19-01-2023 Sr.S60 Elite, Target & LIIT-BTs Theory Based Jee-Main-GTM-14 Q.papeR

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Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI


A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_Elite, Target & LIIT-BTs JEE-MAIN Date: 19-01-2024
Time: 02.00Pm to 05.00Pm GTM-14 Max. Marks: 300
IMPORTANT INSTRUCTION:
1. Immediately fill in the Admission number on this page of the Test Booklet with Blue/Black Ball Point Pen
only.
2. The candidates should not write their Admission Number anywhere (except in the specified space) on the
Test Booklet/ Answer Sheet.
3. The test is of 3 hours duration.
4. The Test Booklet consists of 90 questions. The maximum marks are 300.
5. There are three parts in the question paper 1,2,3 consisting of Physics, Chemistry and Mathematics having
30 questions in each subject and subject having two sections.
(I) Section –I contains 20 multiple choice questions with only one correct option.
Marking scheme: +4 for correct answer, 0 if not attempt and ‐1 in all other cases.
(II) Section‐II contains 10 Numerical Value Type questions. Attempt any 5 questions only, if more than 5
questions attempted, First 5 attempted questions will be considered.
∎ The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer
value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and
less than 11 round off is 11).
To cancel any attempted question bubble on the question number box.
For example: To cancel attempted question 21. Bubble on 21 as shown below
SRI CHAITANYA IIT ACADEMY, INDIA 19‐01‐24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee‐Main_GTM‐14_Q.P

.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and ‐1 in all other cases.
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use of pencil is
strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone any electron
device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in the Hall.
However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet
Name of the Candidate (in Capital): ________________________________________________

Admission Number:
Candidate’s Signature:________________ Invigilator’s Signature: ________________
19‐01‐2023_Sr.S60_Elite, Target & LIIT‐BTs_Jee‐Main‐GTM‐14_Test Syllabus
PHYSICS : Theory Based
CHEMISTRY : Theory Based
MATHEMATICS : Theory Based

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SRI CHAITANYA IIT ACADEMY, INDIA 19‐01‐24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee‐Main_GTM‐14_Q.P

PHYSICS Max Marks: 100


(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Statement-I: The s-t (Position-time) diagram as shown in figure represents the body which
is moving in positive direction but not from origin s  0.
s

t0 t

Statement-II: In the above graph at t  t0, velocity of body changes its direction of motion.
1) Both Statements I and II are incorrect
2) Both Statements I and II are correct
3) If Statement-I is correct but Statement-II is incorrect.
4) If Statement-I is incorrect but Statement-II is correct.
2. A hockey player is moving northward and suddenly turns westward with the same speed to
avoid an opponent. The force that acts on the player is
1) Frictional force along westward 2) Frictional force along northwest
3) Frictional force along south-west 4) Muscle force along south-west
3. The force F required to stretch a spring varies with its elongation (x) as shown in the figure.
If the experiment is performed with the above spring of half the length, then the line OA will
F
A

O x
1) Shift towards F-axis 2) Shifts towards X- axis
3) Remain as it is 4) Become double in length
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4. Assertion (A): A ball tied by thread is undergoing circular motion (of radius R) in a vertical
plane.(Thread always remains in vertical plane). The difference of maximum and minimum
tension in thread is independent of speed (u) of ball at the lowest position (u  5 gR ).

Reason(R): For a ball of mass m tied by thread undergoing vertical circular motion (of
radius R), difference in maximum and minimum magnitude of centripetal acceleration of the
ball is independent of speed (u) of ball at the lowest position (u  5 gR ).

1) If both Assertion and Reason are correct and Reason is the correct explanation of
Assertion.
2) If Assertion is incorrect but Reason is correct.
3) If Assertion is correct but Reason is incorrect.
4) If both Assertion And Reason are correct but reason is not the correct explanation of
Assertion.
5. Work done by friction on a rolling body in case of pure rolling (consider all cases which
might possible)
1) Is always zero 2) Is always positive
3) Is always negative 4) May be positive, negative or zero.
6. Assertion(A): Two identical spheres of same material half filled with two liquids of
densities 1 and  2 (  1 ) .The centre of mass of both the (sphere + liquid) systems lie at
same level.

Reason: The center of mass of a system depends on distribution of mass of the system

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SRI CHAITANYA IIT ACADEMY, INDIA 19‐01‐24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee‐Main_GTM‐14_Q.P
1) If Assertion is incorrect but Reason is correct
2) If both Assertion And Reason are correct but reason is not the correct explanation of
Assertion.
3) If Assertion is correct but Reason is incorrect.
4) If both Assertion and Reason are correct and Reason is the correct explanation of
Assertion.
7. In the figure shown velocity of liquid which comes out is v , time of liquid to fall to ground
is t and range on ground is R. If the vessel is taken to a high mountain and observed
v, t , and R , now pick out correct match the following columns and mark the correct option
from the codes given below.

Column I Column II
A) v (p) will increase
B) t (q) will decrease
C) R (r) will remain same
Codes
1) A-p; B- q ; C- r 2) A-q ; B- p ; C- r
3) A-p ; B- r ;C- q 4) A-q; B- r; C- p
8. The unit of viscosity in the two different system of units are poise (P) and poiseuille  Pl  .

Which of the following statement is correct?


1) 1P  1Pl 2) 1P  10Pl 3) 10P  1Pl 4) 10P  2Pl
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9. The given curve represents the variations of temperature as a function of volume for one
mole of an ideal gas. Which of the following curves best represents the variation of pressure
as a function of volume?

1) 2)

3) 4)
10. Assertion (A): In summer, a metallic   0  scale will read more than the actual length.
Reason(R): In summer, length of metallic   0  scale increases.
1) If both Assertion and Reason are correct and Reason is the correct explanation of
Assertion.
2) If both Assertion and Reason are correct but reason is not the correct explanation of
Assertion.
3) If Assertion is correct but Reason is incorrect.
4) If Assertion is incorrect but Reason is correct.
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SRI CHAITANYA IIT ACADEMY, INDIA 19‐01‐24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee‐Main_GTM‐14_Q.P
11. Assertion (A): If volume of a gas is increasing but temperature of the gas is decreasing, then
heat given to the gas may be positive, negative or zero.
Reason (R): Heat given to a gas is a state function. It is not path function.
1) If both Assertion and Reason are correct and Reason is the correct explanation of
Assertion.
2) If Assertion is incorrect but Reason is correct.
3) If Assertion is correct but Reason is incorrect.
4) If both Assertion and Reason are correct but reason is not the correct explanation of
Assertion.
12. Figure shows the electric lines of force emerging from a charged body. If the electric field at
A and B are E A and EB respectively and if the distance between A and B is r, then

E E
1) E A  E B 2) E A  E B 3) E A  B 4) E A  B
r r2
13. Assertion (A): If temperature is increased, fundamental frequency of a close pipe whose
length does not change with temperature will increase.
Reason(R): By increasing the temperature, speed of sound wave in a gas will increase.
1) If Assertion is correct but Reason is incorrect.
2) If both Assertion and Reason are correct but reason is not the correct explanation of
Assertion.
3) If both Assertion and Reason are correct and Reason is the correct explanation of
Assertion.
4) If Assertion is incorrect but Reason is correct.
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SRI CHAITANYA IIT ACADEMY, INDIA 19‐01‐24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee‐Main_GTM‐14_Q.P
14. Assertion (A): If the surface charge densities of two spherical conductors of different radii
are equal. Then the electric field intensities near their surface are also equal.
Reason (R): Surface charge density is equal to charge per unit volume.
1) If both Assertion and reason are correct and reason is the correct explanation of Assertion
2) If both Assertion and Reason are correct but reason is not the correct explanation of
Assertion.
3) If Assertion is true but Reason is false.
4) If Assertion is false but Reason is true.
15. Figure shows some equipotential lines distributed in space. A charged particle is slowly
moved from point A to point B
20V 40V

100cm 50cm
A B A B

10V 30V 50V


10V 20V 30V 40V 50V
Fig(i) Fig(ii)
20V 40V

100cm
A B

10V 30V 50V

Fig(iii)

1) The work done against field in Fig (i) is the greatest


2) The work done against field in Fig (ii) is least
3) The work done against field is the same in Fig (i) ,Fig (ii) and Fig(iii)
4) The work done against field in Fig (iii) is greater than Fig (ii) but equal to that in Fig (i)
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16. A particle is in uniform circular motion in a horizontal plane. Its angular momentum is
constant about origin when the origin is taken at :
1) Any point outside in the space
2) Any point on the circumference of the circle
3) Any point inside the circle
4) Centre of the circle
17. The circuit diagram shown here corresponds to the logic gate

1) NOR 2) AND 3) OR 4) NAND


18. Assertion(A): Two current carrying resistance wires shown in figure are same material .
They have equal length. More heat is generated in wire B.

Reason(R): In series heat  H   resistance  R  and resistance of wire A is more .


1) If Assertion is false but Reason is true.
2) If both Assertion and Reason are correct but reason is not the correct explanation of
Assertion.
3) If Assertion is true but Reason is false.
4) If both Assertion and reason are correct and reason is the correct explanation of Assertion
19. An ionized gas contains both positive and negative ions initially at rest. If it is subjected
simultaneously to an electric field along the  ve x direction and a magnetic field along the
ve z direction , then

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SRI CHAITANYA IIT ACADEMY, INDIA 19‐01‐24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee‐Main_GTM‐14_Q.P
1) positive ions effectively deflect towards  ve y direction and negative ions ve y direction
2) all ions effectively deflect towards  ve y direction
3) all ions effectively deflect towards ve y direction
4) positive ions effectively deflect towards ve y direction and negative ions towards
ve y direction
20. A square current carrying loop abcd is placed near an infinitely long another current
carrying wire ef .
f
b c

a d
e

Column I Column II
A Net force on bc and da together p Zero
B Net force on part cd q Non-zero
C Net force on complete loop abcd r Right wards
D Net force on part ab s Leftwards
Now, match the column I with column II and mark the correct option from the codes given
below
1) A-p,s; B-r,q; C-p; D-s 2) A-q,r; B-q,r; C-r; D-s
3) A-p; B-q,r; C-q,s; D-q,s 4) A-p; B-r; C-p; D-q,s
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

Note:
From Question number's 21 to 30 rules for Answer marking
If the Questions have options then you have to answer as follows
If your answer is option 3 Then fill the OMR sheet as ‘3’
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If your answer is options 2&4, Then fill the OMR sheet as ‘24’
if you answer is options 1,3&4 then fill the OMR sheet as ‘134’
And if you answer is options 1,2,3&4 then fill the OMR sheet as ‘1234’
If the question is numerical based, then fill the OMR sheet as usual
21. The figure shows the path of a positively charged particle 1 Through a rectangular region of
uniform electric field as shown in the figure. Choose correct options among the following
If negative charged particle 2, positive charged particle 3, negative charged particle 4 are
entering the electric field as shown in the figure (Neglect gravitational force)
Top
2 3
4
1
Down
1) The direction of electric field is towards top
2) The direction of motion of particle 3 is towards top
3) The direction of motion of particle 2 is towards down
4) The direction of motion of particle 4 is towards down
22. The materials suitable for making electromagnets should have.
(Choose correct options among the following)
1) high retentivity 2) high coercivity 3) low coercivity 4) low retentivity
23. The adjoining figure shown the variation of photocurrent with anode potential for a
photosensitive surface for three different radiations . Let na ,nb and nc be the number of
incident photons per unit area and time, f a , fb and f c be the frequencies of incident light,
a , b and c are the de-Broglie matter wave length of fastest photo electrons for the curves
a,b and c respectively

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Column I Column II
A na p 1
nb
B a q <1
c
C fa r >1
fb
Now, match the column I with Column II and choose the correct options from the codes
gives below
1) A matches with p 2) B matches with r
3) C matches with p 4) A matches with q
24. When a progressive transverse wave is propagating along stretched string
(Choose correct options among the following)
1) The small element of string located at extreme position have lowest potential energy
2) The small element of string located at extreme position have highest potential energy
3) The small element of string located at extreme position have highest kinetic energy
4) The small element of string located at extreme position have lowest kinetic energy
25. In the figure shown, S1 and S 2 are two identical coherent point sources of light which are

coherent and out of phase by 1800 . Taking S1 as centre, two circular arcs  and m of radii 1
m and 2 m are drawn. Taking S2 as centre, two circular arcs p and q are drawn having radii
2 m and 4 m respectively. It is given that wavelength of wave produced by each source is
4.0m.Then Choose correct options among the following

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SRI CHAITANYA IIT ACADEMY, INDIA 19‐01‐24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee‐Main_GTM‐14_Q.P
1) Constructive interference is observed at A
2) Constructive interference is observed at B
3) Constructive interference is observed at C
4) Constructive interference is observed at D
26. Seven vectors have magnitude and direction as indicated in the figure, If the vector addition
  
 4    5   n  then find n


 2


8  
1  3



 6
 
9  4 5


7
27. A certain mass of an ideal gas is at pressure p1 and volume V1. It is compressed isothermally
and then allowed to expand adiabatically until its pressure returns to p1 . The gas is then
allowed to expand to its original volume. Upon which of the following p  V graphs are
these processes correctly shown ?
p

P1

V
V1
1) 2) 3)

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SRI CHAITANYA IIT ACADEMY, INDIA 19‐01‐24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee‐Main_GTM‐14_Q.P
p
p p

p1
P1
P1

V V V
V1 V1 V1
4) 5) 6)
p p

P1 P1

V V
V1 V1
7) 8)
28. Two infinitely long conductors carrying equal currents are shaped as shown in figure. All the
short sections are shaped as shown in figure and all the short sections are of equal lengths.
The point P is located symmetrically with respect to the conductors. The magnetic field at P
due one conductor is B. If the total field at P is xB then find x

29. There are certain materials developed in laboratories which have a negative refractive index.
A ray incident from air (medium 1wose   1 ) into such a medium (medium 2) shall
follows a path among the following option(s) given by
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medium(1) medium(1)
i i medium(1) i r

medium(2)
r medium(2) r medium(2)

1) 2) 3)

medium(1) i
r
i medium(1) i medium(2)
medium(1)
medium(2) medium(2) r

4) 5) 6)

medium(1) i medium(1) medium(1) i

7) medium(2) 8) medium(2) 9) medium(2)


30. The direction of ray of light incident on a concave mirror is shown by PQ while direction in
which the ray would travel after reflection is shown by nine rays marked 1,2,3,4,5,6,7,8 and
9. Which of the nine ray/rays can be correctly shows the direction of reflected ray?
(C is center of curvature, F is focus)
8

Q
2 4

9
C 7
F
3
5 6
P

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CHEMISTRY Max Marks: 100


(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
31. Which of the following statements is false
1) Two different solutions of sucrose of same molality prepared in different solvents will
have the same depression in freezing point.
2) The osmotic pressure of a solution is given by the equation   CRT (where C is the
molarity of the solution).
3) Decreasing order of osmotic pressure for 0.01 M aqueous solutions of barium chloride,
potassium chloride, acetic acid and sucrose is BaCl2  KCl  CH 3COOH  Sucrose .
4) According to Raoult’s law, the vapour pressure exerted by a volatile component of a
solution is directly proportional to its mole fraction in the solution.
32. On the basis of information given below mark the correct option.
Information: On adding acetone to methanol some of the hydrogen bonds between
methanol molecules break.
1) At specific composition methanol-acetone mixture will form minimum boiling azeotrope
and will show positive deviation from Raoult’s law.
2) At specific composition methanol-acetone mixture forms maximum boiling azeotrope and
will show positive deviation from Raoult’s law.
3) At specific composition methanol-acetone mixture will form minimum boiling azeotrope
and will show negative deviation from Raoult’s law.
4) At specific composition methanol-acetone mixture will form maximum boiling azeotrope
and will show negative deviation from Raoult’s law.

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SRI CHAITANYA IIT ACADEMY, INDIA 19‐01‐24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee‐Main_GTM‐14_Q.P
33. Electrode potential for Mg electrode varies according to the equation
0.059 1
E 2  Eo  log . The graph of E 2  VS log  Mg 2  is
Mg / Mg Mg 2  / Mg 2  Mg 
2  Mg / Mg  
 

1) 2)

3) 4)
34. Match the terms given in Column I with the items given in Column II.
Column I Column II
i)  m (Molar conductance) a) intensive property
0
ii) ECell b) depends on number of ions per unit volume
iii)  (Conductivity) c) extensive property
iv)  r GCell d) increases with dilution
1) i-b; ii-a; iii-c; iv- d 2) i-a; ii-b; iii-d; iv- c
3) i-d; ii-a ;iii- b; iv-c 4) i-b ;ii-d iii- a; iv-c

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35. Which of the following statements is incorrect about the collison theory of chemical
reaction
1) It considers reacting molecules or atoms to be hard spheres and ignores their structural
features.
2) Number of effective collisions determines the rate of reaction.
3) Collision of atoms or molecules possessing only proper orientation results into the
product formation.
4) Molecules should collide with sufficient threshold energy and proper orientation for the
collision to be effective.
36. Highest oxidation state of manganese in fluoride is 4  MnF4  but highest oxidation state

in oxides is 7  Mn2O7  because ____________.

1) fluorine is more electronegative than oxygen.


2) fluorine does not possess d-orbitals.
3) fluorine stabilises lower oxidation state.
4) in covalent compounds fluorine can form single bond only while oxygen forms double
bond.
37. The colour of the coordination compound depends on the crystal field splitting. What will
be the correct order of absorption of wavelength of light in the visible region, for the
3 3 3
complexes Co  NH 3 6  , Co  CN 6  , Co  H 2O 6 
3 3 3 3 3 3
1) Co  CN 6   Co  NH 3 6   Co  H 2O 6  2) Co  NH 3 6   Co  H 2O 6   Co  CN 6 
3 3 3 3 3 3
3) Co  NH 3 6   Co  CN 6   Co  H 2O 6  4) Co  H 2O 6   Co  NH 3 6   Co  CN 6 

38. Assertion : Phenol forms 2, 4, 6 – tribromophenol on treatment with Br2 in carbon


disulphide at 273K.
Reason: Bromine is highly polarised in carbon disulphide.
1) Assertion and Reason are correct and Reason is the correct explanation of Assertion.
2) Assertion and Reason both are incorrect.
3) Assertion is correct and Reason is incorrect.
4) Assertion and Reason are correct but reason is not the correct explanation of Assertion.
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39. Benzophenone can be obtained by ____________.
1) Benzoyl chloride + Benzene  AlCl3
2) Benzoyl chloride + Diphenyl amine
3) Benzoyl chloride + Methyl magnesium chloride
4) Benzene + Carbon monoxide  ZnCl2
40. Best method for preparing primary amines from non stearically hindered alkyl halides
(RX) without changing the number of carbon atoms in the chain (R) is
1) Hoffmann Bromamide reaction 2) Gabriel phthalimide synthesis
3) Sandmeyer reaction 4) Reaction with limited amount of NH 3
41. Which of the following reactions of glucose can be explained only by its cyclic structure?
1) Glucose forms pentaacetate.
2) Glucose reacts with hydroxylamine to form an oxime.
3) Pentaacetate of glucose does not react with hydroxylamine.
4) Glucose is oxidised by nitric acid to gluconic acid.
42. The probability density plots of 1s and 2s orbitals are given in

The density of dots in a region represents the probability density of finding electrons in the
region. On the basis of above diagram which of the following statements is incorrect
1) 1s and 2s orbitals are spherical in shape.
2) The probability of finding the electron is maximum near the nucleus.
3) The probability of finding the electron at a given distance is equal in all directions.
4) The probability density of electrons for 2s orbital increases as the distance from the
nucleus increases.

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43. The formation of the oxide ion O 2  g  from oxygen atom requires first an exothermic and

then an endothermic step as shown below:

O  g   e  O   g  ; H 0  141kJ mol 1

O   g   e  O 2  g  ; H 0  780 kJ mol 1

Thus process of formation of O 2 in gas phase is unfavourable even though

O 2  is isoelectronic with neon. It is due to the fact that,


1) oxygen is more electronegative.
2) addition of electron in oxygen results in larger size of the ion.
3) electron repulsion outweighs the stability gained by achieving noble gas configuration.

4) O  ion has comparatively smaller size than oxygen atom.


44. Assertion (A): Though the central atom of both NH 3and H 2O molecules are sp 3
hybridized, yet H–N–H bond angle is greater than that of H–O–H.
Reason (R): NH 3 has lone pair-bond pair repulsions which are more than bond pair-bond
pair repulsions where as H 2O has lone pair-lone pair repulsions which are more than
lone pair-bond pair and bond pair-bond pair repulsions
1) A and R both are correct, and R is the correct explanation of A.
2) A and R both are correct, but R is not the correct explanation of A.
3) A is true but R is false.
4) A and R both are false.
q
45. The entropy change can be calculated by using the expression S  rev . When water
T
freezes in a glass beaker, choose the correct statement amongst the following:
1) ΔS (system) decreases but ΔS (surroundings) remains the same.
2) ΔS (system) increases but ΔS (surroundings) decreases.
3) ΔS (system) decreases but ΔS (surroundings) increases.
4) ΔS (system) decreases and ΔS (surroundings) also decreases.

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46. Assertion (A): Spontaneous process is an irreversible process and may be reversed by
some external agency.
Reason (R): Decrease in enthalpy is a contributory factor for spontaneity.
1) Both A and R are true and R is the correct explanation of A.
2) Both A and R are true but R is not the correct explanation of A.
3) A is true but R is false.
4) A is false but R is true.
47. Which of the following statements is incorrect
1) In equilibrium mixture of ice and water kept in perfectly insulated flask mass of ice and
water does not change with time.
2) The intensity of red colour increases when oxalic acid is added to a solution containing
iron (III) nitrate and potassium thiocyanate.
3) On addition of catalyst the equilibrium constant value is not affected.
4) Equilibrium constant for a reaction with negative ΔH value decreases as the temperature
increases.
48. Assertion (A): The compound cyclo octa tetraene has the following structural formula:

It is cyclic and has conjugated 8 -electron system but it is not an aromatic compound.
Reason (R): (4n + 2) π electrons rule does not hold good when the ring is not planar.
1) Both A and R are correct and R is the correct explanation of A.
2) Both A and R are correct but R is not the correct explanation of A.
3) Both A and R are not correct.
4) A is not correct but R is correct.

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49. During hearing of a court case, the judge suspected that some changes in the documents
had been carried out. He asked the forensic department to check the ink used at two
different places. According to you which technique can give the best results
1) Column chromatography 2) Solvent extraction
3) Distillation 4) Thin layer chromatography
50. Arrange the following in decreasing order of their boiling points.
A) n–butane B) 2–methyl butane
C) n-pentane D) 2,2–dimethyl propane
1) A > B > C > D 2) B > C > D > A
3) D > C > B > A 4) C > B > D > A
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
51. The number of the following graphs which are consistent with zero order kinetics
Concentration
of Reactant
Half life

ii)
i)

Concentration Time
of Reactant
Concentration
Reaction rate

of Reactant

slope  k
iii) iv)

Time Time
52. Interstitial compounds are formed when small atoms are trapped inside the crystal lattice of
metals. The number of correct statements regarding the characteristic property of interstitial
compounds is_____
i) They have high melting points in comparison to pure metals.
ii) They are very hard.
iii) They retain metallic conductivity.
iv) They are chemically very reactive.
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53. Number of aromatic alcohols among the following is _________
OH CH 2OH CH 2OH OH CH 2OH

CH 3 CH 3

54. Thiosulphate reacts differently with iodine and bromine in the reactions given below:
2S2O32  I 2  S4O62  2 I 
S2O32  Br2  5H 2O  2SO42  2 Br   10 H 
Number of statements justifies the above data
i) Bromine is a stronger oxidant than iodine.
ii) Bromine is a weaker oxidant than iodine.
iii) Thiosulphate undergoes oxidation by bromine
iv) Thiosulphate is reduced by iodine
v) Bromine undergoes oxidation
vi) iodine undergoes reduction
55. Number of correct parameters among the following regarding the free expansion of an ideal
gas under adiabatic condition.
i) q  0 ii) T  0 iii) w  0 iv) U  0 v) T  0 vi) T  0
56. Number of amphoteric oxides among the following is _______
PbO, PbO2 , CrO3 , SnO, SnO2 , As2O3 ,VO, Sb2O3, BeO, Al2O3 , ZnO, CuO
57. 1mole of KMnO4 can oxidise completely x moles of FeSO4 in acid medium then x is ____
3
58. The spin only magnetic moment of CoF6  is____________ BM
(round off to nearest integer)
3h
59. The angular momentum of electron is a circular orbit is and its orbital angular momentum

is zero then the number of radial nodes in that orbital is ______________
60. Number of compounds that can undergo cannizaro reaction
CHO CHO CHO

CH 3 HCHO CH 3CHO
CHO

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MATHEMATICS Max Marks: 100


(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
61. Define the right derivative of a function f at x  a to be the following limit if it exists.
f ( a  h)  f ( a )
lim , where h  0 means h approaches 0 only through positive values.
h0  h
S1 : f ( x )  x has a right derivate at x  0.

S 2 : If f has a right derivative at x  a then f is continuous at x  a.


S3 : If f is continuous at x  a then f has a right derivative at x  a.
The number of statements among the S1, S 2 , S3 which are always true for every function
1) 0 2) 1 3) 2 4) 3
62. Which of the following is best representation of the region satisfied by z on Argand plane

if arg  z  2  2i   .
4
y
y

O x
 2, 2  450
O x
450

 2, 2
1) 2)
y

y
O x
 2, 2

O x
450

 2, 2
3) 4)

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63. Let A, B and C are any three events
S1 : (i ) p ( A  B )  p ( A). p ( B )
(ii ) p ( B  C )  p ( B ). p (C )
(iii ) p(C  A)  p(C ). p( A) are enough condition for A, B, C are independent
S 2 : p ( A  B  C )  p ( A). p ( B ). p (C ) is enough condition for A, B, C is independent
1) S1 and S2 are true 2) S1 is false and S2 is true
3) S1 is true and S2 is false 4) S1 is false and S2 is false
64. Let 1 = the number of onto function from A  B where A  a1, a2 ,........., an  and
B  b1, b2 ,........., br   r  n 
2  the number of ways in which n different things can be distributed into r  r  n 
different groups is r n  r C1(r  1)n  r C2 (r  2) n  ...  (1)r 1. r Cr 1 .
3  Coefficient of x n in n!(e x  1)r  r  n, r , n  N  .
1) 1  2  3 2) 1  2  3 3) 1  2  3 4) 1  2  3
65. S1 : If a function is defined on [a,b] and continuous on (a,b), then it takes its extreme values
on [a,b].
S 2 : Every continuous and bounded function on  ,   takes on its extreme values.

1) S1 and S2 are true 2) S1 is false and S2 is true


3) S1 is true and S2 is false 4) S1 is false and S2 is false

66. Let S1 : The complex number (e3 )i lies in the third quadrant.
S 2 : If z1  z2  z1  z2 for some complex numbers z1 and z2 , then z2 must be 0.
2
S3 : For distinct complex numbers z1 and z2 .the equation  z  z1   ( z  z2 ) 2 has at most

4 solutions.
Z2
S 4 : Im z1  0 and Im z2  0 Then  Z1  is always a non real complex number.

The number of TRUE statements among the S1, S 2 , S3 , S 4


1) 0 2) 1 3) 2 4) 3
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67. Let f :    be a function ,where  is the set of real numbers. The statements
S1, S 2 , S3 , S 4 are given below,

S1 : If f ( x )  f ( y )  2024 x  y for all x, y then f must be continuous everywhere.

S 2 : If f ( x )  f ( y )  2024 x  y for all x, y then f must be differentiable everywhere.


2
S3 : If f ( x )  f ( y )  2024 x  y for all x, y then f must be differentiable everywhere.
2
S 4 : If f ( x )  f ( y )  2024 x  y for all x, y then f must be constant.

The number of statements among the S1, S 2 , S3 , S 4 which are always true for every function
1) 0 2) 1 3) 2 4) 3
68. Let A be a 2  2 matrix with real entries Let I be the 2  2 identity matrix. tr ( A) denote by

the sum of diagonal entries of A. Assume that A2  I .


Statement-1: If A  I and A   I , then det( A)  1.
Statement-2: If A  I and A   I , then tr ( A)  0.
1) S1 and S2 are true 4 2) S1 is false and S2 is true
3) S1 is true and S2 is false 4) S1 is false and S2 is false
100 
69. Assertion (A): 0 sin x dx  100  sin x dx
0
nT T
Reason(R): 0 f  x  dx  n  f  x  dx, where T is the period of the function and n  R
0
(set of all real numbers)
1) Assertion and Reason are correct and Reason is the correct explanation of Assertion.
2) Assertion And Reason are correct but reason is not the correct explanation of Assertion.
3) Assertion is correct but Reason is incorrect.
4) Assertion is incorrect but Reason is correct.

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70.
  

Let f : R   2n  1 : n  Z   R is defined by f  x   sec2 x  tan2 x .
 2 

S1 : f is periodic function without fundamental period
S 2 : f is continuous at each point in the domain of f
S3 : f is differentiable at each point in the domain of f
S 4 : lim f  x  is does not exist

x
2
The number of TRUE statements among the S1, S 2 , S3 , S 4
1) 0 2) 1 3) 2 4) 3
71. The average incomes of the people in two villages are P and Q , respectively. Assume that
P  Q . A person moves from the first village to the second village. The new average
incomes are P ' and Q ' respectively. Which of the following is not possible?
1) P '  P and Q '  Q 2) P '  P and Q '  Q
3) P '  P and Q'  Q 4) P '  P and Q '  Q
72. Assertion (A): The exponent of 2 in 100! is 97
n  n   n   n 
Reason(R): The exponent of p in n! is          ..........   
 p   p 2   p3  k
 p 
Where . is G.I.F, and p,n
1) Assertion and Reason are correct and Reason is the correct explanation of Assertion.
2) Assertion And Reason are correct but reason is not the correct explanation of Assertion.
3) Assertion is correct but Reason is incorrect.
4) Assertion is incorrect but Reason is correct.
73. The length of side’s of a triangle ABC are positive integers. The smallest side has length 1.
Which of the following statement is true?
1) The area of the triangle ABC is always a rational number
2) The area of the triangle ABC is always an irrational number
3) The perimeter of the triangle ABC is an even integer
4) The information provide is not sufficient to conclude any of the above options 1,2 or 3

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74. Assertion (A): The power of the Point 1,1 with respect to the circle 2x2  2 y 2  1 is 3

Reason(R): The power of the point ,   with respect to circle ax 2  ay 2  r 2 is a 2  a 2  r 2


1) Assertion and Reason are correct and Reason is the correct explanation of Assertion.
2) Assertion and Reason are correct but reason is not the correct explanation of Assertion.
3) Both Assertion and Reason are incorrect.
4) Assertion is incorrect but Reason is correct.
75. Let A   a1 , a2  and B   b1 , b2  be two points in the plane with integer coordinates. Which one
of the following is not a possible value of the distance between A and B?
1) 65 2) 74 3) 83 4) 97
76. Let P  S  denote the power set of S  1, 2,3,...........,10 . Define the relation R on P  S  as
A R B if  A  B C    B  AC     empty set  , A, B  P  S 
1) R is reflexive relation but not symmetric relation
2) R is reflexive relation and symmetric relation but not transitive relation
3) R is reflexive relation and transitive relation but not symmetric relation
4) R is equivalence relation
77. Let S1 : If a function is not monotonic, then it does not have an inverse function
S 2 : If a function is not monotonic on  a, b  , then its square cannot be monotonic on  a, b  .
S3 : If both functions f  x  and g  x  are continuous and monotonic on  , then their sum
f  x   g  x  is also monotonic or constant on .
The number of statements among the S1, S2 , S3 which are always true for every function
1) 0 2) 1 3) 2 4) 3
78. A and B are two sets such that
 x y 
A   x, y  :   r , r is fixed positive real number and  is real 
 cos sin  
 x y 
B   x, y  :   r , r  R  and  is fixed 
 cos sin  
Let C1 and C2 be the curves represented by A and B respectively then
1) C1 is circle
2) C2 is circle
3) C1 is a straight line and C2 is ray
4) The information provide is not sufficient to conclude any of the above options 1,2 or 3
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b b b
79. S1 : If neither of the integrals 
a
f  x  dx and  g  x  dx exist, then the integral
a
  f  x   g  x   dx
a

does not exist for every function f  x  and g  x 


b b
S2 : If neither of the integrals  f  x  dx
a
and  g  x  dx exist, then the integral
a

 a
b
f  x  dx    g  x  dx  does not exist for every function f  x  and g  x  then
b

1) S1 and S2 are true 2) S1 is false and S2 is true


3) S1 is true and S2 is false 4) S1 is false and S2 is false
80. Let S1 : The number of subsets of a, b, a, b is 16
S2 : a, b  a, a, b , c
S3 : For any finite set S , let S denote the number of elements in S . The number of ordered
pairs  A, B  such that A and B are (not necessarily distinct) subsets of 1, 2,3........., n that
satisfy A . B  A  B . A  B then A  B  A or A  B  B
The number of TRUE statements among the S1 , S2 , S3
1) 0 2) 1 3) 2 4) 3
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
81. If e1 and e2 are eccentricities of hyperbola and its conjugate hyperbola respectively then
1 1
 
e12 e22

82. Let f  x   sin 1 x. cos 1 x. tan 1 x. sec1 x cos ec 1x cot 1 x the maximum. value of f  x 
is k 6 then 128k is
2 2
83. Let S and S ' are two foci of the ellipse x 2  y2  1. chords AB and CD are passing through the
a b
foci S and S respectively.
'

If A   a cos  , b sin  
B   a cos  , b sin  
C   a cos  , b sin  
D   a cos  , b sin  
   
Then tan tan tan .tan 
2 2 2 2
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84. The function defined on  1, 4   2 such that f 1  1 and f  3   3 , Diagram given below

1 0 1 2 3 4

1
S1 : f "    0
2

S2 : lim f  x  doesn’t exist


x 2

S3 : f  x  has local maxima at x  3

7
S4 : f '    0
2

The number of TRUE statements among the S1 , S 2 , S3 , S 4 is


85. If S,P and R are the sum, product and sum of the reciprocals of n terms of an increasing G.P
and S n  Rn .Pk , then k is
86. Let f  x  and g  x  are two differentiable functions upto any order. If f  x  and g  x  are

g"  x
inverse of each other and f "
 g  x   then k 
 g '  x 
k

2 3
cos ec  cos ec
87. The value of 7 7 is equals to

cos ec
7

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88. Given two distinct nonzero vectors v1and v2 in 3 dimensions, define a sequence of vectors by
vn  2  vn  vn 1  so v3  v1  v2 , v4  v2  v3 and so on 

 v 
Let S  vn / n  1,2,..... and U   n / n  1,2,......
 vn 
(Note: Here  denotes the cross product of vectors and v denotes the magnitude of the vector
v. The vector 0 with 0 magnitude, if it occurs in S, is counted. But in that case of course the
0 vector is not considered while listing elements of U. number of elements in set S is called
cardinality of S )
S1 : There exist vectors v1 and v2 for which the cardinality of S is 2.

S2 : There exist vectors v1 and v2 for which the cardinality of S is 3.

S3 : There exist vectors v1 and v2 for which the cardinality of S is 4.

S4 : Suppose that for some v1 and v2 , the set S is infinite then the set U is also infinite.

The number of TRUE statements among the S1 , S 2 , S3 , S 4 is


89. If nC4 , nC5 and nC6 are in A.P., then value of n  7  n  20  is

90. Two vectors a and b whose magnitudes are integers. The possible number of value of a

such that a .b  2 and a b  3 is

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