PINNAACLE CLASSES

(b) statement 3 alone is correct

46. A (c) statements 2 and 3 are correct
Pink
Which of the following is correct ? (d) all the statements are correct
(a) X= black, MnO2, Y= Blue, K2 CrO4, Z=KMnO4
(b) X= green, Cr2 O3, Y= Yellow, K2 CrO4, Z=K2 52. Mercury on heating with aqua-regia gives :
Cr2 O7 (a)Hg(NO3)2 (b)HgCl2
(c) X= black, MnO2, Y= green, K2MnO4,
Z=KMnO4 (c) Hg(NO2)2 (d) Hg2Cl2
(d) X= black; Bi2 O3, Y= colourless KBiO2, Z=
KBiO3 53. Which of the following is coloured compound?
(a) CuF2 (b) CuI
47. CrO3 dissolves in aqueous NaOH to give
(c) NaCl (d) MgCl2
(a) (b)
54. Which one of the following ores is known as
(c) (d) Cr(OH)2 Malachite :
(a) Cu2S (b) Cu2O
48. Identify the incorrect statement among the
following (c) Cu(OH)2.CuCO3 (d) CuFeS2
(a) d-block elements show irregular and erratic
chemical properties among themselves. 55. Which of the following statement is correct when a
(b) La and Lu have partially filled d-orbitals and mixture of NaCl and K2Cr2O7 is gently warmed with
no other partially filled orbital. conc. H2SO4?
(c) The chemistry of various lanthanoids is very 1. a deep red vapour is evolved
similar. 2. The vapour when passed into NaOH solution
(d) 4f and 5f-orbitals are equally shielded. gives a yellow solution of Na2CrO4
3. chlorine gas is evolved
49. Cerium (Z = 58) is an important member of the 4. chromyl chloride is formed
lanthanoids. Which of the following statements (a) 1,2, 4 (b)l,2,3
about cerium is incorrect?
(a) The common oxidation states of cerium are (c) 2, 3, 4 (d) all are correct
+3 and +4
(b) The +3 oxidation state of cerium is more 56. Compound that is both paramagnetic and coloured
stable than +4 oxidation state is
(c) Cerium (III) acts as an oxidising agent (a)K2Cr2O7 (b) (NH4)2 [TiCl6]
(d) The +4 oxidation state of cerium is known in
solution (c) VOSO4 (d) K3[Cu(CN)4]

50. In which compound does vanadium have an 57. Assertion: Potassium dichromate is used as a
oxidation number of +4? primary standard in volumetric analysis.
(a)NH4VO2 (b)K4[V(CN)6] Reason: Sodium and potassium dichromates
are strong oxidising agents.
(c) VSO4 (d) VOSO4 (a) Both A and R are correct and R is correct
explanation of A.
51. Select the correct statements. (b) Both A and R are correct but R is nor correct
(1) Ferric bromide is obtained when chlorine gas explanation of A.
is bubbled through a solution of ferrous bromide (c) A is true but R is false.
(2) Sodium sulphate is obtained when SO2 (g),
(d) Both A and R are false.
H2 O (g) and air are passed over heated sodium
chlorine
(3) H2 S gas is liberated when aluminum 58. Match the catalysts with the processes.
sulphide becomes damp. (i) (P) Reaction between
(a) statements 1 and 2 are correct
iodide and persulphate ions

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 PINNAACLE CLASSES

(ii) (Q) Vegetable oil to ghee (b) is stronger acid than

(iii) (III) (R) Sandmeyer reaction (c) formation of protective oxide layer by
(iv) Finely divided (S) Haber’s process (d) formation of protective oxide layer by
(a) (i)-Q, (ii)-P, (iii)-S, (iv)-R
(b) (i)-P, (ii)-Q, (iii)-S, (iv)-R 64. Reduction of metal centre in aqueous
(c) (i)-P, (ii)-R, (iii)-Q, (iv)-S permanganate ion involves
I 3 electrons in neutral medium
(d) (i)-Q, (ii)-R, (iii)-P, (iv)-S II 5 electrons in acidic medium
III 1 electron in alkaline medium
59. Which of the following elements shows maximum Which of the following is/are correct
number of different oxidation states in its
(a) Only II
compounds?
(b) II & III
(a) (c) I & II
(b) (d) All of these
(c)
65. The magnetic moment of a divalent ion in
(d) aqueous solution if its atomic number is 27, is

60. Which of the following are radioactive? (a) .

(a) (b)

(b) (c) .

(c) (d)

(d) 66. March the following columns.

(P) Reagent oxidised to
61. Which of the following is correct about reaction of
(i)
with oxalic acid?

(a) is formed as the product. (Q) Compound having dark purple crystal isostructure

(b) The decolourisaton of is slow in the with (ii)

beginning and become instantaneous after
sometime.
(R) Green compound formed by fusing KOH with
(c) catalyses the reaction.
(d) All of these (iii)

62. The colour of is due to (S) Compound which has orange crystal tetrahedral
structure acidified (iv)
(a) charge transfer
(b) transition
(a) P-(iv) , Q-(ii) , R-(i) , S-(iii)
(c) charge transfer
(b) P-(iii) , Q-(ii) , R-(i) , S-(iv)
(d) transition. (c) P-(iv) , Q-(i) , R-(ii) , S-(iii)
(d) P-(iii) , Q-(i) , R-(ii) , S-(iv)
63. Actinoids are generally slightly affected by
but attacks almost all metals because 67. Which one of the following statements related to
lanthanoids is incorrect?
(a) is stronger acid than (a) Europium shows oxidation state.

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 PINNAACLE CLASSES

(b) The basicity decrease as the ionic radius (b) BF3 < NF3 < NH3 < H2O
decreases from to (c) BF3 < NH3 < NF3 < H2O
(c) All the Lanthanons are much more reactive than (d) H2O < NF3 < NH3 < BF3
aluminum.
74. The number of P–O–P bonds in the structure of
(d) solutions are widely used as oxidising phosphorus pentaoxide and phosphorus trioxide
agent in volumetric analysis.
are respectively:
68. Among the following pairs of ions, the lower (a) 6, 6 (b) 5, 5
oxidation state in aqueous solution is more stable
than the other, in
(c) 5, 6 (d) 6, 5
(a)
75. The type of hybrid orbitals used by iodine atom in
(b)
hypoiodous acid (HOI) molecule are
(c)
(a) sp3 (b) sp2
(d)
(c) sp (d) sp3d
69. The reason for lanthanoid contraction is
76. The correct order of increasing covalent character
(a) greater shielding of ‐ electrons
is :
(b) poor shielding of ‐ electrons
(a) LiCl, NaCl, BeCl2 (b) BeCl2, NaCl,
(c) greater shielding of ‐ electrons
LiCl
(d) poor shielding of ‐ electrons.
(c) NaCl, LiCl, BeCl2 (d) BeCl2, LiCl,
70. Correct set of amphoteric oxides is NaCl

(a) 77. Decreasing order of bond angle is :

(b)
(a) BeCl2 > NO2 > SO2 (b) BeCl2
(c) > SO2 > NO2

(d) (c) SO2 > BeCl2 > NO2 (d) SO2 >
NO2 > BeCl2
71. Consider the following species :

CN+, CN–, NO and CN 78. N2 and O2 are converted into monoanions

Which one of these will have the highest bond
order?
and respectively. Which of the following
(a) NO (b) CN statements is wrong ?
(c) CN+ (d) CN–
72. Which of the following is paramagnetic ? (a) In , N–N bond weakens
(a) N2 (b) H2 (b) ln , O–O bond order increases
(c) Li2 (d) O2
(c) ln , O–O bond order decreases
73. Which of the following is the correct order of dipole (d) becomes paramagnetic
moment ?

(a) NH3 < BF3 < NF3 < H2O

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 PINNAACLE CLASSES

79. Which one of the following arrangements of (c) a *-orbital (d) a *-orbital
molecules is correct on the basis of their dipole
moments ? 85. Which of the following cantain at least one lone
pair in all of its halide
(a) (b)
(a) Xe (b) Se
(c) (d)
(c) Cl (d) N

86. Which is incorrect regarding S and P mixing (along

Z –axis.)

(a) Nodal plane(s) present in ABMO

(b) Nodal plane is absent in BMO
80. ln piperidine , the hybrid state assumed (c) MO formed may have higher energy than
by N is parent AO
(d) MO formed are asymmetric
(a) sp (b) sp2
(c) sp3 (d) dsp2 87. Which contain at least one e– in 2p bonding MO

81. The shapes of SF4 and XeF2 respectively are :

(a) O2 (b) B2
(c) C2 (d) Li2
(a) trigonal bipyramidal and trigonal
bipyramidal
88. Which pair of diatomic species have same bond
(b) see-saw and linear
order ?
(c) T-shape and linear
(d) square planar and trigonal bipyramidal
(a) , C2 (b) ,
82. Consider the statements : (c) , (d) , C2

I. Bond length in is 0.02Å greater than in N2

89. , find out number of lone pair and
II. Bond length in NO+ is 0.09Å less than in
geometry.
NO.
has shorter bond length than O2 (a) 3 – Linear, 2 – Square planar
III.
(b) 3 – Square planar, 2 – Linear
Which of the following statements are true ?
(c) 0 – Linear, 3 – Square planar
(a) I and II (b) II and III
(d) 2 – Linear, 2 – Square planar
(c) I, II and III (d) I and III
83. Correct or der of increasing C—O bond length of
90. Correct order of bond angle is :

CO, , CO2 is : (a) SO2 < H2S (b) SO2 < H2O
(c) NH3 < H2O (d) NH3 < SO2
(a) < CO2 < CO (b) CO2 < < CO

(c) CO < < CO2 (d) CO < CO2 <

84. In formation of NO+ from NO, the electron is

removed from

(a) a -orbital (b) a -orbital

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