Class 12 th

CHEMISTRY

Designed by

Edustudy point
 ❖ Rate of Reaction
𝑫𝒆𝒄𝒓𝒆𝒂𝒔𝒆 𝒊𝒏 𝒄𝒐𝒏𝒄𝒆𝒏𝒕𝒓𝒂𝒕𝒊𝒐𝒏 𝒐𝒇 𝑹
= 𝑻𝒊𝒎𝒆 𝒕𝒂𝒌𝒆𝒏

𝑰𝒏𝒄𝒓𝒆𝒂𝒔𝒆 𝒊𝒏 𝒄𝒐𝒏𝒄𝒆𝒏𝒕𝒓𝒂𝒕𝒊𝒐𝒏 𝒐𝒇 𝑹
=
𝑻𝒊𝒎𝒆 𝒕𝒂𝒌𝒆𝒏

−∆ [ 𝑹 ] ∆[𝑷]
= = K = Rate constant
∆𝒕 ∆𝒕
x y
Reaction:- A + B → Products ⟹ Rate = K [A] [B]

❖ 0rder of Reaction
= x + y
X = order of Reaction with respect to A

y = order of Reaction with respect to B

❖ Zero order Reactions

[𝑹]० − [𝑹]
K = 𝒕

❖ First order Reactions

𝟐.𝟑𝟎𝟑 [𝑹]०
K = 𝒍𝒐𝒈 [𝑹]
𝒕

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 ❖ Half life of a zero order Reaction
[𝑹]०
t1/2 = 𝟐𝑲

❖ Half life of a first order Reaction

𝟎.𝟔𝟗𝟑
t1/2 = 𝑲

❖ Integrated Rate Equation for a

gaseous state
𝟐.𝟑𝟎𝟑 𝑷𝒊
K = 𝒕
𝒍𝒐𝒈 𝟐𝑷𝒊 − 𝑷𝒕

Ea = Activation Energy

A = frequency factor

❖ Arrhenius Equation
K = A e-Ea/RT
𝑲𝟐 𝑬𝒂 𝟏 𝟏
𝒍𝒐𝒈 = 𝒍𝒐𝒈 =൤ − ൨
𝑲𝟏 𝟐. 𝟑𝟎𝟑 𝑹 𝑻𝟏 𝑻𝟐

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❖ Collision theory of Chemical
Reactions
𝟏
Rate = = P ZAB e-Ea/RT
𝝆

ZAB: The collision frequency of rectants A and B

P: Probability factor

e-Ea/RT: Fraction of molecules with energies equal

to or greater than Ea