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Teb CBRN STP 0502 508
Teb CBRN STP 0502 508
e
P.O. Box 18070
o l l y
Pittsburgh, PA 15236
t r o p
Procedure No. TEB-CBRN-STP-0502 Revision: 0.0 Date: 21 November 2006
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c e
DETERMINATION OF CBRN ACID GASES (CYANOGEN CHLORIDE) SERVICE
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LIFE TEST, TIGHT-FITTING POWERED AIR-PURIFYING RESPIRATORS (PAPR)
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STANDARD TEST PROCEDURE (STP)
1.
n t r
PURPOSE
p y
c o C o
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This test establishes the procedure for ensuring that the level of protection provided by the CBRN
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Acid Gases (Cyanogen Chloride) Service Life Test, Tight-Fitting Powered Air-Purifying
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Respirators Standard Test Procedure submitted for Approval, Extension of Approval, or
r o p y
examined during Certified Product Audits, meet the minimum certification standards set forth in
t o
42 CFR Part 84, Subpart G, 84.63(a)(c)(d); Volume 60, Number 110, June 8, 1995 and the
c o n C
Statement of Standard for Chemical, Biological, Radiological, and Nuclear (CBRN) Powered
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Air-Purifying Respirator (PAPR).
U n
2. GENERAL
o l l
n tr p y
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This STP describes Determination of CBRN Acid Gases (Cyanogen Chloride) Service Life Test,
c o C
Tight-Fitting Powered Air-Purifying Respirators Standard Testing Procedure in sufficient detail
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that a person knowledgeable in the appropriate technical field can select equipment with the
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necessary resolution, conduct the test and determine whether the product passes the test.
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3.
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EQUIPMENT AND MATERIAL
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3.1. The list of necessary test equipment and materials follows:
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3.1.1. Miller Nelson Research Model 401 Flow-Temperature-Humidity Control System
tr o
or equivalent. This system is an automated system to control the airflow,
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temperature and humidity of an air supply for an operating system. Laboratory
o n o p
air and distilled water are supplied to the unit. The unit output is air of the
c C
variable volume/flow dependant on the size of unit (10% of max flow to max
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flow in Lpm ± 2%), and relative humidity (10-98 ± 3%) and temperature (20-30
0
l e
C ± 0.3%).
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3.1.2.
t r o py
EdgeTech Dew Prime II Hygrometer, Model 2000 or equivalent. A micro-
o
n C
processor based programmable chilled mirror dew point hygrometer. The
o d
hygrometer uses the dew point and ambient temperature to calculate the relative
n c e
humidity. Ambient temperature range is: -50ºC to 130ºC ± 0.2ºC; relative
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U l
humidity is 1% to 95% ± 0.5%
Approvals
t r o
First Level
c o n Second Level Third Level Fourth Level
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Procedure No. TEB-CBRN-STP-0502
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3.1.3. Labview software developed for NIOSH Service Life Testing.
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3.1.4. California Analytical Instruments, Model 1314 Photoacoustic Multigas Monitor
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with UA0985 optical filter or equivalent. This monitor uses photoacoustic
c e
infrared detection to measure gases that absorb infrared light. A filter is used to
Un o ll select the wavelength specific for the gas being detected. Range for cyanogen
chloride is 1000 to 0.1 ppm ± 0.01 ppm. Two detectors are used, one for
n t r y
challenge concentration and one for downstream concentration
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c o 3.1.5.
C o
Mass Flow Controller, Brooks Instruments, variable flow rate depending on use.
Un le
3.1.6.
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dRead out and Control Electronics, Brooks Instruments, Model 0154. Power
supply and controller for the Brooks Mass Flow Controller or equivalent. The
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flow controllers are an integrally mounted control valve module with which
o
stable gas flows can be achieved. Various flow rates are used with an accuracy of
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± 0.7 % of rate and ± 0.2 % full scale.
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U n 3.1.7.
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Dry Test Meter, American Meter Co., model and size depending on air flow to be
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measured. Must have NIST traceable calibration certificate.
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3.1.8. Cyanogen chloride cylinder, 99 % purity, with regulator and purge valve.
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3.1.9. Kin-Tek491 MB Basic Gas Standards Generator with cyanogen chloride
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permeation tubes that are certified to NIST standard or equivalent.
3.2
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Test fixture for mounting canisters.
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3.3 The test chamber consisting of an air tight box with door opening lined with gasket
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material. Two fittings located on the test chamber for the introduction of the test
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concentration and for the exit of the test fixture. This fixture is not commercially
available
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3.4
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Resistance tester equipment as described in standard test procedures RCT-APR-0003 and
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RCT-APR-0007.
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3.5
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Airflow measurement equipment as described in standard test procedure RCT-APR-
0012.
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4. TESTING REQUIREMENTS AND CONDITIONS
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4.1 For tight-fitting PAPR, this test procedure is only valid if the respirator system has first
U n l l
completed NIOSH Standard Test Procedure entitled Durability Conditions Process For
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Environmental, Transportation And Rough Handling Conditions On Chemical
t r
Biological, Radiological and Nuclear (CBRN) Respiratory Protective Devices (RPD)
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Standard Conditioning Procedure (SCP).
c o
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4.2 Prior to beginning any testing, all measuring equipment to be used must have been
Procedure No. TEB-CBRN-STP-0502
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calibrated in accordance with the manufacturer's calibration procedure and schedule. At a
o l l minimum, all measuring equipment utilized for this testing must have been calibrated
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within the preceding 12 months using a method traceable to the National Institute of
n t r o
Standards and Technology (NIST).
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c o 4.3
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Any laboratory using this procedure to supply certification test data to NIOSH will be
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subject to the provisions of the NIOSH Supplier Qualification Program (SQP). This
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program is based on the tenets of ISO/IEC 17025, the NIOSH Manual of Analytical
n t r y
Methods and other NIOSH guidelines. An initial complete quality system audit and
p
follow on audits are requirements of the program. Additional details of the Program and
c o C o
its requirements can be obtained directly from the Institute.
Un 4.4
le d
Precision and accuracy (P&A) must be determined for each instrument in accordance
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with laboratory procedures and NIOSH/NPPTL guidance. Sound practice requires, under
t r o p y
NIOSH Manual of Analytical Methods, demonstrating a tolerance range of expected data
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performance of a plus or minus 25% of a 95% confidence interval of the stated standard
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requirement. NIOSH/NPPTL P&A tolerance can be higher but not lower.
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U n 4.5
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Compressed gas cylinders must meet all applicable Department of Transportation
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requirements for cylinder approval as well as retesting / requalification.
n tr p y
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4.6 Normal laboratory safety practices must be observed. This includes safety precautions
c o C
described in the current NIOSH Pittsburgh Health and Safety Program.
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Un l e
4.6.1. Safety glasses, lab coats and hard-toe shoes must be worn at all times.
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4.6.2. Workbenches must be maintained free of clutter and non-essential test
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equipment.
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4.6.3 When handling any broken glass laboratory equipment, lab technicians and
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personnel must wear special gloves, which protect against lacerations or
punctures.
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4.7 Please refer to Material Safety Data Sheets and the NIOSH Health and Safety
c C
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Manual for the proper protection and care in handling, storing, and disposing of the
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chemicals and gases used in this procedure.
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5. PROCEDURE
Note:
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Reference Section 3 for equipment, model numbers and manufacturers. For calibration
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purposes use those described in the manufacturer's operation and maintenance manuals.
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5.1
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Follow individual instruction manuals for set up and maintenance of equipment used in
t
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this procedure prior to beginning testing. Malfunctioning equipment must be repaired or
o
replaced and properly set up and calibrated before starting all tests.
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Un
5.2 Calibrate both photoacoustic monitors for cyanogen chloride using the Kin-Tek gas
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generator and cyanogen chloride permeation tubes. The challenge monitor is calibrated
o l lfor the challenge concentration of 300 ppm and the downstream monitor is calibrated for
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the breakthrough concentration of 2 ppm. Make any necessary adjustments to the
n t r o
Labview software so that the concentration display on the software agrees with the
C
o
detector.
c l e d
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5.3 Set up test equipment as shown in Figure 1. The humidity reading controlled by the
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Miller Nelson system and monitored the Dew Point Hygrometer. The sample pickup for
n t r y
the hygrometer is place into the air stream via a tee after the Miller Nelson and before the
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introduction point of challenge agent. The thermocouple for the hygrometer is placed in
c o C o
the challenge gas stream immediately before the test chamber.
Un 5.4
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Verify the following equipment is on:
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t r o
5.4.1
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Air and water supplies.
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c o n 5.4.2
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Miller Nelson Unit.
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U n 5.5
le
Establish the correct humidity and temperature as per the test standard in paragraph 6.3.
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5.6
tr o y
Set the required airflow for the system. Individual canisters will be tested by dividing
o n o p
115 Lpm by the number of air-purifying elements on the system. See appendix 8.2.
C
Verify the airflow from the test fixture using the appropriate dry test meter.
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5.7 Weigh and record initial weight of the test canister on Test Data Sheet.
5.8
r o l py
Take and record initial airflow measurements in accordance with RCT-APR-012. See
n t C o
section 84.1152 (b) Title 42, Code of Federal Regulations, Part 84 for minimum airflow
o d
requirements.
c l e
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5.9 Take and record initial inhalation resistances for tight-fitting PAPR in accordance with
t o
RCT-APR-007. See Sections 84.122, 84.203, 84.1157 Title 42, Code of Federal
r y
Regulations, Part 84 for breathing resistance requirements.
o n o p
c C
5.10 Mount canister onto test fixture and place in testing chamber.
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5.11
l e d
Ensure that the nitrogen gas is ready for immediate flushing of regulator through the
purge valve.
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t r o o py
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5.12 Turn on the cyanogen chloride cylinder.
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5.13 Establish the test concentration of 300 ppm ± 30 ppm cyanogen chloride.
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5.14n o l l
Once the cyanogen chloride concentration has been established, testing may begin.
5.15
n t r
Direct challenge concentration airflow into test chamber.
c o
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5.16 Start timer. Airflow out of the fixture is directed into the breakthrough detector. Monitor
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and record the upstream and downstream temperatures of the air stream throughout
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5.17
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Run test until breakthrough of 2 ppm is observed or selected service life time is
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surpassed. Record this data on the test data sheet.
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5.18 Direct challenge concentration airflow out of test chamber.
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5.19
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Weigh and record final weight of the test canister on Test Data Sheet.
o n o p
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5.20 Take and record final airflow measurements in accordance with RCT-APR-012. See
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section 84.1152 (b) Title 42, Code of Federal Regulations, Part 84 for minimum airflow
le
requirements.
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5.21
t r o p y
Take and record final inhalation resistances for tight-fitting PAPR in accordance with
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RCT-APR-007. See Sections 84.122, 84.203, 84.1157 Title 42, Code of Federal
c o n C
Regulations, Part 84 for breathing resistance requirements.
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U n 5.22
le
Allow clean air to purge through system for 5 minutes.
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5.23
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Repeat steps 5.5 through 5.21 for each test described in section 6.3.
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5.24 When all tests are completed turn off cyanogen chloride cylinder, set temperature and
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humidity to zero and allow air to pass through the system for 30 minutes.
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6.
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PASS OR FAIL CRITERIA
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6.1. The criterion for passing this test is set forth in 42 CFR Part 84, Subpart G,
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84.63(a)(c)(d); Volume 60, Number 110, June 8, 1995.
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Un 6.2.
o l
This test establishes the standard procedure for ensuring that:
r
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84.63
t o p y
Test requirements; general.
c o C
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(a) Each respirator and respirator component shall when tested by the applicant and
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by the Institute, meet the applicable requirements set forth in subparts H through
l
L of this part.
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(c) In addition to the minimum requirements set forth in subparts H through L of this
c o C
part, the Institute reserves the right to require, as a further condition of approval,
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any additional requirements deemed necessary to establish the quality,
U n l l
effectiveness, and safety of any respirator used as protection against hazardous
o
atmospheres.
(d)
n t r
Where it is determined after receipt of an application that additional requirements
c o will be required for approval, the Institute will notify the applicant in writing of
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these additional requirements, and necessary examinations, inspections, or tests,
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stating generally the reasons for such requirements, examinations, inspections, or
o l l tests.
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6.3.
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Acid Gases (Cyanogen Chloride) Test for CBRN Canisters
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6.3.1 Inhalation resistance to airflow of system will be taken before and after each test
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6.3.2 Airflow measurements of system must be taken before and after each test.
n t r 6.3.3
p y
Three canisters will be tested at the determined, continuous air flow, 25 % ± 2.5
c o o
% relative humidity (RH), 25 oC ± 2.5 oC and 300 ppm cyanogen chloride.
C
Un l
6.3.4
l e dThree canisters will be tested at the determined, continuous air flow, 80 % ± 2.5
% relative humidity (RH), 25 oC ± 2.5 oC and 300 ppm cyanogen chloride.
t r o
6.3.5
o p y
Minimum service life will be 15, 30, 45, 60, 90 or 120 minutes as per
c o n C
manufacturer request. End of service life concentration is 2 ppm cyanogen
d
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chloride.
U n o l l
7.
tr
RECORDS AND TEST SHEETS
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7.1.
c C o
All test data will be recorded on the DETERMINATION OF CYANOGEN CHLORIDE
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SERVICE LIFE test data sheet.
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7.2. All videotapes and photographs of the actual test being performed, or of the tested
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equipment shall be maintained in the task file as part of the permanent record.
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7.3.
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All equipment failing any portion of this test will be handled as follows:
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7.3.1. If the failure occurs on a new certification application, or extension of approval
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application, send a test report to the TEB Team Leader and prepare the hardware
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for return to the manufacturer.
o n o p
c C
7.3.2. If the failure occurs on hardware examined under an off-the-shelf audit the
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hardware will be examined by a technician and the TEB Team Leader for cause.
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All equipment failing any portion of this test may be sent to the manufacturer for
l
examination and then returned to NIOSH. However, the hardware tested shall be
t r o py
held at the testing laboratory until authorized for release by the Branch Chief, or
o
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the Branch Chief’s designee, following the standard operating procedures
c o C
outlined in Procedure for Scheduling, and Processing Post-Certification Product
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Audits, RB-SOP-0005-00.
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8. APPENDIXES
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8.1
c o
Bench Top Set-Up
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8.2 Airflow calculations
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8.3 Test Data Sheet
n t r C o
c o l e d
Un r o l
n t o p y
c o C
Un l le d
t r o o p y
c o n d C
U n l le
tr o y
o n o p
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Un l l e
y
t r o o p
o n d C
c l e
Un r o l
n t o p y
c o C
Un l l e d
t r o o py
c o n d C
U n l le
t r o
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Appendix 8.1: Bench Top Set-Up
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c l e d
Un r o l
n t o p y
c o C
Un l le d
t r o o p y
c o n d C
U n l le
tr o y
o n o p
c d C
Un l l e
y
t r o o p
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c l e
Un r o l
n t o p y
c o C
Un l l e d
t r o o py
c o n d C
U n l le
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Appendix 8.2: Service life testing airflow calculations.
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Tight-fitting PAPR
o p y
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___________ Number of filtering elements on a tight-fitting PAPR System.
c l e
Un o l
115 Lpm airflow
n t r p y
Airflow for service life test = 115 Lpm / number of filtering elements
c o C o
Un l le d
o y
Test Flow
n t r o p
4 Canisters
c o d C
3 Canisters 2 Canisters 1 Canister
U n 28.8 Lpm
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38.3 Lpm 57.5 Lpm 115 Lpm
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o n o p
c d C
Un l l e
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t r o o p
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Un r o l
n t o p y
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U n l le
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Appendix 8.3: Test Data Sheet
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Un r o l
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t r o o p y
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Revision
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