r,}r flg'L QUUL UTA TTA NVT X'}- I TTI LtrINH THU (- Iil!

I'HUC IIQC PIIAI{

'rRuoNG E4.r Hec KHoA r-rec TUNHTEN Hec KV r, NAM Hec 2022 - 2023
TOn hgc phAn: H6a Dai cucrrg
M6 hgc phAn: CHE 1080
56 tin chi: 03 D6 sii: 01 (Ca 2)
Ddnh cho sinh viAn bp hoc phd.n: CHE|080 (nt6ru Hoa Eqi a.rong cho todn truCIxg DHKHTN)

Ciu 1 (1.0 tli6m). Hdy tinh sii luqng photon 6nh s6ng nlng lugng ln 2J. Bi6t bu6c s6ng
cAn thi5t d6 tao ra
cua iinh siing dE cho ld 4000Ao.
Ciu 2 (1.5 tli6m). H6y xdy dpg gi6n d6 MO (orbitan ph6n tu) vd vi6t c6u hinh electron cira ion phin tu
Oz-. Dqa vio giin AO UO cta Oz- hiy cho bltit tu tinh cira c6c ion phAn tu Oz, Oz-,Oz* vd cho bi6t phdn tu
hay ion ndo c6 dO dei h6n ktit ngin nh6t.
Ciu 3 (1.5 tli6m). Phan rmg d6t ch6y d6ng sunfua (CuS) bing oxi kh6ng khi duoc thgc hi€n nhu sau:
2CuS1.; + 3Oz1ry * 2CuO1.y + 2SOzttt
Bi6t Ai{"sn (kJ/mol) -93,1 0 -156,0
-296,8
S"(J/mol.K) 66,5 205,0 42,6 249,0
a) Hdy x6c dinh bi6n thi6n ndng lucrng t.u do chuAn AGo (kJ/mol) cria ph6n img 6 25oC?
b) Tinh biSn nQi ndng AU (kJ/mol) cria hC nhiet <IQng 6 25"C.
Ciu 4 (1.0 tli6m). pOi.voi phan img bic 1, 6 27o C,n6ng dQ ch6t tham gia phan img gi6m di mQt nta sau
5000 gi6y. Tai 37o C n6ng dQ giim di m6t nria sau 1000 gi6y.
a) Tinh hing s6 t6c d0 phin img 6 27o C.
b) Tinh thoi gian t10 n6ng tl6 chSt ph6n img gi6m xu6n g cdnYo.
c) Tinh n6ng lugng hoat h6a.
Ciu 5 (1,5 tli6rn). COzphAn ly o nhiQt d6 cao theo phin img:
2COz e) # 2CO 6y + Oz r) rlp su6t cAn bing cria hQ ld. I ahn
a) Tinh d0 phAn ly o cla COz o nhiet d9 2227"C bitit ring o niriQt dg ndy, khi phin fng d3t rr4ng rhrii
cAn bing thi 1,0L h6n hgp l,hindng0,2g.
b) Tinh Kp
Ciu 6 (2.0 di6m).
a) Tinh pH ctra dung dich axit fomic HCOOH O,2M co Ku:5.104.
b) Can tr6n bao nhi6u mL dung dich HCOOH 0,2 M vcri bao nhi6u mL dung dich HCOONa 0,3 N,I d6 thu
duoc 1 L dung dich c6 pH:4,2.
c) Trong qu6 trinh hi6n m6u, d0 ch6ng mriu bi ddng, nh6n vi6n y td s6 dung NazC zOq dd,ket rua ion Ca2*.
Nguoi ta b6 sung 100 mL NazCzO+ 0,155 M vAo 6ng nghiQm chira 104 mi mrlu v6i n6ng d6 Ca2* ld9,7x
I}-s glmL. Hdy chimg minh c6 t5t ma CaCzOqtao thdnh vi tirrh n6ng d0 Ca2* sau xn ly,1i6t tich sd tan
cuaCaCzOa id 1,3x10-8
CAu 7 (1.5 tli6m). MOt pin g6m 2 diQn cpc chudn 6 25'C. M6t di6n cuc ld Pt trong dung clicli Sn4*/Sn2*,
t"
di€n cgc t iift ntrirng trong dung dich Fe3*/Fe2'*. Bitit ring Eosn+*isnu*: 0,15V; Eop"s*,F"2* : AJ7 V
.: : ,: .
crlc.phuong trirrh nua phin img vd thi€t l$p so' d6-:
pin. ( t/+)
i'/q ?)Viet
ah Al finh suat diQn dong cua pin
ff A Neu n6ng d0 cira dung dich Sn4*: 0,01M; Sn2*: 0,1M; Fe3*:0,lM vd Fe2*: 0,00lM thi sric Ci€rr dgrrg
'l/
i
'/1 25"C cua pin t ndyJ binga bao nhi6u.
---- HET
Choi'i1,.:h:6,626x1(t34J.s; c:3xtdm/s;Ra:l09722cnt1.leV:1,602.10']eJ, lm':t(f run; R:8,i14.t'nol.Khaitc
A,082 L.at,fuol.K

E€ thi gdm Lli il.:rg. Cd:r bO coi rhi kl'ring giai';irich gi rh6m
 oAp AN ur cnixn rHrlc (ca2)
Ciu 1: 1,0 tli6m NEng lugng 1 photon: Epho,on : hCl),.: 6,634.10-34x3.108/(4000.10- t/
/2
'o):4,97 6.10-'nI
56 photon cin dri t4o ra2J ld: nptoto o:214,976.10-1e : 4,02.1018 h4t
%
Cf,u 2: 1,5 d Ao (o) Mo (of) AO (O+)

O1 o** fl;1-
Giin
{fr^ * do
-tj
fir-* +,+
TT-
.1rl rtl
- {*+ 1/2
fJrn
T t* t* ** t* t* +*
fh. -t*-
*+*-
-tf- {f." ^i
Lau
{r&* -fr rhl
*t*.- hinh e
{r:* T* -tf- "f** v,

Oz N:2, thu6n tu B0c

Oz*: N:2,5, thufln tu -) DO dii 1i6n t<i!t ngin nhAt lk, tt
Oz-: N: 1,5 ion phdn tu thufn tu tinh
U2
Ciu 3 a) AHroo : (2.AH.r, Cuoo * 2.AH.n, sozo) - (2.AH.q CuSo * 3.AHrr, ozo)
(1,5 tli6m) : -719,4(kJ/rrol) 114
ASo: XSl.pyo - IS6a;o : -166,8 (J/Ifunol) -{O/t U4
AGo : AHo -TAS. : -719,4 -298.(-166,8.10r) : -ltylog(kJ/mol)
,Z
AG < 0, phin img t.u diSn bi6n. i::,,\
b) AU : AH - An.R.T : -719,4 - (2-3).8,3 14.10'3.299: -Jt6,92 (kJ/rnol) U2
Ciu 4 0,693
: 0.693
: U4
kzzoc: 1,39. L0-a.s-1
(1,0 tli6m) ,r, **
0.693
k37oc : : 6,93.10-a.s-1
ffi U4
,' \ 2.3o3.too
a
nl $ w++
( :5\t l',,n: -z;tr:2ooo s
189'^,1=
\-i, 4i4 rn1
U4

t ) +E=L24kl ggtittt
6tre.:!.( '-
ksoo R \300 37O) -- - --t - U4

Cflu 5 2CO', ra * 2CO ttl + OzG)

(1,5 tli6m) Ban dAu 1

Ph6n img cx,

CAn bing 1- ct

T6ng s6 mol cria hQ <r tr4ng th6i cdn bing ld: In.b: l+al2 U4
.'1 , OA dri g6rn 01 trang. C6n b6 coi thi k.h6ng girii thich gi th6m
 ,4
V: nRTIP : ('l+a/2).0,082.(2227+273)/l:205 + 102,5a (L)

O tr4ng thii cl,nbang thi 1,0L h5n hgp khi ndng0,2g) VQy khOi luo.ng
ctra hdn hqp khi 6 k4ng th6i cfln bdng li: QA5 + 102,5a).0,2g r/4

Theo dfnh ludt b6o toin kh6i luong ta c6

(205 + 102,5a).0,2 g : 1 mol (CO2)x 449: 44 > a:0,146 t/4

Pcoz: (l-a)l(l+al2)
U4
Pco: a/(l+al2)

Poz: al2l(l+al2)

Kp : cr2.(cr l2)l(I-o.)2.(I+al2) ) Kp : 2,0.10-3 U4

Ciu 6 (2 tli6m) I a) Dung dich eIffOOH

It. ttcooH e HCoo- + H*
Ban d6u (M): 0,2 0 0
Phnn img (M): -x x x
Cdn bing (M): 0,2 -x x x 1t4

M{t kh6c: K": x2110,2-x) : 5. 04 ; |

Vay x:9,"15.10r (M).
1
I tr+

Y,4-v:-BE : -JqeE[t-qs€J5J0:) : 2.01.

b) Gqi th6 tich dung dich HCOOH 0,2Mcin: x (L);

U4
Gqi th6 tich dung dich HCOONa 0,3 M cAn: y (L);
)x+y:l(L) (1)
M{t kh6c v6'i dung dich dQm: U4

- U?:
Ly
3,3 - b' !Y't
flbaz,
: 3,3 - lno''*
O3r=
4'2

)L:0,189
v
(2)
U4
Tn (1) vd (2) ) x: 0,159 (L) : 159 mL
y:0,841 (L):841 mL

c) T CaCzOq: t,3 x10-8. U4

Ca2* + CzOq2-)CaCzOt
- lCzO+2-): 7,6 l0'2 lCa'*l: 1,236 l0-3 l./
,/4
- Tich s5 n6ng d0 [Ca]1.[CzOi-] :9,4 xl1-s > T(CaCzO+) : 1,3 x10-8
Vfy kdt tua dugc hinh thenh
- D0 tan cta CaCzOq: [T(CaCzO+))1t2: l,ltxl}a
Vdy [Ca2*] sau xt li: 1,23610-3 - 1,14x10a: l,l2xl0-3 1./4

Cf;u 7
a) Catot: Fe3* +le) Fe2* r/4
Anot: Sn2* - 2e ) Sna*
(1,5 tli6m)
C) PtlSn2+, Sn4+llFe3-, Fe2+lPt (+) t/4
OA tfri gOm 01 trang. C6n b0 coi &i kh6ng gi6.i thich gi th6m
 :0,77 + 0,059/1 x 1g (0,1/0,0011:0)9.V ATYYY V
I I c) Er'"3*rF"z* I I

| tn
Es,,4*/sn2*:0,15 + 0,05g/2x lg (0,01/0,1):0gQV 01rtU.5 t/
I I I

I lE:Er"r*m.z*-Es"+vs,z*:0,79-0,09:0,7v 0;-6trr,2 | |

OA *ri gdm 0l trang. Crin b0 coi thi kl16ng giai thich gi th6rn
l.u
 r-,,4\r rl\JU VUL/\- \rrA I-141\Vr Dft, lru UtlINtI lttuU KE'f"f'HUC HOC KY 1
TRUONG DAI HQC KHOA HQC TT/ NHIEN NAM HQC 2019 - 2O2O

M6n thi: H6a D4i cuong

Ldp m6n hgc: CIIE 1080 56 tin chi: 03
Ddnh cho sinhviAn bp mdn hgc: CHE1080 (hoc phdn Hda Eai cuong,
lradng DHKHTN)
Thdi gian ldm bdi: 90 nhfi (Khdng k€ thdi gian phdr di)

Ciu I il.O di€m\. Nang lugng ion h6a ld ndng lugng cAn thitit AO Uut electron ra khoi nguy6n tir o
trang thrii khi. Ndng lucr,ng ion h6a 1 electron tir tr4ng th6i co b6.n cria 1 mol nguy6n tO hOa hqc X ld
4,729 x 104 k/mol. Hdy x5c nguyOn t6 hOa hqc X?
Civ 2 0,5 di€m). Hdy xdy dpg gidn do MO (orbitan phan tu) vd vitit c6u hinh electron cria ion phdn
tt CN-. Dua viro gian d6 MO cria CN- hay cho bi6t tt tinh cria c6c ion phdn tri CN-, CN, CN* vd cho
bitit ch6t ndo ben nh6t.
Ciu3 (2,0 diAm.\. Axit xianua (HCN) dugc sin xu6t trong c6ng nghiQp theo phucrng trinh sau :

ffi'"o' + -'il:d
(kh, 3oz tr'r'D ---) 2H{N .*'o u51?:,6*' + +
Bi6t AHo,i,n nr,ret (kJ/mor)
S"(J/mol.K) 240,0 193,0 205,0 2OI,g 70,0
a) Hdy x6c dinh bi0n thi6n ndng lugng t.u do chu6n AGo (kJ/mol) cria phan r?ng b 25oC?
b) Tinh bitin nQi ndng AU (kJ/mol) cira h9 nhiet dQng o 25oC.
Ciu 4 0,0 di€m\. Sulfuryl chloride ph6n hriy theo phuong trinh dQng hqc b4c I o 320oC c6 thdi ban
ban htry (tYr) liL 8,75 gio. Phan fng: SozClz (kh0 Soz rpo + Clztr.r,o. N6u 6p su6t ban dAu cta
SOCIz la 1,05 at vd phan img xiy ra trong binh kin----)
dung tich 1,25 L. HEy cho bi6t hing sO tOc dQ phan
tmg k li bao nhi6u? C6 bao nhi6u phdn tu SOCIz cdn lai trong binh phdn img sau 12,5 gid?
Ci 5 fi,0 di€d. A 25oC hing sO Ko:2,9 x 10'3 cho phucrng trinh phan fmg sau:
NH4OCONHz(.in) * 2NHsGhq + COzfr,r,O
Ngucri ta d(t mQt lugng nh5t dinh NH4OCONH, t grrg binh kin chdn kh6n g b 25oC vd dgi cho den khi
hQ dat trang th6i cdn bdng? HEy cho bi6t tdng 6p su6t cua hQ ld bao nhi6u oir4rg thdi cdn bdng?
Ci! 6 Q,0 lieml. a) HEy x6c dinh pH cria dung dfch axit p-ropanoic CzHsCOOH c6 ndng dO 0,20 M d
2SoCbi€thang sO diQn ly Ku cta u*it prop*oic la 1,3 x l0:5.
b)TinhpHctradungdichmu6iKNo20,T5Mb25oc,uiethangsodignliKnNoz:4,0x 10a.
c) Hdy tinh thc tich dung dfch HNO2 O,2sMvd th6 tich dung aicn NaNO, O,Svt .Ar, itirit troo vdo nhau
thu dugc 1,0 I, dung dich dQm c6 pH = 3,875 6 zsoc,biet hing so dign liKnNoz : 4,0 x 10J.
Qiu T 0,5 di,€mt -IvIOt pin diQn h6a dugc xdy dlmg tir 2 ntra pho*g trinh phan img oxi h6alkht c6 th6
diQn cgc chu6n (go) tucrng img:
Zn2+loungolctr; + 2e --. Znv Oin) goganzry : - 0,76Y

a) Hiy virit phucms,,t3ll#lTidlt*i,3i,e,,lu fi#h *,,, uu3,$"fr'/;,,1;?i "

b) Tinh sric diQn dQng Af vn hAnS ;6 c6n bdng K phucrng trinh h6a hgc cria pin tdm viQc d 25oC.
c) O 25"C ntiu n6ng d0 ban dAu [Zn2*]p: 0,010 M vd n6ng d0 ban dAu [H*]e: 2,5 M,6p su6t ddng khf
n'1-::-11-i:.-:3i:.:11:.li::11111i:l-:::::.:!?':3::*:i:1..
Cdchiingsii:h:6,626.10t0J.s; c.=3,0.1dm/s;R:B,3l4J/mol.KhoficR=0,082L.at/mol.K;
F : 96500 C/mol; t m : td run; I eV = 1,602.17'teJ Sti avogadr:o Ne: 6,023.1023
1
z
H H€
101 2 13 l4 15 16 1'' a.oo
3 4 5 6 , a I

6,S4
Li E€ B
10.4,
c
t2-o1
N
,t.o1 r
o
6.oo
F =-
Ne
tl 12 13 15 ri 17 18
hIa Mg AI Si P S cl Ar
22.fi 2a-m 34567e9101r12 2G-gS 32.06 F+ 3S.35
l9 2n 21 ?2 21 24 25 2a 27 4 20 rc 3l a s 3 35 3t
K Ca Sc TI Cr Mn Fa Co Ni Cu Zn Ga Ge As Se Br Kr
39. ro a7.gt SUrg 5?-OO 5a.g 55.45 ss.t3 s-& 4e.72 n.u 71 92 7a 9C
37 $ 39 40 11 42 i€ 46 at 49 ao 5l a9 a
Rb Sr Zr Nb Mo Tc RU Rh Pd Ag cd ln Sn Sb Te I XB
45.47 87-42 tg-91 e2_gl E-96 10 t-o, 10zrl oa4 107 -t,7 14.82 118_47 f ?t -7t 1T _da ula
55 5C
57-
7Z 73 ta n fr 70 & 81 & E & 85 s
Cs Ba Hf Ta R6 Os lr Pt Au Hg TI Pb Bi Po Rn
1Q,el 174.4t 207 2 tr
Od ttri gdm 0l trang. C6n bO coi thi khdng gidi thich gi th6m
 oAr Ax or sO r
CAU Chuy6n dich electron tir trang thai c
1: :
Trang th6i co bdn: Er -2,18.10-tB 1Z2ln21 0,5
1,0 d :
Trqng th6i ion h6a Eco - 2,18.10-'r tZ'/*')
N[ng lugng ion h6a 1 ion: LF.: 4J26 x 104 kJ/mol16.0231023 mol An*: 7,g4gg,10-r7 J
:
AE : Eoo - El o + 2,19.10-18 (Zzn\ J 7,g499.10-17 J
'
:
:
Z2:31,99, Z 6 (A ld nguy6n tu Cacbon) 0,5
Cdu Gian d6 MO cria CN-
a.
Z. Ao (c) Mo (cN) Ao (N)
1,5 d
alp {< tily
ff1,, 1,0 l,7S

0lp +l
tv
E e{rl lhl
trlp +
tv tv
,tt
ofu* -t+-
I

a3r -f+
CN' N: 3, Nghich tu ) D0 ddi li6n k6t ngin nfr6t
CN: N : 2,5,ion phdn tu thu{n tir
CN*: N :2,0 ionphdn tir thuQn tir
0,5
Cdu a) AHo : l2xl35,I + 6x(-286) l- lzx o,t
3: ASo :
12x201,8 + 6x7Ol - 12x240 +2x193 +2x01 : I
0,5
2,0 d AGo = AH -TA S: -1203,8 -298K x(-42,4x10-3) kJ/mol.K
: -1203,8 -12,6352: 0,5
b) Bi6n thi6n nQi ndng AUo : AH -AnRT; Bi6n thion s6 mol: Ln:2 -2-2 -3;$
t/9 &" n{L
AUo:AHo_AnRT:.l2o3,8kJ/mol_(5)x298Kx8,314J/mo1.Kx10-3=re 0,5
C6u Phan img: SOzClz --+ SOz (1.1,0 11.1,O
+ Clz tnrO
4: Phucrng trinh dQng hqc b?c 1: k: ln2l\o: 0,25
1,0 d Phucrng trinh bflc 1: ln Po/Pt: kt
: (1.2,518,75)xln2 : 0,9902; (1,051pt) :2,692 -> pt = 0,39 atm
ln 1,05/?t 0,50
Ap su6t SOCIz sau 12,5 gid ld Pt : 0,39 atm. 56 ph6n tri SOCIz ld:
n: PV/RT: 0,39 at.l,25 L/0,082 L.atlmol.L: 0,01 mol. I
Sd phan tu SOCI2 : 0,01 x 6.023 x1023 : 6,023.1021 ph6n tfr SOCI2. 0,25
Cdu Phucrng trinh phan img: NHaOCONH2 (rin; * 2NHs (khD + COr g.hi)
5: Ban dAu: (a)
1,0 d Phan ung -P 0,25
Cen beng a-P 0,50
H6,'gs6c6nbangKp:Pmr2.Pcg2:(2P)2.P:4P31,9xl0-3)m 0,25

Od tH g6m 0l tang. C6n bO coi thi khOng giai thich gr th€m G ,, ..^; t4L
 a) Dung dfch axit you
Cdu

6:2 ETCOOH ---+ H* + ETCOO-

d
Ban dAu (M): 0,2 0 0

Phan img (M): xxx

Can bang (M): 0,2-x x x
Ka : x2l1o,2o-x1: x2110,25 x 1,3.10's) x=lr6l2x10-3
0,5
b) KNOz --- K* + NOz-

NO2- + H2O ++ HNOz + HO- KnNoz :4,0)0'4

Ban dAu (M) 0,75 00
Phanrmg(M) x ) x x
Cen b5ng @) 0,75 -x x x
HA"g s6 cdnb6ng: Kuoz- :x2l(0,75-x): Ks26A(s1,1ez: l0-r414,0x10a :2,5J0-rl
x:4,33 x 10'6;
c) Ggi sO tfr0 tich HNOz th6m vdo ld Vl: 0,5
Gqi s(5 tne tich NaNOz th6m vdo ldy2:
pH : pKu + log [NaNO2]/[HNO2] : -log(4,0.10'4; + lg (0,5y2)l(0,25v1) :3,g75
lg2Y2Nl = 3,875
= 3,398 + 0,5
lg2Y2Nl=0,477 )2V2Nl =3,00 )2Y2:3 Vl vdY2+V1 = I L

0,5
C6u a. Phucrng trinh ldm vi6c cta prnz Zn6y+ 2lftool *, Zo*f*l + tlzt*l
7: Anot: Zn/ Zn2* ; Cathod: Pt(H) I 2H*
1,5 d AEopin : go12L{tH2) - go(Znz*lZn) : 0,00 - (-0,76): 0,76 (v)
AEopin : (0,05912)lgK : 0,76 )K = 5,79 x102s
m 0,5

0r5
c) Ap dpng phucmg trinh Nerst (n:2) I
AEpin : AEopin - e,05912)lg 1z**1. pl2tlr{12 : ,,'rk- e,osg/z) lg (0,01x0,3y2,t\
0r5

O6 thi gdm 01 trang. C6n bO coi thi kh6ng gi6i thich gl thOm
I
 DAI HQC QUOC GIA HA N9I EB THI CHINH THUC KET THUC HOC KY 1
TRTJONG DAr HQC KHOA HQC TUNHTEN NAM HQC 2Ot7 - 2Ot8

Mon thi: H6a Dai cuo'ng

L6'p mOn hgc: CHE 1080 S6 tin chi: 03
Dimh cho sinh viAn l6p mon hoc: CHE|080 (hpc phdn H6a Dqi cuong cho todn tnrdng DHKHTN)
Thdi gian tdm bdi: 90 plttit (Kh6ng kA thdi qian phdt di)

CAu 1 (1.0 tli6m). N[ng lugng ion h6a ld ning lugng cAn thi6t loai b6 electron d6 chuyCn 1 mol nguy€n til
0 trang th6i khf thdnh i
moi ion ngr.ry6n til o tr4ng th6i khi. Tinh ndng lu_ong ion h6a cria nguy6n til H
(theo don vi kJ/mol, cho bi6t: I eV: 1,6 x 10-re J, 1 m: 10e nm).
Ciu 2 (1.5 tli6m). Hdy x0y dgng giin aO tvtO (orbitan phdn trl) vd vi6t c6u hinh electron c[ra ion ph6n tti'
O2*. Dua vdo giAn AO HAO cfia 02* hdy cho biet tt tinh ctra c6c ion phdn tri Oz, Oz-, Oz* vdr cho bi6t ion
ndo c6 d9 ddi li0n k€t ngin nh6t.
Cf,u 3 (2.0 tli6m). Cho phAn ting oxi h6a - khr}sau:
+ ---, 2 Nz tr.i + COz tr.l + 3 H2O
Bi6t AHo,in. nL;61(kJ/mol) T:il't" Tx3]d' 0 - 393,5 -296,0
19

S"(J/mol.K) 166,0 178,0 192,0 274,0 70,0

Hdy xdc dinh AGo (kJ/mol) cria phin 0'ng o' 25oC vitcho bitit chiAu hu6ng phin ['ng o nhiQt d0 ndy?
Ciu 4 (1,0 tli6m). PhAn ring ph6n hriy H2O2 thdnh HzO vd 02 b 20oC ld phin rlng bdc I c6 hing s6 t6c d0
criaphAn r1ng ld k: 1,8.10-ss-r. Tinh tho'i gian b6n hfiy (t y) crtaphAn rlng phdn huy tr6n. N6u ndng do ban
dAu cria HzOz Ih 0,30 M thi h6i sau bao ldu s€ ph6n hriy nltgOy" HzOz ban clAu?
Cffu 5 (1.0 tliOm). Metan (CH+) vd hidro sunfua (HzS) phin ri'ng v6i nhau:
CH+ trl + 2 H2S (k) +
+ 4 Hz tr.t CSz rr.t
Khi h9 phAn ring dpt trang th6i c6n bing o 727oc,6p suAt ri6ng phAn cria CH+ la 0,20 atm; H2S ld" 0,25
atm; CS2 ie 0,52 atm: H2 ia 0, i 0 aim. iinh xo ud -K" cua phdn r1ng o nhiet d6 tr6n.
Cflu 6 (2,0 di6m). a) Metylamin (CH:NH2) tan trong nudc hinh thdnh ion CH:NH3* vd OH-. Tinh n6ng dQ
CH:NH:+ vd pH cria dung dich CH3NHz 0,50 M d 25oC, cho biiit K*I,NH, :4,38 x10-a.
b) :
Jinh q$ cfia dung dich mu5i tan NaCN 0,25 M d 25oC, cho bi6t hing s6 dien li KHCN 6,2x 10-10.
c)TinhthetichHNO20,60Mvdth€tichNaNO20,45 McdnthiCtdetr6nvhonhauthuduoc l,0Ldung
dich dem c6 pll : 3,574 6 25oC, bi6t hing sO Oign li KnNo, : 4,0 xl0-4.
C0u 7 (1,5 tli6m). MQt pin di6n h6a dugc xdy dpg tir 2 ntaphuong trinh phin ring oxi h6alkh& c6 thtl
diQn cr,rc chuAn Gi hieu th6 dien cuc chuAn li qo hodc f) tuong ring:
'c;r- ;;-;-A; ir
+0,34 v =- l'oCc'.'*/Gc )
e"i .*r -):
Fe2* *2e ---+ Fe <p'1Fe2YFe; :-0,44y.
a) Hdy vi6t phuo-ng trinh lhm viQc cria pin diQn h6a tr6n vir chi ra ddu li catot vd anot?
b) Tinh AGo (theo J/mol) vd hing sd c6n bing K cta phin rlng diQn h6a tr6n b 25oC.
Q A 25"C n6u n6ng dQ [Cu2*] : 0,30 M thi cAn nOng Aq [F"'*] li bao nhi€u d0 sri'c diQn dQng cira pin (AE)
dat duoc 1,03 V.

Cdc
1
,to,: ;;;;;,--;:;;,;-;;;:;1",T,;;;;;';,;,;;;;';;;;;;;,;--;;;ii,,*,
lt:6,626x l0'" J.s; c:3x l7E m/s;R:8,314J/mo\.K,0,082 L.at/mol.K; F:96500
z
H H,e
i.!1 2 13 14 -r5 16 i? +.aE
? 5 a e E ia'
Li
E.g4
B€
10s1
B
i 2.s:
N o
1e.+a
F
19.4D
NE
i3
2C_
11 12 :.e
ft'19
2i.3i 3 .1 5 4 7 g 1a
Si P S CI Ar
22.95 I 11 1.2 ?s.s9 3C.3i 3?,LlE 3 5.45 3E.EE
:e z! 21 27 25 z6 27 29 ]a 3_r 35 3a
-1i
K Sc Ti Mn Fe Ni Cu Za Ge nqs S6 Br Kr
3E.iC 49.Ca i4.i6 4;_87 5g.s 5Z.tC 3a.s 55.35 34.S3 59. eP o3 5a E5.33 aE 72 72.E1 ?4.9t 73.S6 73 Sa s3.a€
37 39 3E 42 43 da €E 49 45 :"f 5'i 53
Rb
43.4i
Sr
g:.82 !e..9, Br.2!
ti!b L,ls T: Ru Rh Pd Ag UO l:n Sn Sb Te I Xe
92.*1 9e.gE 1Ua.e? 1!2-SJ 1"f,E.t? 1e7.ef ! {.aa I 1€. ?: I 2:.7e 1?.e2 :46.9S :31..?i
,l

5e g.a 72 73 :E ?E :,1 a2 B3 84 e5 +a
57-
CS 3a Hf T,a RE oL lr Pt AU Hg TI Pb 8i F-o ftn
r;€.<9 reo.Ea 1S 8C 1 3D.23 46.3e 19E.gt zE!.5! zra 33 )37 Z :aa.3e
./r. " OC tfri gOm 01 trang. C6n b0 coi thi kh6ng gidi thich gi th6m
 nAp AN Bn so I
Cflu 1: I di6m E6 ion h6a 1 nguy6n ttr H o trpng th6i khf ta 6p dung c6ng thri'c:
I"i{s} '*, t{ ''ig) * e* l/
/2
AE : Ez-Er : RH (llnzz - llntz), rlt : l, oz: co LE:2.18 x 10-18 J
Ion h6a I rnol khi H cAn ndng luo-ng ld:

te =(2,18x10-r8 J )(u,orrr19z:
n8uYen tu'')
= ,.,3014r10u J l/
/2
( nguyen tu r( mol ) mol
Cdu 2: 1,5 tI GiAn d6 MO cfia Oz
Ao (o) l,to (oz*) Ao (o+)

Op 'il*+ 'Cl.r

1,0
ii r,,
a'
-r "t-
t. .i .+
T-
.it .i.t
+r
TT'T
.i

ff)., ..t I rr. I +! .+t

1Tr T,1 l.f t,* t+ t.,
{Y+
a^
.+.t
t1l.
*Tr
+l .+r
-Tr
{:n} rF ,+,
I*
I
:TT
+l *Tf*
+t
.tI
r'fui t*' 1r
"+,1
t. &r

Oz N:2, thudn ti'

O2+: \:2,5, thudn tri -) Dg ddi li6n k6t ngin nh6t 0,5

Oz-: N: 1,5 ion phAn tt thudn tir

Ciu 3 AHo: - 1263,5 kJ/mol 0,5
(2,0 tli6m) ASo: + 464 Jimol.K : + 0,464 ki/mol U,J
AG : AH -TA S : -l'263,5kJ - 298K x0,464 kJ/mol.K
: -1263,5 - 1.38,272: -1401,77 kJ/mol o5
AG < 0; Tg diSn bi6n. 0,5
Cflu 4 a) H2O2 HzO + Yz Oz
-
(1,0 tli6m) Thdi gian b6n hriy ph6n fng bdc 1:
tn: ln2lk: 38508,17 s (- 38500 s hay 10,7 h).
Khi 90% H2O2 bi ph6n hiry h6t, tric ld cdn t)yoH2O2 chua ph6n hriy. Do vdy %
ta c6 ndng d0 HzOz cdn lai ld:
{Hrill& (*-,i.i}} ({'}-]I{} }vI}
I,t",lrfi:&F *"I(', [,I - i)-t* Y4

Thd'i gian dC ph6n hfiy htit g}YoHzOztd:

,--f :iu,n.,rr--f I i
'- -t rx.x rE::_,t x,ljt x,*--.J[-l-]c] - l-l ]{ It}"r[J*h] t/
/2

Ciu 5 Metan (CH+) vi

hidro sunfua (HzS) ph6n ring vdi nhau:
(1,0 {Ii6m) CHcrro + 2 HzS (k) + CSzrrl + 4 Hzrrl
Can biing: 0,s>' 0,10 '
0,26 0,25
Hdng s6 cdn blng Kp:
{Fr+"}tl'rrf
X_
f = {pcHj{prra#

OC ttrl gOm 0l trang. C6n bO coi thi kh6ng gi6i thich gi th6m
 II'r:.-JIIir,J{ i(}.::lit}.lt}lr
'" [,nrrr.]iI'ir,s.]' [*.]'31[t"]-1;]'r
1/
/2

Tfnh Kc: Ap dgng c6ng thri'c: Ko: f".(Rf;^" v6'iR: 0,082; f : 1000 K,
Ln- (1+4)-(1+21:2
t'
rra
t'a+
"d j-]l
[ ,r:

Tlru duoc: IQ= 6,246x l0-7

%
a) Dung dich CHTNHz
C0u 6
CH3NH2 + H2O -+ CH3NH3* + OH-
(2 tliem) Ban diu (M): 0,5 0 0
PhAn ring (M): x x x
CAn b6ng (M): 0,5 - x x x
Do hing sO Ka kh6lon n6n phAi gi6i phuong trinh bAc 2:
2

K,=-,-t
" (0,5 - x),=4.38x10-a
Gi6i phuong trinh bQc 2 duoc x: 0,01458 ) [OH-] : [CH3NH3+] :
0,01458M
pOH: :1,84,pIJ: 12,16. 0,5

b) NaCN --, Na* + CN-

CN- + H2O € HCN + OH- KscN :6,210-10

Ban dAu (M) 0,25, 0
Phnn&ng(M) x ) x x
CAn bing (M) 0,25 -x x x

L;v=wriy_n?!
K.^,_ = ,=!=' -= +]1= _ lo_ :- = l,6l.10-5
LCfr- j (0,25 - x) Krrr, 6,2.i0-'u^
0,5
---+ x : 2,OJO-3 :> pOH :2,69 :> pH : llr30

c) NaNOz ---+ NOz- + Na+

HNO2*NOz-+Ff
Gqi thC tich NaNOz ld Vl, s5 mol NaNOz: 0,45V1
Ggi th€ tich HNOz ldY2, sti mol HNOz:0,60 V2
Vrurpu:1 L:V1 +V2
---' Sau PU: IHNOz] :0,60Y217 (M)
[NaNO2]:0,45V1/l (M)
Dung dich sau PU'le dung dich dQm cria axit y6u vd mu6i
pH: pKu + log [NaNO2]/[HNO2] : -log(4,0.10-4; + lg 0,45V1/0,60y2:
3,574
: 3,398 + lg 0,45V110,60Y2:3,574
lg 0,45V1/0,60V23 : 0,176
0,45Y1/0,60Y2 : 1,5 t Vl :2Y2 0,5
Vdy cAn th6m: Vl + V2 : l;3Y2: l,Y2: ll3;yl:213

OA ttri gdm 01 trang. C6n bQ coi thi kh6ng gi6i thich gi them
 EAI HOC QUOC GIA HA NQI EE THI CIIii{H THUC KET THUC HOC XY T
TRUoNG EAr Hec KHoA Hec rU NurpN NAu Hec 201 s - 201s
M6n thi: Hoa Epi cuong
Lop m6n hqc: CHE 1080 56 tin chi: 03
Ddnh cho sinh vi€n ldp m6n hpc; CHE|080 ftpc phdn H6a Dqi cuong, Tradng DHKHTN)
Thdi gian ldm bdi: 90 phrtt Khdng k€ thdi gian phdr di't

Ciu I tt H d trqng th6i kich thich ph6t x4 5nh sring c6 bu6c song 1282,4 nm
0,0 di€d. Mqt nguy6n
.i . .l ,
d6 tro mric nang lugng c6 n:3. H6i s6 lugng tri chinh (n) cua mric ndng lugng kich thich ban dAu
vC

tr6nnguy6ntirHlibaonhi6u (chobi€t: I eV:1,602x lT'te J, I m: ITe nm:1010 A).

Cdu 2 (1,5 di€m\. HEy x6y dpg gian d6 MO (orbitan phdn tu) vd vitlt c6u hinh electron cria ion phdn
tt C0*. Dpa viro gian dO MO cria CO* hay cho bi6t tt tinh cira c6c ion phdn hi CO-, CO, CO* vd cho
bitit ch6t nio b6n nh6t.
Ciu 3 Q,0 diAnqt Acrylonitrile li monome d6 san xu6t sgi polime acrylonitrile duoc di6u ch6 nhu sau:
+ (khD +
3oz o'r'0 ---) 2crHsN u*?,6*, .*o +
Bi6t AHo,inrr nnet (kJ/m"r) 1:',f"-t' llfd
So(J/mol.K) 266,9 205,0 723,0 193,0 189,0
a)
Hdy x6c dinh bi0n thi6n n6ng luqng tU do chuAn AGo (kJ/mol) cira phan ung b 25oC?
b)
Tfnh bi6n thi6n n5ng iugng tu do cua phan trng tpo thdnh 7,95 garnsdn phim CrHrN 6 25oC.
Ciu 4 (1,0 di€mt Phin img phgn htry CIOzF thanh CIOF vd O ld phin img b.4c 1 c6 nang lucrng hoat
:
h6a Liu 186 kJ/mol, h6ng s6 t6c d0 cria ph6n tmg o 322'C ld 6,76.10-o s''. H6i o ffiCt d0 nao thi k:
phdn img sE c6 hing sO tOc d6 & : 3,00.10t2 s-1?
Cnu 5 0,0 diAil. Ch? 10,0 gam Sbcls vdo binh kin dung tich 5,00 lit d 448"C vd dqi dtin khi hQ phin
img h6a hqc d?t c6n b[ng 6 448oC c6 K. : 2,51x 10-2:
Sbcls (r<rr0 SbCl3 (khD + CIz tm,O
=:
Hoi c6 bao nhi6u gam SbCl5 c6 trong binh phan rmg khi hQ dat trqng th6i cdn bing.
Cl'u 6 (2,4di€m\. a) DQ diQn ly (a, %o) cria axit ld ph0n tr[m nitng dQ axit da bi phan ly. DO diQn ly cria
m6t axit y6u HA 0,25 M b 25oC lir o : 3,0 o . Hay cho bi6t pH ciia dung dich axit tr6n vd tring sO Aign
ly K" cira I{A.
b) Tinh pH cira dung dich mu6i NHaNOs 0,20 M d 25oC, bi6t hing sO Aien li KNu: : 1,8 x 10-s.
c) Hdy xric dinh ktrOi luqng natri hidroxit (NaOH) cAn thi6t cho vdo 1,00 lit dung dlch axit benzoic
(C6HsCOOH) 0,50 M d0 thu dugc h6n hgrp dQm gOm axit benzoic vd mu6i benzoit (C6H5COOH vd
C6H5COONa) c6 pH: 4,795 6 25oC, bi6t KcoHscooH : 6,4 xl}-s, gin thi6t th6 tich hSnhqrp kh6ng d6i.
Cdtt T (1,5 di€mt MQt pin diQn h6a dugc xdy dpg tu 2 niia phucrng trinh phin img oxi h6alkht c6 th6
di6n cuc chuAn (po) tuong img:
Mn2* + ze * Mno q'1Mrf*lly'rn): - 1,1g v
cd2* + 2e --- cdo ,p"icdz*lcd) : - 0,40 v.
a) Hdy viOt phuong trinh ldm viQc cira pin diQn h6a tr0n vlr chi ra ddu ld catot vd anot?
b) Tinh sric diQn dOng Ad va hing s6 cdn bdng K phucrng trinh h6a hoc ctia pin ldm viQc 6 25oC.
c) O 25"C n6u n6ng dQ ban d6u [Mn2*lo : 0,09 Vf va n6ng dg ban dAu [Cd'*lo : 0,06 M thi sric diQn
a': @
::: -13_1l yl
dQng cri
! :::- 11 :: -Y: ""* 1_: -:l: -'-i-'# try
- ? 1 1
Cdchiingsii: h=6,626x lT3t J.s; c= 3xld m/s; R:8,314J/mol.K,0,082L.at/mol.K; F:96500C/mol; t m: td nm
1 2
H He
r91 2 13 14 t5 16 17 {_oo
3 4 5 G 7 a s !o
Li
o-g
Be B
10.t1
c
lz_o1
N
!{,o
o
rc.oo
F
13-6
Ne
1 20.1 A
,1 12 16 17 t8
Na Mg AI S; P S ct Ar
2.99 24-30 345e7A910,1112 2GJA 2A-oe 30-c7 32.04
re 20 z7 23 24 25 25 ZE 29 3€ 3r 32 3{ 35 36
K Ti
s-s Cr
Ca Sc Mn F6 Co Ni Cu Zn Ga Gs AS S6 Br Kr
39-10 ao-B 47.47 5A.C3 S,E 6-55 85.* 4e.72 D,U 7494 74.96
3T g 39 40 a1 42 € a{ 45 46 4 49 ,o 5l s s
Rb Sr Zr Nb Mo f_c RU Rh Pd Ag cd ln Sn sb Te I Xe
45.47 c7-62 84-9! e1.22 92-91 95-96 10r.o7 107.87 71L.l 14.82 114"21 12r.76 1V-@ r2!-gc
55 s 57-
72 73 7a 75 76 77 n 7g m af E4 s aa
Cs Ba Hf Ta Rr Os lr
132,81 r37-33
71
176.49 iao.ea 1A3-8{ 1az2 t95-O: 194.e7
Pt Au
&.9 &t2
Hg TI Pb Bi
&a.gg
Po
tt Rn
F)A thi oA- O1 trano C4n hA cni thi lzhAnc oi,ii thinl' ai thA*
 U;
ur ''
oAp Ax oB sO r
Ciu 1:1tli6m Chuy6n dich electron tir trang thrii cu6i vd trang th6i dAu:
AE=Ez-Er:Ru(1/32-1ln12), n1 : ffi 0,5

Trang thdi ban diu h'='5 0,5

Ciu 2: tr,5 it Gi6n d6 MO cua CO
Ao (o) MO (O2+) AO (O+)
c0+
r-'l :k
"2-p
7,25
,arr*

Dro-l-
E
Jzp J+ -+ts

CO N:3, Nghfch tu ) D0 ddi 1i6n tet ngan nh6t

CO*: N :2,5, ion phAn ttr thufn til
0,25
CO-: N:2,5 ion phdn tir thufn tu
Ciu 3 a) AHo : 6x(-242))- 12x20,4 + 2x(aQl: - 103r,6 kJ/mol
12x780,6 + 0,5
(2,0 di6m) ASo: [2x123 + 6x189) -12x266,9 +2xt93 +2x205) = -ti3/,g J/mot.K 0,5
AGn : AH -TA S : -1039,6kJ - 29gKx (-1534,8 x10-3) kJ/mot.K
: -1039,6 + 457,37 :& 0,5
b) 2 mol san phem tao ra AGo : - 582,22kJ s33 --
7,95153: 0,15 mol s6.n pham t4o ra AG : (- 582,22 x 0,15)12: m 0,5
Cflu 4 clo2F)cloF+o
(1,0 tli6m) lnkrzlkrr: (E,/R) [I /T rl lT z]
-)4t 5 0.5
1n44,37 8 : 4[OOOOra 3 t 4)Lr I sg s -1 tT
3,793 : 2237 1,9 U I 595-l lT2)
0.5
Cffu 5 l0.0eSbCl. lmol
(1,0 tli6m)
N6ng <IQ ban dAu ctra SbCl5:
lsbclsl = -l;0L-- " zss c,
= 0.00669 M Sbcls

Phuong trinh phan img:

sbcl, .-sbctr+ ctz
0.N669Ivt 0 0
-x fuI +x M _+r )W
(0.00669 - r) tuI * 1,1 r M

_, -lsbclsl
lsbcl]llcrzl
I(" =
Ta c6 phucrng trinh theo hing sd Kc: 0.5
(tXr)
2.5lx1o-2=0.00669
- "r
12: 1.68 x- 10-4x 10-2js
2.51
p + 2.51x 10-2r - 1.68 x 10-a = 0

Gi6i phucrng trinh thu dugc: x: 5'49 x 10-l and -3.06 x 10-2

})A *hi oA- Ol tranc a-,ir hA an; thi lzhAna |ni^h fr: +hafr
 [Sbclj] : (0.0066q - x> M= (0.00669 - 0.00549) M = t.20x 10-r rtr{
I.20 X 10-3 rnol 299 s
gSbClr:5.00t* *ff: 1.79gsbcl5
0.5
a) Dung dich axit y6u
Ciu 6
(2 tli6m) . (M): HA-+ H* + A-
Ban dAu 0,25 0 0
Phdn img (M): x x x
Cdn bang (M): 0,25 -x x x
E0 diqn ly o : x10,25: 0,03
: ' ig (0'25x0
Ka : x2r10,25-x1 : (0,25x 0,03)2/(0,25-0,03x0pH '03i:2''1,
Kti... -. 5,625 .7 0's I 0,2A2tr : 2,32:li'! 0,5

b) NHTNOs --- NHr* + NOs-

NHI* + HzO e NH3 * H+ KNrr: 1,8.10-5

Ban dAu (M) 0,20 0 0
Phan tmg (M) x ) x x
Cdn bAng (M) 0,20 -x x x
._ [NIH:][tliO*] l.0x lo-r+
------= [M{tl[H;O+]
'ta - rNTrJ +1 4. n'rr,-r: 5.6 x l0-l-o_
- iM{4+j
t,!.1+ J (s
o,", 1.8 x 10-5

-_ [Nrr{31[-I]o+l
K,: : (rG) = 5'6 x lo-rJ
fNH*t (o2o;
GiAi phumrg trinh thu dugc:
r : 1.1 x 10-5
huy
i4: [H]O*l 0,5
c) Gei s5 moi CoHsCOONa th6m vdo ld x:
CsHcCOOH + NaOH CoHsCOONa
xxx -
csHocooH + Hzo €) coHscoo' + H:o*
0,5_x x0
PhAn ly y x+y y 0,5
C6n bdng: 0,5-x-y y x+y
vi phdn img theo chi0u nghfch non y nh6_ qu6 xem nhu b6 qua. Ta c6 dung
dich sau PU 1a dung dich d6m cira axit y6u vi mu6i:
pH: pK, + log [C6H5COONa]/[C6HsCOOH] -lo9(6,4.10{y + lg (x)i(0,5- :
x):4,795
= 4,193 + 1g ></0,5-x= 4,795
1gxi0,5-x= 0,60 ) x/0,5-x = 4,00 ) x=0,40
0,5

Ciu 7
a. Phucrng trinh ldm vi6c cuapln: Mn14 + Cd2*m 0,5
Anot: Mn/Mn2*; Cathod: Cdldd2*
(1,5 tli6m)
b. AEopin: qo(Cd2+/Cd) - q',o(Mn2*/Mn) :;glg:l-t,l_U = 0,78 (v)
AGo : - nFEo : - 2 x96500 x 0,78 = -i

c. Mn1.y + Cd2*1oo; .t_, Mn2*(aa; + Cd14 0,5

Ban dAu
0,035 0,035
Cdn l4i 0,125 0,025
Ap dpng phucrng trinh Nerst
AEpin: AEopin"-(O,05912)lg 1vtn2.1l;ca2*l : 0,79 + (0,059/2)lg 0.5
0,r2510,025

m,>L
 TRUbNG DAI HOC KHOA HOC TU'NHIEN NAM Hoc 2o2t - 2022

Nl6n thi: Hoa Dai cuong

Lop rndn hoc: CHE 1080 (1-5) 56 tin chi 03
l)dnh c'lto sinh fi|n lrryt mdn hpc: ('HIilAB0 (mdr Hda f)qi cuorrg cho trtitt.t trw)ttg ilHKH I'N.t
'l'hrli gian lam bdi: 90 phfu (Khdng k0 tltcri gian phat d0)

Ciu I (1.0 tli6m). Nglydn tu He (Z:2) bi m6t I electron d6 thanh ion He . Tinh d0 ddi bucrc s(rng )" cua
He khi electron chuy6n tu trang th6i kich thich n:3 vC tr4ng thai ccv bdn.
Cf,u 2 (2"0 di6m). Vd gi6n d6 obitan phin tu MO cua phin tu XO. Vidt ciu hinh clcctrorr, tinh bdc lien ket.
cho bi6t tinh thudn tu, nghich tu cira NO, NO-, NO' r,a NO2', vd so sinh d0 bdn lidn kdt cua chung.
C6u 3 {1.5 tli6nr}. Sit, th}rnh phin chinh trong thdp, thu dugc qua phdn ung khu oxit s6t (lll) boi hvclro.
FezO:1,.; + 3Hzrr.l -+ 2Bet.l + 3HzO6.r
AH"ri,,t, nr,;;t (kJ/mol): - 824,2 -241.8
S"(K.rnol-l.K ): + 87.4 +130,6 -r./. I .) + 188,7
Hiy tinh AG" r,i cho bi6t chidu huong di6n bi6n cua phdn ung tai didu kien nily.
Ciu 4 (1.0 tli6m). Phdn ung CH:-CHr - CHz:CH: + Hz c6 h6ng s6 tdc d0 cua phan ung la lr - 2,3r l0'a
s-r cr 507"C. Hing s5 t6c d0 cua phdn ung tdng l6n gep doi tv 527'C. Tinh ning lugng hoat ho5 (1r,,. kJ/nrol)
vi chcr bi6t thoi gian b5rn huy cua phin ung trdn o 527'C bing bao nhi6u.
CAu 5 (1"0 di6m). Cho phan ung thudn nghich N2O4&)+ 2NO2(k) . Phan ung ti6n hanh cv nhiet do
300K trong binh kin co the tich l0L. O cdn bing co 2 mol NzO+va I mol NOz. Hiy tinh hlng so cAn hanq
Kc. Kp cia phdn ung.
Ciu 6 (2"0 tli8m!. Bi6t hing s6 baro cta NH.r la 1.75 10-5
a) Tinh pH dung dich NHr 2,0M vd pH cua dung dich NH+CI 2,0M.
b) TrQn lOml dung dich NHi 2.0M vao lOml dung dich NH+CI 2,0M ta thu dugc 20ml dung diclr ddnr co
pH bnng bao nhi6u?
c) TrQn 20ml durrg dich N{gClz 0.02M v<yi 20rnl clung dich clQrn o trdn. Hoi co k6t tua Mg(OH): khting,
bi6t rang tich s6 tan cua Mg(OH), le 5. l0-r2.
Ciu Z fi.S Ci6ml. Mqt pin diQn hoa dugc xiy dpng tu 2 n*aphurong trinh phan u'ng ori hda/khrr co the
di6n cuc chuin (ll') tuong ung:
Ag' *e -- Ag /r"(Ag /Ag): + 0,80 V
Fez * 2e ----' Fe 1',''(Fe2'/Fe; : - 0,.{4 V
a) H[y vi6t phuong trinh ldm viQc cia.pin dien hoa tr6n vi chi ra ddu ld catot vd anot?
b) Tinh A(i" (theo KJ/mol) vd hing s6 cin bang K cira phiin ung diQn hoa trdn o 25"C.
c) O ZS"C. trong qui trinh ldm pin c1i6n hoa tr6n. nguoi thq da 5n bot dung dich Ag' ndn sti'c didn dfing
cua pin thuctdia t:ll
-I-l_1::_:::: [:]-l -1-1 Y ill$l :::-:1-f-: Y-:::-i:i:::
0,0,\2 l,.ot nol.K

at $e
I
B lrl * F
! 4.:
": Ll 'ti
Ai *r P S Ci
_i l,l 345*:3il J 13 i* ,.1 39 :* as: 11 ,:.c

2" 3: 3.} :i

?' Cr Fe a3 Zn fi:"1' $* 3r Itr

j3:8 5: :f :a:i 53 !:
:e :::. J} ;i i: r* :: i'

9a 4:
Y
!: ?-
: \l- Tc .:,i.
6i: Ag
':,i i: ',:: i-
a,J ln
:{ ;i
Sr'
'a: ' :r: ni
Xe
1i :i a- :: ai
ts' td Re I r. TI 3L A:
:: ia. r:,1ii iii :'i !3S 3i
 oAp An or so l
Ciu l: I tli6m Tinh d0 dii bucrc song

E, : -1 3.6221n2 [eV] . tu n:3 vd trang thii co ban ta c6: ttz

AE:r : E"r - Er : -13,6.22(1,32-ll1?): 48,36 eY : 77.47. l0-re J

AE:rr hcil, * I : hclAE:J : 6.625.10-14.3. rc8107,47,0't9) = 0,2565. I0-7

: t,1

m:2-5.65 nm:256,5 A"

(N6u dung Rydberg ctng dusc 2/4 di6m. 1fi':Pts.L2.11/n1'lln,21
tr : t/[4.Rrr.(1/nr2-]/n"2)l : 1114.109722x(1112-182)l = 2,56.10-6 crn I
0.256. l0-7 rn =25,6 nm:256 A"

'z/4
Ciu 2: 1,5 d a. Ve giin d6 di0n tu MO cua phdn tu NO

o"
I ==N
i lif5== ?r3p.

iupffiffi ffiffi
. lt o,o

,, lf,lt nro

?X 0.a,

jrs
:& .ff . tl.
W o2s

' (N)
1

AO {NO} Ao {Ol
M0

b. Vi6t ciu hinh di€n tu, tinh bac li6n kdt, cho bi6t tinh thuOn tu',
nghich tu vd d0 bdn li6n k6t

C6u hinh electron

'-t lA
CAu hinh e cua No. o.2 o.*2 7t.r4 op2 (ro')' Lt'.?

C6u hinh e cua NO-. o.2 o.*2 [r1,4 6p2 (n",*)'

C6u hinh e cua NO'. o.2 o**l7r"4 op2

Ciu hinh e cua NO2': o.2 o.*2 fi...4 opl

Bfc li6n t6t, Og ndn:

NO : N : (8-3)12:2,5, thuQn tri 1/4
NO-. N: (8-4)12:2, nghich tu tl4
NO': N: (8-2)12:3. nghich tu r/4
NO2': N: {7-2)12:2,5, thuin hr rl4
Sip x€p theo d$i btin tlng dAn: NO-< NO = NO2' < NO'
t/z
Cffu 3 AHo: 3x(-241.8) - I x(-824.2): +98,8 kJ
(2,0 tli6m) AS": [3r188.7 + 2x27,37-157,4 + 3x130,6] : 620.7 - 479.2: 141.5 J K-' ),,
AGn: AHn - T. AS.,:98,8 - 298x141,5.10-3: 56,63 kJ Y2

Ciu 4 a)ln(kzlkt): tr^lR.(llTr ' Il'tz) U4

(1,0 ili6m) ln2 : |:n18,314(11780 - l/800)---- I:.,,: 180 (kJ/mol) 112

kz : 4,6.1O-as-1 *+ tr,z : ln}lkz: 507s I v4

D0 thi g6m {} I trturg. Cdn bi) coi thi kirOng giai thich gi thCm
 r\2v4(k)- -r\v2(k)
(l.0.li6m) t:tcn ? 1 mol
hay 0.2 0,1 mol/L t/4
Kc: [NOz]2/[N:O+]
: A,1210.2: 0,05 (mol/L)

An:2-l:1
KrKc(RT)'u' : 0,05r(0,082 1 x300) =1,23 (atnt)

Ciu 6 (2 tliOnr) a)

* Dung dich NHr 2M

NH: + HzO r* NHr'+ OH-

CBC-x x x

Ka:x212-x ) x : 5,9. 10=rM ) pOH : 2,2 ) pH : 1 1,8

* Dung dich NH+CI 2M

NH+CI)NH+t+Cl-
CC
NH+u + HzO r*NHr + F{3O'
CB C-x x .x

x2l2-x: KNH4, :10-14/I(b ) x : 3,4.10-5 M) pH : 4,5

b)
* TrQn 10ml dung dich NHr 2,0M vio 10ml dung dich NH+CI 2,0M
[NHr]: lM; [NH1CI] : lM
NH+CI)NH+'+Cl-
IM lM
NH: * HzO ** NHr* + OH-
Bd IM lM
CB l-x l+x x

x(l+x)/(l-x):Kt,) x: 1,75. l0-s : [OH'] ) pOH:4.8 ) p}l:9,2

c) Tr$n 20ml dung dich MgClz 0,02M voi 20ml dung dich d$m

[MgClz] :0,0212:0,01M, ffi:l :0,5M. [NfH4Cl] :0,5M

)
NH+CI NH+'+ Cl-
0,5M 0,5M

NH: + HzO e* NH+, + OH-

Bd 0.5M 0,5M
CB 0,5-x 0,5*x x

x(0,5+x)i(0,5-r): Kr, ) x: 1,7-5. ,6-s : [OH-

D0 thi gdm ()l trang. (lrin b(i coi tld kl0ng giai thioh gi thtm
 [Mgz']:0,01M

[N{g' ][OH-]2 :0,01 (1,75 10-5)2:3,06.10-r2 < Trrg(ou)z ) kh6ng tao kCt
tua Mg(OH
Lau /
a. Phuong trinh ldm vi6c c0a pin: Fe(r) + 2Ag+(dd) ** p'g2+(dd) + 2Ag(r)
Anot. FelFe2+; Catot. Ag/Ag+
(1,5 tliorn)
b Eopin : Eo(Ag+/AS) - Eo(Fe2+/Fe) : 0,8 * (-0,44) : I.24 (V)

AGo : - nFEo : - 2 x96500 x 1,24 - - 239320 (J/mol) : 239.32K.1/mol

K: 8,92x 1041

L_.r irirrr), fl* i

t,-t.l::--"""7
rI [Ag I
t) rr\Q
!:l t:"* - *iu I

: -lAg I'
Ag' | :0.3 M

t)i thi gdm t) I trang. C'rin ba) coi tlil khtine giai 0rioh gi thtm
,t rntIltr'rc i;ar uoc xrroa noc rU rrrlltN NAtvt Hgc 2014 -201,5

or cniNn rntlc r MOn thi: H6a Dgi cucrng

Lop m6n hoc: CHE 1080 56 tin chi: 03
Ddnh cho sinhviAn md ldp mdn hpc: CHEI080 (m6n Hda Dqi caong cho todn trudng DHKHTN)
Thdi sian ldm bdi: sir duns tdi liA

edu 1 (1.75 di6m). Sri dgng thuy6t MO, h6y xdy dimg gian dO ndng lugng cira anion CN-. Vi6t c6u
hinh electron, x6c dinh sO 1i6n ktit vir cho bi6t ion trOn c6 tu tinh hay kh6ng? DUa vdo gi6n d6 MO
cria ion CN-, h6y sip xtip ndng lugng li6n ktit theo tr4t t.u teng dAn cria c6c ion hay phdn tu: CN-, CN,
CN2*.

Cdu 2 (2.0 di6m). Cho he phan img N2Oa ph6n htiy nhu sau: NzOr o.l --+ 2NO21s
vdi c6c dt kiQn nhiQt dQng hgc chuAn: AHozsa r (kJ/molr: 10 34
Sozssr (J/mol.K) 304 240
oC
a) Hdy tinh bi6n thi0n n5ng lugng tU do AGo cria .r6i phan img tr6n 6 25 vd cho Uitit O di6u kiQn
niy phan img phdn hriy NzO+ c6 x6y ra kh6ng?
oC
b) Ntiu ndng nhiQt dO h9 ftn 47 thi c6n bEng dlch chuy6n theo chi0u thuqn hay chi6u nghlch? Tinh
oC
hang sO cdn b5ng Ke b 47 v6i gia tfri6t AH cira phan img kh6ng thay d6i theo nhiQt d9 25- 47 oC.
Ciu 3 (1.0 cli6rn). Ph6n img phdn hiry N2O51r; thlmh NOzt) vir NO36.y ld phan tmg bAc m6t. O 25 oC,
phan img c6 thtii gian ban hriy ld 2,81 gi6y.6 45 oc,phan img c6 thoi gian ban hty ld 0,31gi6y. HEv
x6c dinh n[ng lugng ho4t h6a (E") cria phan img tr0n.
Ciu 4 (1.5 di6m). Cho phan img : Nzru * Ozrx) --- 2NO1r.; c6 K. :4,7x10-4 6 2000 "C.
a)Hdy x6c dinh n6ng dQ cira khi NO t4i nhiet d9 phan img tr0n khi phan img d4t trqng th6i cdn b6ng,
Uitit irdn hgrir kni ban dAu gdrn 0,40 mol N2 vh 0,30 mol 02 chria trong binh phan img kin dung tich
2,9 L.
$\ 't'y2 Oz0o * N0tr.l i!' 2000
oC.
b) Hay tinh K, cta ph6n img: % N2

Cf;u 5 (2.25 rli6m). HEng sd cdn blng Ku cua HNO2 li 4,0x 10+. a) Tinh pH cira dung dich HNO2 0,5
M.
b) Tin-h pH c;tra dung dlch chira Nal.trO2 0,5 M.
c) CAn tr6n bao rfiiCu mL dung dlch HNO2 d trOn vir bao nhiOu mL dung dich NaNO2 tr6n d6 dugc
1,0 L dung dich dQm c6 pH:3,55.

Ciu 6 (1.5:Ii6m).MOt pin gavani dugc xdy dyng tu 2 diqn cgc: diQn clrc thr? nfr6t ta kim lo4i Pt
nhring trong dung dlch Sn4*/Sn2* cdn diQn cgc tht hai ld kim lo4i Pt nhring trong <tung dlch Fe3*,6e2*.
a) HZy vi6t phucrng trinh ldm viQc vd tinh su6t diQn dQng (AE) cria pin gavani b 25 oC bi6t ring tht!
.A
diQn cuc chu6n cria c6c cdp oxi h6a - khri li6n hgrp: Eo5na+/sn2+ 0,15 Eo..r,,^.r* : 0,77 Y. : V;
b) N6u n6ng dQ cria dung dlch Sna*: 0,0lM; Sn2*: 0,lM; Fe3*:0,lM vd Fe2*: 0,00lM thi sric diQn
rlQng AE b 25oC cria pin bdng bao nhi6u?
HET
il Hang sO khf (R) :8,374 J/mol.K hay 0,082 L.atlmol.K He
1.41 I 13 t4 t5 tA 17 4.OD
4 6 7 a I
Li Be B C N o F Ne
E-94 1Q.BI 12-01 't4.o t le.os l9.go lc.:a
t'l 13 ta tT 1E

Na lvlg AI si p S CI ,Ar
2c-9s 24"3t 34567&S10t'.t12 26-98 2.9-8S 30., 7 32.O8 35-*5
lo ?t 22 ?s 2,4 2E z7 2g 29 3s 32 14 3E
K Ca Sc Ti V Cr Mn F6 Co Ni Ctl Zrt Ga Ge NS Se Br Kr
3$.1& 4!.118 *4-SE 47.87 5if .g* 32.Ofr 5*.9e 55.85 58.8S 58,EE '6534 ffg-72 72-6{ 7r[-92 7e.s6 7*.go 83.8G
37 3A 39 *8 41 *2 43 44 45 {6 {7 €8 49 5C 51 e{
Rb Sr v Zr Nb Mo Tc Ru Rh Fd Ag Cd ln Sn $b Te I Xe
85.47 a7-62 eE-g 1 e1.22 t5sG 13r"{I? r0a9, 1C6..t2 107.97 ,'12-4i 1 1.(.6t 118-?_1 1rt.78 127.€.t 1"36"Sit 1:.r1.29
5€ tz 73 7* 75 l6 7't 78 7Z AE & 84 AE 8e
f-,.
ft{ Ba 5i-
Hf ,d w Re Os lr Pt AU Hg T1 Pb E;
UI e-o
,
1s-sI 1 7&-{€r 183.A.{ 1.SS.21 't 9D.23 rge22 'rs5.68 196.97 ?d-1 io ar:t2 a3E^gg 1, [n L
Ciu 1: Gi6n dd MO cria ion CN-
1,75 di6m
qr*
*{p*-

Fe -
x -l*--
rf:- @ @@
Ugu* 414
-p4*
&r
N<s
Cdru hinh electron: o 12 o r*2 o.2 Tc*2 Tcr2'. at- :=
s6 uon t6t N : (B-2)t2:3. Uv 45
Kh6ng c6 electron
BO+on:ryH
dQc thdn n€n ph6n
(lrtf
ffi"rr{wr,
tt nghich.
1an, 1 Crtz--
tir
'% z'
'kztq 4b

Cdu2 Phan tmg ph6n hriy NzO+ nhu sau: NzO+ Gl ---+ 2NOz tr,)
(2 tliem) nhiQt dQng hoc: AHozqrr [kJ/mol] 10 34
Sozss r [J/mol.K] 304 240
a)
- AHozss [kJ/mol] :58 kJ/mol t,/
/4
- ASozss [J/mol] :]rq.rlrnol .4f6 Y4

- AGozss [kJ/mol] :58 -298 xl79 x 10-3kJ/mol:4,658 kJ> 0 5SS, Lf %

-) kh6ng xiry ra l/
/4

b)
- Theo chi6u nghich vi AH > 0. t/
/4

-AGozss ) lnK:- 1,88 ) Kp:b>tQt I /061

[kJ/mol]:-RTlnKp l/
/4

- C6 ln (Ko,rrlKp,rz): (AH0/RX1/T1 llT2) - t/

/4

Thay c6c giri tri vdo tinh dugc Kp,rzo*: @5 b, S ? t l/

/4

Cflu 3
(1,0 tli6m) kl, 25oC : lrZl2,8l:0,247 t/o

k2,45 oC : ln2l0,3l :2,235 ,/o

ln(k2lk1) :ln(tllt2): -EalR(l/Tz - llTl) -+ Ea: 86.5 kJ ,/z

Ciu 4 Theo dC bdi c6 [Nz] : 0,2M, [Oz] :0,15M

(1,5 di6m) NzG) + Oz0.) 2NO6y
t:0 0,2 0,15 0
tncu 0,2-x"6 0,15-x"6 2x"t
:
. Kc tNol'z/(Nzl.[Oz]) K" : (2x"6)'1770,2-*"61.( 0,15-x.6)f : 4,7.10-4 %
-) Xcb 0,00175 l//2

. [NO] :2x"b:0,0035 : 3,5.10-3M.

Kp : K..(RT)', r:.0 :) Ke: JK. = fr,t 10_4 K : 0,020 %

Lau 5 pKo - 3,2 ) Ku: 10-'''.

(2,25 di6m) a) Tfnh pH cua dung dich HNOz 0,5 M.

HNOz = Hn + NOz- K, - 10-3'2

DC thi g6m 0l trang. Cen b0 coi thi khdng gi6i thich gi them
 PhAn tmg (M) x )x tx
CAn bing (M) 0,5 -x
4,6 tL.
ft{=Lffh-
,ff": 0,5-x
I- =!' :1o-3" )x:0,0178(M):[H*];
Vay : :
pH: - lg[H*] -lg 0,0178 1,75.
frw
b) Tinh pH cira dung dich NaNOz 0,5 M.
rH
:Tt{F^q C6: Ku.Ks: 1g-t+ ) Ku: 1g-t+719-:'2 - 10-10'8

.W NaNOz)Na*+NOz-
0,5M ) 0,5 M

NOz-+HzO +
----|
HNO2 + OH- K5: lg-lo'8
Ban ddu (M) 0,5 00
PhAn ung (M) x )x ) x
Can bang (M) 0,5 - x xx
Kb:
t,
,-,+-=
X2
- [s-10,a
\J 14) - rL )x:2,9)0-6(M):toHl
pOH: -lgtoH-l : -lg 2,8.10-6 : 5,55. Vfly pH : 14 _pOH: 14 - 5,55: 8,45.
%

V{y pH:8,45.
{c
c) Ggi th6 tich dung dich HNO2 0,5 M cAn: x (L);
Goi th6 tich dung dich NaNOz 0,5 M c6n: y (L);
flfrwr,'
)x+y:1(L) (1)
M[t kh6c v6i dung dfch dQm:

pH : p,o-*: =t__ff#: r+_ rro,r,:

3.ss

) f - s,44r (2)
rt(1)vd(2)>xffi tfn\,- Wtr{
6
Ciu 6 | a) PT ldm vi6c: Sn'* + Fer* Sn4* + Fe:
:
1f ,S Oi6m; j :
E E.F"3*/F.2* - Eosn4*/sn2* :0,77 - 0,15 :0,62Y
b) Ep.:*r.z* :0,77 + O,059ll x lg (0,1/0,OOf ) :bfg V 0/ Ytr*
Es,4*/sn2*:0,15 + 0,059/2x lg (0,01/0,1):h9 V 01,tt
E: Er.3*F.2+ - Esn4..7srz*:b,q- 0A?:\v 0,YE

g,tu+ Fo*t
pd,.
= tnvT f fr-"r
LL ttN7L qt M ? Ca= Tsp.
'it ; 02s
2e, \,
w wrb/Etf + qL
= \Sy. ,

€\
P+t-- L qls N'p

bretg (_

!,' t,'t5

Oe tni gOm 0l trang. Can b9 coi thi kh6ng gi6i thich gi thdm
'1r 4v
1l - 1z
 ;;.'(f,,* L,L , Urd bfrru t+) + (rff,rat
cn) t6o.cd)

{^Hia= -,tlbs
&
(svt,s)t t(-L+'t,ilJ= Ls+s,r q*
,fl{y,rt= &N,+ 6K&05,,4 eV<rt,1+) 16^lW,K4= -
'I
\

4*4Lr ft 2t'1,+L
- - =,-g+2,5y
Tl,Ntk
^il'-
Ta Eo
= t5i3i - 2strr(glt,S.> )o o -
(,t W
z tv
0\- (,,,rt)
N= s: a 45 4*l
)-

6,4't %ffoot^ o + rL)ul + Anrorrt+e4r9tq

?LL*rgL
/* /"et
I lnt .L lnt l*z
"L=
-
,L iF)
,/
t-
- ulr
.-
bgl-
= otDzt 4,-t 0*)
I
2
,(*A-=l* q +-LL aa_ = .1 .l^.C = Ur3
G Cr D/z,l_ ApLCo /*
Cc, = 4Z c,) t,t_t1
 b"Z Wl = o,nlt{
a q.r+ LttLo,, 5 frow)*att t n D*@).
Fh=
zzL

Md o,rol.
t.i r C)O 2c.

|fbl -r- L.
% 7L

,KA far*t*l ln rl L
=
Itb,l ->
= ,tfqL
[ru'!
+ = t,W ,to-+ ) fn = g, aI
7,,- cf)
NL g0+ t &Na] + CrL;-
6t+ + C,o;- 3 cago+,
0p4*St-| ;

tcroiJ = [Ng"rol : y ! 0,455, :,tli,D-',,

,lWL
(Vd = l*t)
tc"\ Lcrl;l :. 0,ot4tf r lss, r/D-
r

= Srlt ,o-( 7 T",rur

-2 Lhl +* u;,r"
,rf
 0.0F4 4,s g {e;
0$ol lfot 0rit(. (rrr6t/L)
a,3er 6fi? @t L)
0/+Dl

,tL .
orFl :ADJ a,6& ofi,l*t opr!$
,
r+ *;l
lm'y,1. b, t L=
tA"L
/f\
6r
4\ ""XtI
T A=L
V^ 0,
L \

6rt
,) tnrl c$sroar,f^ o/04 r,,1 + lfD rrt ff/ 0,0'lS't'7
r^_
Qqromv." r
D/[05 M -ftL. - a,o&ou

W'ttpr+ +,$ r"C(--

ego-t fi'b
5z %6r,4 +su-rl
DpDs t7 @
rc. p
a

p,_o,l,ql
o,uu .,rfi: @: H* 5n
.-rt?{
 pL7- :. zo)J
CC' I Z-
I
t Arrorr, t Wrr, ? nolt l rtttu;g) to\,
K=? lG-o 7- Br^0*K
lols ra 3
T /l'(g
Y,st+ @+rzB) =
2 K -. 4s+tr4frs4
D QHrr% + {0, + 6h-+,(tfro .a,Q'=Qs,

o FP = dl G193,5).+ kGtttt,s) GtUs) = - ts/r 3/g 5h

AS"= 6rGL45\>+t (16,s3) - ztz -€xurl+
?- 151 2,3
4,*t ,R

bQ = a tto - --lA S' =, - rls+ 3,t -

i
 :,
DAr Hgc ou6c cn HA ruQr GIAYNHAPTHI

Chfr ky cia CBCT :.............

o:=
tag ,/0, <:) MF7 A ll *44r,g l[/*,/- @
t, /-
*=
rdx
= .- zf gq
Affo- Tt So T"*1, r

3ry +2 NL P ktp N+ =
i
-,t4tY - 2fYx (-zr,grs)
- 4Jt, rj
--.
(o^g-^to-'
A#o= -,{40,t lil*t _/"

DSO : x.,l * +fixT _ 4-/4$8 _

Q|Url*,ty;
-9
Ld= atto - TA So = -/40,3 - Atr n CgD rl0 '= -3zrS ,1-o
ltl't
N, + o,
- [t) u))'
L- zN,o u>
o/t/
-/1Dzu)
\ '

AH=r\
, *rrrrr,
dH :- s)-t,tt6ilz_ z 1tr0 -/tlz. = ,6f /f
*

Ar- Lv'?Ltt

@r-= g[8 --
vLro
\,/-:P.\
'\F,/
i4r
lo,rrJttSHp
-r t-
&n (q l/
 THI CHiNqTHIIC KEIT}Y': IIQC KV 1
TRUS$IT1?'!33i'?I1TfiU?L NHIfl?
M6n thi: H6a D4i cuong
Lcrp m6n hgc: CHE SO tin chi: 03 1080
Ddnh cho sinh vi€n l6p m6n hgc: CHE1080 (mdn H6a Eai cuong cho todn trudng DHKI{TN)
Thdi gian ldm bdi: 90 phtu (Kh6ng kA thdi gian phdt di.t

Ciu 1 (1.0 di6m). Tinh bu6c s6ng (theo nm) cria 6nh s6ng phdt xa khi electron chuy6n tt n : 3 vO n = 2
trong nguydn ti? hidro.
C0u 2 (1.5 di6m). HEy xdy dpng gi6n aO UO vd viOt c6u hinh electron cria ion phdn tu Fi. Hay tinh bQc
li6n k6t cin cdc ion ph0n tri F2, Fz',Fz* vd cho bi6t chring ld thufln tir hay nghich tir.
Cdu 3 (2.0 tli6m). Nhi6n liQu tOn hia dAy tAu vfi t4r trong khdng gian sii dpng phin r?ng du6i d6y:
3AI (') + 3NH4clo4 (r) * +61 + 6H2o s1 *
ei6t l H"s],r (kJ/mol) I;i;t' tf?'u' 'ilo
So(Jimol.K) 28 186 51 11 1 21,1 189
Hdy x6c dinh AG" (kJ/mol) cria phin ring o 25oC vd cho bi6t chiAu hucmg phAn fng o nhiQt dQ ndy?
Cffu 4 (1,0 di6m). Cho phin rlng phdn hriy N2O5:
-+ 4NO2 tr.l * Oz (r.)
2NzOs 1r9

A 25"C hing s5 tdc dQ phdn ring la ki : l,72.l}'s s-'. O 35 oC hing s6 t6c dQ phin ung ld h:6,65.10-5 s-r.

Tinh ndng luqng ho4t hori (Eu) cria ph6n ring phdn hriy N2O5 6 trOn.
CAu 5 (1.0 tli6m). MOt m6u khf PCls dugc cho vio binh chin kh6ng, 6p su6t ban clAu cta PCls ld 0,5 atm
O 25A "C. O diOu ki6n ndy, PCl5 phAn hriy theo phin ring: PCl5g.y iz PClso.l + C1219
Ap su6t t6ng cQng cria hQ khi dat cdn bing le 0,84 atm. Hdy tfnh K, va K" cria phdn trng o nhiet dg nay.
C6u 6 (2,0 di6m). a) Tfnh pH cria dung dlch axit benzoic CoHsCbOH 0,2 M c6 Ka : 6,4J0-s vd pi{ cria
dung dich KCN 0,1M c6 Ks6p :'7,910-ro.
b) TrQn 100mL dung dich HCOOH 0,1M v6i 100mL dung dlch NaOH 0,05M dugc 200mL dung dich A.
Hdy xfrc dlnh pH c0a dung dich A. Bi6t HCOOH o ctng di6u kiQn c6 hing sO Oign ly Ku : 1,7 .70'4.
' c) Tinh dQ tan (s) cria Mg(OH)z biiSt tich s6 tan cho tucrng ring TMglsHp: 8,9.10-12.
, CAu 7 (I.5 di6m). Pin gavani dugc xdy dung ti 2 r,baphuoiig tiinh vd th6 ,iign cpc chuAn (qo) tuong ',rng:
Ag* + e --- Ag 0 <p"1Ag*/ag): * 0,80 V
+
Cu2* 2e --Cuo qo(Cu2*/Cu) : + 0,34 V.
a) Hdy vi6t phuong trinh lim viQc cria pin gavani tr€n vd chi ra ddu ld catot vd anot?
b) Tfnh AGo cta ph6n frng O 25 oC.
c) Tinh sirc diQn dQng (AE") cta pin ldm vi6c 6'n6ng dO
S6c ctr6t ta [Ag*]
: 0.01M vd [Cu2*] : 0.01M.
cho biat: ,,:;;;;;;;:;;;;,-;:;;;;;;;;;;::;, ;;, ;:;,;,;;;; ;-iii,-r-,,,*,, u
1 2
H He
.1.{ 2 13 14 15 16 17 4.SA
5 6 I g '!
Li tla B C N 0 t\e
8.94 1A \r 16 nt
11 t2 i3 !7
l.Ja Mg
g
A; Si F s CI Ar
2?.St 3d.lL1 3 4 5. 6 ? I 1* 1t 12 2e-9e zs.o$ 3a"gi 3t.oB s5.45
3n 25 z7 a) 34 3ts
K Ud Cr Ti Cr ?i;1n tra Co Ni CLr Zn ud Ge As Se Br Kr
4!.04 44"!8 47 .87 5.1.s4 52.a"JC 5{.9.i 59..95 49.72 12.6* ?4.32. 7r.93 53.49
:<7 3E 4! 13 4E 4A {,8 49 5C 51 5l
DL Y Zr Nb fi r- 'l.-
IU Rs Rh Fd. Cd ln CL I
Xe
&5.4.? s7.az 93.!i 31.2: 92.97 131.t? iEE..g1 '+O6.*2 147 _47 : '1,8.?; 121.1& 'r27.88 'i31.23
73 75 7E t-7 7A 71 B" e2 84
L,E 8a l*+ Ta tAI Re Os lr Pt Au Hg TI pb Bi At Rn
r32..gl .tA7.33 17&44 .?8.E5 134.2: 1E?.?.2. 'i98.9? 2r{,_?.s -l1f 2 !3.Se 1r
Od ttri g6m 01 trang. Crin bQ coi thi kh6ng gi6i thich gi th€m
i'i {
 nAp AN oB so I
C0u 1: I eli6m song: n :!n,:2 tL
.Btt'6c
'I'n
n: :
3 r,6 n :2, s0 sr5ng fr I\n(1/22 - ll3,) t/z
) L: 656 nm (chdp nhfln sai s6 O+S -660 nm)

CAU 2: 1,5 tl Gidn d6 M0 cria Fz-:

Ao (F) Mo (E-) AO (r_)

,--t--',
/o.\
,rr,fi___i_1tr...,
Tx fry tr.,ta.
,/rr'
+-+-+*(
2p t).
.t/ \\

)+1.-+-+
,',,' 2p
,','
"tt
'\. rx fty ,/,
".'g-----11',,'
t
--lJ---'

----+T----
os
oz

---
r,
---Tf-----
--JL---" LL \
2s ---_ IL _--- -.'--TF-- 1,0 I

os
2s
q
\
\\
Cfing tir gi6n rt6 MO trdn, ta c6 thr4 vi6t dugc cdu hinh electron cira ion $-

nhu sau:
%
o!o!2"l"f,nln!"f;o.1
F2-: N: 0,5, ion phdn tu'thurin til:
F':: N: 1, phdn tti' nghich tir Y,

Fz*: N : l,S.icn phAn tu'thuAn tir'

Cim 3 AH': [6.(-242) + 3.90 + (-704) + (-1676)]- [3.(-295) + 0] : - 2677 kJ/mol t/
/2
(2,0 di6m) llinh S:
ASo: [6.1S9 +3.211 + Illl- 51] *{3.7 + 3.1861 :1929 -642: Yz

:
AG AH - r^s = - 2677 - 2sB .tzl7.t;{::::rli':;;;5, : -rouo.S kJ/mor %
AG < 0; TU di6n bi€n. Yz

Ciu 4 ln(k2lk1) :
EalR(l /T 11 lTz) Yz

(I,0 cli6m) ln(6,65.10's/1,72.10's1 : Eai8,3 14(11298- 11308) + E. : 103,19 kJlmol %

C0u 5
(1,0 tti6m) ['t ilr:g: trt'l1iXi - (..l"i.qi

Ban cldu: 0,5 atm 0 0

I'.ilng: -x x x
Cdnbing: 0,5-x x x
Ap sudt t6ng cQng: (0,5 * x) + x * x: 0,84 (atm)
Vfy: x: 0,3.1 atm. Y4

Od ttd gdm 0l trang. C6n b0 coi thi kh6ng giai thich gi them
i!t,,.-..1
 ty'*
Pr..'t' x Ptr-
o
'strz-
{0.14x{}.34} _u.72
L
r k- r(J.16)
t,(.1,
,/o
Ap dgng: Kp: K*(RT)^'

K&: u_71
: t).(li7 t,/
{u.(rH 2(}(ii{523} /4

a) Dung dich CollsCOOH

Cfiu 6 (2 diSm)
CaHsCOOH CrHsCO0- + I{*
Ban d6u (h4): A,2 00
Phin img (M): x XX
Cdn b[ng (M): A,2 -x xx
M{t khfc: Kc : x?/(0.2-x):6,4 x 10-s; GAn dring x2 :0,2 x 6,4x10-s
Vfl,vx:3,58.10-3(M).

V0y: rrll : - IoglII+l : -los(3,58.10-3) :2.45.

t/
/2
CN- + HzO *+ HCN + Oft- Kgcrv:7,gJA-Lo
Ban dAu (M) 0,1 00
PhAnir:ng(M) x + x x
C6n b6ng (M) 0,1 - x x x
-]
u^ =[ucrl][of
'*b - , *' ,= l0-'o - ,0-'o,. -= t'LvJo't
-(o,t-x)-
=
[car ] K, ii.to-'o 1.265g.10-s
---) x: 1,125.10-3 :> FOH:2.9S :> pH: I1"0S n

b) HCOOH + NaOH -+ HCOONa + HzO

llucooH:0,01 rnol
llNaoH: 0,005 mol
\/ -nrT
--* Sau IHCOONa] : 0,005i0 ,2: A,A25 M
Plf:
IHCOOHI :0,025 M
Dung dich sau PU lA dung clich dgrn ctra axit y6u vi rnuili
pH : pKu + iog IHCOONaI/|HCOOHI : -log(1,7. lA'41= 3,77

c. Mg(OH) 2, T(ntg(OtI) z : 8,9 x10-12. t/

/2

(s) s 2s
Ticlr s6 tan: 1> ;nag2"l. ;OH-fz : t.(2,s)2 8,9 x I 0-r 2 :
- V$y dQ tan: s: 1,305.10-4 pf;. %

t-au / a. Phucrng trinh llm vi6c crla pin: Cu + Z1.,lg* *-+ Cu'* + 2Ag(r) %
t/^
(1,5 ili6rn) b. Eo: rpn(Ag*ro*) - <p"icu2-/cu) : 0.80 - 0,34 : a,46 y
AGo: - nFE : -2x96500 x 0,46 s88,8 kllmol @
c. E: Eo + (0.a5g/2).log([Ae*12l[cu2*]) :0,46 - 0.059:0,4$1v I /

O6 tfri gdm 01 trang. C6n bQ coi thi kh6ng gi6i thich gi th6m
 NaNO2, 0,45 M: Yl:2/31, 0,5
HNOz, 0,60 M: Y2: 113 L
Lau /
a. trinh ldm vi6c cua pin: Felr; + Cu'*(oa)
Phuo-ng .- Fe'*(ao) + Cu(r) 0,5
Anot: Fe/Fe2+; Cathod: CulCttl+
(1,5 tli6m)
b. : En(Cu2+/CLl) - EoGe2*/Fe) : 0,34 - (-0,44): 0,78 (v)
Eopin
0,5
AGo - nFEo : - 2 x96500 x 0,78 : -150540 (Jimol)
:
K= 7,44 x 1026
c.

Loj v * o.ls r' -

o'059: l'
b*
'"-*
jI+
a r"s- " I
: [Cu=*J
0,5

,ti-'r,' : 3.6xlt.l-$
lcu--l
[F*ro] = 3,*x,I0-i'xO.]fi,,tf : r.rxIfr-$,+'/

,Yi Oe tni gdm 01 trang. Can b0 coi thi khdng gi6i thich gi them