PINNAACLE CLASSES

1. Which of the following alkanes has the lowest boiling point?  

(a) CI — CI CI  CI (b)
(a) n-Pentane (b) Isopentane  
(c) Neopentane (d) n-Hexane. CH3  CI
CH3CI
   
CH3
2. The maximum C—C bond length is in: (c) CH4 + CI + HCl (d) CI  CI

(a) C2H6 (b) C2H4 CI — CI

(c) C2H2 (d) C6H6 10. The major product obtained in the reaction, :

3. Marsh gas mainly contains:

(a) C2H2 (b) CH4

(c) H2S (d) CO

4. When water vapours are passed over aluminium carbide, we

get: (b) (c)

(a) acetaldehyde (b) ethylene

(a)
(c) methane (d) methyl alcohol

5. The complete combustion of CH4 gives :

(a) CO + H2 (b) CO + N2 (d)

(c) CO + N2O (d) CO2 + H2O
11. Only two isomeric monochloro derivatives are possible
for :-
6. Action of heat on a mixture of sodium propionate and
sodalime produces: (a) n-Pentane (b) 2,4-
Dimethyl pentane
(a) methane (b) ethane
(c) Toluene (d) 2,3-
(c) propane (d) ethylene
Dimethyl butane
7. What is the volume of oxygen required for the the complete
combustion of 4 litre of ethane?
12. Ethylene readily undergoes:
(a) addition reaction (b) substitution
(a) 4 litre (b) 8 litre reaction
(c) 12 litre (d) 14 litre (c) elimination reaction (d) rearrangement
reaction
8. Halogenation of alkanes is an example of
13. Kharasch effect regarding addition of HBr is not observed in :
(a) Free radical addition reaction (b)
Free radical substitution reaction (a) hex–1–ene (b) prop–1–ene
(c) Nucleophilic substitution reaction (d) (c) hex–3–ene (d) pent–1–ene
Nucleophilic addition reaction.
14. Intermediate in the following reaction is
9. During chlorination of methane to methyl chloride, the
propagation step is represented by
CH3–CH=CH2

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 PINNAACLE CLASSES
22. Which will undergo reaction with ammonical AgNO3 :

(a) (b)

(c) (d) (a) (b)

15. Peroxide effect is observed CH3–CH=CH–CCH

(a) Only with HBr (b) Only with HI (c) CH3–CH2–CH=CH–CH2–CH3 (d)
(c) Only with HCI (d) Only with HF CH2=CH–CH2–CH3

16. Reaction of HBr with propene in the presence of peroxide 23. Marsh gas mainly contains:
gives:
(a) C2H2 (b) CH4
(a) isopropyl bromide (b) allyl bromide
(c) n-propyl bromide (d) 3-bromopropane (c) H2S (d) CO

24. When water vapours are passed over aluminium carbide, we

17. The number of possible monochloro derivatives of 2, 2, 3, 3-
get:
Tetramethylbutane is -
(a) acetaldehyde (b) ethylene
(a) 2 (b) 3
(c) methane (d) methyl alcohol
(c) 4 (d) 1
25. The complete combustion of CH4 gives :
18. An organic compound C4H6 on ozonolysis gives
formaldehyde and glyoxal. What is the structure of organic
compound ? (a) CO + H2 (b) CO + N2
(c) CO + N2O (d) CO2 + H2O

26. Which among the following reagents convert alkyl halide into
(a) (b)
alkane?
(c) (d) CH3–CH2–CCH
(a) LiAlH4 (b) Na/dry ether
19. To prepare But-2-yne from 2, 2, 3, 3-Tetrachlorobutane, (c) R2CuLi (d) All of these
reagent used is : 27. 20 ml of methane are burnt with 50 ml of oxygen, the volume
of the gas left after cooling to room temperature will be
(a) Zinc dust /  (b) Sodamide
(c) Alc. KOH (d) aq. KOH (a) 80 ml (b) 60 ml
(c) 30 ml (d) 20 ml
20. Which of the following will react most readily with bromine?
28. By Wurtz reaction, a mixture of methyliodide and ethyliodide
(a) CH  CH (b) CH2 = CH2 gives
(c) CH3CH = CH2 (d) CH3CH2CH3.
(a) Butane (b) Ethane
(c) Propane (d) A
21. Ammonical AgNO3 give white ppt. after reaction with any mixture of the above three
compound then this reflects the presence of
29. Electrolysis of cold concentrated aqueous solution of
(a) One – CHO group (b) potassium succinate yields
One triple bond
(c) A terminal alkyne (d) (a) Ethane (b)
Compound is unsaturated Ethyne

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 PINNAACLE CLASSES
(c) Ethene (d) (a) 1-Chloro-2-propanol (b) 2-
Ethane-1, 2-diol Chloro-1-propanol
(c) 3-Chloro-1-propanol (d) 1-
30. In which of the following pairs, the bromination of first Chloro-1-propanol
member is easier than the second member ?
37. Addition of HCl to 3, 3, 3-trichloropropene gives
(a) Isobutane, n-butane (b)
n-Butane, isobutane (a) Cl3CCH2CH2Cl (b)
(c) Methane, ethane (d)
Cl3CCHClCH3
None of these
(c) Cl2CHCHClCH2Cl (d)
31. A gaseous hydrocarbon ‘X’ on reaction with bromine in light Cl2CHCH2CHCl2
forms a mixture of two monobromo alkanes and HBr. The
hydrocarbon ‘X’ is : 38. Kharasch effect regarding addition of HBr is not observed in :

(a) CH3–CH3 (b) (a) hex–1–ene (b) prop–1–ene

(c) hex–3–ene (d) pent–1–ene
(c) (d)
39. Intermediate in the following reaction is
32. The number of monochloro derivatives of isohexane is (Only
structural isomers)
CH3–CH=CH2
(a) 3 (b) 4
(c) 5 (d) 6
(a) (b)
(c) (d)
33. What will be the least molecular mass of an alkane which is
optically active?

(a) 70 (b) 80
40. Which of the following reacts most readily with conc.
(c) 90 (d) 100 H2SO4 ?

34. Reaction of ethene with Br2 in CCI4 gives: (a) CH2 = CH2 (b) CH3CH=CH2
(c) (CH3)2C = CH2 (d) with same rate
(a) Bromoethane (b)
1, 2-Dibromoethane
(c) 1, 1-Dibromoethane (d) 41. Which of the following will not form a colloidal system?
(a) Solid – gas (b) Liquid – Gas
1, 1, 2, 2-Tetrabromoethane. (c) Gas- gas (d) Gas – Liquid

42. Tyndall effect is not observed to

(a) Smoke (b) Emulsions
35. + Br2 P, P will have configuration : (c) Sugar solutions (d) Gold sol

43. Which of the following is not an example of an emulsifying

agent?
(a) Proteins (b) Gums (c) Soaps (d) Electrolytes
(a) (b) (c)
both true (d) none is true 44. Freshly prepared precipitate sometimes gets converted to
colloidal solutions by …………… .
(a) Coagulations (b) Electrolysis
36. Addition of CI2 water (or HOCI) to propene gives (c) Diffusion (d) Peptisation

45. Which is correct in case of van der Waals adsorption?

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 PINNAACLE CLASSES
(a) High temperature, low pressure +
(c) Negative catalysis takes places due to formations of H
(b) High temperature, high pressure
ions
(c) Low temperature, low pressure
(d) Catalyst poisoning takes place after some time in the
(d) Low temperature, high pressure
reactions.

46. Which of the following is not characteristic of

53. Traces of molybdenum are used with finely divid ed iron
chemisorptions?
which acts as a catalyst during Haber’s process for systhesis
(a) Adsorption is specific.
of ammonia. The Mo
mol−1 .
(b) Heat of adsorption is of the order of 200 kJ (a) Ac ts are a promoter to increases the activity of the catayst
(c) Adsorption is irreversible. (b) Acts as a poison to decrease the activity of the catalyst
(d) Adsorptions may is be multimolecular layers (c) Provides a new pathway to the reactions
(d) Forms another intermediate compound with lesser
activations energy.
47. Which of the following statement does not show correct
different between adsorption and absorption?
(a) In adsorption, the substance is concentrated only at the 54. Which of the following types of metals make the most
surface while in absorption it is uniformly distributed in the efficient catalysts?
bulk. (a) Alkali metals (b) Transition metals
(b) Adsorption is instantaneous while absorption is a slow (c) Inner transition metals (d) Alkaline earth metals
process.
(c) A substance can be adsorbed as well as absorbed 55. The oxide of nitrogen which acts as a catalyst in lead chamber
simultaneously and the process is called sorption. process is
(d) Only gases are adsorbed while solids and liquids are
(b)
NO 2 N O
(c) 2 4
N O
(d) 2 5
absorbed. (a) NO

48. The incorrect statement about physical adsorption is
(a) It lacks specificity
(b) It is generally reversible
(c) Porous surfaces are good adsorbent
(d) Heat of adsorption is quite high.
49. Which of the following graphs would yield a straight line?
(a) x / m vs P (b) log x / m vs p
(c) x / m vs log P (d) log x/m vs log p
50. Adsorption is accompanied by the evolution of heat. So
according to Le – Chatelier principl, the amount of substance 57. Lyophilic sols are also called reversible colloids because
adsorbed should
(a) Increase with decreases in temperature
(b) Increases with increases in temperature
(c) Decreases with decreases in temperature
(d) Decreases with increase in temperature
58. Which of the following is not a method for coagulations of
51. Which of the following catalysis is an example of negative
catalysis?
56. Which of the following statement about zeolites is not
correct?
(a) Zeolites are open structures of silica in which trivalent
aluminium is substituted by a fractions of silicon atoms.
(b) Shape selectivity of zeolites depends upon porous
structure of the catalyst.
(c) Zeolites are synthetic microporous aluminosilicates which
do not exist naturally.
(d) Zeolites are aluminosilicates having three dimensional
network.
(a) They can be reformed by mixing residue (dispersed phase)
(b) They can be easily precipitated from the colloidal system
(c) Once formed, the dispersion medium and dispersed
(d) Special reversible reactions are used to prepare them.
lyophobic sols?
(a) By electrophoresis

(a)
2 SO 2 +O 2 ⃗ V 2 O5 2 SO 3 (b) By mixing oppositely charged sols
(c) By adding electrolyte

(b)
CHCl 3 +O2⃗ Alcohol 2 COCl 2 +2 HCl (d) By adding a protective colloid

(c)
2 KClO 3 ⃗ MnO2 2 KCl+3 O 2 59. The substances which behave as colloidal solutions at higher
concentrations are called.
CO+ 3 H 2 ⃗ Ni CH 4 + H 2 O (a) Associated colloid (b) Multimolecular colloids
(d) (c) Macromolecular colloids (d) Protective colloids

52. Reactions of nitric acid with copper powder is initially not 60. What happens when a lyophilic sol is added to a lyophobic
fast but it becomes rapid after some time because sol ?
−
(a) Auto-catalysis takes place due to formations of
NO 2 (a) Lyophilic sol is protected
ions. (b) Lyophilic sol is protected
(b) Partial catalysis takes places due to formations of copper (c) Both the sols are coagulated
nitrate (d) Electrophoresis takes place

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 PINNAACLE CLASSES
69. When an excess of a very dilute aqueous solutions of KI is
61. Some medicines are more effective in the colloidal from added to a very dilute aqueous solutions of silver nitrate, the
because of colloidal particles of silver iodide are associated with which
(a) The charged colloidal particles present in it of the following Helmholtz double layer?
(b) The large surface area and easy assimilation
(a) AgI / Ag+⋮I − (b)
AgI / K +⋮NO−3
(c) Precipitation of medicine in the blood
(d) The stabilizations of medicine in colloidal form. AgI / NO−3 ⋮Ag+ −
(d) AgI / I ⋮K
+
(c)
62. Which of the following examples is correctly matched?
(a) Butter-gel (b) Smoke- emulsion 70. Which of the following is not the correct different between
(c) Paint – foam (d) Milk – aerosol lyophobic and lyophilic sols ?
Lyophobic sols Lyophilic sols
63. What is the role of adsorption in froth floatation process used (a) Require special Can be Prepared by
especially for concentrations of sulphide ores? Methods for Shaking with the
(a) Shape selective catalysts Preparation solvent
(b) Adsorption of pine oil on sulphide ore particles (b) Are reversible Are irreversible
(c) Adsorption of pine oil on impurities (c) Easily coagulate Cannot be easily
(d) Productions of heat in the process of exothermic reactions. By electrolytes coagulate
(d) Are less stable Are more stable
64. Which of the following is an example of absorption?
(a) Water on silica gel
(b) Water on calcium chloride
(c) Hydrogen on finely divided nickel
(d) Oxygen on metal surface

65. W hich of the following will show Tyndall effect?

(a) Aqueous solutions of soap below critical micelle
concentrations
(b) Aqueous solutions of soap above critical micelle
concentrations.
(c) Aqueous solutions of sodium chloride
(d) Aqueous solutions of sugar

66. A colloidal system having a solid substance as a dispersed

phase and a liquid as a dispersion medium is classified as
………. .
(a) Solid sol (b) Gel (c) Emulsion (d) Sol

67. Which of the following statements is not correct for

chemisorptions and physisorption?
(a) Physical adsorption occurs at a low temperature and
chemisorptions occurs at all temperature.
(b) Magnitude of chemisorptions decreases with rise in
temperature while physisorption increases with rise in
temperature.
(c) Chemisorption is irreversible and physisorption is
reversible.
(d) In physisorption activation energy is low while in
chemisorptions it is high.

68. Which of the processes is being shown in the figure ?

(a) Electrodialysis (b) Dialysis

(c) Electroosmosis (d) Electrophoresis

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