***

oSUN STATE UNIVERSITY, OSOGBO

LTY:
COLLEGE:ScIENCE,ENGINEERING AND TECIHNOLO,
ASIC &APPLIED SCIEN.S DEPARTMENT,PUAE & A'TH UI CHi
2020/2021RAIN SEMESTER EXAEINATION
********-***
Course Ttie: General chemistry u
O u r e code: CHM 102
NoOr
tnstruction:
Shade the appropriate options in the answer sheet TYPE B TTie

Which of these cHbracteristics is not

as5ociated with aliphatic compounds h y contain (an."
9ontan strachain compounds C. Contain branched chain compoundsD. Has apprograte hut r
atoms and functiönal groups
dentity the corrggt alkane name for the molecular formula Gxotez A. Prodecane B
Eicosane iatont.nt
Oodecane
dd
During sodfum tussion test, the formation of a white precipitate with aqeous amnionia atter the adu

diuie HNO and AgNO, to sodium fusion filtrate indicates the presence of A Mitrogen B Ppo:phi
Chiorine D ioding
4 if the siver mirror test is positive, it indicates the pre sence of A Alkyne B. ikanol (,. Alkanonep. Aia

5 The bond angles of Sp' hybridizatlon is A. 90p 120 10950. 180

0 i e c t the incorrect statement regarding terminal h l k y n e s A . Terminal alkynes have high pKa valu

alkanes and alkenes B. Terminat alkynes are more acidic when compared with alkenes,t Terminal aw yre
not as acidic as alkanes D. They have a replaceabie acioic hydrogen
tunephrine jadrenaline) is a hormone secreted into the biooastream in times ot stress. it tontams >

7.15% H, 26.20% 0 and 7.65% and has a molar masiof 183p/mol What is its molecular formula A. Cti

CaHsN0, C. CH:iy0; D. CaHlO

molar
nydrocarbon is tound o be
LHg.
in
a separate expermient, tie
en
Tre empirical tormula tor a f
determined to be pproximately 1-g/mo
the
umber
or hydrogens J the nolecuiar tofmulg
hydrocarbon is rerore.. A.812C16 D. if
and water as the only products.
Propane gas (C3Hs) Durns compietely in ONVBen to
p0 uce carcondiogide
with a bali2ncen camical eutaion using sn.aller integer coefficignts, the coefficlen
reaction is descripea
A. 1 B. 3 C. 6 D.
water will be A 13
bonds respectively are
in the tollowing molecule CHCH;CHCHCH,CH
10. How many sigmaand pi
17,1 C. 19, 0 D16,
sodium fusion extract is acidified with which of the foilowing
the
11. tn the test for nitggen, C. concentrated hydrochioric acidD, concenlrated sulp
hyarochioric acia
A.Dilute sulphunic acid B Dilute
acid mobile phase respectiuely i
pertormance quid chrorgatogrdphy
uses what type ot stationary and
D. Liqurd, Sofd
B Gas, Liquid C. Liquid, Liquid
operation A. Solld, Liquid extracted is iess soiubte or trapped i an insoiubie matre es

used a material to be
A device
when extractor D. Diferential
Soxhlet
extractor

Distillation appatatus B. Separating funnele. is ig

halogens, the presence of yelcw precipitate

trat
ngoiue
test tor
During sodium
fuSSion dne
3. Chlorine C. Bromine.
arimonia snows wichn
hàiogen element
A PIuorine intermoiecuiar torces, tne g h e r
the
Donpit it

A, The stronger the

which
Statemens correct? the boiling point. The wexer
the intermoietolàr ita
torces, thie lUwer
Strunger the interrnaierular
D. None of above
higher the boilingpoint
 IN e
Courae Code CM 102
type and
number of bonds TYPE A of Units
VG tp eY covalent n
Nia A Time
e and ouble electravalernt and dauble
Allowed- 70 min
nterh@lecular forces B
eiectrovalert
Instantaneous dipole inducedbetween
d fwo
polar iol

gait of uter zhell electrons which doesn I take part in bonding is ca lied (hlone p

ais 0, valence pairs

*.
congtont, tne relatlonship betwmen temperature and volume ls diretsjCtort
e
one of auave

6 One way 2o increase pressure on a gas is tc A, decrease temperature B, decre ase- vplume t

number ot gas particles D. lower the kinetic energy of the R3s

ne pressure of a gas is 0.987atm when its volumé is 400.0 mL. Calculate the pressure i
moecuie the gas alie wes

expand to 600 mL at a constant temperature A. 0.658 atmB. 1.48 atm C. 500 0a

of If the originai temperarure
Thevofune a gas is incheased from 150.0 L to 350.0 mL by heating it.
was5.0 oC, what willitsfinal temperature br(in oC)? A. 146 °C B. 10.7C C. 58.5 D.
A quantity of gas has a volume o f 2 5 0 0 liter a t 17,0 oC and 3.00 a t m a f p r e s s u r e . To w h a t volun e u

Ras be increased for the gas to be under STP conditlons? A. 78.4 L B 88.5L C. 706 wD. 771L
he intal pressure of a gas is 457 mmHg: th: final volume Is 750 mL with a finat pressure of 630 mme
the inital volume of
thegas? A.
2101 mt 8. 1500 mt C. 1067 mL D. 1010 m
s s u r e s caused byA. Gas molecule" heating up B. Gas molecules reacting with other E35 o e t t i
3 5molecuies
hitting the walls of a container D. Gas molecules hitting other gas molecules
Which one of the following best descrines th: properties of a solld? A. Fixed volume fived shape and no

oove B. Ng tNed volume, flixed shape anit not free to move C. Fixed volume, no dfinite shape t
and tree
iove D. o tixed vOiurme, no tixed shape ani tree to move

13.Th
14he
dCR
25 The nomenclature ot the tompound dHCHCCE is A. Pent-3-yn B. Pent-2-yné'C. 3-mehtyibut 1 y
methylbut 3-yne
3.Wh
26. The general tormula of haloalkanes is given . Cntza*A 5. CaHznX C. GaHn* 1X 0. CaH-
6.Guc

whic
Lacto 27
ucto
Selest tne correct
UPAC name for the
cmpoundCHCHCHCOCH A. 2-methyipentanone
rethyipetan-2-0he C. 4methyipentan-2-an D.2-methyipentan-1-one
19. The s
The accurate name for the compound given elow is:
CHC-CH:

CH3 A.
2-meth-1-butene B. 2-4 1hyl-1-prapene C. 2-ethyl-1-pentane
Tiethyi-2-butene
Select the correct luPAC hame
tor

gz A5-methyl-5-ethy liactane 8.
5-methyl--propyiheptane
ethvitg-metayoctane D. 3methyl-3-propyloctane
30. Conjugated oiene s mustrated by

e, e
aTond t y Value for
A B.2 C3D
 wwhat type, of
isomerism is shown in the two
ompound isted below,

H
A Positional isomerisn B. Structural
isomerisn C. Functional group
33. In the molecule Ci Be Ci isomerism D.
Metamerism
the
pairs and 3 n nber
of bond
pairs and lone
ione pairs B. 2 bond
paifs ànd b ine pairs of electrons are. A b
ONE pairs pairs C. 4 bond pairs and 12 lone palrs 0 3
bord
p3irs an

3 The correct
Lewis dot structure tor Cla molecile is.
A. =B
C C DC C
35 Twa
class of
hydrocarbons A and Y were treated wit'i bromine
water. X
compound does Y belong? decolorizes the solution a-d Y did nat
benzune B. alkynes C. alkenes A.
36 Which of the D. alkanes
folowing alcohols would be oxidized to
methyipropan-2-ol D. Butan-1-ol propan-2-one? A Ethanol B. Propan 2d
7.Ethanol regcts with
concentrated tetraoxosi
Ethanone iB. Ethene C. lphate (Vi) acid at a
temperature above
s The
Ethyne D. Ethanoi 170 "C to form

D. Butane
de-carboxylaton of ethanoic acid will produce carbon (iv) oxide and .A.
Methane B. Ethane C Pepn
39. An organic compound with a pleasant
smell
. RCOR
z
likely to have the
general formula A. RCHO B. RcOOH RCO01
40.
Complete
hydrogenation of ethyne yleldsA, Benzene B. Methane C.
The
type ot isomerism that Ethene D. Ethane
exists between n pentane and
C.Structural D. Geometric 2,2-dimethyipropane is A Pos.tionalt iursticna
42.The general formula C.Haa belongs
i and ii C. li and iw 9. , l and iv
to)alkanes (i) alkenes (üi) cycloalkanes(iv) cycloalkenes A 1du3
3 The type of isomerism that exists
Optical D. Tautomerism
between a molecule and its mirror image is A. Geome.nt B. Funcu1C
4 Vhich of these
isan alkyl halide A. CH,CH.3B CH,CH,Ci c. CHCH2CoOH D.
5. The conversion 'of ojen chafn alkanes into cycloalkanes and aromatics CH CH3CH
150merization compounds calied.. is
tritei, 5
6 Which of the
Reforming 0. Palymerization.
following acids is strongest: HI, HCI, HBr, HI? A HF B. HCI
The bond C. HBr D. HI
sigma In the C-c of ethyne is fornutd by the overlap of
A8 The fallow.ng are the features of the new hybrid orb.tals after A.s-sp B. sp-sp . sp-sp" Dp
hybridization, A They havegEqual
identipai ln shape C. They are 3 iymmetrically oriented in shapeexcept
. They are emtgY
form equal bond length and band D. Participate in themical tunil fto
n 3 mo.ecule ot
strength
etnene, an unbybridized hat-fillec
2p orbital in a tarbon atom cvelaps side-by sitte he s
tyid.ted, halt-t.lled 2p arbital In other
tatbon atom to give. A.
sigma bond bond npe t o i t
i
he crder Or
ircreasig acid ty of HEECH, H-CH, :C=CH is arranged as: A. HC-CH >ICati;
. HCECH <
BCacH HaC-CHj CH:CzCl;> HCECH> i
1. in overali imbiante HC-CH, D. H:C=CH; > H,C--CH, >
in
tnarze trom ore zite 0t a mclecule to
the other side is Called a
iGie ngmen . - p d a r Lowarent
bont C. Fesonante U cavalency
 . he equilibrium distance between the nuclei of the bonded atoms in a molecule is called

A, chemical equilibrium B. bond strength C. bond angle D. bond length

$3. Which of the following is false of hybridization in methane A. all the four hybrid orbitals are o
B. each of the hybrid orbital has 33% s-character and 67% p-character C. The axes of the hybrig

towards the corners ot atetrahedron D. sigma bonds involving the hybrid orbitals tarbon are p
thase involving unhybridized 2s or 2p orbitals
54. The sigma bond of theC-H in CHCH) results from the bonding of and.orbitals
A S and sp' 3. 5p and sp C. s and s D. sand p
$5. Consider CH;CHa. CHaCHa and CHCH, which of the compounds would have the shortëst C-C bond leng
A. CHCH; B. CHCH C. CHCH D. none, because they all have the same bond length
S6. In abenzene ring, the orbitals involved in bonding
B.
hýbrid two carbon atoms a r e . . .
and... A.
sp
p and sp C.
sp sp' 0. sp and p and
S7. Paulis's exclusion principle states that
A. degenerate orbitals are filled
gradually with electrons in parallel spin and no
pairing of electrons
all vacant orbitals have each
recelived an el::tron. B. degenerate orbitals are filled
occu u
parallel spin and pairingof electrons can ocrur before. all vacant gradually with elect rons
orbitals have each
C.an
ofbital may contain geceived an electron

ng more than two electrons both of which must be of opposite spins D. an orbital i
contain no more than two electrons both o: which
must be of similar spins
58.
The pka for compounds i, i, ill, and iv are 16, 26, 45 and 62,
respectively. Which of the compounds is
A.i C ifi B. fi D. lv mos: ac

59.The property which makes alcohol soluble in water is the A.

60. cooling B. wetting C. covalent nature D. bund
Which cf these occur asaresuit of
metal ions A.
electrostatic attraction between conduction electrôns and positively c
Electronfbonding Chemical bonding C. Metallic
B. 1ar
61 What is the shape of bonding D. Covalent bonding
this compound CH A Pentagonal B,
62. What is the shape of
the compound Boron trichioride A. Square
C. Decagonal D. Tetrahedral Hexagonal
Pentagona pianar B. Trigonal planar C.
5. Valence bond theory
Texagctna
uses -

topredict the shape of

Hybridization 0. Association the molecule Aonding B. Attraction
64 WHich of these have the
highest saturation A.
H;C=C=CH-CH-CH-CH; D. H;C=CH-CH=C=CH
H
H3C-CHa-CH2-CH2-CH2-CH B.
H2C=CH-CH-CH-CH: CH
Aromatic must
obey...ule with a whole raumber A.
5
Amino acids in
protein are
Boyle's B. Solomon's G. Hezekiah's D. Huckel's
joined by A. Pepsin linkage B. Carbon
rWhen protein contalns equal number of amino acid
a linkage C. Atom linkage D. Peptide linsag
Neutral D. Alkeline and carboxyl group, It is saidto be A, Basic B. A:rdic
ne poymers of
D 11ole cular bond
monosaccharides are bound together by A. Covalent bond B. Atomic bond
ttose C. Glycosicdc bor
is
a. 5ugar (a) Lactose (b) Ketose (c) Sucrose (d) Starcn
he D-gucose units in cellulose are joined
-1-2ycosidic linkäges D.
together by A.
a-1,2-glycosidic linkages.B. a-1.3-glycosidie
B-1,7-glycosicdic linkages l ska
 CHemisTRy $OLUTIONNS 200/2o2
RAN SEMESTER
YOmabi conpoundls Contams tn+2 pi elicboa S nsted. (A

2) C- Trio cotane

) D- Mtanal
B - 120

B
HO N
15 24-0 65

15 6t 0-65
SaagT 412 0 55
055 0 55

Ef CqHsN
{s)F(16X 3) +(ixp)] n =I83
(2x1)
CI83)n i83

N)
MF =1(cqH,0,
-GH,0, (6)
3) EF C4
CH2 1l2
12
1242) o =
4n-12

M (cu,)

H 16C)

Now, L t s oalanA.
 2H, + 10, Co +6 H0
C 6
C6 t 12

0 18

H,0 = 6
Co- & fhiet of

C
oCH Has Simbonds iri bo
nd (B)
- C

2-

3 C

A- Charle's law
moleeults
C-noease in number of gas
) PV Pa Va
O-154 4UD = PXoD

Pa 0:653 (A)

350
25
50T, 3 1 S o

7, 3160
50
7,-104C (B)
a V 50L 5ox 13 y
1: 170'C
10
3 V -0 L(C)

x
 V,8F 150X 650
51

Y l06tm-C)
a 3)

25
26

24
A

30
3 C
32 D
33
2 bond par ond 0 lou pair CNo msor
34 C
35 D-Mkanes
3B Ppan-2 -o
34) 8
35) A menwne
34 -RCOTR
AnanR

42
43
44 A
45
4 D
4
46 C
49
50 A
A
 52) D

54) B

5 )A ad Sp
67
53)A
6 D -Hydogen boding
6C
61DD
62) B
63 B
hs only
64) A A Satate tonfowd
-

on od n hs Cabon

65) D
)D

6s)C

ALL NATDMS BApTIST CHtuRCH (ABC)

ACE MT C UNTT

blacts O8131 25 0 4