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Ecological Engineering 138 (2019) 237–247

Contents lists available at ScienceDirect

Ecological Engineering
journal homepage: www.elsevier.com/locate/ecoleng

Effects of super absorbent polymer on scouring resistance and water T


retention performance of soil for growing plants in ecological concrete
⁎ ⁎
Laibo Lia, Haiming Zhangb, Xiangming Zhouc, Mingxu Chena, Lingchao Lua, , Xin Chenga,
a
School of Materials Science and Engineering, University of Jinan, Jinan 250022, China
b
Department of Asset Management, Qilu University of Technology, Jinan 250353, China
c
Department of Mechanical, Aerospace and Civil Engineering, Brunel University, London, Uxbridge, Middlesex UB8 3PH, United Kingdom

A R T I C LE I N FO A B S T R A C T

Keywords: Ecological concrete could protect the slopes along a motorway or on a river bank and prevent water/soil loss and
Scouring resistance beautify and built the environment compared to ordinary concrete. Overlaying soil, as a key component of
Water retention property ecological concrete, plays an important role in greening rate of ecological concrete. However, natural soil used as
Super absorbent polymer overlaying soil cannot meet plants growing demand due to its unsatisfying scouring resistance and water re-
Soil
tention properties. In this paper natural super absorbent polymer (SAP) was utilized to modify the natural soil for
Ecological concrete
the preparation of a material with enhanced scouring resistance and water retention performance which are
indispensable for growing plants in ecological concrete. Experimental results suggested that 1.5 wt% SAP con-
tent in the soil was the most suitable option. At this natural soil replacement level, the scouring resistance
increased by 68.9% while its water retention performance improved by 11.1% at the age of 160 h. In addition,
other performance improvements of the soil were determined including increasing of the water absorption rate
which was tested increasing by up to 69.4% and the cone index of up to 0.39 MPa, and the advancements of
perennial ryegrass were measured increasing of the survival ratio which was found increasing by up to 97.9%
and the dry weight of up to 2.16 kg/m2.

1. Introduction absorb the water and nutrition from underground (Fig. 1(b)). Hence,
ecological concrete has been considered as a cost-effectively and en-
Pervious concrete is a kind of environmental-friendly material, de- vironmental friendly candidate for the aim of growing plants, pro-
veloped by coating moderate amount of cement paste on the surface of tecting soil and water (Yan et al., 2013; Li et al., 2018). In general,
coarse aggregates to achieve a structure with high porosity (Bhutta ecological concrete system consists of three components, including
et al., 2013; Tamai et al., 2004). Because of the favorable water- herbaceous plants, overlaying soil and porous concrete (Fig. 1(a)) (Li
draining, -permeating, and -retaining performance of the pervious et al., 2017a). Currently, the major concern for growing herbaceous
concrete, it has been widely applied in sidewalks, parks and road pa- plants in the ecological concrete is how to improve the scouring re-
vements et al., as well as for pervious gutters and plants bedding (Park sistance and water retention of overlaying soil which determines the
and Tia, 2004; Ćosić et al., 2015; Kim and Lee, 2010; Agar-Ozbek et al., fate of herbaceous plants and greening rate of ecological concrete
2013). Pervious concrete used for planting bedding is appropriately (Fig. 1(c)). The improvement of scouring resistance can be achieved
named as ‘ecological concrete’ (Fig. 1), which is mainly utilized to using solidified agent (Cao et al., 2017; Li et al., 2001; Rajasekaran,
protect the slopes along a motorway or on a river bank (Gong et al., 2005), which could be divided into two main types: Portland cements
2017; Li et al., 2017a). Although normal concrete (Ordinary Portland (PC) and sulphoaluminate cement (SAPs). On the one hand, cement has
Cement Concrete) has been widely used as a covering layer for slope been widely used for solidifying soil because it can produce a me-
protection, the environment underneath is too dense for plant growth chanically stable form by the hydration and hardening of the cement
because the low porosity of concrete greatly limits the transportation (Rajasekaran, 2005; Stanforth, 2001). In most cases, PC was adopted as
among water, soil, air and plants. This problem can be well resolved by the solidified agent to solidify the soil. However, the pore fluid alkali-
using ecological concrete as a covering layer since the plants’ roots can nity (pH) of the hardened PC paste can reach up to 13.5 due to the
pass through the ecological concrete via interconnected pore and formation of cement hydration products (Zhang and Yan, 2017; Codina


Corresponding authors.
E-mail addresses: Lingchao_lu@163.com (L. Lu), Chengxin_ujn@outlook.com (X. Cheng).

https://doi.org/10.1016/j.ecoleng.2019.07.030
Received 22 February 2019; Received in revised form 10 June 2019; Accepted 25 July 2019
Available online 03 August 2019
0925-8574/ © 2019 Elsevier B.V. All rights reserved.
L. Li, et al. Ecological Engineering 138 (2019) 237–247

Fig. 1. (a) Sketch map of ecological concrete; (b) Actual-effect pictures of ecological concrete; (c) Actual-effect pictures of ecological concrete greening rate.

et al., 2008), calcium silicate (CeSeH; C]CaO, S]SiO2, H]H2O) gel alkalinity (pH) and hardening degree, and mechanical performance of
and calcium hydroxide (CH), and such a high PH value is not beneficial ecological concrete overlaying soil were comprehensively investigated.
for the growth of plants. Compared with PC, SAC has a relatively lower
alkalinity with the PH value of 11.4 because of the formation of AFt 2. Materials and methods
(C3A·3C$·H32; A = Al2O3, $ = SO3) and AFm (C3A·C$·H12) (Li et al.,
2017b), so the utilization of SAC as the solidified agent, instead of PC, 2.1. Materials
can provide a more suitable environment for plant growing. Moreover,
the manufacture of SAC clinker also has the many advantages, such as Natural soil was from a cornfield, which is located in Duanzhuang
lower formation temperature (~1250 °C), lower carbon dioxide emis- Village, Changqing County, Shandong Province (36°537 N, 116°699 E).
sions and easier grinding with less lower energy consumption (Zhang The physicochemical properties of the natural soil are presented in
et al., 2014; Lu et al., 2014; Chen et al., 2016; García-Maté and Torre, Table 1. SAC (Grade for 42.5 R, manufactured in Qufu Zhonglian Co.,
2013; Marie et al., 2012; Lu et al., 2016). On the other hand, SAPs are Ltd, China) was utilized in this study due to its lower alkalinity. SAP
capable of absorbing a large amount of water from the surroundings (manufactured in Hebei Yanxing Chemcal Co., Ltd, China) was used as
and retaining the water within their structure chains (Jensen and soil improvement agent due to its high water absorption and retention
Hansen, 2001). A previous study suggested that SAPs can stabilize the properties. The water absorptions of the SAP were 72 g water per gram
soil structure and enhance the soil water holding capacity, and finally of it in deionized water and 57 g water per gram of it in NaCl solution
reduce the soil and water erosion in furrow-irrigated fields (Eneji et al., with concentration of 3% and pH of 8.2, and the water absorption was
2013). In addition, SAPs can also effectively reduce shrinkage (Luo determined by the teabag method (Jensen and Hansen, 2002). In ad-
et al., 2017), control crack potential (Snoeck et al., 2012), and regulate dition, vermiculite was often used in agriculture due to its desirable
the rheology of the fresh concrete (Mechtcherine et al., 2014; Shen water retention capacity and loose layered structure (Dzene et al.,
et al., 2016). Therefore, the addition of SAPs is beneficial to improving 2017; Drelich et al., 2011). So vermiculite was adopted as the soil
the water retention of overlaying soil, but the dosage should be care- amendment by a fixed amount of 15.0 wt%. The vermiculite was
fully controlled since excessive amount of SAPs can cause harden of soil sourced from Wangda Minerals Factory, Lingshou County, Hebei
(Pramthawee et al., 2017) and is not good for plant growth.
The objective of this paper was to improve the scouring resistance Table 1
and water retention performance of ecological concrete overlaying soil Physicochemical properties of the natural soil.
with satisfied degree of soil hardening. The solidified agents (SAC &
Properties Natural soil
SAP) were added into natural soil as partial replacement of soil to
prepare an ecological concrete overlaying soil with enhanced scouring Scouring resistance of soil (L/g) 4.25
resistance and water retention performance. Then, the adaptability Water absorption rate (wt%) 50.5
pH 7.54
between overlaying soil and plants was studied by characterizing the
Cone index (MPa) 0.23
germination ratio, survival ration, and dry weight of plants. Finally, Bilk density (g/cm3) 1.87
basic physicochemical properties, such as water absorption ratio, Equilibrium moisture content (wt%) 4.2

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L. Li, et al. Ecological Engineering 138 (2019) 237–247

Table 2 Table 3
Chemical compositions. Physical properties of recycled aggregate.
Component Amount (% by mass) Properties Recycled aggregate

Natural soil SAC Vermiculite Gradation (mm) 20–25


Crush index (%) 18.3
SiO2 65.74 9.60 41.00 Density (kg/m3) 2590
CaO 3.38 45.16 1.82 Water absorption (%) 5.6
Al2O3 17.05 21.64 15.10 Unit weight (kg/m3) 1320
Fe2O3 – 2.45 16.14 Absolute volume (%) 51.6
MgO 2.26 1.28 12.53
K2O 3.02 1.38 5.14
Na2O 1.46 0.17 0.48
added in the ecological concrete mixing as retarder and superplasticizer
TiO2 0.83 1.03 1.91
SO3 0.31 10.73 0.08 admixtures, respectively. Moreover, three alkali-resistance plants (i.e.
Ignition loss 4.51 6.35 3.20 cynodon dactylon, festuca elata and perennial ryegrass) were used to
measure the adaptability between overlaying soil and plants.

2.2. Experimental design

A control specimen of natural soil with vermiculite was marked as


NSV ref. SAC was utilized to partially replace natural soil at the dosages
of 1.0%, 2.0%, 3.0% and 4.0% by weight and marked as NSVC 1.0,
NSVC 2.0, NSVC 3.0 and NSVC 4.0, and SAP was adopted to partially
replace natural soil at the contents of 0.5%, 1.0%, 1.5% and 2.0% by
weight and marked as NSVP 0.5, NSVP 1.0, NSVP 1.5 and NSVP 2.0,
respectively. The mix proportions are shown in Table 4.

2.3. Test methods

2.3.1. Basic properties


The scouring resistance of soil (SRS) was measured in accordance
with (Zhou et al., 2010), for which the test set-up is presented in Fig. 4.
Specimens were wetted from bottom for 12 h, in order to prevent air
entrapment. After that, specimens were placed in the above of a layer of
sand and allowed to drain for 8 h. The specimens were then each putted
Fig. 2. FT-IR analysis of SAP.
into ‘Samples chamber’ and exposed to a flow rate of 4 L/min on a slope
of 25°over a period of 10 min in the ‘Scouring flume’. In this study, all
Province, China, and which was calcined at 850 °C. The chemical outflows were collected for each measurement. After the suspended
compositions of natural soil, SAC and vermiculite were analyzed by an sample particles had settled, the clear water was drained off and the
X-ray fluorescence spectrometer (XRF, Tiger S8, Germany), and the sediments were dried at 105 °C. The SRS was determined according to
data are shown in Table 2. FT-IR spectrometer (Nicolet 380, USA) was the Eq. (1).
employed to determine the functional groups of SAP, and the data are
f×t
presented in Fig. 2. Furthermore, crushed waste demolition concrete AS =
W (1)
was adopted as the coarse aggregates to produce the ecological con-
crete. The crushing of the waste demolition concrete was carried out in where AS is the SRS (L/g), f is the water flow rate (L/min), t is the
the laboratory, and the crushing process is shown in Fig. 3, and the scouring time (min), W is the weight of the oven-dried sediment (g).
basic properties of recycled aggregates are shown in Table 3. Boric acid The equation indicated higher AS values of samples represent higher
(with a purity of 99.0 wt%, manufactured in Sinopharm Chemical Re- resistance to scouring of it.
agent Co., Ltd, China) along with polycarboxylate polymer (manu- The soil compaction was presented by the soil resistance through
factured in Shandong Academy of Building Research, China) were cone index (CI, MPa). The cone index was defined as penetration

Fig. 3. The lab-based preparation process of recycled aggregates.

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L. Li, et al. Ecological Engineering 138 (2019) 237–247

Table 4
Mix proportions (wt%).
No. Natural soil Vermiculite SAC SAP

NSV ref 85.0 15.0 – –


NSVC 1.0 84.0 1.0 –
NSVC 2.0 83.0 2.0 –
NSVC 3.0 82.0 3.0 –
NSVC 4.0 81.0 4.0 –
NSVP 0.5 84.5 – 0.5
NSVP 1.0 84.0 – 1.0
NSVP 1.5 83.5 – 1.5
NSVP 2.0 83.0 – 2.0

resistance (PR, N) divided by cone cross-sectional area (CCSA, mm2)


according to the ASABE Standards (ASABE Standards EP542, 2009; Lin
et al., 2014). To evaluate the cone index of samples, a handheld cone
penetrometer (OK-JS1, China) was fixed on a press, as shown in Fig. 5.
Soil specimens with moisture content of 30% were packed into the
samples cylinders and compacted by a cylindrical ironwork (diameter:
200 mm) at 5 kg. The maximum vertical movement was designed at
500 mm. In addition, the penetration velocity was set at 30 mm/s by the
press to meet the ASABE Standards (ASABE Standards EP542, 2009).
Each resultant value of cone index was an average calculated from three
determinations.
The ex-situ leaching method (Li et al., 2005) was used to extract the
liquid to test the alkalinity (pH) of samples. After that, a laboratory
grade pH meter (pHs-3E, China) was employed to measure the pH of
samples. Each resultant value of alkalinity was an average calculated
from three determinations. Fig. 5. Sketch map of cone index test (h1, 18.6 mm; h2, 21 mm; h3, 30 mm; θ,
The water absorption and absorbency ratio (WAR) of samples was 30°).
determined according to the teabag method (Jensen and Hansen,
2002). A teabag (pre-wetted in the deionized water, mass m2) con- were put in an environment of 25 ± 2 °C and 35 ± 2%RH. At pro-
taining some 5–10 g of soil particles (exact mass m1) was soaked in a grammed times (i.e. 1 h, 2 h, …, 10 h, 12 h, 15 h, 20 h, 25 h, 30 h, 40 h,
container filled with the deionized water. After 3 h, the teabag with the …, 100 h, 120 h, 140 h and 160 h), the specimens were accurately
soil was removed from the water and weighed (mass m3). The WAR of weighed again and the test results were marked as m5. The water re-
the soil was determined by the Eq. (2). lease rate (WRR) of a specimen was obtained by Eq. (3).
m3 − m2 − m1 (m4 − m5) × (1 + WAR)
WAR = × 100% WRR = × 100%
m1 (2) (m4 − m 0) × WAR (3)

The specimens after water absorption measurement were trans-


ferred into a certain weight (m0) of glass dishes (φ 100 × 30 mm), re- 2.3.2. Adaptability
moved air bubbles by vibration, and then wiped the surface flat with In order to investigate the adaptability between ecological concrete
the scraper. After which specimens (samples and glass dish, as follows) overlaying soil and plants, the experiment of plants growth in ecolo-
were accurately weighted and marked as m4. The wiped specimens gical concrete was designed. Firstly, an outdoor land (9 × 9 m2) was

Fig. 4. Set-up for SRS test.

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L. Li, et al. Ecological Engineering 138 (2019) 237–247

Fig. 6. Actual-effect pictures of adaptability investigation; a) Leveling land; b) Ecological concrete preparation and paving; c) Covering soil with seeds; d) Watering
and Covering adumbral netting; e) Sowing seeds for 7 days; f) Sowing seeds for 60 days.

Table 5 compared with sample NSV ref. A possible reason was that SAP could
Mix proportion and basic physical properties of ecological concrete. stabilize the soil structure due to its hydrophilic networks. Wang et al.
Mix proportion (kg/m3) SAC 220
(Wang et al., 2019) also utilized a flume scouring experiment to study
Recycle aggregate 1320 the effect of the sediment content on the SRS of natural soil. The ex-
Boric acid 0.87 perimental results presented that the SRS of soil decreased with the
Polycarboxylate polymer 2.39 increasing of sediment content. In this paper, the fine soil particles
Water 55
could be bonded by SAC and SAP to form particles that resemble se-
Physical properties Void Ratio (%) 35.0 diment. In addition, the study of Cao et al on SAP modified soil sug-
Permeation coefficient (cm/s) 2.95
gested that the initial runoff time of natural soil increased with the
Compressive strength (MPa) 8.4
increasing of SAP content (Cao et al., 2017). Hence, SAC and SAP were
suitable to enhance the SRS of ecological concrete overlaying soil.
leveled (Fig. 6a) and then the ecological concrete with a void ratio of The measurement results of cone index (Fig. 7b) representing the
35% was prepared according to (Li et al., 2018) and paved on the land compaction of the soil. Soil compaction is a key issue for plants growth
(Fig. 6b), and the mix proportion and basic physical properties of (Chen and Weil, 2011). Moderate compaction may improve the grass
ecological concrete is shown in Table 5. Secondly, after 24 h later, the seed germination rate and prevent water runoff, otherwise excessive
overlaying soil with a certain amount (N0) of grass seeds was covered compaction leads to higher soil strength and cannot supply adequate
on the concrete, and the ply of the soil was controlled in about 3 cm spaces for plants roots (Tolon-Becerra et al., 2011; Modolo et al., 2011).
(Fig. 6c). Finally, an appropriate amount of water was sprayed (after The cone index of sample NSV ref was only 0.31 MPa. With a replace-
which, the water was sprayed once every two weeks), and an adumbral ment of 1.0% SAC, the cone index reached up to 0.42 MPa, an in-
netting was adopted (Fig. 6d). After 7 days later, the adumbral netting creasing of 35.5% compared to that of sample NSV ref. Furthermore,
was removed, and the amount of plants was determined and record as with the content of SAC at 4.0 wt%, the cone index increased by 261.3%
N1 (Fig. 6e). When the time of sowing seeds for 60 days, the amount of to a value of 1.12 MPa compared to that of sample NSV ref. Therefore it
plants was determined again and record as N2 (Fig. 6f). After which, is obviously that the cone index increased significantly with the in-
plants were cut down and put in an drying oven of 105 ± 2 °C for 24 h, crease of SAC content. On the other hand, in cases of a SAP addition of
and then the dry weight of plants was tested. The equations employed no more than 1.5 wt%, the cone index increased slowly with the in-
to obtain germination ratio (GR) and survival ratio (SR) a sample was as crease of SAP content; the difference was no more than 45.2%. For
follows: instance, the cone index of sample NSVP 0.5 was 0.33 MPa, an increase
of only 6.5% compared with the reference. Yet, when the addition of
N1 SAP reached up to 2.0 wt%, the cone index increased to 0.76 MPa, an
GR = × 100%
N0 (4) increasing of 145.2% compared with that of sample NSV ref. The work
N2 by Chung et al. on the strength and cone index of soil (Chung et al.,
SR = × 100% 2013) provided that the cone index of soil was linear as a function of
N1 (5)
unit weight of soil, cohesion, adhesion. Therefore, the increasing of
cone index represented the increase of cohesion and adhesion of the
3. Results and discussion soil, which is also consistent with the SRS test results (Fig. 7a).
Fig. 7c shows the data of alkalinity measurement. It clearly de-
3.1. Basic properties monstrates that increasing the SAC content leads to increase of pH of
the soil. Compared to the sample NSV ref (pH = 7.47), the pH of spe-
The test results of scouring resistance the soil are presented in cimens increases by 4.0% (pH = 7.77), 11.2% (pH = 8.31), 23.6%
Fig. 7a. The scouring resistance of soil (SRS) increased with the in- (pH = 9.23) and 26.8% (pH = 9.47) with increasing SAC content from
creasing of SAC addition. When the dosage of SAC reached up to 4 wt% 1.0 wt%, 2.0 wt%, 3.0 wt% and 4.0 wt%, respectively. The phenomenon
(i.e. sample NSVP 4.0), the SRS increased by 28.7% to a value of 6.91 L/ could be attributed to that some alkaline substances (e.g. potassium
g compared with sample NSV ref. Therefore, SAC could improve the SRS hydroxide, sodium hydroxide et al.) could be produced by the hydra-
of the soil effectively. This possibly because a mechanically stable form tion of SAC. Fortunately, application of SAP did not have any sub-
could be built by the hydration and hardening of SAC. Furthermore, the stantial influence on the pH of specimens which was almost equal for all
SRS of samples were significantly increase by the addition of SAP, and mixtures; the difference was less than 2.5%. This was mainly due to that
the SRS of sample NSVP 2.0 increased 74.3% to a value of 9.36 L/g SAP was a hydrophilic networks polymer, and alkaline substances were

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L. Li, et al. Ecological Engineering 138 (2019) 237–247

Fig. 7. Basic properties: a) Scouring resistance of soil; b) Cone index; c) Alkalinity; d) Water absorption rate.

not be produced by it. SAC addition, the water absorption rate increased very slowly. This
Water is necessary for plants growth. Ecological concrete is a porous trend continued with the increase of SAC dosage. So SAC was testified
concrete with high void ratio and water permeability coefficient. Loss to be unsuitable to enhance the water absorption of the overlaying soil.
of water can occur very easily in ecological concrete, which often On the other hand, with the dosage of SAP at 0.5 wt%, the water ab-
causes plants withering and even dying (Jara-Rojas et al., 2013; sorption rate increased 13.6% to a value of 62.1 wt% compared with
Valášková et al., 2009). Hence, it is needful to enhance the water ab- the reference. Furthermore, with a content of 2.0 wt% SAP, the water
sorption and retention properties of the overlaying soil of ecological absorption rate reached up to 76.1 wt%, an increase of 39.4% compared
concrete (Valášková et al., 2009; Tang et al., 2018). Fig. 7d presents the with that of sample NSV ref. Hence, it is obviously that the water ab-
test results of water absorption rate of soil, and the corresponding ab- sorption rate increased with the increase of SAP addition. This is chiefly
sorbency ratios are shown in Fig. 8. When the dosage of SAC was 2.0 wt because SAP could absorb a large amount of water from the sur-
%, comparing with sample NSV ref the water absorption rate increased rounding. Additionally, there was not much effect of SAC content on the
only by 1.5% to a value of 55.4 wt%. Evidently, with the increase of water absorbency ratio of soils. On the contrary, the water absorbency
ratio increased significantly with the increase of SAP dosage, which
means that the soils containing SAP could absorb more water in the
same time. Hence SAP was demonstrated to be efficient to enhance the
water absorption of the soil.
Fig. 9 shows the test data of water release rate of samples, re-
presenting their water retention property. Compared with sample NSV
ref, the water release rate increased with the increasing of SAC addition.
With the addition of 4.0 wt% SAC, the water release rate increased by
7.8% to a value of 75.9 wt% at 160 h. This could be because that the
main hydration products of SAC were AFt and AFm with compact
structure, and the water retention property of AFt and AFm was lower
than that of the soil. So it is evidently that SAC was not benefit to en-
hance the water retention property of the overlaying soil. Compared
with the reference, the water release rate of sample NSVP 0.5 decreased
by 2.8% to 68.4 wt% at 160 h. In addition, with a dosage of 2.0 wt%
SAP, the water release rate reduced to 60.7 wt%, a decrease of 13.8%
compared with that of sample NSV ref at the same time as described
above. So it is obviously that the water release rate reduced with the
increasing of SAP content, which was consistent with the experimental
result of Yang et al. (Yang et al., 2014). This might be due to that SAP
Fig. 8. Water absorbency ratio of soils.

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L. Li, et al. Ecological Engineering 138 (2019) 237–247

Fig. 9. Water release rate of soils.

could absorb plenty of water from the surroundings and to save the important reason to enhance the water erosion resistance of the soil and
water within their structure chain. In addition, the work by Cao et al. maintain fertility. Hence SAP was demonstrated to be efficient to ad-
(2017) suggested that the temporal and spatial distribution of moisture vance the water retention property of ecological concrete overlaying
was optimized by SAPs, and utilization SAPs was beneficial to the soil soil.
aggregate structure. Moreover, SAPs were high polymer electrolytes
and adsorb electrically opposite ions and small soil groups, which is an

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L. Li, et al. Ecological Engineering 138 (2019) 237–247

Fig. 10. Germination ratios of the plants.

3.2. Adaptability 70.7%. Fortunately, in cases of a SAP addition of no more than 1.5 wt%,
the survival ratios of plants enhanced with the improvement of SAP
Fig. 10 shows the germination ratios of the plants. For sample NSV content. For instance, with an addition of 1.5 wt% SAP, the survival
ref, the germination ratio of cynodon dactylon, festuca elata and per- ratio of cynodon dactylon, festuca elata and perennial ryegrass were
ennial ryegrass were 98.7%, 93.5% and 98.2%. With the addition of 96.3%, 93.2% and 97.9% higher than that of sample NSV ref. The work
SAC at 2.0 wt%, the germination ratios of cynodon dactylon, festuca by Yang et al. also suggested that the utilization of SAPs was beneficial
elata and perennial ryegrass decreased by 10.4%, 10.5% and 2.7% to for the survival of plants in slopes eco-engineering (Yang et al., 2014).
88.4%, 83.7% and 95.5%. At the same time, with a dosage of 4.0 wt% However, 2.0 wt% SAP could decrease the survival ratios of plants
SAC, the germination ratios of cynodon dactylon, festuca elata and compared with the sample with 0 wt% SAP, which proves that excessive
perennial ryegrass decreased to 71.9%, 62.8% and 88.7%, decreases of SAP is harmful to the survival of the plants. Hence SAP addition should
27.2%, 32.8% and 9.7% compared with that of sample NSV ref. Evi- be no more than 1.5 wt%, which could enhance the survival ratios of
dently, with the increase of SAC content, the germination ratio of the cynodon dactylon, festuca elata and perennial ryegrass.
plants decreased. Furthermore, in cases of a SAP dosage of no more The dry weights of the plants are presented in Fig. 12, which re-
than 1.5 wt%, the germination ratio of the plants reduced slowly with present the state of plants growth. The dry weight of plants decreased
the increasing of SAP content. For instance, with an addition of 1.5 wt% with the increasing content of SAC. With a content of 4.0 wt% SAC, the
SAP, the germination ratio of cynodon dactylon, festuca elata and dry weight of cynodon dactylon, festuca elata and perennial ryegrass
perennial ryegrass were 93.7%, 88.6% and 93.4%, the decreases of decreased by 49.4%, 44.0% and 47.2% compared with that of sample
5.1%, 5.2% and 4.9% compared with that of sample NSV ref. However, NSV ref. On the other hand, in cases of a SAP dosage of no more than
when the addition of SAP reached up to 2.0 wt%, the germination ratio 1.5 wt%, the dry weight of the plants increased with the increasing of
of plants as described above decreased by 13.2%, 13.5% and 16.2% to SAP addition. For instance, the dry weight of perennial ryegrass of
values of 85.7%, 80.9% and 82.3%. On the contrary, the work by Yang sample NSVP 0.5, sample NSVP 1.0 and sample NSVP 1.5 were
et al. on the seed germination for slopes eco-engineering modified by 1.69 kg m−2, 1.87 kg m−2 and 2.16 kg m−2 higher than that of the re-
SAPs proved the germination of plant increased with the increasing of ference. However, 2.0 wt% SAP could decrease the dry weight of plants
SAP addition (Yang et al., 2014). This might be due to that the SAPs compared with sample NSV ref, which proves that excessive SAP con-
contents were no more than 0.45% in the study of Yang et al., and the tent is harmful to the growth of plants. Hence SAP content should be no
water absorption and water retention capacity of soil were significantly more than 1.5 wt%, which could enhance the adaptability between the
improved by SAPs, and the cone index of soil was essentially un- plants and the soil.
changed. However, in this paper, 0.5% to 2.0% SAPs was adopted in
order to increase the scouring resistance, water absorption and water
4. Conclusions
retention of soil, which resulted in the significantly increase of cone
index of soil and limited the germination of plants.
In the current study, from the basis of multiple perspectives, the
The results of survival ratios of the plants are presented in Fig. 11.
effects of sulphoaluminate cement (SAC) and super absorbent polymer
With the increase content of SAC, the survival ratios of the plants de-
(SAP) on scouring resistance, water absorption, water retention cone
creased. When the content of SAC reached up to 4 wt%, the survival
index and alkalinity properties of the soil, and on adaptability (i.e.
ratios of cynodon dactylon, festuca elata and perennial ryegrass de-
germination ratio, survival ratio and dry weight of plants) between
creased by 25.8%, 27.6% and 25.9% to values of 67.9%, 63.1% and
three alkali-resistance plants (i.e. cynodon dactylon, festuca elata and

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Fig. 11. Survival ratios of the plants.

perennial ryegrass) and the soil were investigated. The investigation increased by 74.3% to a value of 7.41 L/g due to 2.0 wt% SAP.
supports the following conclusions: (2) The utilization of SAP shown to be suitable for the improvement of
the water absorption and water retention property of the soil. With
(1) The scouring resistance of soil (SRS) significantly improved with an addition of 2.0 wt% SAP, the water absorption rate reached up to
the increase of SAC/SAP addition. When the content of SAC was 76.4 wt%, an increase of 39.4% compared with the reference, and
4 wt%, the SRS reached up to 6.91 L/g, an increase of 28.7% the water release rate decreased by 13.8% to a value of 60.7 wt%
compared to the sample with 0 wt% SAC. Furthermore, the SRS compared to that of the reference at 160 h.

Fig. 12. Dry weights of the plants.

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(3) The cone index of the soil improved with the increase of SAC/SAP Jensen, O.M., Hansen, P.F., 2001. Water-entrained cement-based materials: I. Principles
addition. With a content of 4.0 wt% SAC, the cone index increased and theoretical background. Cem. Concr. Res. 31 (4), 647–654. https://doi.org/10.
1016/S0008-8846(01)00463-X.
by 261.3% to a value of 1.12 MPa compared with the reference, and Jensen, O.M., Hansen, P.F., 2002. Water-entrained cement-based materials: II.
with a content of 2.0 wt% SAP, the cone index increased to Experimental observations. Cem. Concr. Res. 32 (6), 973–978. https://doi.org/10.
0.76 MPa, an increase of 145.2% compared to that of the reference. 1016/S0008-8846(02)00737-8.
Kim, H.K., Lee, H.K., 2010. Acoustic absorption modeling of porous concrete considering
(4) The alkalinity (pH) of the soil increased with the increasing SAC the degradation and shape of aggregates and void ratio. J. Sound Vib. 329, 866–879.
content. The alkalinity increased by 11.2% to a value of 8.31 by https://doi.org/10.1016/j.jsv.2009.10.013.
2.0 wt% SAC, and this trend continued with the increase of SAC Li, L., Nam, J., William, H.H., 2005. Ex situ leaching measurement of concrete alkalinity.
Cem. Conc. Res. 35 (2), 277–283. https://doi.org/10.1016/j.cemconres.2004.04.
content. Therefore, SAC was harmful to plants growth due to its 024.
high alkalinity. In other hand, application of SAP did not have any Li, L., Gong, C., Wang, S., Lu, L., Cheng, X., 2017b. Effect of natural zeolite on perfor-
substantial effect on the alkalinity which was almost equal for all mance of sulfoaluminate cement-based planting cementitious material. J. Wuhan
Univ. Technol. 32 (3), 586–590. https://doi.org/10.1007/s11595-017-1638-2.
soils; the difference was less than 2.5%.
Li, L., Chen, M., Zhou, X., Lu, L., Li, Y., 2017a. A case of water absorption and water/
(5) In cases of a SAP dosage of less than 1.5 wt%, the germination ratios fertilizer retention performance of super absorbent polymer modified sulphoalumi-
of plants decreased slowly with the increasing SAP dosage. In ad- nate cementitious materials. Constr. Build. Mater. 150, 538–546. https://doi.org/10.
dition, the survival ratios and dry weights of the plants of SAP 1016/j.conbuildmat.2017.05.219.
Li, L., Chen, M., Zhou, X., Lu, L., Wang, Y., Cheng, X., 2018. Evaluation of the preparation
containing soils were for an up to 1.5 wt% soil replacement level and fertilizer release performance of planting concrete made with recycled-concrete
better than the reference sample but higher SAP dosage appeared as aggregates from demolition. J. Clean. Prod. 200, 54–64. https://doi.org/10.1016/j.
quite unsatisfactory. jclepro.2018.07.264.
Li, X., Poon, C.S., Sun, H., Lo, I.M., Kirk, D.W., 2001. Heavy metal speciation and leaching
behaviors in cement based solidified/stabilized waste materials. J. Hazard. Mater. 82
Declaration of Competing Interest (3), 215–230. https://doi.org/10.1016/S0304-3894(00)00360-5.
Lin, J., Sun, Y., Lammers, P.S., 2014. Evaluating model-based relationship of cone index,
soil water content and bulk density using dual-sensor penetrometer data. Soil Till.
The authors declare no conflict of interest. Res. 138, 9–16. https://doi.org/10.1016/j.still.2013.12.004.
Lu, Z., Xu, B., Zhang, J., Zhu, Y., Li, Z., 2014. Preparation and characterization of ex-
Acknowledgment panded perlite/paraffin composite as form-stable phase change material. Sol. Energy
108, 460–466. https://doi.org/10.1016/j.solener.2014.08.008.
Lu, Z., Asad, H., Ning, C., Shao, H., Yin, R., Li, Z., 2016. Steric stabilization of graphene
This work is supported by the National Key Point Research and oxide in alkaline cementitious solutions: mechanical enhancement of cement com-
Invention Program of the Thirteenth through the grants of NO. posite. Mater. Des. 127, 154–161. https://doi.org/10.1016/j.matdes.2017.04.083.
Luo, Y., Jiang, S., Qi, X., Chen, C., Li, B., 2017. Highly reusable and superhydrophobic
2016YFC0701000.
spongy graphene aerogels for efficient oil/water separation. Sci. Rep-UK 7 (1), 1–10.
https://doi.org/10.1038/s41598-017-07583-0.
References Marie, M., Jean-François, G., Jean, A., 2012. Improving the mechanical performance of
high-grade slag cement by the addition of Portland cement and sulfoaluminate ce-
ment. Constr. Build. Mater. 37, 291–300. https://doi.org/10.1016/j.conbuildmat.
Agar-Ozbek, A.S., Weerheijm, J., Breugel, E.S.K., 2013. Investigating porous concrete 2012.04.041.
with improved strength: testing at different scales. Constr. Build. Mater. 41, 480–490. Mechtcherine, V., Secrieru, E., Schröfl, C., 2014. Effect of superabsorbent polymers
https://doi.org/10.1016/j.conbuildmat.2012.12.040. (SAPs) on rheological properties of fresh cement-based mortars-development of yield
Bhutta, M.A.R., Hasanah, N., Farhayu, N., Hussin, M.W., Tahir, M.B.M., Mirza, J., 2013. stress and plastic viscosity over time. Cem. Concr. Res. 67, 52–65. https://doi.org/10.
Properties of porous concrete from waste crushed concrete (recycled aggregate). 1016/j.cemconres.2014.07.003.
Constr. Build. Mater. 47, 1243–1248. https://doi.org/10.1016/j.conbuildmat.2013. Modolo, A.J., Trogello, E., Nunes, A.L., 2011. Effect of soil compaction upon the seed on
06.022. the development of bean culture. Acta. Sci-Agron. 33, 89–95. https://doi.org/10.
Cao, Y., Wang, B., Guo, H., Xiao, W., Wei, T., 2017. The effect of super absorbent poly- 4025/actasciagron.v33i1.4236.
mers on soil and water conservation on the terraces of the loess plateau. Ecol. Eng. Park, S.B., Tia, M., 2004. An experimental study on the water-purification properties of
102, 270–279. https://doi.org/10.1016/j.ecoleng.2017.02.043. porous concrete. Cem. Concr. Res. 34, 177–184. https://doi.org/10.1016/S0008-
Chen, M., Wang, S., Lu, L., Zhao, P., Gong, C., 2016. Effect of matrix components with low 8846(03)00223-0.
thermal conductivity and density on performances of cement-EPS/VM insulation Pramthawee, P., Jongpradist, P., Sukkarak, R., 2017. Integration of creep into a modified
mortar. J. Therm. Anal. Calorim. 126 (3), 1123–1132. https://doi.org/10.1007/ hardening soil model for time-dependent analysis of a high rockfill dam. Comput.
s10973-016-5718-x. Geotech. 91, 104–116. https://doi.org/10.1016/j.compgeo.2017.07.008.
Chen, G., Weil, R.R., 2011. Root growth and yield of maize as affected by soil compaction Rajasekaran, G., 2005. Sulphate attack and ettringite formation in the lime and cement
and cover crops. Soil Till. Res. 117, 17–27. https://doi.org/10.1016/j.still.2011.08. stabilized marine clays. Ocean Eng. 32 (8), 1133–1159. https://doi.org/10.1016/j.
001. oceaneng.2004.08.012.
Chung, S.O., Sudduth, K.A., Motavalli, P.P., Kitchen, N.R., 2013. Relating mobile sensor Shen, D., Shi, H., Tang, X., Ji, Y., Jiang, G., 2016. Effect of internal curing with super
soil strength to penetrometer cone index. Soil. Till. Res. 129, 9–18. https://doi.org/ absorbent polymers on residual stress development and stress relaxation in restrained
10.1016/j.still.2012.12.004. concrete ring specimens. Constr. Build. Mater. 120, 309–320. https://doi.org/10.
Codina, M., Cau-Dit-Coumes, C., Bescop, P.L., Verdier, J., Ollivier, J.P., 2008. Design and 1016/j.conbuildmat.2016.05.048.
characterization of low-heat and low-alkalinity cements. Cem. Concr. Res. 38 (4), Snoeck, D., Steuperaert, S., Tittelboom, K.V., Dubruel, P., Belie, N.D., 2012. Visualization
437–448. https://doi.org/10.1016/j.cemconres.2007.12.002. of water penetration in cementitious materials with superabsorbent polymers by
Ćosić, K., Korat, L., Ducman, V., Netinger, I., 2015. Influence of aggregate type and size means of neutron radiography. Cem. Concr. Res. 42 (8), 1113–1121. https://doi.org/
on properties of pervious concrete. Constr. Build. Mater. 78, 69–76. https://doi.org/ 10.1016/j.cemconres.2012.05.005.
10.1016/j.conbuildmat.2014.12.073. ASABE Standards, 2009. EP542: Procedures for Using and Reporting Data Obtained With
Drelich, J., Li, B., Bowen, P., Hwang, J.Y., Mills, O., Hoffman, D., 2011. Vermiculite the Soil Cone Penetrometer. ASABE, St. Joseph, MI.
decorated with copper nanoparticles: novel antibacterial hybrid material. Appl. Surf. Stanforth, R., 2001. Comment on ‘Leaching microstructural analysis of cement-based
Sci. 257, 9435–9443. https://doi.org/10.1016/j.apsusc.2011.06.027. solidified wastes’. Environ. Sci. Technol. 35 (21), 4394–4395. https://doi.org/10.
Dzene, L., Ferrage, E., Viennet, J.C., Tertre, E., Hubert, F., 2017. Crystal structure control 1021/es010693z.
of aluminized clay minerals on the mobility of caesium in contaminated soil en- Tamai, M., Mizuguchi, H., Hatanaka, S., Katahira, H., Nakazawa, T., 2004. Design, con-
vironments. Sci Rep-UK 7 (1), 1–12. https://doi.org/10.1038/srep43187. struction and recent applications of porous concrete in Japan. Proceedings of the JCI
Eneji, A.E., Islam, R., An, P., Amalu, U.C., 2013. Nitrate retention and physiological ad- symposium on design, Construction and Recent Applications of Porous Concrete.
justment of maize to soil amendment with superabsorbent polymers. J. Clean. Prod. Japan Concrete Institute.
52 (4), 474–480. https://doi.org/10.1016/j.jclepro.2013.02.027. Tang, W., Mohseni, E., Wang, Z., 2018. Development of vegetation concrete technology
García-Maté, M., Torre, A.G.D., 2013. Hydration studies of calcium sulfoaluminate ce- for slope protection and greening. Constr. Build. Mater. 179, 605–613. https://doi.
ments blended with fly ash. Cem. Concr. Res. 54, 12–20. https://doi.org/10.1016/j. org/10.1016/j.conbuildmat.2018.05.207.
cemconres.2013.07.010. Tolon-Becerra, A., Tourn, M., Botta, G.F., 2011. Effects of different tillage regimes on soil
Gong, C., Zhou, X., Ji, L., Dai, W., Lu, L., 2017. Effects of limestone powders on pore compaction, maize (Zea mays L.) seedling emergence and yields in the eastern
structure and physiological characteristics of planting concrete with sulfoaluminate Argentinean Pampas region. Soil Till. Res. 117, 184–190. https://doi.org/10.1016/j.
cement. Constr. Build. Mater. 162, 314–320. https://doi.org/10.1016/j.conbuildmat. still.2011.10.003.
2017.10.012. Valášková, M., Martynková, G.S., Smetana, B., Študentová, S., 2009. Influence of ver-
Jara-Rojas, R., Bravo-Ureta, B.E., Engler, A., Díaz, J., 2013. An analysis of the joint miculite on the formation of porous cordierites. Appl. Clay Sci. 46, 196–201. https://
adoption of water conservation and soil conservation in Central Chile. Land Use doi.org/10.1016/j.clay.2009.08.003.
Policy. 32 (3), 292–301. https://doi.org/10.1016/j.landusepol.2012.11.001. Wang, Y., Luo, J., Zheng, Z., et al., 2019. Assessing the contribution of the sediment

246
L. Li, et al. Ecological Engineering 138 (2019) 237–247

content and hydraulics parameters to the soil detachment rate using a flume scouring different temperatures. Constr. Build. Mater. 150, 287–294. https://doi.org/10.
experiment. Catena 176, 315–323. https://doi.org/10.1016/j.catena.2019.01.024. 1016/j.cemconcomp.2018.08.011.
Yan, X., Gong, C., Wang, S., Lu, L., 2013. Effect of aggregate coating thickness on pore Zhang, X., Zhao, M., Zhang, Y., 2014. Preparation and properties of self-pulverizing
structure features and properties of porous ecological concrete. Mag. Concr. Res. 65 calcium sulfoaluminate cement. Constr. Build. Mater. 34, 107–113. https://doi.org/
(1), 1–8. https://doi.org/10.1680/macr.12.00234. 10.1016/j.conbuildmat.2012.02.006.
Yang, L., Yang, Y., Chen, Z., Guo, C., Li, S., 2014. Influence of super absorbent polymer on Zhou, Z., Gan, Z., Shangguan, Z., Dong, Z., 2010. Effects of grazing on soil physical
soil water retention, seed germination and plant survivals for rocky slopes eco-en- properties and soil erodibility in semiarid grassland of the Northern Loess Plateau
gineering. Eco. Eng. 62, 27–32. https://doi.org/10.1016/j.ecoleng.2013.10.019. (China). Catena 82 (2), 87–91. https://doi.org/10.1016/j.catena.2010.05.005.
Zhang, Z., Yan, P., 2017. Hydration kinetics of the epoxy resin-modified cement at

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