"..

me

- ⑫ ⑫
--
- Nis + H2S
NISH -

[93 [9]
(5) --

Yes I
1 -
I
+ pleas
-

k = PxD

=144

2
* = 144

:
P
= 444
e
TOTAL PRESSURE :

PNI3 +P H2S .

12 + 12

2
=

-T
-

fota-Bressur F
oF
E9 .
 ~
WiBH2 19 291
ERNHS
(8)

KC :
ON o

fur 3
Ne + 3H2

~
2N4 3

42
G(bre
(4) (9) [I]

&

NOCES N2 3 H2 2NH
3

& NITAL
a b -

CONC .

NOCES Of b-x 2x
a x
#9
-

ACTIVE

3
a x
2x
-

Mass
x
[E9- CoN2)

- e
 K
N?

He +12 => 2 #I

(9) (9) [S]

-
MOLES H2 12 &H

NIAL I I -

NOCES 1 -
x 2x -

1
Eq
-
x
A ·

ToT #9 :

i
CONC .

422

x
= jey -Day *-
**
0
-
Racow :

-
/Ans : 10
Y

~ 2c D B'
I
=
+

-
NITIAL MOLES Of
-

Is tricE THAT OF
AFFIIUM NOCES A

AND ARE AQUAL .

CALWATE THE % DISSOCIATION

of ?

2c
D
B
+

~
3A + > .

& NIN A L I 0
2
O 0

2 x 2x x -

1-3x
I9
-

At
-
1-3x = 1
/5
2x x
GIVEN =

Isation E cation
100
N #AKEN

~ % Bassociakon

Ex
Bryxo :
 Ferrag
ke. And

AccoRyrg to
>
->
VANT HOFFS EQUATION

STD
:

. FREE
ENERGY

-
⑧
Hawats
/4 =
04 +e-303 xR+log & .

X -X -
~
FREE
ENERG SAS
CONSTANT
REACTION

⑧
-
& HANGES
D
.

&
⑦atEt
-

w I
19 k

6 -I
-
=

04 20
-
04 =
04 2 303xRylogK
144 ~
+ . .

=
8

-
24° 2-303x1rlog Eq-
⑮
0 =
+

-os
-

ge
t
e

-
Itty-anyt
-
 -

FREE ENERGY # .
CONSTANT CONCENT"
CHANGES

24 =
0 kc = 1 R& =

Pro

-9 >o KCC I REACTINST PRODUCTS

04
REACTHNSC PRODUCTS
0 Ke7I ·

I-
⑥ O
& 4°= 0H- TOS

-
-

↳ famlpy chara
STANDARD s

"
FREE LaERcy
CHANGES
24° =
&H
*
-
+Est

08
 ~

Simi
-
I
I
x~
-

#
OF
-

CAANSt
ROLE I
~
-
ECT
I
CHANGE IN

of
-
I

#
-
uctot

OF CHANGE

:
-

CHAwst

~
PRESSURE
In

-
coNe"

IN

TEMPERATUR
~
M

I
 ⑰
wancome conte
0
i
->

0
0 .
A
INCREASING 29) [S] (S)
e
FORRVARD REACTION
CONC
[FORWARS) (BackWan5] FAVOUR5-
NH3 ↑
>
->

BALIC WARD

RFACTION .

②
I FiferStesews]ot-
⑧
YELLOW
(PEEPRED]
(CS)
e

-
=
↑
come
NCREASING
DEED
↳
COLOUR
--

T
-
-

-
WTENSE)
-

② of CHANGE In
PRESSURE :
-
&

i
direction
-
2 ACTION
Oug de the
& EACTION
m
:

⑫ E FORWARD
Ne-t3H2 FINAB **. * DIRECTION
-
:

pcl5 = pastcle
⑧
1 PNE SHIFT
FORWARD
to
DIRECTION .

H 2 + I2 EZC O No EFFECT of PRESSURE

 425024O2 =20y *9 u
0 C -

(2-3)

5) N202 -
2 NO2

0
1 P
~
[2 - -

3)
-RA
EFFECT OF
TURE
CHANGE IN

0 ENDO HIGH TEmpr

LOW PRESSURE
FORWARD DIREGION

B ACKWARD

0
EX0 HIGH tEmp .

FORWARD
~
~
LOW PRESSURE DIRECTION
B ACKWARD
.

-
Nomohel
+3H2
Ne - 2 NHB
Ung ! -

&
(S
O
V I9 E9)
0
I
4
3 Ete
- 2

HIGH PRESSURE
Low TEMP

/
2NH3 => N2 + 312
2
4
Ang
-

(9) (949)
Low
-
+ -
e

PRESSURE
H I4H TEMPERATURE
④ of Catalyst :

get :

S
7
⑧
e
Mb02

2kal +3024 :

*
NCREASE 2kdos
RATE of REACTION
.

⑰
P
2H202 220
-
+1 02

↳zengfan
) ECREASE

R AT
THE

OF

REACTION .
2H202 ->

arayst
REACTION
Anot
elizo +202

INA A

~ DOES Na ALTER The

Chayst

Rosiow Equ
-

of

CANY AFFEATHE
~ CAASIT
REACHON
Compositio or of
↑ANTURE

-
 EqUBRIUN :

↳
--
* tavolving Als in
Aqueous Socution .

ROLYTES
THE DISSOCIATED
compounds WHICH Is INTO

fors ON
Dissolving SOWENT (H20)
-

I
-w
/intr /17
range hara
WEAK .

e Patsy
e
D ISSOC AtEb

+
IN
SOLVEN-
:
(1)
(H3-100H
SVCROSE NacI
HCN
Strost H2504
HCS

Two
s
NH40H
#Es
LESTROLYTES or :

& ARHEMUS THEORY ELECTROGYTES

*
Loweay- BRONSHES ACID-BASE
THEORY
LEWIS
THEOgy
* ·

THEORY
S ECECROLYTES OF :

* HA0 HT
fA-COPPOSITELY
CHAR
<ED)
PARTI2LES)
*

-
7->
/orisation & arrows)
Arrows S
* PROCESS Of CONIZATION IS
REVERSIDLE
AB =
At +Br

⑲ & ONISATION CONSTANT

O Ka
=B
[OR]
⑩ Dissociation Constant)
 (x) OF ONSATON : -

The fractor of foxAL Amount of ELEAROL

-

:
TES GETS &
ONSED ARE "LDD" (4) DHX
-

I- Disor e
ocs
PRESENT
.E

AmirAcly

mum are :
o

T
Ka
>
->C
Dicuriou Law -
O !
--> 0
It

-
(
- -

- * Vau for Vu Weak CEROLYES

way

⑭Narcoor+
H
CH3-COOH
-
(43(1)
[WEAK ELECTROLY +E
·
CPARTIALLY
IONISEgy
6005
-
CH3-200H -
- CHS-coor + Ht
-

O
* 0

A -
1 - -
CX-

↓=
CX
cfl 2) -

-
a
I V

ka=
Sie
↑
,
It