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Poll
CHEMISTRY (C-06)
Syllabus: Haloalkanes and Haloarenes
Choose the correct answer. 3 In the following
1. Match the items given in column I with that given
reaction,
3R OH + PCl3
’3R- CI+X
in column Il R- OH+ PCls ’R-CI + HCI +Y
Columnl
The products X and Y are
Column Il (1) X= HsPO2; Y =H3PO3
sec-Butyl Bromoethene eXH3PO3 ; Y=POCb
bromide (3) X=POCls; Y= H3PO3
(4) X= POCh; Y=HsPO2
b neo-Pentyl (ii)2-Bromobutane Product 'A' in the following reaction is
bromide
HH
C. tert-Butyl (i) 1-Bromo-2;2 cE457 H,C-C-= CH,
bromide
dimethylpropane + HCI A(Major)
Vinyl bromide (iv) 2-Bromo-2
CI H H
methylpropane

(1) a(ii), b(i), c(i), d(iv)

Hc-¢-¢-CH,
(2) a(i), b(i), c(ii), d(iv)
JY a(i), b(ii), c(iv), d() (2) H,C-ÇH - CH,- CH, -CI
(4) a(iv), b(ii), c(i),d()
2. The given compound is an example of (X is
halogen)
H X (3) H,C-CH-¢-CH,
H-c=b-¢-CH,
Cl
(1) Vinylic halide 4HC-c- CH, - CH,
(2) Benzylic halide
(3) Ary halide
(4YAllylic halide
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 Poll-06
5 In the given reaction, Chemistry
NH, 9 The correct order for the rate of a, B
dehydrohalogenation for the following compounds
NaNO, + HCI is
273-278 K X cu (a)
(intermediate)
The intermediate 'X will be (b) C
NCI, N,CI (c)
CI
(1)
(1) (a)s (b) <(c) (2) (a) >(b) >(c)
NO, H-N-cI
(3Y (b) <(c) <(a) (4) (b) <(a) <(c)
10. In the following reaction:
(3)
(4) Mg (excess)
Dry ether Sintermediate x
Predict the order of
isomers towards SN2reactivity
reaction.
of the
following four the 'X' will be

CH3CH2CHCH2Br; (CH3)2CHCH2Br; (2)

CH3CH2CH(Br)CHs,
(1)
(CH3)sCBr
CH3CH2CH2CH2Br<
CH:CHaCH(Br)CH3 <(CH3)2CHCH2Br
(CH3)sCBr < (4)

LCHs):CBr <CHsCH:CH(Br)CH% < (11. ) Consider the reaction

(CHs)2CHCH2Br <CH3CH2CH2CH2Br CH, CH,
(3) CHsCH2CH2CH2Br < H,C - -Br +NaOH ’H,C -C-OH +NaBr
CHs}CHCH2Br <(CHa)CBrCH3CH2CH(Br)CH3 <
4 CHsCH2CH(Br)CH3 < (CH)2CHCH2Br < CC457 The reaction will be fastest in
CH3CH2CH2CH2Br <(CH3)3CBr AO:Wates
7. Best reagent for converting an alcohol into (2) Acetone
Corresponding chloride is
(3) N-N-Dimethylformamide (DMF)
(1) HCI/ ZnCh
(3) NaBr /H2SO4
(2) PCls
BIBY 4) Acetonitrile
12. Order of reactivity of haloarenes towards
8 The major product in the following reaction is nucleophilic substitution for the following
compounds is
CI CI
Anhy. AICI
+ H,C- C- Br

CI
(e) ()||
NO
CH,
NO
CI C

NO, o,N NO,

CH, (d)
Br Br
NO, NO,
CH,
(3) (4) (1) (d) >(c) >(b) >(a)
(2) (a) > (b) > (c) > (d)
(3 >(c) >(a) >(b)
cH, (4) (b) > (a) > (c) > (d)
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Chemistry
13. ldentify the correct order of boiling point of the Poll-06
following compounds YFinkelstein reaction
(1) CH3CH2CH(Br)CH, > CH3(CH2)2CH2Br> (2) B-elimination reaction
(3) Swartz reaction
(CH3):CBr > Cl (4) WurtzZ reaction
18. Given below are two
(2)
CI-Ci> CH:CH:CH(B)CH > Assertion(A) and thestatements: one is
other is labelled aslabelled
as
Reason
(R).
(CHs)3CBr >CH3(CH2)2CH2Br Assertion(A): CH3Cl
forming CH;OH, This reacts with aqueous NaOH
(3) (CH3)3CBr > CHCH2CH(Br)CH3 > SN2 mechanism. reaction proceeds through
Reason(R): by SN2CH3C prefers nucleophilic
CHs(CH2)2CH;Br > substitution mechanism due to less steric
crowding around carbon atom.
In the light of above
option.
statements, select the correct
> CHs(CH2)2CHaBr >
(1) Both (A)and (R) are true and (R) is the correct
CH3CH2CH(Br)CH3 >(CHs)3CBr explanation of (A)
(2) Both (A) and (R) are true but (R) is not the
14. Elimination reaction of 2-bromobutane to form correct explanation of (A)
but-2-ene is (3) (A) is true statement but (R)is false statement
(a) B-elimination reaction (4) Both (A) and (R) are false statements
19. Choose corect option among the following:
(b) Follows Saytzeffs rule Statement 1: The order of reactivity for SN2
(c) Dehydrohalogenation reaction reaction is 3° halide<2° halide<1° halide <CHsX
(d) Dehydration reaction Statement 2: The order of reactivity for SN1
reaction is CH3X<1° halide <2° halide <3° halide L
(1) (a), (c) and (d) (2) (a), (b) and (d) CC457 (Both statements are correct
(3)4a). (b)and (c) (4) (b), (c) and (d) (2) Statement 1 is correct but statement 2 is
incorrect
15. Chloroform is slowly oxidised by air in the
presence of light to an extremely poisonous gas, (3) Statement 1 is incorrect but statement 2 is
correct
which is
(4) Both statements are incorrect
CHCb. Oz light ’ HCI + A
20. The product for the following reaction is
(2) CH3CI Br
Dry ether
(4) CHsCOCI + 2Na X
(3) CCl4
in presence of
16. When ethene reacts with bromine Br
CCi4 it forms
(1) Geminal-dibromide (2)
(1)
2YVicinal-dibromide
(3) Geminal-dichloride Br Br
(4) Vicinal-dichloride
NaCl
17. R-Cl +Nal’R-|+
as
Above reaction is known

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