1. A solution is made of 2.00 g of sucrose. C12H22011, in water, H20.

The molar mass (MM) of sucrose

is 342 g/mol. Calculate the (a) boiling point and (b) freezing point of the solution.

The molar mass of sucrose= 342 g/mol

mass
No. of moles of sucrose = 2 g342 g/mol0.00585 mol
molar mass
2g
=
342 g /mol
= 0.00585 mol

Molality

no . of moles of solute
m=
mass of solvent ∈kg
0.00585 mol
m=
0.1 kg
m = 0.0585

a.) Boiling point

∆Tb = kb x m

∆Tb = 0.512°C/m x 0.0585 m

= 0.0300°C

∆Tb = Tb - Tb0

Tb = ∆Tb + Tb0

= 0.0300°C + 100°C

= 100.03°C

b.) Freezing point

∆Tf = kf x m

∆Tf = 1,86°C/m x 0.0585 m

= 0.109°C

∆Tf = Tf – Tf0

Tf = ∆Tf + Tf0

= 0°C + .109°C

= .109°C
2. A certain nonvolatile hydrocarbon that weighed 1.00 g was dissolved in 50.00 g of benzene. The
resulting solution was boiled at 0.285°C higher than the boiling point of pure benzene which boils at
80.1 °C. Find the molar mass of the hydrocarbon.

Tsol = TPS + ∆Tb

∆Tb = Tsol – TPS

∆Tb = 80.385°C – 80.1°C

∆Tb = 0.285°C

∆Tb = i x Kb x m

n
° C . Kg
0.285°C = 1 x 0.512 x 50
mol Kg
1000
0.285 ° C x 0.05 mol
n=
0. 512 ° C
0. 01425
n= mol
0.512
n = 0.028 mol