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Cet Aprs STP CBRN 0305 508
Cet Aprs STP CBRN 0305 508
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National Personal Protective Technology Laboratory
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P.O. Box 18070
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Pittsburgh, PA 15236
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Procedure No. CET-APRS-STP-CBRN-0305
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DETERMINATION OF CBRN ACID GASES (HYDROGEN SULFIDE)
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PURPOSE
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This test establishes the procedure for ensuring that the level of protection provided by
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the CBRN Acid Gases (Hydrogen Sulfide) Service Life Test, Air-Purifying Respirators Standard
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Test Procedure submitted for Approval, Extension of Approval, or examined during
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Certified Product Audits meet the minimum certification standards set forth in 42 CFR
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Part 84, Subpart G, Section 84.63(a)(c)(d); Volume 60, Number 110, June 8, 1995 and
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the Statement of Standard for Chemical, Biological, Radiological, and Nuclear (CBRN)
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Full- Facepiece Air- Purifying Respirator (APR) Dated March 7, 2003. .
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2. GENERAL
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This STP describes the Determination of CBRN Hydrogen Sulfide Service Life Test, Air-
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Purifying Respirators Standard Test Procedure sufficient detail that a person
knowledgeable in the appropriate technical field can select equipment with the necessary
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resolution, conduct the test, and determine whether or not the product passes the test.
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3.
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EQUIPMENT AND MATERIAL
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3.1. The list of necessary test equipment and materials follows:
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3.1.1. Miller Nelson Research Model 401 Flow-Temperature-Humidity Control
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System or equivalent. This system is an automated system to control the
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airflow, temperature, and humidity of an air supply for an operating
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system. Laboratory air and distilled water are supplied to the unit. The unit
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output is air of the variable volume/flow dependant on the size of unit
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(10% of max flow to max flow in liters per minute (Lpm) ± 2%), and
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relative humidity (10%–98% ± 3%) and temperature (20ºC–30º 0C ±
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0.3%).
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Approvals: 1st Level 2nd Level 3rd Level
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Procedure No. CET-APRS-STP-CBRN-0305
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3.1.2. EdgeTech Dew Prime II Hygrometer, Model 2000 or equivalent. A micro-
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processor based programmable chilled mirror dew point hygrometer . The
hygrometer uses the dew point and ambient temperature to calculate the
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relative humidity. Ambient temperature range is: -50ºC to 130ºC ± 0.2ºC;
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relative humidity is 1% to 95% ± 0.5%.
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3.1.3. Labview software developed for NIOSH Service Life Test.
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3.1.4. Interscan Corporation Model RM-17-0 hydrogen sulfide detector or
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equivalent. This detector is an electrochemical voltammetric sensor.
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Detector range: 0 - 1999 ppm, resolution: 1 ppm.
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3.1.5. Interscan Corporation Model RM-17-2 hydrogen sulfide detector or
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equivalent. This detector is an electrochemical voltammetric sensor.
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Detector range: 0 - 19.99 ppm, resolution: 0.01 ppm.
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3.1.6. Mass Flow Controller, Brooks Instruments, variable flow rate depending
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3.1.7. Read out and Control Electronics, Brooks Instruments, Model 0154,
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Power supply and controller for the Brooks Mass Flow Controller or
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equivalent. The flow controllers are an integrally mounted control valve
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module with which stable gas flows can be achieved. Various flow rates
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are used with an accuracy of ± 0.7 % of rate and ± 0.2 % full scale.
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3.1.8. Dry Gas Meter. Must have NIST traceable calibration certificate.
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3.1.9. Certified cylinders of 5 parts per million and 1000 parts per million
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hydrogen sulfide in nitrogen.
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3.1.10. Hydrogen sulfide cylinder, 99 percent purity.
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3.2 Test fixture for mounting canisters.
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3.3 The test chamber consisting of a 12" x 11½" x 7" air tight metal box with door
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opening lined with gasket material. Two ½" bulkhead Swaglok® fittings located
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on the backside of the test chamber for the introduction of the test concentration
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and for the exit of the test fixture. This fixture is not commercially available.
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3.4
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Resistance tester consisting of a vacuum source capable of delivering 85 Lpm, a
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6-inch water column slant manometer or electronic manometer and connections
appropriate for items being tested. See description in RCT-APR-003 and RCT-
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APR-007.
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Procedure No. CET-APRS-STP-CBRN-0305
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4. TESTING REQUIREMENTS AND CONDITIONS
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4.1.
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This test procedure is only valid if the respirator system has first completed
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NIOSH Standard Test Procedure entitled Determination Of Durability Test For
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Environmental And Transportation Conditions And Rough Handling Drop Test
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On Chemical Biological Radiological Nuclear (CBRN) Air-Purifying Respirators
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(APR) And Canisters Standard Test Procedure (STP).
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4.2. Prior to beginning any testing, all measuring equipment to be used must have
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been calibrated in accordance with the manufacturer's calibration procedure and
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schedule. At a minimum, all measuring equipment utilized for this testing must
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have been calibrated within the preceding 12 months using a method traceable to
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the National Institute of Standards and Technology (NIST).
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4.3.
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Any laboratory using this procedure to supply certification test data to NIOSH
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will be subject to the provisions of the NIOSH Supplier Qualification Program
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(SQP). This program is based on the tenets of ISO/IEC 17025, the NIOSH
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Manual of Analytical Methods and other NIOSH guidelines. An initial complete
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quality system audit and follow on audits are requirements of the program.
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Additional details of the Program and its requirements can be obtained directly
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from the institute.
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4.4. Precision and accuracy (P&A) must be determined for each instrument in
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accordance with laboratory procedures and NIOSH/NPPTL guidance. Sound
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practice requires, under NIOSH Manual of Analytical Methods, demonstrating a
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tolerance range of expected data performance of a plus or minus 25% of a 95%
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confidence interval of the stated standard requirement. NIOSH/NPPTL P&A
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tolerance can be higher but not lower.Compressed gas cylinders must meet all
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applicable Department of Transportation requirements for cylinder approval as
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well as retesting / requalification.
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4.5.
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Compressed gas cylinders must meet all applicable Department of Transportation
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requirements for cylinder approval as well as retesting / requalification.
4.6.
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Normal laboratory safety practices must be observed. This includes safety
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precautions described in the current NIOSH Pittsburgh Health and Safety
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Program.
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4.6.1. Safety glasses, lab coats and hard-toe shoes must be worn at all times.
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4.6.2. Workbenches must be maintained free of clutter and non-essential test
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equipment.
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4.6.3. When handling any broken glass laboratory equipment, lab technicians
Procedure No. CET-APRS-STP-CBRN-0305
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and personnel must wear special gloves, which protect against lacerations
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or punctures.
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Please refer to Material Safety Data Sheets and the NIOSH Health and
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Safety Manual for the proper protection and care in handling, storing, and
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disposing of the chemicals and gases used in this procedure.
5.
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PROCEDURE
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c o Note: Reference Section 3 for equipment, model numbers and manufacturers. For
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calibration purposes use those described in the manufacturer's operation and
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maintenance manuals.
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5.1.
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Follow individual instruction manuals for set up and maintenance of equipment
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used in this procedure prior to beginning testing. Malfunctioning equipment must
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be repaired or replaced and properly set up and calibrated before starting all tests.
U n 5.2.
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After the manufacturer's specified warm-up period, calibrate both hydrogen
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sulfide analyzers using the certified gas cylinder containing the 5 or 1000 ppm.
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5.3 Set up test equipment as shown in Figure 1. The humidity reading controlled by
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the Miller Nelson system and monitored the Dew Point Hygrometer. The sample
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pickup for the hygrometer is place into the air stream via a tee after the Miller
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Nelson and before the introduction point of challenge agent. The thermocouple
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for the hygrometer is placed in the challenge gas stream immediately before the
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test chamber.
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5.4. Verify the following equipment is on:
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5.4.1 Miller Nelson Unit.
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5.4.2 Air and water supplies.
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NIOSH Service Life Apparatus Controller software program.
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5.4.4
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Hydrogen sulfide cylinder, 99 percent purity.
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5.5
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Establish the correct humidity and temperature as per the test standard in
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paragraph 6.3.
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5.6
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Set the airflow to the required airflow for the test. Verify the airflow from the test
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fixture using the appropriate dry test meter.
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5.7 Weigh and record initial weight of the test canister on Test Data Sheet.
Procedure No. CET-APRS-STP-CBRN-0305
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5.8
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Take initial inhalation and exhalation resistances of the canister mounted on the
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facepiece and canister alone as described in RCT-APR-003 and RCT-APR-007.
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Record the values on Test Data Sheet.
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5.9 Make sure that the diverter valve in the system is diverting the challenge
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concentration airflow to discharge and not into the testing chamber.
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5.10
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Mount canister onto test fixture and place in testing chamber.
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5.11 Divert 0.5 Lpm airflow from air flow line to the hydrogen sulfide challenge
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detector.
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5.12
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Ensure that the nitrogen gas is ready for immediate flushing of regulator through
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the purge valve.
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5.13
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Turn on hydrogen sulfide cylinder.
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5.14
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Establish the test concentration of 1000 ppm hydrogen sulfide.
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5.15 Once the hydrogen sulfide concentration has been established, testing may begin.
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Direct challenge concentration airflow into test chamber.
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5.17
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Start timer. Airflow out of the test chamber is directed into the breakthrough
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detector. Monitor and record the upstream and downstream temperatures of the
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airflow throughout test.
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Run test until breakthrough of 5 ppm is observed or minimum service life is
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surpassed. Record this data on the test data sheet.
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5.19 Direct challenge concentration airflow out of the test chamber.
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5.20
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Weigh and record final weight of the test canister on Test Data Sheet.
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5.21
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Take final inhalation and exhalation resistances of the canister mounted on the
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facepiece and canister alone at 85 liters per minute. Record the values on Test
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Data Sheet.
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5.22
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Allow clean air to purge through system for 5 minutes.
5.23
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Repeat steps 5.5 through 5.22 for each test described in section 6.3.
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5.24 When all tests are completed turn off hydrogen sulfide cylinder, set temperature
Procedure No. CET-APRS-STP-CBRN-0305
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and humidity to zero and allow air to pass through the system for 30 minutes.
6.
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PASS OR FAIL CRITERIA
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6.1. The criterion for passing this test is set forth in 42 CFR Part 84, Subpart G,
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Section 84.63(a)(c)(d); Volume 60, Number 110, June 8, 1995.
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6.2.
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This test establishes the standard procedure for ensuring that:
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c o 84.63 Test requirements; general.
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(a) Each respirator and respirator component shall when tested by the applicant
and by the Institute, meet the applicable requirements set forth in subparts H
t r o p y
through L of this part.
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(c) In addition to the minimum requirements set forth in subparts H through L of
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this part, the Institute reserves the right to require, as a further condition of
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approval, any additional requirements deemed necessary to establish the
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quality, effectiveness, and safety of any respirator used as protection against
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hazardous atmospheres.
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(d) Where it is determined after receipt of an application that additional
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requirements will be required for approval, the Institute will notify the
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applicant in writing of these additional requirements, and necessary
t r o o p
examinations, inspections, or tests, stating generally the reasons for such
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requirements, examinations, inspections, or tests.
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6.3. Acid Gas (Hydrogen Sulfide) test for CBRN canisters
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6.3.1. Resistance to airflow of both canister and system will be taken before and
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after each test.
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6.3.2. Three canisters will be tested at 64 Lpm, continuous air flow, 25 % + 5 %
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relative humidity (RH), 25 oC + 5 oC and 1000 ppm hydrogen sulfide.
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Minimum service life will be 15, 30, 45, 60, 90 or 120 minutes as per
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manufacturer request.
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6.3.3. Three canisters will be tested at 64 Lpm, continuous air flow, 80 % + 5 %
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relative humidity (RH), 25 oC + 5 oC and 1000 ppm hydrogen sulfide.
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Minimum service life will be 15, 30, 45, 60, 90 or 120 minutes as per
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manufacturer request.
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6.3.4. Three canisters, or pairs of canisters, will be tested at 100 Lpm,
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continuous air flow, 50 % + 5 % relative humidity (RH), 25 oC + 5 oC and
Procedure No. CET-APRS-STP-CBRN-0305
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1000 ppm hydrogen sulfide. Minimum service life must be 5 minutes.
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6.3.5. End of service life concentration is 5 ppm hydrogen sulfide.
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7. RECORDS OR TEST SHEETS
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7.1. All test data will be recorded on the HYDROGEN SULFIDE SERVICE LIFE test
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data sheet.
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c o 7.2. All videotapes and photographs of the actual test being performed, or of the tested
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equipment shall be maintained in the task file as part of the permanent record.
7.3.
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All equipment failing any portion of this test will be handled as follows:
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7.3.1. If the failure occurs on a new certification application, or extension of
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approval application, send a test report to the RCT Leader and prepare the
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hardware for return to the manufacturer.
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7.3.2. If the failure occurs on hardware examined under an Off-the-Shelf Audit
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the hardware will be examined by a technician and the RCT Leader for
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cause. All equipment failing any portion of this test may be sent to the
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manufacturer for examination and then returned to NIOSH. However, the
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hardware tested shall be held at the testing laboratory until authorized for
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release by the RCT Leader, or his designee, following the standard
t r o o p
operating procedures outlined in Procedure for Scheduling, and Processing
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Post-Certification Product Audits,
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RB-SOP-0005-00.
8.
Un ATTACHMENTS
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8.1
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Bench Top Set-Up.
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8.2 Data Sheet.
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Procedure No. CET-APRS-STP-CBRN-0305
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Revision History
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Revision l Date
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20 September 2004 Historic document
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1.1 13 December 2005 Update header and format
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No changes to method
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