Mole Fraction Ethyl Alcohol VP, mm Hg Margules

X Y Temp, deg C Ethyl Alcohol Water γ1 γ2

0.00 0.00 100.09 1,699.09 760.00 4.964 1.000
0.03 0.23 93.65 1,355.04 601.42 4.314 1.002
0.06 0.35 89.78 1,177.22 520.02 3.781 1.008
0.10 0.44 86.60 1,046.49 460.47 3.212 1.023
0.15 0.51 84.30 959.27 420.88 2.671 1.050
0.20 0.54 82.94 910.83 398.94 2.268 1.087
0.28 0.58 81.72 869.00 380.04 1.824 1.164
0.40 0.62 80.65 833.48 364.01 1.411 1.326
0.50 0.65 79.99 812.34 354.48 1.220 1.493
0.60 0.69 79.41 794.18 346.30 1.107 1.680
0.70 0.75 78.94 779.45 339.67 1.043 1.872
0.80 0.82 78.60 769.13 335.03 1.012 2.045
0.90 0.91 78.40 763.19 332.36 1.001 2.170
1.00 1.00 78.30 760.00 330.93 1.000 2.214

Molar Composition Bottoms Feed Distillate

Ethyl Alcohol 0.02 0.40 0.88
Water 0.98 0.60 0.12

Reflux Ratio 6
Feed, q 0.999

Reference Line Stripping Feed Rectification

Slope 1.00 Slope 1.18 Slope 999.00 Slope
Intercept 0.00 Intercept (0.00) Intercept (399.20) Intercept
X Y X Y X Y X
0.00 0.00 0.02 0.02 0.40 0.40 0.88
1.00 1.00 0.40 0.47 0.40 0.47 0.40

Step Data
Mole Fraction, Vapor Phase

X Y
0.02 0.02 McCabe-Thiele Diagram
0.02 0.17
0.15 0.17 1.00
0.15 0.50
0.44 0.50 0.90
0.44 0.63
0.59 0.63 0.80
0.59 0.69
0.66 0.69 0.70

0.66 0.72
0.60

0.50

0.40

0.30
 0.90

Mole Fr
0.80

0.70

0.60
0.70 0.72
0.70 0.75
0.50
0.73 0.75
0.73 0.77
0.40
0.75 0.77
0.75 0.78 0.30
0.76 0.78
0.76 0.79 0.20
0.78 0.79
0.78 0.80 0.10
0.79 0.80
0.79 0.81 0.00
0.80 0.81 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90
0.80 0.82 Mole Fraction, Liquid Phase
0.81 0.82
0.81 0.83
0.82 0.83
0.82 0.83
0.83 0.83 McCabe-Thiele Diagram
Mole Fraction, Vapor Phase

0.83 0.84
0.84 0.84 1.00
0.84 0.85
0.84 0.85 0.90
0.84 0.85
0.85 0.85 0.80
0.85 0.86
0.86 0.86
0.86 0.87 0.70
0.87 0.87
0.87 0.87 0.60
0.87 0.87
0.87 0.88 0.50
0.88 0.88
0.88 0.89
0.40
0.89 0.89
0.89 0.90
0.90 0.90 0.30
0.90 0.90
0.91 0.90 0.20
0.91 0.91
0.92 0.91
0.10
0.92 0.92
0.93 0.92
0.93 0.93 0.00
0.94 0.93 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.9
0.94 0.94 Mole Fraction, Liquid Phase
0.95 0.94
0.95 0.95
0.97 0.95
0.97 0.97
0.98 0.97
0.98 0.98
1.00 0.98
1.00 1.00
1.02 1.00
1.02 1.02
1.04 1.02
1.04 1.04
1.07 1.04
1.07 1.06
1.09 1.06
1.09 1.09
1.12 1.09
1.12 1.11
1.15 1.11
1.15 1.14
1.18 1.14
1.18 1.16
 Margules Model van Laar Model
Partial Pressure
Ethyl
Alcohol Water Difference γ1 γ2 γ1 γ2
0.00 760.00 (0.00) 4.964 1.000 5.364 1.000
175.38 584.62 (0.00) 4.314 1.002 4.506 1.003
267.09 492.91 (0.00) 3.781 1.008 3.851 1.010
336.16 423.84 0.00 3.212 1.023 3.197 1.026
384.38 375.62 0.00 2.671 1.050 2.618 1.056
413.06 346.94 0.00 2.268 1.087 2.211 1.094
440.72 319.28 (0.00) 1.824 1.164 1.787 1.170
470.39 289.61 0.00 1.411 1.326 1.409 1.320
495.44 264.56 (0.00) 1.220 1.493 1.235 1.469
527.32 232.68 (0.00) 1.107 1.680 1.128 1.639
569.28 190.72 (0.00) 1.043 1.872 1.063 1.830
622.98 137.02 (0.00) 1.012 2.045 1.025 2.041
687.89 72.11 (0.00) 1.001 2.170 1.006 2.270
760.00 0.00 0.00 1.000 2.214 1.000 2.516
(0.00)

Murphree Tray Efficiency: 1

Segment 1 Origin Segment 2 Origin

Murphree
Rectification Step X Y X Y
0.86 Reboiler 0.02 0.02 0.02 0.17
0.13 1 0.15 0.17 0.15 0.50
Y 2 0.44 0.50 0.44 0.63
0.88 3 0.59 0.63 0.59 0.69
0.47 4 0.66 0.69 0.66 0.72
5 0.70 0.72 0.70 0.75
6 0.73 0.75 0.73 0.77
7 0.75 0.77 0.75 0.78
8 0.76 0.78 0.76 0.79
e Diagram 9 0.78 0.79 0.78 0.80
10 0.79 0.80 0.79 0.81
11 0.80 0.81 0.80 0.82
12 0.81 0.82 0.81 0.83
13 0.82 0.83 0.82 0.83
14 0.83 0.83 0.83 0.84
15 0.84 0.84 0.84 0.85
16 0.84 0.85 0.84 0.85
17 0.85 0.85 0.85 0.86
18 0.86 0.86 0.86 0.87
 19 0.87 0.87 0.87 0.87
20 0.87 0.87 0.87 0.88
21 0.88 0.88 0.88 0.89
22 0.89 0.89 0.89 0.90
23 0.90 0.90 0.90 0.90
24 0.91 0.90 0.91 0.91
25 0.92 0.91 0.92 0.92
26 0.93 0.92 0.93 0.93
27 0.94 0.93 0.94 0.94
28 0.95 0.94 0.95 0.95
29 0.97 0.95 0.97 0.97
30 0.98 0.97 0.98 0.98
0.50 0.60 0.70 0.80 0.90 1.00 31 1.00 0.98 1.00 1.00
n, Liquid Phase 32 1.02 1.00 1.02 1.02
33 1.04 1.02 1.04 1.04
34 1.07 1.04 1.07 1.06
35 1.09 1.06 1.09 1.09
36 1.12 1.09 1.12 1.11
Thiele Diagram 37 1.15 1.11 1.15 1.14
38 1.18 1.14 1.18 1.16

Reference Line
VLE Curve
Stripping
Feed
Rectification
Tray Steps
Murphree VLE

0 0.60 0.70 0.80 0.90 1.00

Liquid Phase
Solution Model
None 1
Margules 2
van Laar 3

VP, mm Hg Margules Partial Pressure

Temp, deg Ethyl Ethyl
VLE Y C Alcohol Water γ1 γ2 Alcohol Water Difference
0.17 95.42 1,443.10 641.88 4.516 1.001 130.35 629.65 (0.00)
0.50 84.36 961.35 421.82 2.687 1.049 383.19 376.81 0.00
0.63 80.36 824.27 359.85 1.320 1.392 480.25 279.75 0.00
0.69 79.47 795.77 347.02 1.115 1.662 523.92 236.08 0.00
0.72 79.13 785.21 342.26 1.065 1.791 550.11 209.89 0.00
0.75 78.95 779.73 339.80 1.044 1.868 568.23 191.77 0.00
0.77 78.84 776.36 338.28 1.033 1.919 581.89 178.11 0.00
0.78 78.76 774.06 337.25 1.026 1.956 592.81 167.19 0.00
0.79 78.71 772.37 336.49 1.021 1.985 601.91 158.09 0.00
0.80 78.66 771.06 335.90 1.017 2.009 609.75 150.25 0.00
0.81 78.63 770.00 335.42 1.015 2.028 616.70 143.30 0.00
0.82 78.60 769.12 335.03 1.012 2.045 623.00 137.00 0.00
0.83 78.58 768.37 334.69 1.011 2.060 628.82 131.18 0.00
0.83 78.55 767.71 334.39 1.009 2.073 634.29 125.71 0.00
0.84 78.53 767.13 334.13 1.008 2.085 639.51 120.49 0.00
0.85 78.52 766.60 333.89 1.007 2.096 644.57 115.43 0.00
0.85 78.50 766.11 333.67 1.006 2.106 649.53 110.47 0.00
0.86 78.49 765.65 333.46 1.005 2.116 654.47 105.53 0.00
0.87 78.47 765.22 333.27 1.004 2.125 659.43 100.58 0.00
0.87 78.46 764.80 333.08 1.004 2.134 664.47 95.53 0.00
0.88 78.44 764.41 332.91 1.003 2.143 669.65 90.35 0.00
0.89 78.43 764.02 332.73 1.003 2.151 675.03 84.97 0.00
0.90 78.42 763.64 332.56 1.002 2.160 680.68 79.32 0.00
0.90 78.41 763.26 332.39 1.002 2.168 686.67 73.33 0.00
0.91 78.39 762.89 332.22 1.001 2.176 693.08 66.92 0.00
0.92 78.38 762.51 332.06 1.001 2.184 700.01 59.99 0.00
0.93 78.37 762.13 331.88 1.001 2.191 707.57 52.43 0.00
0.94 78.36 761.75 331.71 1.000 2.198 715.90 44.10 0.00
0.95 78.34 761.35 331.53 1.000 2.205 725.14 34.86 0.00
0.97 78.33 760.93 331.34 1.000 2.210 735.46 24.54 0.00
0.98 78.31 760.48 331.14 1.000 2.213 747.05 12.95 0.00
1.00 78.30 760.00 330.92 1.000 2.214 760.09 (0.09) 0.00
1.02 78.28 759.44 330.67 1.000 2.210 774.72 (14.72) 0.00
1.04 78.26 758.78 330.38 1.000 2.201 790.98 (30.98) 0.00
1.06 78.23 757.95 330.00 0.999 2.184 808.70 (48.70) 0.00
1.09 78.19 756.89 329.53 0.999 2.158 827.37 (67.37) 0.00
1.11 78.15 755.55 328.93 0.997 2.120 846.07 (86.07) 0.00
1.14 78.10 753.96 328.21 0.994 2.073 863.48 (103.48) 0.00
1.16 78.04 752.26 327.45 0.990 2.020 878.28 (118.28) 0.00
Difference
Total 3,916.90
 Antoine Coefficients Mol Wt
A B C MW
Methyl Alcohol 8.08097 1582.271 239.726 32.042
Water 8.01352769 1701.78587 231.466749 18.015
Methane 6.61182948 389.926958 265.99 16.043
Ethane 6.80265848 656.401366 255.99 30.07
Propane 6.95916997 857.736201 252.414186 44.097
Toluene 7.05282866 1397.197 224.2974 92.141
Acetic Acid 7.49044999 1604.16592 229.902701 60.052
Isobutane 6.74811109 882.803422 240 58.124
n-Butane 6.96820966 1000.63935 245.310958 58.124
Isopentane 6.78967307 1020.01442 233.1 72.151
n-Pentane 6.83902998 1059.01668 231.448959 72.151
n-Hexane 6.76098367 1112.56081 218.029908 86.178
n-Heptane 6.81342209 1224.41518 212.94937 100.21
n-Octane 6.85804739 1316.95574 205.523542 114.232
Ethyl Alcohol 8.1122 1592.864 226.184 46.069