 x
Put cos x  t
1
dt 
2 I  4   I  4  2.
1
1 t2 4
64.  f 1  3  g  3  1
 Point   3,1
1 1 1
g f  x    g  3   
f x  f  1  4
1
 Tangent  y  1   x  3  x  4 y  1  0 .
4
65.  f   x   ax  x  1  f   2  6  a3
2
3x
f   x   3  x2  x   f  x   x3  C
2
  3
f x   x2  x  
 2
f  2  2  C  0 .

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 Narayana IIT Academy 31-12-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-4_KEY&SOL
66.

Point A be the intersection of AC & AB i.e.  4,5  & B be the intersection of AB & BC i.e.  3, 2 
 1 7
Mid–point of AC will be   , 
 2 2
7
7  1
Equation of diagonal BD is y   2  x    7 x  y  0
2 1  2
2
23 2  ax  by1  c1 
Distance of A from diagonal BD  d   50d 2   23   d  1 
50  a 2  b 2 
50 d 2  529 .

67. Let F, H and B be the sets of television watchers who watch football, Hockey and Basketball
respectively.
Then, according to the problem, we have
n U   500, n  F   285, n  H   195,
n  B   115, n  F  B   45,
n  F  H   70, n  H  B   50,
And n  F   H   B   50,
Where U is the set of all the television watchers.
Since, n  F   H   B   n U   n  F  H  B 
 50  500  n  F  H  B   n  F  H  B   450
We know that,
n  F  H  B  n  F   n  H   n  B  n  F  H   n  H  B  n  B  F   n  F  H  B
 450  285  195  115  70  50  45  n  F  H  B 
 n  F  H  B   20
Which is the number of those who watch all the three games. Also, number of persons who watch
football only  n  f  H   B 
 n  F   n  F  H   n  F  B  n  F  H  B
 285  70  45  20  190
The number of persons who watch hockey only
 n  H  F   B
 n  H   n  H  F   n  H  B   n  H  F  B   195  70  50  20  95
And the number of persons who watch basketball only
 n  B  H   F 
 n  B   n  B  H   n  B  F   n  H  F  B   115  50  45  20  40
Hence, required number of those who watch exactly one of the three games
 190  95  40  325 .

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 Narayana IIT Academy 31-12-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-4_KEY&SOL
68.  The image of ‘z’ in the line y  x is i z .
i z i  
 The image of the given curve is arg  
 i z 1  4
 z 1 
 arg  
 z i  4
z 1  
  arg    arg  z    arg  z  
 z i  4
 z i     z1   z2  
 arg    arg     arg    .
 z 1  4   z2   z1  
69. x  sin 1  sin10   3  10
y  cos 1  cos10   4  10
 yx .
70. I ) Sum of perimeters = 3  24  12  6      
 
 1 1   1 
72 1   ........   72   144
 2 4  1
 1 
 2
II) log 2  a  b  c  d   4
  a  b  c  d   24
abcd 4
   a  b  c  d   a  b  c  d  8 .
4
1 1  x  1  y 
A  x  A  y   1  x  1  y  
1
71.  
  x 1   y 1 
1 1  xy  ( x  y 
 1  xy  ( x  y )   
( x  y) 1  xy 
 x y 
1 
1  xy 
1
 x y 
 1      A z 
 1  xy    x  y 1 

 1  xy
 
72. The given equation can be written as
 x 2     1 x  5  0
  ,  are the roots of this equation.
 1 5
    and  
 
  4
But, given  
  5
2  2 4
 
 5
   1
2
10

   
2
 2 4  2
 4
  
 5 5 5

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   1
2
 10 4
    2  12  1  4
5 5
  2  16   1  0
It is a quadratic in  , let roots be 1 and 2 , then 1  2  16 and 12  1
1 2 12  22  1  2   212 16   2 1
2 2

      254 .
2 1 12 12 1
73. A  1, 2,3, 4,5,6,7
Case–I: When exactly 4 values follows f  i   i
1 1
C4  3!    70
7

 2! 3! 
Case–II: When exactly 5 values follows f  i   i
7
C 5  1  21
Case–III: When all 7 values follows f  i   i
Number of function = 1
Total functions = 70 + 21 + 1 = 92.
74.     
Let l  0iˆ  0 ˆj  0kˆ   aiˆ  bjˆ  ckˆ   aiˆ  bjˆ  ckˆ 
iˆ ˆj kˆ
 aiˆ  bjˆ  ckˆ  1 2 3  4iˆ  5 ˆj  2kˆ
2 2 1


 l   4iˆ  5 ˆj  2kˆ and 
l1 1    iˆ   11  2  ˆj   7  3  kˆ
P is intersection of l and l1
 4  1   , 5   1  2  , 2   7  3
By solving there equation   1, P  4, 5, 2 
Let Q  1  2 , 2 ,1   
Then, PQ   5  2 , 5  2 ,1   

 
PQ. 2iˆ  2 ˆj  kˆ  0  2  4  4  1    0
1  7 2 10 
 Q , , 
9  9 9 9 
7 2 10
                y  .
5
 9 9 9  9
75. Let DC  CB  BA  AD  k
 Coordinates of B are  k , k  ,
Which lie on y x
 k  k
 k  2
 BC  k   2
Also, let CG  GF  FE  EC  k1
 Coordinates of F are   2  k1 , k1  ,

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Which lie on y   x
Then k1    2
 k1 
 k12   4   2 k1
Or k12   2 k1   4  0

2   4
 4 4  k1 1 5
 k1  Or 
2  2
2
FG 5 1
Or 
BC 2
2 4  2 4 8
sin 2 sin 2 sin 2 sin 2 sin 2 sin 2
76. S 7  7  7  S 7  7  7
 2 4  2 4
sin 2 sin 2 sin 2 sin 2 sin 2 sin 2
7 7 7 7 7 7
  2 4    2 4 
S  4  cos 2  cos 2  cos 2   4  1  2 cos  cos  cos 
 7 7 7   7 7 7 
 1
 4 1  2    5 .
 8
4 1
77. Let X denote the number of aces. Probability of selecting an ace, P  
52 13
1 12
Probability of not selecting an ace, q  1  
13 13
 1   12  24
P  X  1  2       
 13   13  169
1 1 1
P  X  2   
13 13 169
24 2 2
Mean  Pi X i    .
169 169 13
 
20
78. Let 8  3 7  I  f, where f = fractional part and I = integral part

 
20
Also let 8  3 7  g then 0  g  I

   8  3 7  
 2 820  20 C2.818. 3 7    
20 20 2 20
Here I  f  g  8  3 7 
 ......  20 C20 3 7

 I  f  g = even integer
But 0  f  g  2
So, I  1  even Integer  f  g  1
 I  odd Integer
79. Possible favourable outcomes will be getting by, either all outcomes are positive or any two are
negative.
3 1
Now, p  P  All positive   
6 2
2 1
q  p  both negative   
6 3
So, required probability
5 2 3 4 1
1 1 1 1 1 521
 C5    5C2      5C4     
5
.
2  3  2  3   2  2592
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80. Arranging the data in ascending order of magnitude, we obtain
Height (in 150 152 154 155 156 160 161
cm)
Number of 8 4 3 7 3 12 4
students
Cumulative 8 12 15 22 25 37 41
frequency
Here, total number of items is 41, which is an odd number.
th
41  1
Hence, the median is  21st item.
2
From cumulative frequency table, we find that median i.e., 21st item is 155.
81. Putting x = y = 1, we get f 1  2
Putting y = 1, f  x   x  1
 f 1  x   x  1
 f  x  f 1  x    x 2  1  f  2  f 1  2   22  1  3
xdy  ydx
82.  dy
y2
x
   d     dy
 y
x
   yc
y
At x  1, y  1  c  2 .
3
x  3   y  2
y
y2  2 y  3  0
 y2  3y  y  3  0
 y  y  3   1  y  3  0
  y  1 y  3  0
 y3  y  0 .
 2 4  x3 4 x 
83. f  x   a  x    f  x   a     b passes through  0,0  and 1, 2 

 3 3 3 

-2 O
2

 b  0, a  2
2x 2
f  x 
3
 x  4
  2
2

Required area   2  4 k 4.
2 2

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1  7 cos x
2
sec 2 x 1
84. We have  7 2
dx   7
dx  7  dx
sin x cos x sin x sin 7 x
I    sin x   sec2 x  dx  7   cos ecx  dx integrating by parts
7 7

    
I II

tan x cos x dx
  7 tan xdx  7 
 sin x   sin x   sin x 
7 8 7

tan x cos x dx tan x

  7  7  C
 sin x   sin x   sin x   sin x 
7 7 7 7

Hence, g  x   tan x
So, g   x   sec2 x
And g   x   2sec2 x tan x

 g   0   1 and g     4
4
 
Hence, g   0   g     1  4  5 .
4
85. Given

R
P C  P  
C  C 
Now, P   
 R  P A P R   P B P R   P C P R 
           
 A B C 
1 

3   4
 0.4   6
1 4 1 5 1 
   
3 10 3 10 3    4 
86. Let P divides AL in the ratio  :1
P divides DB in the  :1
  
Let AB  a , BC  b

 b 
a   
 3    a   b  
 1  1
   3;   3

BD 4
  2
PQ 2

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87.
H h H
  r
H  h R
r R H
 r 2h  R2
hH  h
2
 V  
3 3H 2

dV  R 2   R2
   
  H  h  H  3h 
2
 H  h  2 h H  h 
dh 3 H 2  3H 2
H H
 Vmax when h    3 .
3 h
88. Required circle
x2 y2

 1   x2  y 2  0
16 9

Using x2 coefficient  y 2 coefficient.
1 1 7
     
16 9 288
288
Required circle x 2  y 2  .
25
89. In the given figure there are 8 squares and we have to place 6X’s this can be done in
8.7
8
C6  8C2   28 ways
1.2
But these include the possibility that either headed row or lowest row may not have any X. These
two possibilities are to be excluded.
 Required number of ways = 28 – 2 = 26.

90. Now, A  adjA  A I

x 3 2
Now, A1 y 4
2 2 z
 x  yz  8  3  z  8   2  2  2 y 
 xyz   8 x  4 y  3z   28
 60  20  28  68
From equation (i), A  adjA   68I .

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