Unit 3 Electro Chemistry

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RAJ KUMAR JAIN CLASSES Address : 41, Old MLA jahar Chowk, Bhopal Mob. : 9981949311 patna, —Elechochemttay ” _ ne ‘dhe _bsanch of chemf Which dealt with the study 0 sielasBrship_ bet. ejectricad eneyay- and chemfcod enes ood 2 fntexconyersfon of one -form of cae fnto_an: caved ae at ‘attr’ ia ie Oxidation - ~ Redu chon — ioe —LKeslox Reacttons ) ‘ vid ley 2 2 oxidadion. ard sglettten ee “| Jose catted » sedox. cea S ~ Redox _coacti pepsi e Hu |_eleshon -transtex , themes kits “fr “oxidation .3-> Acco ccordfrg-t0_electonte. concep ere effned. aS | one ox More Cleotront . Ihus y i ee Meads 9p Which an atom os for | for Ex s Noe Nak es Sodfum actom $edfum fon Zn eh Unt De Zine atom ine fon Cit ek Cee Luprous Yon. qi Cupric: fon r “Thus _veduttion fs eleetysnatfen forex: nia*t te" — ata conelin fe concept , xed fon tS om cept_ane oF more electrone. __ Teer, , P 81057 taht +loe- 99, + 6 RAJKUMAR JAIN ChASEES suidiistng, qgent 3 > The sttbstance undergoing oi pet oxtdiding ert. Hence , the et a | steadily 0 accept electronc fram. pr iy. | Catted Jas an pean nine: ov. oxfdart Reduchl ogent The _subslance undesgetng orfdn. 1s cauled a Ri eee Ao othe, substance 45_ cotted a _Acd ——.optik Or gedieterts E ae Condueloe 3» = WhEh dawned allows tre eblebitso cuvurd ao flow sraough it known! op 0 conductor , Tria propuly. ds tne substance of allowing tne cleetrfe Current +0 How through tt 1s Known as Electtaal conduckivity- Gt, Ag and AY axe some lmmpostent example of conductors ee Tneutedors : i> AL subs. “Wohfth doer not allow tne eb, Current a. aac iE fs Raown 2$ ’ non=coniuctor or _| Srsulator eg: Oubss good ; Rubbex ete: > {Types ot conductors g— (0) .| Slectronfe ‘or metalic: conductor at Co): | Sletalite dorductor ( Flecdolytes) : re axles ot lint sala y e RAJ KUMAR JAIN CLASSES . Address : 41, Old MLA Quarter, Jawahar, Chowk, Bhopal Mob. : 9981949311 > dont ancient te Electronfe ov _metalife conduct eeu oS RSictronte o_metalife concductame tor Ghent, fou 4 et a5 SS fakaough olactions , ann vowsiictancs yor funn’ a» 3 tloctadnie er masetife conductances! dn imelala » cbrduction Jake ete coon! any. a ee cea ae to. Lainie gee eae > Gi), | Ponfe ox lee | fe conductance s-> DA the cepacia ts Ske > [4o_enovernent= Of “fans , then “uf type oftieanduclabee ts Known #4 - Tonfe 0 deeb ye conductance this type ost conductance > | 9S sshown: dn bys clasient oc fn molten gtate of: cubstances , tata “ehemtead ie. _decarapestten of > electrolyte. ,tuemslats., tabih ao elec iki oie al et > — - ; Bence bets Melablies » any ia Mesauut. sit At ia) - Electsn yh Z conduchin pid alent eonduchon | > > te | Shoo Jrwolu mnourmut rf Fe unuolud nunc 4 _ eedons Up arena Sti aie condurctin. > 3 ye fis gj duct atu ps en tal > -wabthout phos tom Dalastiaiasas | gf tle att ons Ss fate a ay M4 doe not frvoluc i gt io > ap = = taku ploes dist to mound of elections . ‘ | clections durdo Ko dolifon of clectrolyte | obstactes of ubbtaling Keinolo <5 | Fhe Blectar’ca) conductance — AIN CLASSES pal Mob, ; 9981949311 _| ‘The Sejfstance OF tha flaw of: "gho. teatslares of tha. fo due -to tnlefonic _ of metal atoms ao os = a ie a “Hh subkénees whi donot cor __|Hhedk moltth state or | eso: enthed mon- e condusel lt ain 10 gh Hrs" woodn solution. Eleaheyes a va FSi Fong, comp eaaata a “htyhiy »hon-fonte. compound s OhIGh, .. or dAfssocfatents fo (Ceodfors and: anfons) shen dissolved ‘tn wattan, ae Solsent. of: -distectic. conclarct ) . AUy elect RAJ KUMAR JAIN CLASSES ‘Address: 41, Old MLA Quarter, Jawahar Chowk, Bhopal Mob. : 9961949311 | Ce ee | strona Cleedrolytes 1 cfne, electrolyler which a almett comple! ia fonfsed or dtsocfated tato tons jo alutfon ave catled sang clectenlydes .. €.9 | aon aeids Wike Het y HNO, » HaSO, 5 stoong bases tke Nad, ROH ete . and most of ne: Snort Uke _Naets KNOs 5 Kel NHyN Q5 1 eho. Wonk Glecholyier 2 the cleetrolu les Which donoh tontee ae Completely tn__oluson or have loud demee of Aftsocfasfon | ose ected weak ear wea! nefds Uky CHycooH , + we a eae “Ly. C0} 58, BO, ete. weak based “Like, MMOH 5 @COHDs 9 — > ALCOK), 5 Sous UKt Zhe > CBr, ete. hte a > gat aw sh : > @® [factor Atfectiny’ Concluctence ‘oF epsheoly te Fy acs dhe ssintes fonie. qnneney le see. ahs x RAJ KUMAR JAIN CLASSES oer Muito hive : focics_dimtthos Ord RoE of ta! fwutotiy of satuant > bt Re depend cipar: dno athoetdtn ntugefione bebe pol tho omoleeuty. hte da: Rnain ag glued $0 uae Interoctfons | sda golwoat'~ Soyer , “faaiges’ ga fyich whithy ote, a Jomp. nw syedse' call dx oboe Suits 8 Fine tings + q- iegifdiend eee co E@ Clectrle current 2» Tha Aad, g ange Wotrerdustae (Colecttonfe, __ o& seb ) fs costed. eleetite cunent , ae i dt haw, dq, fo tha ctoctart, want a I ce leat. ap fas post schas.ge. (on :0ppo - to dustin» of ve res = pate astumed Jo ne. dsiecion of ft ay | -electte._ aera es 15a | Timea a. Tremp equa do plow of one Tae pie ‘tuuaud Fe meajused 5 ompero., jit ze Sd come crosye pat Setond v0 ot Conductance 7 Specific condutfante Condueigg and spe > | fe tre. reciprocal of speci-tie _Aesistance and’ tt Ys alsa called > au conduclvity - ; = |Fh may also he differed as tne gonduesence of one ___|tendingitre cutie of Hho tondutor 2 Ht outa Tt dante ay > ot Cueek Lotte, Hoppasli) «su > ea i ee = ais} ee . a ith is ae > Bibi ti 0 5" ee =, > = i sas de g 7 =e > é = , ‘ Walt. Dap SSP. isan of conductivity care» saath g Sent ie f 9 a r aushincth ivi se utvatont = a. goludfon Peale “dubuskion Fe danas z | 00 the conducane, of aU the font ee __phufvaterc of dno ra of Aiitolued ty Vern? of and __| solubton whan the distance between the clectoder Ts one em — and ra ares’ ofstiu dantroder fe 0: lange Aor udnole of the ||] BluKen ts contatined between them. sf aes (lambda) ae ; Rotation fe un ak and specttte conduity = (dn ht volume 4 dna solution containing. ane gtom el equiv ale igeeaate electec olistae fs Vem Rqubvatint conduekvidy = gpeothe conus Saban KV , SE a 2 4m atm of coneintratiin + tre rolusten has a toncendralts of cogtam equivalent per ifpre «pide, C gram equivolerdt ors pretest ta_looo tn? af dite so Udhion Merrett) wtnon tng Volum of tar solution, (obit E Syakn $n ne aban oe Vit ra: Volume. oft tia. Te cms at are oh tneseleay Rem ral sensual Poggee aaa fs the tondutionee — je! Pett jon Pe SaaeiGl a in Vort of Hw g , > > : ae | Sets be malar conductivity ene sete conduchtvity oo ee >— Ae. Ky Xv en = ik - sae + — . M : what, K > Spetye conduct eg : eee F Vs volume of coin, contain: ning Pei eee teary C2 molar” concenjradfirn entradtion (mol eae unfit so ern 2 KX lowe = oben! cmt x cm? EN mole = ~AV em mol? or 6 enrol Different Units Relates) do Retistene and conducteoee 29 Papa 2 ok | Restetance » j ohm (~2) | fpic RestStance —_ ohm era (Lem) | Concluctance. = ohm! (2.7) er mho or _ pis — 5 et ey \ Sdomens(s) fispeciffe conductance, =) ohn crt pf. Som! colt condant 6 az tml Raut ductors sa aa ; fo hen’ Em Tad onion pes ¥ gan e fii te dat aman 2 ait of epee ESE al Z Lit pats Odin fam i, Ea 9 al i od + and oe eee { ‘ = 5 ne (eats) & ue ; ) Hus, for monovaterd etoctiotyte » = ) : EN wt ) » de | One Bet ancl two Cl sso ade obfeuded from one gourrula 2 0} Bot , a ) Bpsteset OO é Neh? Meg 2 Rae Ks Bs [Two Nat wed S04 —_& [aladdin of eq ufvotud wonduckiutty of eoenk Cledrh = ak sft Gan ; “t 4 Calealadvor ef dagcee af hci fa lea i 13+ | Calaadion. of. Slassectatio conden gh ‘yb wenk : ‘a | cleetrolater 4 ted. telat 4. | Sebemtnation of fonte _ po eb ofan: 6B) | Numasfeabs o> PG.) [Gtadoks, | Xe, fox Cath, and M980, faom sna dollowty cates é 1 92-( Semtmol) + Cott = 119.0, Mgi*> 106.0 Me 16-3, e lisopeeeslconol e ale ol By _usi oht sou. $ Sol 4 { $ ‘d ere nea (Cots) = Nett + 2A%y- Sess 9 4 Is2.6 = 271.6 Ser? moll eee oe = flog + Leo le ea RAJ KUMAR JAIN CLASSES ‘Address : 41, Old MLA Quarter, Jawahar Chowk, Bhopal Mo! EUPTEG ik NAO 42604 fo ee wi Silgigs aswis ce nie aa : pe. 1390.50 Bom! ‘molt Ee colander run Ee Ss fois ¢ i eae = 129.0. Sentinal! , Km CNaon)= 242 20Sen : aes Nact ) “= 126.0. Sen# mel, ty ESTE Am (Niue) = Aru ci Ae = To pe a a OEE bow iwi and eee G):f; | sums 4b t: . wii Bs TR Ganeno a= Ntscan) + Nintsasia = = 109 + 248-126 = asi Sem*molt RAJ KUMAR JA JAIN CLASSES | ‘Address : 41, Old MLA Quarter, Jawahar Chowk, Bhopal Mob. : 9981949311 Fo “She “pow “of “chanteal "decomposition of an ast tho. pass of —alectsle _CLimerck sce sits agutour Sohn 0g fused state cin Krew 90 . | ‘ceeds ai chomical deenmpostiion of a erp t electsic “cuskert un KWON ay £ cout ot f edly + % _ Fbegt aw of echolysfs ¢ st _ a eet man re _ fhe 9 ony sates aye liad ml 40. v8. quantity of ; teeny sa [haat wa gen af tne sulutares 2 apesina on psig | othr | Lcoulomb of otectrielty eee oO we |eusent of Tt oe 2 arhpesa aa pal fat Send fd a dian QoDKt WZ oP xPRb = b- — edad; 2p 24 foulomb ot D2 1ampers amd t= Ldecord, [stun w= 2 « Heret, electrochemtes aq alunite of a | guste stance be. defined OG 9 > eC tho, man of tue. s¢retertannce. depo cited uohen | rere pf ont ama ao path em cond EAE ant | Heo nef ee taal oducad coptha eteb | ase olbed i pacpnconad +o trol es eno”? axaday'’s second law of lectrolysis $—> When tne same set of tected chy fe passes ssongh , Golunshs of av santas — = 5 4 eos lat tai, ps n ee "alm. Connected: fn SEIS y of —leeabtiye ts passed. ee of Cu_cipos septa aden na 2 is 4 = 1eS onpset , = Hho = 20 mints « 7 cae ) 2 GOS, care at ee Ged | 0.1478 ene cpp 08 “deposited ye i ae ay ach 2 t= 0° De XSOKSO Hie : re goocoulemb : Amount’ of Gu dpsed by 600 at 0(978 _ — denownt ef Ca coe 7 on G13 ¢—— i Z00 UI ee UTI ITIP: ERE: Donate He |Blectinchemntead equivalent ext of cops = = 0005246 , 7 Qed 5 sft ona efole of — alumfnium vom an aqueous : “[ soln. ‘gt Ala (S0y)% 3 what Is the. = »—_| Oo coulomb _srequtred g 7 maa eum o leche cHy | SIA The segue acne “to deposte mde Of ALR a , 5 » eS es ——_use_k oh saat JP. 416.500 coulomb Wi So, 4p. “depth on one “gin mole ef clumfofum 4ne ne annul of = _ Klett sequined Xe anes pe BP > 5X4 6500 coulomb __|ptence arg at call te dapofited by 2g9Sc0 coulomb — 64 Haw meng “heuy_cloes take 4 to “produce 3 mole of Fee? sal ¢ aad ss eae aoe 5 ldo Pe2™ with 9.0 A ¢ rad 9 CP =16S00¢). Y Reds of feat £01 CB2A on po pOrPy.o a fest ten 5 per? ew i it 6S hp hed. of Sd of Fe2* gogustey 2 9&S00C > gedn. of Bmol of Fert sogusse = 3% 16S00 od ae xietet Eee 2 2-945 x09 = _LeQUTS x 10% gecond 2 Tht > le G&Ts xX lo “Uo eA hour . pase! ee 40x 60 us _ - a i — ee FEES : S% arihant phi Nt ping Urs RAJ KUMAR JAIN CLASSE y901949311 ; " Chemie) Cel te “| dussiee, zh cohtah. ehembead commuted dbo ebucatal ena ood ite = Sat ne folsatton : fs wed 0, —— — ee Sat pom selcete i - — bf ie Ap om lipgprnt: motsfad ef bata edi eres is : ane a dtu lad, 4 Matrode ftw and gy. prods. Beye and 2+ | anode. 1s regasfus fo) ve) cathode fs yen £90) | | ctandax nd _Glechrode Potential 1 (BE) : 7 wut ee jeer) ___| ond _dre:_colm + | (898K) ui cated _ghomdand electrode Pakeivad o {Sf : sf 7 pi Bt => Rhchode ir 6 quai, 0 te gu ae Fasinda psn thin is shee Ley 7 eed ogres dale Oem a jon ¢ pat al wut molortty (4) ot 25% ___+* | Oxfelaston Potenital > uy _ts deftned a0 ) tae ender 3 = aa —p fittest tata gab anlind 9. | 2G = ant og.) te a Stas) ey yp ten a - SY arinant H@ = LH ag.) F207 educky paca Gy ae = 4 Ft us dapinrd 00 tne stendlency of a 2 ae lt _to_gain electrons a fo get seoluced Pee SEC) Fine SAG Cut Ga) 4 se" == EMF egy = Ered - Fox og eee Org, Con ee | sthe antoasre erent of a COU vo mecuuredl by conneckng thé_voltmetir bw the 4wo olechodes of a gy «ne aru a 7 ee Fess | tatutats tho EMC of the con wth tut. folio = falls 5 Zn(s) + Rag? (Aaq.)_ ——+ r Zi *Cag. d+ og e Zn and oa value 4-076 Vand 0.90 V auraeesete Zine 3 a _di ef + ia ° eA zines sod _f tn Out Mg » of. Z>S0 ipps n | =Y Caloud axe Locate at rio dilution at 29? abn ee © potential CE 2/25 = Hbarsv Gide | At what comdgatfon of ihe By ule ta A | Ueehrode, hawt: @ rolex [Sol]! (9), the sadn. shen a en {ae ay 7 teers = 06% Om = | Baarpy, = 06 = 0.059 hg Tyas wef ON. Gig Betts) 0709S joo CW. | E Gat Jan) © Een pan) = = aOR 2 ie : toi = aa ofa) Oe 0.76 SES [| 0 706 re 0-054 te 109) ed - — . = Cpr ; bet danas Aer’ Jer on0 205 | rent 2 owt toms ey ec ore = 9St765 - ‘ 00295" _ - : os [r= amy 8 we 1 se Dyin = — pide 2 : 7 - —___— - a . ee L : - : a » — 7 ~ _- - -— Pad tal et ——T ~ Marihant s| 4 | RAJKUMAR JAIN CLASSE 4 ‘Address : 41, Old MLA Quarter, Jawahar Chowk, Bhopal Mob. : 99 el eNele la DD Ene Patent me le _| $¢ BS dhs. f 4h dquo dip. of to clos Yur dod oo made : Sto yoga tt ode (GE) [Standard ydaagen Electrode consttk of « vessel contate a JAM He Mt Month o _ ft dabe_contafafng a _platin a | fofl_ot one end 9 Ymmensed . he bina fils ft toated _vofin_inely afvided plotfhum ‘black » dri -esfablithes the seveyrtble equates , 7 de sping RAJ KUMAR. JAIN CLASSES opal Mob; 9981949311 _| Th wi a et Ta tot | hydrogen a men a + % absorbed on feil_and mest hb sholes «She as USE be pute — lana Pade tte Wo “ate. ain vod oie Si fp Reuse th cal tan bi. sy A —— Feltey. sony i= toth ed _ fs Li, (9) jae ut — See 7 == OL _ HY (age) (UA) | La (3) dom Pt = Senda dso aoe “ack ‘ag a ‘aoversTble electrode —__|SF_ NHE otk’ ay an andde_sneh oxfdadfon _occuxs _ Ond the sceaeth, fs_seapseserdtad of —* — ‘ - ths (9) SS hte tle Te & b— “od odeen_psoit use oP — Plafiqutin_vatee a otass “jacket i — Flosinur fe ~~ arihant png abs ft ES ef.

Reduelon tectrode pater a OBS = standoxd EME of Ha eu). Se | Re bear _tonstane (gonhit Kimo) To Kelisio Jemparaipe, (24%). + > Not of electrons Gavolved. tn ane cell react . = Fanndaiy af: gecesi stay 46500 Coulomb 7 —_— a RAJ KUMAR JAIN CLASSES Addi ees £47, UU MLA Guarier, iawahar Chowk, Bhopal Mob. 286 dts uate of Ub 34 Thao!) 7 (era = 00 coulomb) , tne ee ot 25°C € E po-ost) jog (""" Se ae Exell Calowlose anu euch. potirdod 4 a coppe wale dipped si ~ | OL M CuSOy solutn at 25°O | nln dampens ho. ——...,-stamdssd “esdoeo: + dt_potendial qf copper lao .d4 Ye ~ = Gkht ge 9G [nee aaa Ee om 0. as ce : - ash rua © Ose oss ig ol =O a4 ~ 0.09455 co 5 f i Oe 2 StI al een eerste ce i= O-5IOUS — : a Oe - Seven pinging Ove [ Beamptes of faek ella | colt 3 he }W8tOL ago» Jearmet to Aesseutd “ty bm para) ouashiin yuke | piace _ eusy ont aa cen a wat ssecause One peactima gal iy #2 sffolage attr 0.9 wad vse ord Nie ae he Fe ge ae — Mn, re +20" —¥ vino (0) #20 Mind, ots 00 depotoaciur the Paes ie sed . Ree re ayn a aaa RAJ KUMAR JAIN cLaSSEE Address : 41, Old MLA Quarter, Jawahar Chowk, Bhopal M: GA} defect of Oy eat i ee —fsguien)_ainp gata sit ata Gi 7 The main ct of oe et con iy pyae une jo_acrdut _| mary ¢ i mae of q [Place ancl tne, COO COUe beeones ». atte) wong | dose hdten Leakage ¢ Coureuds: 4 BL comad of “of. Jusoeteetodes moda tree ae 3 letlluut 99 moles enrale) She, ae din « abe 7 of cas oh at OH Dg ae pag Ousty, tid coh_ Lung et promeetr af abauk So aml ath fasts «ito dine © i Seah pe ee Aate di rouge Sol. § mn Kak, do ge he Tht yo ‘cate ae eee maxtor efpicong Sho. a tees wa pe tata eee com atihant | | | | | | | o z, Dp 3 im a RAJ KUMAR JAIN KUMAR JAIN CLASSES \ddress : a SE SEMA Guar, Jawahar Chowk, Bhopal Mob. : 9! —— Atoms ty ag — Jot ss Opty any) UE a > Lowes, a: Tile geet Siesta ef PRK BL) —e alt) oi a a Ge ( - F The SOCEM lool = : Urdanteahie *F tonuuiion of eta . compouwclt (rou St mages hound) motijuce phsoert “ie abbicgp —_| eoexogednn .” fee be & man nap oh —_| 20001 fon at Bula sb hyiated - peaute ontde (6 £2305; m4 ‘Piscean ater Ceduna aang ok a : —|Conesten us om, cleetun charmed now Wo opich dion | fushoes funckdna 0.0 'on"" omo rd H COs ( found — Hy Migourtdn of. co, f ama te Hy Cea __[Reastn:at anode 9. : ffon Otomo od amoce gk ont et | ound panes Wat? Sl, a fo2* Fong , dro “swteared | ebecttona Fa tao ential ie fron _procest “punked Ido | fe ea +E Gopttn.) OMY “| Reasth. od-an node > Tho ¢ ‘ctortiona | “agteaoed by. ud “ot | Bnode ase ae ie H+ ovis cot Catnoote (OLA a a besoin t at Se cblen_sutfore) ——_aTH_+—#§!_|_—__, HO 0005) 9 pcg Nathan | { a ane i pa ot to toe caval Eevaraveuny eftnor todd ath gue Ato ong ree cata afk , bo" foren Oadin pos isiecVeeuect iain a oe eo [ant so +207 23,0 Eng + Stes complete. ctl seoon. co alg ta. uty gfe t+ unt +0, > apett ea aa a ET “Hho €>* soto aw “fuithon ats Eo? by adnan onyae and. erattiodeouiak Lrydiatad aude ox a sea aes | Pe ot + 0, ut 2h 0 fe 0x that £05 410° —> > FeO KAD = Soa ODL Pouseiver ¢ ae mnogal £ att < ccs (fae Who “impute sunpgaee onan 4 rca ere by I | eae of call Mi sy mon ol | tenoded Shuws , Wades pofilbn iy etsetuodrarntcal ee bof meet grou ie pote autulty amd also ‘ fe pass mow Patti for_gatiuct candied. —7 I He | Prue C0, and 00, 2, 4% go soa 00, wl t +} dip-atinys, dReteneus cgancteom Poss? ound. extewt i | of eomptfon = el ‘Puuntin coustion > ot a ae 3 ; nkosi 49 pint pane a § 2}. eouotfon ane a9 ie (as $ Lip pat dhe eu ace $ senna oak a oe ain aa —§ Site 4 Tati re and cord @ See thee tt shacks tre contact Wit, moftcju and air i aft. — : IF Cleetuoplatt Be wintns iocun % i map ain, Some CAR sie encdale Usher _nufhad ,-chwomiive ate, “dn, 3 arihant

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