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    This document provides an overview of an organic chemistry course covering several topics: [1] types of organic reactions and properties of reactive intermediates; [2] methods for determining reaction mechanisms; [3] factors that influence reaction selectivity and pathways; [4] experiments to study reaction mechanisms; [5] concepts of nucleophilicity and electrophilicity; [6] substitution and elimination reactions; [7] applications of oxidation and reduction reactions and reagents; [8] stereochemistry in organic reactions. The course also lists two primary textbooks and three references used.

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    This document provides an overview of an organic chemistry course covering several topics: [1] types of organic reactions and properties of reactive intermediates; [2] methods for determining reaction mechanisms; [3] factors that influence reaction selectivity and pathways; [4] experiments to study reaction mechanisms; [5] concepts of nucleophilicity and electrophilicity; [6] substitution and elimination reactions; [7] applications of oxidation and reduction reactions and reagents; [8] stereochemistry in organic reactions. The course also lists two primary textbooks and three references used.

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    © All Rights Reserved
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    17 views1 page

    CH221 Syllabus

    Uploaded by

    Yash Vardhan Srivastava
    This document provides an overview of an organic chemistry course covering several topics: [1] types of organic reactions and properties of reactive intermediates; [2] methods for determining reaction mechanisms; [3] factors that influence reaction selectivity and pathways; [4] experiments to study reaction mechanisms; [5] concepts of nucleophilicity and electrophilicity; [6] substitution and elimination reactions; [7] applications of oxidation and reduction reactions and reagents; [8] stereochemistry in organic reactions. The course also lists two primary textbooks and three references used.

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    CH 221 Organic Chemistry (3 1 0 8)

    Introduction to types of organic reactions; Introduction and application of electronic and field
    effects to study structure and stability of reactive intermediates- carbocations, carbanions,
    free radicals, carbenes, arynes and nitrenes; Methods of determining organic reaction
    mechanism-thermodynamic and kinetic requirements, transition state theory, Hammond
    postulate related to kinetic analysis; Reactivity vs. selectivity principle, Curtin-Hammett
    principle, kinetic vs. thermodynamic control reaction; Experiment to study reaction
    mechanism-Isotope effects, substituent effects, Hammett linear free energy relationship, Taft
    equation; Introduction to nucleophilicity, electrophilicity,Acidity, Basicity of organic reactants;
    Nucleophilic substitution reactions; Elimination reactions; Idea of IUPAC terminologies and
    recommendations for naming organic reaction mechanisms; Stereochemistry in organic
    reactions; Electrophilic and nucleophilic addition reaction to C=C; Nucleophilic addition
    reaction to C=O; Preliminary idea of radical reactions; Application of Oxidation reactions and
    reagents- Swern oxidation, Kornblum oxidation, Pyridinium Chloro Chromate, Dess-Martin
    periodinane, DCC oxidation, osmium tetroxide, DDQ, selenium dioxide, oxidation by nitroso
    radicals Fremy's salt and TEMPO; Application of Reduction reactions and reagents- Birch
    reduction, Meerwein-Ponndorf-Verley reduction, NaBH4, LiAlH4, NaBH3CN, DIBAL,
    Rosenmund reduction, Cannizzaro reaction, Wolff-Kishner reaction, Lindlar catalyst.

    Text Books:
    1. E. V. Anslyn and Dennis A. Dougherty, Modern Physical Organic Chemistry, 1st Ed.
    University Science Books, California ,2006.
    2.F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Structure and Mechanisms
    (Part A and B),Kluwer Academic/ Plenum Pub.,2000

    References:
    1. P. Sykes, A guide to mechanism in Organic Chemistry, 6th Ed, Pearson Education ,2004.
    2. M. B. Smith and J. March, Advanced Organic Chemistry, 6th Ed., John Wiley and Sons, Inc
    2007.
    3. D. Nasipuri, Stereochemistry of Organic Compounds ,Wiley, 1994.

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