SOLUTI

ON
SET1

1.Thevolumeoccupi
edbyasi
ngl
egasinamixt
ureatt
hesamet
emper
atur
eand
pressur
eisref
err
edtoast
hesi
ngl
e-gasvol
ume.
a)Absol
utev
olume
b)Par
ti
alv
olume
c)Tot
alv
olumeofagasmi
xtur
e
d)Noneoft
hement
ioned
Answer
:b
2.Thepressur
ethatasi
ngl
ecomponenti
nagaseousmi
xtur
ewouldexer
tifi
texi
sted
aloneint
hesamev ol
umeasthemixt
ureandatt
hesametemper
atur
easthemixturei
s
refer
redt
oas.
a)Absol
utepr
essur
e
b)Par
ti
alpr
essur
e
c)Tot
alpr
essur
eofagasmi
xtur
e
d)Noneoft
hement
ioned
Answer
:b
3._
___
___
___
___
____obey
sRaoul
t’
slawi
nal
lst
agesofconcent
rat
ion.
a)I
deal
Sol
uti
on
b)Non-
Ideal
sol
uti
on
c)Real
Sol
uti
on
d)Noneoft
hement
ioned
Answer
:a
4.Whentwoper
fectsol
uti
onswi
thv
olumeVeachar
ecombi
ned,
Whati
sthev
olumeof
thesol
uti
onasaresul
t?
a)V
b)2V
c)Gr
eat
ert
han2V
d)Lesst
han2V
Answer
:b
5.Theheatofsol
uti
onormi
xi
nghasanegat
ivesi
de.
a)Heatofsol
uti
on
b)Heatofdi
ssol
uti
on
c)Heatofr
eact
ion
d)Heatofmi
xi
ng
Answer
:b
6.Asol
uti
onmadeupofnumer ouscomponentsi
nwhicheachcomponent
’spr
oper
tyi
s
thewei
ght
edsum ofi
tssepar
ateproper
ti
es.Theansweri
s
a)I
deal
Sol
uti
on
b)Non-
Ideal
sol
uti
on
c)Real
Sol
uti
on
d)Noneoft
hement
ioned
Answer
:a
7.Whati
sanexampl
eofcamphori
nN2gas?
a)Sol
i
dingassol
uti
on
b)Gasi
ngassol
uti
on
c)Sol
i
dinl
i
qui
dsol
uti
on
d)Li
qui
dingassol
uti
on
Answer
:a
8.Whathappenswhenasol
utecr
yst
ali
saddedt
oasuper
sat
urat
edsol
uti
on?
a)I
tbecomesacol
l
oidal
sol
uti
on
b)Thesol
utedi
ssol
vesi
nthesol
uti
on
c)Thesol
uti
ondesat
urat
es
d)Thesol
utepr
eci
pit
atesoutoft
hesol
uti
on
Answer
:d
9.Whi
choft
hef
oll
owi
ngopt
ionsi
snotav
iabl
eopt
ion?
a)Br
ass
b)Br
onze
c)Hy
drat
edsal
ts
d)Aer
ateddr
inks
Answer
:d
10.Whatmakesasol
uti
on?
a)Sol
uteandsolvent
b)Sol
uteandsolute
c)Sol
ventandsolvent
d)Noneoftheabov e
Answer:a)

SET2
Q.1.Whichofthef
oll
owingf
luor
idei
susedasratpoi
son?
(a)CaF2
(b)KF
(c)NaF
(d)MgF2
Answer(c)Sodi
um f
luor
idei
susedasratpoi
son.

Q.2.Vapourpr
essur
eofapur
eliqui
dXi s2atm at300K.I
tislower
edto1atm on
dissol
vi
ng1gofYi n20gofl
iquidX.I
fmolarmassofXi s200,whati
sthemolarmass
ofY?
(a)20
(b)50
(c)100
(d)200

Answer
Answer
:(b)50

Q.
3.Mostoft hepr ocessesi
nourbodyoccuri
n
(
a)soli
dsolution
(
b)li
quidsolution
(
c)gaseoussol uti
on
(
d)coll
oidalsoluti
on

Answer
(b)Al
mostal
lthepr
ocessesi
nourbodyoccuri
nli
qui
dsol
uti
on.

Q.
4.Thet erm homogenousmi xtur essi
gni
fiesthat
(
a)it
scomposi t
ionisunifor
mt hroughoutthemi xture.
(
b)itspropert
iesar euni
formthroughoutthemi xture.
(
c)bothcomposi t
ionandpropertiesareunifor
m
t
hroughoutthemi xture.
(
d)neit
hercomposi
ti
onnorpr
oper
ti
esar
euni
for
m
t
hroughoutt
hemixt
ure.

Answer(
c)Inhomogeneousmi
xtur
escomposi
ti
onandpr
oper
ti
esbot
har
euni
for
m
thr
oughoutthemi
xtur
e.

Q.5.Whichoft hefol
lowi
nguni
tsi
susef
uli
nrel
ati
ngconcent
rat
ionofsol
uti
onwi
thi
ts
vapourpressure?
(
a)Mol efracti
on
(
b)Par t
spermi l
l
ion
(
c)Massper centage
(
d)Mol al
ity

Answer
(a)Mol
efr
act
ion

Q.6.Whi chofthefoll
owingmi xt
ureis(
are)cal
l
edsol
uti
on?
(
i)wat er+ammoni a( i
i)water+acetone
(
ii
i)acetone+al cohol(iv
)hexane+wat er
(
a)( i
),(i
i)and(i
ii
)(b)(i
),(i
ii
)and(iv
)
(
c)( i
)and( iv
)(d)(i
i)and(ii
i)

Answer
(a)Hexanei
snotwat
ersol
ubl
e,hencesol
uti
oni
snotf
ormed.

Q.
7.Apl antcel lshri
nkswheni
tiskepti
na
(
a)hypot onicsolution
(
b)hy per
t onicsolution
(
c)isotonicsol uti
on
(
d)pur ewat erAnswer

Answer
(b)hy
per
toni
csol
uti
on

Q.
8.Therel
ati
veloweringinvapourpressur
eisproporti
onaltotherati
oofnumberof
(
a)sol
utemoleculestosolventmolecul
es
(
b)sol
ventmoleculestosolutemolecul
es
(
c)sol
utemoleculestothetotalnumberofmoleculesinsoluti
on
(
d)sol
ventmoleculestothetotalnumberofmoleculesinsoluti
onAnswer

Answer
(c)sol
utemol
ecul
est
othet
otal
numberofmol
ecul
esi
nsol
uti
on
Q.
9.Whichofthefol
l
owi
ngi
saquant
it
ati
vedescr
ipt
ionoft
hesol
uti
on?
(
a)Dil
ute
(
b)Concentr
ated
(
c)Satur
ated
(
d)Molar

Answer(
d)Dil
ute,concentrat
edandsatur
atedt
ermsar
equal
it
ati
vemet
hodsof
descr
ipt
ionofconcentrat
ionofsol
uti
onwhereasmol
arormol
ari
tyi
squant
it
ati
ve
method.

Q.
10.Whenasol uteispr
esenti
ntr
acequant
it
iest
hef
oll
owi
ngexpr
essi
oni
sused
(
a)Gram permil
li
on
(
b)Mill
i
gram per
cent
(
c)Microgr
am percent
(
d)Part
spermi l
l
ion

Answer
(d)

Q.11.Thelawwhi chindi
catest
her
elat
ion’
-
hipbet
weensol
ubi
l
ityofagasi
nli
qui
dand
pressur
ers
(a)Raoul
t’
slaw
(b)Henry’
slaw
(c)Loweri
ngofv apourpressur
e
(d)Van’
tHof fl
awAnswer

Answer
Answer
:(b)Henr
y’sl
aw

Q.
12.Mol
ari
tyofl
i
qui
dHCl
wil
lbe,
ifdensi
tyofsol
uti
oni
s1.
17gm/
cc
(
a)36.
5
(
b)32.
05
(
c)18.
25
(
d)42.
10

Answer
(b)

Q.13.1M,2.5l
itr
eNaOHsol
uti
oni
smi xedwithanot
her0.
5M,
3li
tr
eNaOHsol
uti
on.
Thenfindoutt
hemolar
it
yofr
esul
tantsol
uti
on
(a)0.
80M
(b)1.
0M
(c)0.
73M
(d)0.
50M
Answer
(c)

Q.14.Howmuchoxygeni
sdi
ssol
vedin100rnLwat
erat298Ki
fpar
ti
alpr
essur
eof
oxygenis0.
5at
m andK=1.4×10-3mol
/L/
atm?
(a)22.4mg
(b)22.4g
(c)2.
24g
(d)2.24mg

Answer
Answer
:(d)2.
24mg

Q.
15.AnXmol al
sol
uti
onofacompoundi
nbenzenehasmol
efr
act
ionofsol
uteequal
t
o0.2.Thev
alueofXis
(
a)14
(
b)3.2
(
c)1.4
(
d)2

Answer
(b)

Q.16.Themol
ari
tyoft
hesol
uti
oncont
aini
ng7.
1gofNa2SO4i
n100ml
ofaqueous
solut
ioni
s
(a)2M
(b)0.
5M
(c)1M
(d)0.
05M

Answer
(b)

Q.17.Part
ialpressur
eofasol
uti
oncomponenti
sdi
rect
lypr
opor
ti
onal
toi
tsmol
e
fr
acti
on.Thisi sknownas
(
a)Henr y’
slaw
(
b)Raoul t
’slaw
(
c)Di st
ri
butionlaw
(
d)Ost awald’sdil
uti
onl
aw

Answer
Answer
:(b)Raoul
t’
slaw

Q.
18.3molesofPand2mol esofQar emixed,whatwil
lbet
hei
rtotalvapourpr
essur
e
i
nthesol
utioni
fthei
rpar
ti
alvapourpr
essuresare80and60tor
rrespecti
vely
?
(
a)80torr
(
b)140torr
(
c)72t
orr
(
d)70t
orr

Answer
Answer
:(c)72t
orr

Q.19.Sprinkli
ngofsalthelpsincl eari
ngthesnowcoveredroadsi
nhi
l
ls.The
phenomenoni nvol
vedint hepr ocessis
(a)l
ower i
ngi nvapourpressur eofsnow
(b)depressioninfr
eezingpoi ntofsnow
(c)melti
ngofi ceduet oincreasei ntemperat
urebyput
tingsal
t
(d)i
ncreasei nfr
eezingpoi ntofsnow

Answer
Answer
:(b)depr
essi
oni
nfr
eezi
ngpoi
ntofsnow

Q.
20.Whi chofthefol
lowi
ngsol
uti
onsshowsposi
ti
vedev
iat
ionf
rom Raoul
t’
slaw?
(
a)Acetone+Ani l
ine
(
b)Acetone+Et hanol
(
c)Water+Ni tr
icacid
(
d)Chlorofor
m +Benzene

Answer
Answer
:(b)Acet
one+Et
hanol

Q.
21.Thesy stem thatf
ormsmaxi
mum boi
l
ingazet
ropei
s
(
a)Acetone-chlor
oform
(
b)ethanol
-acetone
(
c)n-
hexane- n-
heptane
(
d)carbondisulphi
de-acet
one

Answer
Answer
:(a)Acet
one-
chl
orof
orm

Q.22.Asolut
ioncont
aini
ng10.2ggl
ycer
ineperlit
rei
sisot
oni
cwi
tha2%sol
uti
onof
glucose.Whati
sthemolecul
armassofglycer
ine?
(a)91.8g
(b)1198g
(c)83.9g
(d)890.3g

Answer
Answer
:(a)Acet
one-
chl
orof
orm

Q.23.Whatweightofgl
ycer
olshoul
dbeaddedt
o600gofwat
eri
nor
dert
oloweri
ts
fr
eezingpoi
ntby10°C?
(
a)496g
(
b)297g
(
c)310g
(
d)426g

Answer
Answer
:(b)297g

Q.
24.Theosmot i
cpressureofasoluti
oncanbei
ncr
easedby
(
a)incr
easingthev ol
ume
(
b)incr
easingthenumberofsol ut
emol ecul
es
(
c)decreasingthetemperatur
e
(
d)remov i
ngsemi per
meabl emembr ane

Answer
Answer
:(b)i
ncr
easi
ngt
henumberofsol
utemol
ecul
es

Q.
25.Forcarryingr everseosmosi
sfordesal
i
nat
ionofwat
ert
hemat
eri
alusedf
or
maki
ngsemi per meabl emembraneis
(
a)potassium nit
r ate
(
b)parchmentmembr ane
(
c)cel
luloseacet ate
(
d)cel
l membr ane

Answer
Answer
:(c)cel
l
uloseacet
ate

Q.26.Whatwi
llbet
hedegr
eeofdi
ssoci
ati
onof0.
1M Mg(
NO3)
2sol
uti
oni
fvan’
tHof
f
fact
oris2.
74?
(
a)75%
(
b)87%
(
c)100%
(
d)92%

Answer
Answer
:(b)87%

Q.
27.Atequili
bri
um therateofdi ssociat
ionofasol
i
dsol
utei
nav
olat
il
eli
qui
dsol
venti
s
(
a)lesst
hant herateofcrystal
lisati
on
(
b)great
erthanther at
eofcr ystall
isat
ion
(
c)equaltotherateofcrystall
isati
on
(
d)zer
o

AnswerAnswer
:(c)equal
tot herateofcr
ystal
l
isat
io
Q.28.I
f2gm ofNaOHi spresentis200ml ofi
tssolut
ion,
itsmol
ari
tywi
l
lbe
(a)0.
25
(b)0.
5
(c)5
(d)10

Answer
Answer
:(a)0.
25

Q.
29.Theat
mospher i
cpol
l
uti
oni
sgener
all
ymeasur
edi
ntheuni
tsof
(
a)masspercentage
(
b)vol
umeper centage
(
c)vol
umefraction
(
d)ppm

Answer
Answer
:(d)ppm

Q.30.A5%soluti
onofcane-sugar(
molecul
arwei
ght=342)i
sisot
oni
cwi
th1%sol
uti
on
ofsubstanceA.Themolecul
arweightofXi
s
(a)342
(b)171.
2
(c)68.
4
(d)136.
8

Answer
Answer
:(c)68.
4

Q.31.234.
2gm ofsugarsyr
upcont
ains34.
2gm ofsugar
.Whati
sthemol
al
concentr
ati
onofthesol
uti
on.
(a)0.
1
(b)0.
5
(c)5.
5
(d)55

Answer
Answer
:(b)0.
5

Q.32.H2Si
satoxi
cgasusedi
nqual
i
tat
iveanal
ysi
s.I
fsol
ubi
l
ityofH2Si
nwat
eratSTPi
s
0.195m.whati
stheval
ueofKH?
(a)0.
0263bar
(b)69.
16bar
(
c)192bar
(
d)282bar

Answer
Answer
:(d)282bar

Q.
33.At
omicmassi sequalto
(
a)numberofelect
ronsofanatom
(
b)sum oft
henumber sofel
ectronsandpr
otonsofanatom
(
c)sum oft
henumber sofneutr
onsandprotonsofanat
om
(
d)noneofthese

Answer
Answer
:(b)sum oft
henumber
sofel
ect
ronsandpr
otonsofanat
om

Q.34.Henr
y’slawconst
antformolal
i
tyofmethanei
sbenzeneat298Kis4.
27×
5
10 mm Hg.Themol efract
ionofmethanei
nbenzeneat298Kunder760mm Hgi
s
-
3
(a)1.
78×10
(b)17.
43
(c)0.
114
(d)2.
814

Answer
Answer
:(a)

Q.
35.Amongthef
oll
owi
ngsubst
ancest
hel
owestv
apourpr
essur
eisexer
tedby
(
a)water
(
b)al
cohol
(
c)et
her
(
d)mercury

Answer
Answer
:(d)mer
cur
y

Q36.Atequil
li
bri
um therateofdi ssoluti
onofasol
i
dsol
utei
na
vol
ati
lel
iqui
dsolventis__.
(
a)lessthantherateofcrystal
lisati
on.
(
b)great
erthanther at
eofcr ystall
isati
on.
(
c)equaltotherateofcrystall
isati
on.
(
d)zero

Answer
Answer
:(c)

Q.
37.Abeakercont
ainsasol
uti
onofsubst
ance‘
A’.Preci
pit
ati
onofsubst
ance‘
A’t
akes
pl
acewhensmallamountof‘
A’isaddedt
othesol
ution.Thesol
uti
onis__
.
(
a)satur
ated
(
b)supersaturat
ed
(
c)unsaturated
(
d)concentrated

Answer
Answer
:(b)

Q.
38.Maxi mum amountofasolidsol
utethatcanbedissol
vedi
naspeci
fi
edamountof
agi
venliquidsolentdoesnotdependupon_
v __
___
__.
(
a)Temper atur
e
(
b)Natureofsolute
(
c)Pressure
(
d)Natureofsolvent

Answer
Answer
:(c)

Q.39.Lowconcentrati
onofoxy geni
nthebloodandtissuesofpeopl
eli
vi
ngathi
gh
alt
it
udeisduet o_.
(a)l
owt emperatur
e
(b)lowatmospheri
cpr essure
(c)highatmospheri
cpr essur
e
(d)bothlowtemperatureandhighatmospheri
cpressure

Answer
Answer
:(b)Bodyt
emper
atur
eofhumanbei
ngsr
emai
nsconst
ant
.

Q.
40.Val ueofHenr y’
sconst antKH _
.
(
a)increaseswithincreaseint emperature.
(
b)decr easeswit
hi ncreaseint emperature.
(
c)remai nsconstant.
(
d)fir
sti ncr
easesthendecr eases.

Answer
Answer
:(a)

Q.
41.Thev alueofHenr y’
sconst s_
antKH i .
(
a)great
erforgaseswi t
hhighersolubi
li
ty.
(
b)great
erf orgaseswi t
hlowersolubil
it
y.
(
c)constantforallgases.
(
d)notrelat
edt othesolubil
i
tyofgases.

Answer
Answer
:(b)
SET3

Questi
on1.
I
f2gm ofNaOHi
spr
esenti
s200ml
ofi
tssol
uti
on,
itsmol
ari
tywi
l
lbe
(
a)0.25
(
b)0.5
(
c)5
(
d)10

Answer
:(a)0.
25

Questi
on2.
Theatmospher i
cpollut
ioni
sgener
all
ymeasur
edi
ntheuni
tsof
(a)masspercentage
(b)vol
umeper centage
(c)vol
umefraction
(d)ppm

Answer
:(d)ppm

Question3.
A5%sol uti
onofcane-
sugar(
molecul
arweight=342)i
sisot
oni
cwi
th1%sol
uti
onof
substanceA.Themolecul
arwei
ghtofXis
(a)342
(b)171.2
(c)68.4
(d)136.8

Answer
:(c)68.
4

Questi
on4.
234.2gm ofsugarsy
rupcont
ains34.
2gm ofsugar
.Whati
sthemol
alconcent
rat
ionof
thesol
uti
on.
(a)0.
1
(b)0.
5
(c)5.
5
(d)55

Answer
:(b)0.
5

Quest
ion5.
H2Sisatoxi
cgasusedi
nquali
tat
iveanal
ysi
s.I
fsol
ubi
l
ityofH2Si
nwat
eratSTPi
s
0.195m.whati
stheval
ueofKH?
(a)0.
0263bar
(b)69.
16bar
(c)192bar
(d)282bar

Answer
:(d)282bar

Questi
on6.
Atomicmassi sequalt
o
(a)numberofelect
ronsofanatom
(b)sum oft
henumber sofel
ectronsandpr
otonsofanatom
(c)sum oft
henumber sofneut
ronsandprotonsofanat
om
(d)noneofthese

Answer
:(b)sum oft
henumber
sofel
ect
ronsandpr
otonsofanat
om

Questi
on7.
Henry’
slawconstantf
ormolal
i
tyofmethanei
sbenzeneat298Ki 27×105mm Hg.
s4.
Themol ef
racti
onofmethanei
snenzeneat298Kunder760mm Hgi
s
( 78×10-3
a)1.
(b)17.
43
(c)0.
114
(d)2.
814

Answer
:( 78×10-3
a)1.

Quest i
on8.
Howmuchoxy geni
sdi
ssol
vedin100r
nLwat
erat298Ki
fpar
ti
alpr
essur
eofoxy
geni
s
-
3
0.5atm andK=1.
4×10 mol/L/
atm?
(a)22.4mg
(b)22.4g
(c)2.
24g
(d)2.24mg

Answer
:(d)2.
24mg

Questi
on9.
Thelawwhi
chi
ndi
cat
est
her
elat
ion’
-
hipbet
weensol
ubi
l
ityofagasi
nli
qui
dand
pressur
ers
(a)Raoul
t’
slaw
(b)Henry’
slaw
(c)Loweri
ngofvapourpr
essur
e

Answer
:(b)Henr
y’sl
aw

Questi
on10.
Amongt hefol
l
owi
ngsubst
ancest
hel
owestv
apourpr
essur
eisexer
tedby
(a)water
(b)al
cohol
(c)et
her
(d)mercury

Answer
:(d)mer
cur
y

Questi
on11.
Vapourpressur
eofapur
eliqui
dXis2atm at300K.Iti
sloweredt
o1atm ondi
ssol
vi
ng
1gofYi n20gofli
qui
dX.IfmolarmassofXis200,whatist
hemolarmassofY?
(a)20
(b)50
(c)100
(d)200

Answer
:(b)50

Quest i
on12.
Parti
alpressur eofasol
uti
oncomponenti
sdi
rect
lypr
opor
ti
onal
toi
tsmol
efr
act
ion.
Thisisknownas
(a)Henry ’
slaw
(b)Raoult’
sl aw
(c)Distr
ibutionlaw
(d)Ostawal d’sdil
uti
onl
aw

Answer
:(b)Raoul
t’
slaw

Question13.
3mol esofPand2mol esofQaremixed,
whatwil
lbet
heirt
otalvapourpr
essur
eint
he
solut
ionifthei
rpar
ti
alv
apourpr
essur
esare80and60tor
rrespecti
vel
y?
(a)80t or
r
(
b)140torr
(
c)72torr
(
d)70torr

Answer :(c)72torr
Questi
on14.
Whichoft hef
ollowingsol
uti
onsshowsposi
ti
vedev
iat
ionf
rom Raoul
t’
slaw?
(a)Acetone+Ani l
i
ne
(b)Acetone+Et hanol
(c)Water+Ni tri
caci d
(d)Chloroform +Benzene

Answer
:(b)Acet
one+Et
hanol

Quest i
on15.
Thesy stem thatf ormsmaxi mum boi
l
ingazet
ropei
s
(a)Acetone-chlorof orm
(b)ethanol-
acet one
(c)n-hexane-n-hept ane
(d)carbondisul phide-acet
one

Answer
:(a)Acet
one-
chl
orof
orm

Question16.
Aplantcel lshr
inkswheni
tiskepti
na
(
a)hypot onicsoluti
on
(
b)hy pertonicsolut
ion
(
c)isotonicsolution
(
d)pur ewat er

Answer
:(b)hy
per
toni
csol
uti
on

Quest i
on17.
Ther el
ativ
eloweringinvapourpr essurei
spr
oporti
onaltotheratioofnumberof
(a)solutemoleculestosolventmol ecul
es
(b)solventmoleculestosolutemol ecul
es
(c)solutemolecul
est othetotalnumberofmoleculesinsoluti
on
(d)solventmoleculestothetotalnumberofmoleculesinsoluti
on

Answer
:(c)sol
utemol
ecul
est
othet
otal
numberofmol
ecul
esi
nsol
uti
on
Questi
on18.
Asolut
ioncont
aining10.
2gglycer
ineperli
tr
eisi
sot
oni
cwi
tha2%sol
uti
onofgl
ucose.
Whatisthemolecularmassofgl
ycer
ine?
(
a)91.8g
(
b)1198g
(
c)83.9g
(
d)890.3g

Answer
:(a)91.
8g

Question19.
Whatwei ghtofgl
ycer
olshoul
dbeaddedt
o600gofwat
eri
nor
dert
oloweri
tsf
reezi
ng
pointby10°C?
(a)496g
(b)297g
(c)310g
(d)426g

Answer
:(b)297g

Quest i
on20.
Theosmot i
cpressureofasol
uti
oncanbeincr
easedby
(a)i
ncr easingthev ol
ume
(b)increasingthenumberofsolut
emolecul
es
(c)decr easingthetemper
atur
e
(d)remov i
ngsemi per
meablemembrane

Answer
:(b)i
ncr
easi
ngt
henumberofsol
utemol
ecul
es

Quest ion21.
Sprinklingofsalthelpsinclearingthesnowcoveredr
oadsinhil
ls.Thephenomenon
i
nv olvedi ntheprocessis
(a)lower i
nginvapourpressureofsnow
(b)depr essi
oninfreezi
ngpoi ntofsnow
(c)mel t i
ngoficeduet oincreaseintemperat
urebyputt
ingsal
t
(d)incr easeinfr
eezingpointofsnow

Answer
:(b)depr
essi
oni
nfr
eezi
ngpoi
ntofsnow

Questi
on22.
Forcar
ryi
ngrev
erseosmosi
sfordesal
i
nat
ionofwat
ert
hemat
eri
alusedf
ormaki
ng
semipermeabl
emembr anei
s
(a)pot
assium ni
trat
e
(b)par
chmentmembr ane
(c)cel
l
uloseacetate
(d)cel
lmembr ane

Answer
:(c)cel
l
uloseacet
at

Question23.
Whatwi l
lbethedegr
eeofdi
ssoci
ati
onof0.
1M Mg(
NO3)
2sol
uti
oni
fvan’
tHof
ffact
ori
s
2.74?
(a)75%
(b)87%
(c)100%
(d)92%

Answer
:(b)87%

Questi
on24.
Whichoft hefoll
owinguni
tsi
susef
uli
nrel
ati
ngconcent
rat
ionofsol
uti
onwi
thi
ts
vapourpressure?
(
a)Mol efracti
on
(
b)Par t
spermi ll
ion
(
c)Massper centage
(
d)Mol al
ity

Answer
:(a)Mol
efr
act
ion

Question25.
Atequili
brium therateofdissociat
ionofasol
i
dsol
utei
nav
olat
il
eli
qui
dsol
venti
s
(a)l
esst hant herateofcr
ystall
isat
ion
(b)great
ert hanther at
eofcr y
stall
i
sati
on
(c)equaltot herateofcry
stall
isati
on
(d)zero

Answer
:(c)equal
tot
her
ateofcr
yst
all
i
zat
ion
SET4

1.Mol efr
acti
onofgl
ycer
ineC3H5(
OH)
3insol
uti
oncont
aini
ng36gofwat
erand46gof
glyceri
neis
(a)0.46
(b)0.40
(c)0.20
(d)0.36

Answer
:c

2.Outofmolal
it
y(m)
,molari
ty(M)
,for
mal
i
ty(
F)andmol
efr
act
ion(
x),
thosewhi
char
e
i
ndependentoft
emperat
ureare
(a)M,m
(b)F,
x
(c)m,x
(d)M,x

Answer
:c

3.Whichoft hefoll
owingcondi
ti
oni
snotsat
isf
iedbyani
deal
sol
uti
on?
(a)ΔHmixing=0
(b)ΔVmixing=0
(c)Raoul t’
sLawi sobeyed
(d)Format i
onofanazeotropi
cmixt
ure

Answer
:d

4.Theboilingpointofanazeot ropicmixt
ureofwat
erandet
hanol
isl
esst
hant
hatof
waterandet hanol.Themi xt
ureshows
(a)nodev i
ati
onf rom Raoult
’sLaw.
(b)posit
ivedev i
ationfr
om Raoul t
’sLaw.
(c)negati
vedev i
at i
onfrom Raoult’
sLaw.
(d)thatt
hesol uti
oni sunsatur
ated.
Answer
:b

5.Whichhast
helowestboi
l
ingpoi
ntat1at
m pr
essur
e?
(a)0.
1M KCl
(b)0.
1M Urea
(c)0.
1M CaCl2
(d)0.
1M A1Cl3

Answer
:b

6.Osmoticpressur
eofasol ut
ioni
s0.
0821at
m atat
emper
atur
eof300K.The
concent
rati
oninmol es/
li
tr
ewillbe
(a)0.
33
(b)0.
666
( 3×10-2
c)0.
(d)3

Answer
:c

7.Peopleaddsodium chloridetowat
erwhi
l
eboi
l
ingeggs.Thi
sist
o
(a)decreasetheboi
lingpoint.
(b)i
ncreasetheboil
ingpoint .
(c)prev
entthebreakingofeggs.
(d)makeeggst asty
.

Answer
:b

8.Thev an’tHofffactor( i
)accountsfor
(a)degreeofsol ubil
isati
onofsolute.
(b)theextentofdi ssociati
onofsolute.
(c)theextentofdissol uti
onofsolute.
(d)thedegr eeofdecomposi t
ionofsolut
ion.

Answer
:b
9.Whi
chr
elat
ionshi
pisnotcor
rect
?

Answer
:b

10.Themol alelev
ati
onconstantdependsupon
(a)natureofsol ut
e.
(b)natureoft hesolvent
.
(c)vapourpr essureofthesol
uti
on.
(d)enthalpychange.

Answer
:b

SET5

Question1.
Theosmot icpressureofasol ut
ionisdi
rect
lypr
oport
ional
to
(a)themolecularconcentr
ationofthesolut
e
(b)theabsolut
et emperat
ureatagi venconcent
rat
ion
(c)theloweri
ngofv apourpressure
(d)allt
heabov e.

Answer
:(d)al
ltheabov
e.

Questi
on2.
I
sotonicsol
utionarethesol
uti
onshav
ingt
hesame.
(
a)surfacetension
(
b)concentration
(
c)osmot i
cpr essur
e
(
d)v i
scosi
ty

Answer
:(c)osmot
icpr
essur
e

Questi
on3.
Whichoft
hefoll
owi
ngi
sacol
l
igat
ivepr
oper
ty?
(
a)osmoticpr
essur
e
(
b)boili
ngpoint
(
c)vapourpressur
e
(
d)electr
ical
conduct
ivi
ty

Answer
:(a)osmot
icpr
essur
e

Questi
on4.
Whichoft
hef oll
owi ngsol
uti
onshav
ehi
ghestf
reezi
ngpoi
nt?
(
a)0.1M NaCl
(
b)0.1M BaCl2
(
c)0.1M Al
2( SO4)3
(
d)0.1M urea.

Answer
:(d)0.
1M ur
ea.

Questi
on5.
Whichofthefol
lowing0.
1M aqueoussol
uti
onswi
l
lhav
ethel
owestf
reezi
ngpoi
nt?
(
a)potassi
um sulphat
e
(
b)sodium chl
oride
(
c)urea
(
d)glucose

Answer
:(a)pot
assi
um sul
phat
e

Question6.
Themassof( COOH)
2.2H2Oneededt
opr
epar
e500ml
of0.
1mol
arsol
uti
oni
s
(a)12.6gm
(b)6.3gm
(c)4.
5gm
(d)9.0gm

Answer
:(b)6.
3gm

Questi
on7.
Whichoft
hefol
l
owi
ngsol
uti
onshashi
ghestosmot
icpr
essur
e?
(
a)1M NaCl
(
b)1M MgCl2
(
c)1M urea
(
d)1M gl
ucose.

Answer
:(a)1M NaCl

Questi
on8.
Whichofthefol
l
owi
ngsol
uti
ons(
inwat
er)hashi
ghestboi
l
ingpoi
nt?
(
a)1M NaCl
(
b)1M MgCl 2
(
c)1M Urea
(
d)1M glucose.

Answer
:(b)1M MgCl
2

Quest i
on9.
Whi chofthef oll
owingaqueoussol
uti
onscont
aini
ng10gofsol
utei
neachcase,
has
highestm.pt ?
(a)NaCl soluti
on
(b)KC1sol ution
(c)sugarsol uti
on
(d)glucosesol uti
on.

Answer
:(c)sugarsol
uti
on

Questi
on10.
Equalvol
umesof0.
1M AgNO3and0.2M NaCl
sol
uti
onsar
emi
xed.Theconcent
rat
ion
–
ofNO3 ionsi
nmixt
uresol
uti
onwi
ll
be
(a)0.
1M
(b)0.
05M
(c)0.
2M
(d)0.
15M

Answer
:(b)0.
05M

Question11.
Themol alf
reezi
ngpointconst
antf
orwat
eri
s1.
86°CM.Thef
reezi
ngpoi
ntof0.
1m
NaCl sol
uti
onisexpectedtobe
(a)13.6
(b)68
(c)34
(
d)136

Answer
:(c)34

Questi
on12.
Thesoluti
oncontai
ning6.
8gofnon-
ioni
csol
utei
n100gofwat
erwasf
oundt
ofr
eeze
at-0.
93°C.IfKff
orwateri
s1.
86,
themol.massofsol
utei
s
(a)13.
6
(b)68
(c)34
(d)136.

Answer
:(d)136.

Quest
ion13.
I
ncaseofelect
rol
ytewhi
chdi
ssoci
atesi
nsol
uti
ont
heVan’
tHof
f’
sfact
or,
iis
(
a)>1
(
b)<1
(
c)=1
(
d)=0

Answer
:(a)>1

Quest i
on14.
Whichoft hefol
l
owi
ngsal
twi
l
lhav
esamev
alueofVantHof
f’
sfact
or(
i)ast
hatofK4[
Fe
(
CN) 6]
(
a)Al 2(SO4)
3
(
b)NaCl
(
c)Al (NO3)3
(
d)Na2SO4

Answer
:(a)Al
2(
SO4)
3

Questi
on15.
120gofureaispr
esenti
n5Lofsol
uti
on,
theact
ivemassofur
eai
s
(a)0.
2
(b)0.
06
(c)0.
4
(d)0.
8
Answer
:(c)0.
4

Quest i
on16.
Thelawst at
ingthattherel
ati
veloweri
ngofvapourpr
essur
eisequal
tot
hemol
e
fract
ionofasoluteinthesolut
ionisknownas
(a)Henry’
slaw
(b)Van’tHoff,
Law
(c)Raoult
’sl
aw
(d)Ostwald’
sdilut
ionlaw

Answer
:(c)Raoul
t’
slaw

Questi
on17.
Azeotr
opi
cmixt
ureofHCl
andH2Ohas
(a)48%HCl
(b)22.
2%HCl
(c)36%HCl
(d)20.
2%HCl

Answer
:(d)20.
2%HCl

Questi
on18.
Whichofthefol
l
owi
ngmodesofexpr
essi
ngconcent
rat
ioni
sindependentof
t
emper at
ure?
(
a)Mol ar
it
y
(
b)Normal i
ty
(
c)Formalit
y
(
d)Mol al
it
y

Answer
:(d)Mol
ali
ty

Quest i
on19.
A500gt oothpast
esampl
ehas0.2gf
luor
ideconcent
rat
ion.Whati
stheconcent
rat
ion
offluori
neinter
msofppm l
evel
?
(a)250
(b)200
(c)400

Answer
:(a)250
Question20.
Anaqueoussoluti
onf
reezesout-
0.186°
C(Kf=1.
86°
,kb=0.
512)
.Whati
stheel
evat
ion
i
nboilingpoi
nt?
(a)0.
186
(b)0.512
(c)0.
86
(d)0.
0512

Answer
:(c)0.
86

Questi
on21.
Theaverageosmoti
cpressur
eofhumanbipodis7.8barat37°
C.Whati
sthe
concent
rati
onofanaqueoussol
uti
onofNaClthatcoul
dbeusedinbl
oodstr
eam?
(a)0.
15mol L-1
(b)0.
30mol L-1
(c)0.
60mol L-1
(d)0.
45mol L-1

Answer
:(a)0. L-1
15mol

Questi
on22.
Whichhasthemi
nimum osmot
icpr
essur
e?
(
a)200ml of2M NaCl
(
b)200ml of1M gl
ucose
(
c)200ml of2M ur
ea
(
d)allhav
esame.

Answer
:(b)200ml
of1M gl
ucose

Question23.
Soluti
onAcont ains7gL-1MgCl 2andsol
uti
onBcont
ains7gL-1ofNaCl
.Atr
oom
temper at
ure,t
heosmot i
cpr essur
eof
(a)soluti
onAi sgreat
erthanB
(b)bothhav esameosmot icpressur
e
(c)soluti
onBi sgreat
ert
hanA
(d)Can’tdeter
mine.

Answer
:(c)sol
uti
onBi
sgr
eat
ert
hanA

Quest
ion24.
Equimolarsoluti
onsinthesamesol venthave
(a)SameB. Ptbutdi
ff
erentF.Pt
(b)SameF.Pt ,butdif
ferentB.Pts.
(c)SameBoi li
ngandsamef reezingpoint
(d)Dif
ferentboil
inganddifferentfr
eezingpoi
nts.

Answer
:(c)SameBoi
l
ingandsamef
reezi
ngpoi
nt

Questi
on25.
Themol ef
ract
ionoft
hesol
utei
nonemol
alaqueoussol
uti
oni
s
(a)0.
027
(b)0.
036
(c)0.
018
(d)0.
019

Answer
:(c)0.
018

Question26.
Thev apourpressureoft
hetwoli
quids‘
P’and‘
Q’ar
e80and60tor
rrespect
ivel
y.The
total
v apourpressur
eofthesol
uti
onobtai
nedbymixi
ng3molofPand2mol eofQ
wouldbe
(a)68t orr
(b)140t orr
(c)72t orr
(d)20t orr

Answer
:(c)72t
orr

Quest i
on27.
Xisdi ssolv
edi nwater
.Maximum boi
l
ingpoi
nti
sobservedwhenXis…………(0.
1M each)
(a)CuSO4
(b)BaCl 2
(c)NaCl
(d)Urea
Answer :(b)BaCl2
Quest i
on28.
I
fanaqueoussol uti
onofglucosei
sall
owedtof
reeze,
thencr
ystal
sofwhi
chsubst
ance
will
besepar at
edandfirst
?
(a)glucose
(b)wat er
(c)bothoft hese
(d)noneoft hese
Answer
:(b)wat
er

Question29.
IftwosubstancesAandBhaveP0A:P0B=1: 2andhav
emol
efr
act
ioni
nsol
uti
oni
n
solut
ion1: 2,t
henmolef
ract
ionofAi
nvapour
swill
be
(a)0.
33
(b)0.
25
(c)0.
52
(d)0.
2
Answer :(
d)0.2

Questi
on30.
I
fai st
hecl egr
eeofdi
ssoci
ati
onofNa2SO4t
heVan’
tHof
ffact
or(
i)usedf
orcal
cul
ati
ng
themolecularmassi
s
(a)1+α
(b)1–α
(c)1+2α
(d)1–2α
Answer:(c)1+2α

Questi
on31.
Theelevati
oninboili
ngpoi
ntofasolut
ionof13.
44gofCuCl
2in1kgofwat
er(
Giv
en
-
1
Kb=0.52Kkgmol ,M.Wt.ofCuCl
2= 134.
4)
(a)0.
05
(b)0.
1
(c)0.
16
(d)0.
21
Answer:(c)0.
16

Questi
on32.
Twosoluti
onsofasubst ance(
non-
elect
rol
yte)ar
emixedi
nthefol
l
owingmari
ner
: 480
mLof1. 5M off
irstsol
ution+520mLof1.2M secondsol
uti
on.Wfct
ati
sthemolari
ty
ofthefi
nalmixt
ure?
(a)1.
20M
(b)1.
50M
(c)1.
344M
(d)2.
70M

Answer
:(c)1.
344M

SET6
Directi
ons:Thesequestionsconsistoftwostatements,
eachpri
ntedasAsserti
onand
Reason.Whi leansweri
ngt hesequesti
ons,youarerequi
redt
ochooseanyoneoft he
foll
owi ngf
ourresponses.
(a)IfbothAsserti
onandReasonar ecorr
ectandtheReasonisacorrectexpl
anati
onof
theAsser t
ion.
(b)IfbothAsserti
onandReasonar ecorr
ectbutReasonisnotacorrectexpl
anat
ionof
theAsser t
ion.
(c)IftheAsserti
oniscorrectbutReasonisincorr
ect.
(d)IfboththeAsserti
onandReasonar eincor
rect
.

Q.1.Asser
ti
on:Mol
ari
tyofasolut
ioni
nli
qui
dstat
echangeswi
thtemper
atur
e.
Reason:Thevol
umeofasolut
ionchangeswi
thchangei
ntemper
atur
e.

Answera

Q.2.Assert
ion:Ifaliqui
dsolutemorevol
ati
l
ethanthesolv
enti
saddedtothesol
vent
,
thevapourpressureofthesoluti
onmayincr
easei.
e.,
ps>po.
Reason:Inthepr esenceofamor evol
ati
l
eli
quidsol
ute,
onlyt
hesol
utewil
lfor
mthe
vapoursandsolventwi l
lnot
.

Answer

Q.3.Asser
ti
on:Ifonecomponentofasoluti
onobeysRaoul
t’
slawoveracer
tai
nrange
ofcompositi
on,t
heothercomponentwil
lnotobeyHenry
’sl
awinthatr
ange.
Reason:Raoult
’slawi
saspecialcaseofHenry’
slaw.

Answerb

Q.4.Assert
ion:Azeot
ropi
cmi xt
uresar efor
medonl ybynon-i
dealsolut
ionsandthey
mayhav eboil
ingpoi
ntseit
hergreaterthanboththecomponentsorlessthanboththe
components.
Reason:Thecomposi t
ionofthev apourphaseissameast hatoftheli
quidphaseofan
azeotr
opicmixtur
e.
 Answerb

Q.5.Assert
ion:Whenmethy
lalcoholi
saddedtowater
,boil
i
ngpointofwaterincr
eases.
Reason:Whenav olat
il
esol
uteisaddedt
oav ol
ati
l
esolventel
evat
ioninboil
ingpointi
s
observed.

Answerd

Q.6.Asser
ti
on:WhenNaCl i
saddedtowateradepr
essioninfr
eezi
ngpoi
ntisobser
ved.
Reason:Thelower
ingofv
apourpressur
eofasolut
ioncausesdepr
essi
oninthe
fr
eezingpoi
nt.

Answera

Q.7.Asserti
on:Whenasol uti
onisseparat
edfrom t
hepuresolventbyasemi-
permeablemembr ane,t
hesolventmolecul
espassthroughi
tfrom puresol
ventsi
det
o
thesolut
ionside
Reason:Di f
fusi
onofsolventoccur
sfrom aregi
onofhighconcentrat
ionsol
uti
ontoa
regi
onofl owconcentr
ati
onsoluti
on.

Answerb

SET7[
NCERT]

1.Whichofthef oll
owinguni
tsi
susef
uli
nrel
ati
ngconcent
rat
ionofsol
uti
onwi
thi
ts
vapourpr
essur e?
(
i)molefracti
on
(
ii)par
tspermi ll
i
on
(
iii
)massper centage
(
iv)molal
ity
2.Ondissol
vingsugarinwat
eratroom t
emperatur
esolut
ionfeel
scool
totouch.
Underwhichofthefoll
owi
ngcasesdissol
uti
onofsugarwil
lbemostrapi
d?
(i
)Sugarcryst
alsi
ncoldwater
.
 (
ii
)Sugarcr
yst
alsi
nhotwater
.
(
ii
i)Powder
edsugari
ncol
dwat er
.
(
iv)Powder
edsugari
nhotwater.
3.Atequi l
i
brium therat
eofdissoluti
onofasol
i
dsol
utei
nav
olat
il
eli
qui
dsol
venti
s
________
_ _
__.
(i
)lessthant herateofcr
ystall
i
sat i
on
(i
i
)gr eaterthantherat
eofcr y
st al
l
isat
ion
(i
i
i)equal totherateofcr
ystall
isati
on
(i
v)zero
4.Abeakercont ainsasol
uti
onofsubst
ance‘A’.Pr
ecipi
tat
ionofsubst
ance‘A’t
akespl
ace
whensmal lamountof‘A’i
saddedtothesoluti
on.Thesolut
ionis__
____
____
___.
(
i)satur
ated
(
ii
)supersatur at
ed
(
ii
i)unsatur
at ed
(
iv)concentrated
5.Maximum amountofasol i
dsolutethatcanbedissol
vedi
naspeci
fi
edamountofa
gi
venliqui
dsolventdoesnotdependupon_ _
___
__ _
__.
(i
)Temper at
ure
(i
i
)Nat ur
eofsolute
(i
i
i)Pressure
(i
v)Natureofsolvent
6.Lowconcentr
ati
onofoxygenint hebl
oodandtissuesofpeopl
eli
vi
ngathi
ghal
ti
tudei
s
dueto____
____
_____
.
(i
)lowtemper
ature
(i
i
)lowatmospheri
cpressure
(i
i
i)hi
ghatmospheri
cpressure
(i
v)bot
hlowtemperatur
eandhi ghatmospher
icpressur
e
7.Consideringt hefor
mat i
on,br
eaki
ngandst
rengt
hofhydrogenbond,
predi
ctwhi
choft
he
foll
owingmi xtur
eswill
showapositi
vedev
iat
ionfr
om Raoult
’sl
aw?
(i
)Met hanol andacetone.
(i
i)Chloroform andacetone.
(i
ii
)Nitri
caci dandwat er.
(i
v)Phenol andanil
ine.
8.Coll
igat
ivepropert
iesdependon.
(i
)thenatureofthesolutepart
icl
esdissol
vedinsol
uti
on.
(i
i
)thenumberofsol uteparti
clesi
nsoluti
on.
(i
i
i)thephysicalpr
operti
esofthesolutepart
icl
esdi
ssol
vedi
nsol
uti
on.
(i
v)thenatureofsolventpar
ti
cles.
9.Whichofthefol
l
owi
ngaqueoussol
uti
onsshoul
dhav
ethehi
ghestboi
l
ingpoi
nt?
(
i)1.0M NaOH
(
ii
)1.0M Na2SO4
 (i
ii
)1.0M NH4NO3
(i
v)1.0M KNO3
10.
Theunitofebul ioscopicconst anti s_
______
.
–1 –1
(i
)Kkgmol orK( molali
t y
)
–1 –1
(i
i)mol kgK orK ( molali
ty)
–1 –1 –1 –1
(i
ii
)kgmol K orK ( molali
ty)
–1
(i
v)Kmol kg orK( molalit
y)
11.
Incompar i
sont oa0. 01M sol uti
onofglucose,thedepressi
oninfreezingpoi
ntofa0.
01
M MgCl 2sol utioni s_ __
__.
(i
)thesame
(i
i)abouttwi ce
(i
ii
)aboutt hr eet imes
(i
v)aboutsi xt i
mes
12.
Anunr i
pemangopl acedi naconcent rat
edsaltsolut
iontoprepar
epi ckle,
shr
ivel
s
because.
(i
)itgainswat erduet oosmosi s.
(i
i)i
tloseswat erduet oreverseosmosi s.
(i
ii
)itgainswat erduet or everseosmosi s.
(i
v)itl
oseswat erduet oosmosi s.
13.
Atagiv entemperatur
e,osmoticpr
essur
eofaconcentr
atedsolut
ionofasubst
ance.
(i
)ishigherthanthatatadil
utesol
uti
on.
(i
i)i
slowert hanthatofadil
utesol
uti
on.
(i
ii
)issameast hatofadil
utesol
uti
on.
(i
v)cannotbecompar edwit
hosmot i
cpressur
eofdi
l
utesolut
ion.
14.
Whi choft hef ol
lowingst atement si sf alse?
(i
)Twodi f
fer entsoluti
onsofsucr oseofsamemol al
it
yprepar edi ndif
ferentsolv
ent s
wi l
lhavet hesamedepr essi oni nf r
eezi ngpoint.
(i
i)Theosmot i
cpr essureofasol ut ionisgivenbyt heequationΠ=CRT(wher eCi sthe
mol ari
tyoft hesol ut
ion).
(i
ii)Decreasi ngor derofosmot icpr essur ef
or0. 01M aqueoussol uti
onsofbar i
um
chlori
de, pot assium chloride, aceticaci dandsucr oseisBaCl 2>K Cl >CH3COOH>
sucrose.
(i
v )Accor dingt oRaoul t
’sl aw, t
hev apourpr essureexer t
edbyav olati
l
ecomponentofa
soluti
oni sdi rectlyproport i
onal toitsmol efracti
oni nthesolut i
on.
15.
Thev aluesofVan’ tHofff actorsf orKCl ,NaCl andK2SO4, respect ivel
y,are_
________.
(i
)2, 2and2
(i
i)2,2and3
(i
ii)1,1and2
(i
v )1,1and1
16.
Whi choft hef ol
lowingst atement si sf alse?
(i
)Uni t
sofat mospher i
cpr essureandosmot i
cpr essurearet hesame.
(i
i)Inrev erseosmosi s,sol ventmol eculesmov ethroughasemi permeablemembr ane
from ar egionofl owerconcent rationofsol utet oar egi
onofhi gherconcent r
ati
on.
 (
ii
i)Theval
ueofmolaldepressi
onconstantdependsonnat
ureofsol
vent
.
(
iv)Rel
ati
velower
ingofvapourpressur
e,i
sadi mensi
onl
essquant
it
y.
17.
ValueofHenr y’sconstantKH_____
______.
(i
)increaseswi t
hincreaseintemperature.
(i
i)decreaseswi t
hincreaseintemperature.
(i
ii
)remai nsconstant.
(i
v)fir
stincreasesthendecreases.
18.
Thev al
ueofHenr y’sconstantKH i
s______
_.
(i
)greaterforgaseswi t
hhighersolubi
li
ty.
(i
i)gr
eaterforgaseswi thl
owersol ubi
li
ty.
(i
ii
)constantforallgases.
(i
v)notrelatedtothesolubil
it
yofgases.
19.
ConsidertheFig.andmar kthecorrectopti
on.

(i
)waterwil
lmovef r
om side(A)toside(B)ifapressurelowerthanosmoticpressureis
appli
edonpist
on( B)
.
(i
i)waterwi
l
lmov efrom si
de(B)toside(A)ifapressuregreaterthanosmoti
cpr essure
i
sappl i
edonpist
on( B)
.
(i
ii
)waterwi
llmovefrom side(B)toside(A)ifapressureequaltoosmoticpressureis
appli
edonpist
on( B)
.
(i
v)waterwi
llmovefrom side(A)toside(B)ifpr
essureequaltoosmot i
cpressureis
appli
edonpist
on( A).
20.
Wehav ethr
eeaqueoussol
uti
onsofNaCl l
abel
ledas‘A’
,‘
B’and‘C’wi
thconcent
rati
ons
0.1M,0.
01M and0.001M,r
espect
ivel
y.Theval
ueofvan’
tHofffact
orfort
hesesolut
ions
will
beintheorder.
(i
)iA<iB<iC
(i
i)i
A>iB>i C
(i
ii
)iA=iB=iC
(i
v)iA<iB>iC
21.
Ont hebasisofi
nformat
iongivenbelowmar kt
hecor r
ectopti
on.
Inf
ormation:
(A)Inbromoethaneandchlor
oethanemi xturei
ntermolecul
ari
nter
act
ionsofA–Aand
B–Bt ypearenearl
ysameasA–Bt ypeinteract
ions.
 (B)Inethanol andacetonemi xt
ureA–AorB–Bt ypeintermol
ecul
arinter
acti
onsare
strongerthanA–Bt ypeinteracti
ons.
(C)Inchloroform andacet onemi xtur
eA–AorB–Bt ypeinter
moleculari
nter
act
ionsar
e
weakert hanA–Bt ypeinteracti
ons.
(i
)Solution(B)and( C)wi l
lfoll
owRaoul t’
slaw.
(i
i)Soluti
on(A)wi ll
f ol
l
owRaoul t’
slaw.
(i
ii
)Solution(B)willshownegat i
vedeviati
onfrom Raoult
’sl
aw.
(i
v)Solution(C)wi l
lshowposi t
ivedevi
ati
onf r
om Raoult’
slaw.
22.
Twobeaker sofcapacit
y500mLwer etaken.Oneofthesebeakers,
label
l
edas“A”,was
fi
ll
edwi th400mLwat erwhereast
hebeakerlabell
ed“B”wasfi
ll
edwi t
h400mLof2M
sol
utionofNaCl .Att
hesamet emper
atur
ebot hthebeaker
swereplacedincl
osed
containersofsamemat er
ial
andsamecapacityasshowni nFi
g.

Atagiv
entemperat
ure,
whichofthefol
l
owingstat
ementi
scor
rectaboutt
hev
apour
pr
essureofpur
ewaterandthatofNaClsol
uti
on.
 (
i)v
apourpr
essur
eincont
ainer(
A)i
smor
ethant
hati
ncont
ainer(
B).
 (
ii
)vapourpr
essur
eincont
ainer(
A)i
slesst
hant
hati
ncont
ainer(
B).
 (
ii
i)v
apourpr
essur
eisequal
inbot
hthecont
ainer
s.
 (
iv)v
apourpr
essur
eincont
ainer(
B)i
stwi
cet
hev
apourpr
essur
eincont
ainer(
A).
23.
Iftwol i
quidsAandBf or
m mi ni
mum boilingazeot
ropeatsomespeci
fi
ccompositi
on
then.
(i)A–Bi nteracti
onsarestrongerthanthosebetweenA–AorB–B.
(ii
)vapourpr essureofsolutioni
ncreasesbecausemor enumberofmolecul
esofl
iqui
ds
AandBcanescapef rom thesoluti
on.
(ii
i)vapourpr essureofsoluti
ondecreasesbecauselessnumberofmolecul
esofonly
oneoft hel i
quidsescapef rom t
hesolution.
(iv)A–Bi nteracti
onsareweakert hanthosebetweenA–AorB–B.
24.
4Lof0. 02M aqueoussolut
ionofNaCl
wasdi
l
utedbyaddi
ngonel
i
treofwat
er.The
molali
tyoftheresul
tantsol
uti
onis.
(i
)0.004
(i
i)0.
008
(i
ii
)0.012
(i
v)0.016
25.
25.Onthebasi
sofi
nfor
mati
ongi
venbelowmarkt
hecor
rectopti
on.
Inf
ormati
on:Onaddi
ngacet
onet
omet hanol
someoft
hehy dr
ogenbondsbet
ween
 met hanol moleculesbr eak.
(i
)Atspeci fi
ccomposi tionmethanol-
acet onemi xturewil
l f
orm minimum boili
ng
azeotropeandwi l
l showposi t
ivedeviati
onf rom Raoult’
slaw.
(i
i)Atspeci f
iccomposi ti
onmet hanol
-acetonemi xtureformsmaxi mum boi l
ing
azeotropeandwi l
l showposi t
ivedeviati
onf rom Raoult’
slaw.
(i
ii
)Atspeci fi
ccomposi t
ionmethanol-acetonemi xturewillf
orm minimum boil
ing
azeotropeandwi l
l shownegat i
v edeviat
ionfr om Raoult
’slaw.
(i
v)Atspeci fi
ccomposi t
ionmethanol-acetonemi xturewillf
orm maximum boili
ng
azeotropeandwi l
l shownegat i
v edeviat
ionfr om Raoult
’slaw.
–5
26.
KH v alueforAr (
g), CO2( g)
,HCHO( g)andCH4( g)ar e40.39,1.
67,1.83×10 and0. 413
respectivel
y.
Arranget hesegasesi ntheorderoftheirincreasi
ngsol ubil
it
y.
(i
)HCHO<CH4<CO2<Ar
(i
i)HCHO<CO2<CH4<Ar
(i
ii
)Ar<CO2<CH4<HCHO
(i
v)Ar<CH4<CO2<HCHO

Shor
tAnswerTy
peQuest
ions
1.Component sofabinarymi xtureoftwoliqui
dsAandBwer ebeingsepar
atedby
dist
il
lat
ion.Aft
ersomet imesepar ati
onofcomponent sstoppedandcompositi
onof
vapourphasebecamesameast hatofl
iquidphase.Bot
ht hecomponentsst
arted
comingi nthedi
sti
ll
ate.Explainwhythishappened.
2.Explai
nwhyonaddi t
ionof1molofNaClt
o1lit
reofwat
er,
theboi
l
ingpointofwater
i
ncreases,
whileaddi
tionof1molofmet
hylal
coholt
ooneli
tr
eofwaterdecr
easesit
s
boil
i
ngpoint.
3.Expl
ainthesol
ubi
l
ityr
ule“
li
kedi
ssol
vesl
i
ke”i
nter
msofi
nter
mol
ecul
arf
orcest
hatexi
st
i
nsoluti
ons.
4.Concent
rati
ontermssuchasmassper
cent
age,ppm, molef
racti
onandmol al
it
yare
i
ndependentoftemper
atur
e,howev
ermol
ari
tyi
saf unct
ionoftemperat
ure.Expl
ain.
5.hati
sthesi
gni
fi
canceofHenr
y’sLawconst
antK?
6.Whyar
eaquat
icspeci
esmor
ecomf
ort
abl
eincol
dwat
eri
ncompar
isont
owar
m wat
er?
7.(
a)Explai
nthefoll
owi
ngphenomenawi t
ht hehelpofHenr y
’sl
aw.
(
i)Pai
nfulcondi
ti
onknownasbends.
(
ii
)Feel
ingofweaknessanddiscomfor
tinbreathingathighal
ti
tude.
(
b)Whysodawat erbott
lekeptatr
oom temperaturefi
zzesonopening?
8.Whyi
sthev
apourpr
essur
eofanaqueoussol
uti
onofgl
ucosel
owert
hant
hatofwat
er?
9.Howdoesspri
nkli
ngofsalthel
pincl
ear
ingthesnowcov
eredr
oadsi
nhi
l
lyar
eas?
Expl
aint
hephenomenoninvolv
edint
heprocess.
10.
Whati
s“semi
per
meabl
emembr
ane”
?
11.
Giv
eanex ampleofamat
eri
alusedf
ormaki
ngsemi
per
meabl
emembr
anef
orcar
ryi
ng
outrev
erseosmosis.

Mat
chi
ngTy
peQuest
ions
Not
e:I
nthefol
lowi
ngquest
ionsmat
chtheit
emsgi
veni
nCol
umnIandCol
umnI
I.
1.Mat
cht
heit
emsgi v
eni
nColumnIandColumnII
.

Col
umnI Col
umnI
I

(i
)Sat
urat
ed (a)Solut
ionhavingsameosmot
icpr
essur
eatagi
vent
emper
atur
east
hat
sol
uti
on ofgivensolut
ion.

(i
i)Bi
nary
solut
ion (
b)Asol
uti
onwhoseosmot
icpr
essur
eisl
esst
hant
hatofanot
her
.

i
ii
)Isotoni
c
sol
ution (
c)Sol
uti
onwi
tht
wocomponent
s.

i
v)Hypot
oni
c (d)Asolut
ionwhi
chcont
ainsmaxi
mum amountofsol
utethatcanbe
sol
uti
on dissol
vedi
nagivenamountofsol
ventatagi
vent
emperat
ure.

(v)Soli
d
solut
ion (
e)Asol
uti
onwhoseosmot
icpr
essur
eismor
ethant
hatofanot
her
.

vi
)Hyper
toni
c
sol
uti
on (
f)Asol
uti
oni
nsol
i
dphase.
2.Mat
cht
hei
temsgi
veni
nCol
umnIwi
tht
het
ypeofsol
uti
onsgi
veni
nCol
umnI
I.

Col
umnI Col
umnI
I

(
i)Sodawat
er (
a)Asol
uti
onofgasi
nsol
i
d

(
ii
)Sugarsol
uti
on (
b)Asol
uti
onofgasi
ngas

i
i
i)Ger
mansi
l
ver (
c)Asol
uti
onofsol
i
dinl
i
qui
d

i
v)Ai
r (
d)Asol
uti
onofsol
i
dinsol
i
d

(
v)Hy
drogengasi
npal
l
adi
um (
e)Asol
uti
onofgasi
nli
qui
d

(
f)Asol
uti
onofl
i
qui
dinsol
i
d
3.Mat
cht
hel
awsgi
veni
nCol
umnIwi
thexpr
esi
onsgi
veni
nCol
umnI
I.
4.Mat
cht
het
ermsgi
veni
nCol
umnIwi
thexpr
essi
onsgi
veni
nCol
umnI
I.

Asser
ti
onandReasonTy
peQuest
ions
Note:I nthefol
lowingquest
ionsast atementofassert
ionfol
lowedbyast atementof
reasonisgiven.Choosethecorrectansweroutofthefoll
owingchoices.
(i
)Asser t
ionandreasonbotharecor rectst
atementsandreasoniscorrectexpl
anat
ion
forasserti
on.
(i
i)Asserti
onandr easonbot
har ecorrectstat
ementsbutreasonisnotcor r
ect
explanati
onforasserti
on.
 (i
ii)Asserti
oniscor r
ectst atementbutr easoni swr ongstat ement.(i
v )Asser ti
onand
reasonbot harei ncorrectst atement s.
(v)Assertioniswr ongst at ementbutr easoniscor rectstatement .
1.Asser t
ion:Mol ar i
tyofasol utioninliquidstatechangeswi thtemper ature.
Reason:Thev olumeofasol uti
onchangeswi thchangei nt emper ature.
2.Asser t
ion:Whenmet hyl alcohol isaddedt owat er,boili
ngpoi ntofwat erincreases.
Reason:Whenav ol
atilesol uteisaddedt oav olatil
esol ventelevati
oni nboi l
ingpoi nti
s
observed.
3.Asser t
ion:WhenNaCl i
saddedt owat eradepr essi oninfreezingpoi ntisobser ved.
Reason:Thel ower i
ngofv apourpr essureofasol utioncausesdepr essi onint he
freezi
ngpoi nt.
4.Asser t
ion:Whenasol utioni ssepar atedfrom t hepur esolventbyasemi -permeabl e
membr ane,thesol ventmol eculespasst hroughi tfrom puresol v
entsi det othesol uti
on
side.
Reason:Di f
fusionofsol v entoccur sf r
om ar egi onofhi ghconcent rat i
onsol uti
ont oa
regionoflowconcent rati
onsol ut
ion.

LongAnswerTy
peQuest
ions
1.Definethef ol
lowingmodesofexpr essi
ngtheconcent
rat
ionofasol
uti
on.Whi
chof
thesemodesar eindependentoftemperat
ureandwhy?
(i
)w/ w(massper centage)
(i
i)V/V(volumeper cent
age)
(i
ii
)w/ V(massbyv olumeper cent
age)
(i
v)ppm.( par t
spermi ll
ion)
(v)x(molef racti
on)
(vi
)M (Mol ari
ty)
(vi
i)m (Molalit
y)
2.UsingRaoul t
’slawexplainhowthet ot alvapourpressureoverthesolut
ioni
srel
atedt
o
mol ef
ractionofcomponent sinthef ollowingsoluti
ons.
(i
)CHCl 3(l
)andCH2Cl 2(
l)
(i
i)NaCl(s)andH2O( l
)
3.Explai
nt hetermsidealandnon-i
deal soluti
onsinthelightofforcesofi
nter
acti
ons
operat
ingbet weenmol ecul
esinliquidsol uti
ons.
4.Whyisitnotpossi
bletoobt
ainpureethanol byfr
acti
onaldi
sti
l
lat
ion?Whatgeneral
nameisgiventobinar
ymixtureswhichshowdev iat
ionfr
om Raoult
’sl
awandwhose
componentscannotbeseparatedbyfract
ionaldi
sti
ll
ati
on.Howmanyt ypesofsuch
mixt
uresarether
e?
5.Whenkepti
nwater
,rai
sinswel
lsinsize.Nameandexplai
nthephenomenoni
nvol
ved
wi
ththehel
pofadiagr
am.Givethreeappli
cat
ionsoft
hephenomenon.
6.Di
scussbi
ologi
cal
andi
ndust
ri
ali
mpor
tanceofosmosi
s.
7.Howcany
our
emov
ethehar
dcal
ci
um car
bonat
elay
eroft
heeggwi
thoutdamagi
ngi
ts
 semipr
ermi
ablemembrane?Canthi
seggbeinser
tedi
ntoabot
tl
ewi
thanar
rowneck
wit
houtdi
stor
ti
ngi
tsshape?Expl
ainthepr
ocessi
nvol
ved.
8.Whyisthemassdet
erminedbymeasur
ingacol
li
gat
ivepr
oper
tyincaseofsome
sol
utesabnor
mal?Di
scussitwi
tht
hehelpofVan’
tHofff
act
or.