PINNAACLE CLASSES

1. A large increase in the rate of a reaction for a rise in Ea Ea

temperature is due to log e A=log e K + log K =A
(a) RT (b) RT
(a) The decrease in the number of collisions Ea
(b) The increase in the number of activated molecules log e K =log e A−
RT 2 log A=RT ln E a−ln K
(c) (d)
(c) The shortening of the mean free path
9. An endothermic reaction A→ B has an activation energy
(d) The lowering of the activation energy
15 kcal /mole and energy of reaction 5 kcal /mole . The
2. According to the collision theory of chemical reactions
activation energy of the reaction B→ A is
(a) A chemical reaction occurs with every molecular
(a) 20 kcal/mole (b) 15 kcal/mole
collision
(c) 10 kcal/mole (d) None of these
(b) Rate is directly proportional to the number of 10. Which of the following plots is in accordance with the
collisions per second Arrhenius equation
(c) Reactions in the gas phase are always of zero
order
(d) Reaction rates are of the order of molecular
speeds
3. According to Arrhenius theory, the activation energy is
(a) The energy it should possess so that it can enter
into an effective collision
(b) The energy which the molecule should possess in
order to undergo reaction
(c) The energy it has to acquire further so that it can 11. The Arrhenius equation expressing the effect of
temperature on the rate constant of a reaction is
enter into a effective collison −E a/ RT k =Ea / RT
(a) k =e (b)
(d) The energy gained by the molecules on colliding
Ea
with another molecule k =log e − E a / RT
c) RT (d) k = Ae
4. The energy of activation is
(a) The energy associated with the activated 12. For a reaction, activation energy ( Ea )=0 and rate
6 −1
molecules constant ( K )=3 .2×10 s at 300 K. What is the value of
(b) Threshold energy – energy of normal molecules the rate constant at 310 K
−12 −1 6 −1
(c) Threshold energy + energy of normal molecules (a) 3 .2×10 s (b) 3 .2×10 s
12 −1 6 −1
(d) Energy of products – energy of reactants (c) 6 . 4×10 s (d) 6 . 4×10 s
5. Which one of the following does not represent Arrhenius 13. Activation energy is given by the formula
equation

k = Ae − E/ RT log e k=log e A−
RT
E
(a)
log
K2
=
Ea
[
T 2−T 1
K 1 2. 303 R T 1 T 2 ]
[ ]
(a) (b) K1 Ea T 2 −T 1
log =−
E K2 2. 303 R T 1 T 2
log 10 k =log 10 A− −RT (b)
2 .303 RT k = AE
[ ]
(c) (d) K1 Ea T 1−T 2
log =−
6. Arrhenius equation is K2 2. 303 R T 1 T 2
(c) (d)
d ln K d ln K
=ΔE ¿ /RT =ΔE ¿ /RT 2 None of these
(a) dT (b) dT
14. Collision theory is applicable to
d ln K ¿ 2 d ln K ¿ (a) First order reactions (b) Zero order reactions
=−ΔE /RT =−ΔE /RT
(c) dT (d) dT (c) Bimolecular reactions (d) Intra molecular
7. Activation energy of any reaction depends on reactions
(a) Temperature 15. A graph plotted between log K vs 1/T for calculating
(b) Nature of reactants activation energy is shown by
(c) Number of collisions per unit time
(d) Concentration of reactants
8. Relation between rate constant and temperature by
Arrhenius equation is

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 PINNAACLE CLASSES

16. The rate constant is doubled when temperature

increases from 27°C to 37°C. Activation energy in kJ is
(a) 34 (b) 54
(c) 100 (d) 50

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