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Repeater Wt-23 Key Solution
Repeater Wt-23 Key Solution
29. (a)
The average value of output direct current in a
half wave recti ier is
= (average value of current over a cycle)/2
= (2 / )/2 = / .
30. (c)
Total resistance in the circuit = 2 Ω
21. (d) = 20
ℎ 12400 12400
= ⇒ = = = 4960Å
( ) 2.5
This is the maximum wavelength i.e., the signals
having wavelength greater than this value
are not detected by photodiode. Hence
correct option is (d)
22. (c) 20
∴ The current = = 10
2000Ω
31. (c)
0.6
=− = = 6 × 10 Vm
10
32. (b)
Potential difference across diode
= 3.2 – 3 = 0.2 V
The truth table can be written as ∴ Current through diode
.
= = 2 × 10 A
= =
+
33. (a) used to create P type semiconductor
The output of NOR gate gives = + 40. (b)
The output of NAND gate gives
= ( + ). ( + ) 41. (c)
1. = −10 and = −5
=( + )+( + )
=( + )+( + )= + Diodes and are reverse biased and is
The output of NOT gate, = + forward biased
It is a boolen expression for NOR gate R
34. (b)
R
A – 10 V –5V B
35. (b) 3
⇒ = + + =
4 4 2
2. When = −5 and = −10
36. (d) R
Positive charge ( , holes) should move in the 4
4
direction of current and negative charge
A –5V – 10 V B
( , electrons) should move opposite to
the direction of current. ⇒ = + + =
37. (b) 4 2 4
The truth table of the circuit is given (iii) In this case equivalent resistance between
and is also
= = = Hence (ii) = (iii) < (i)
0 0 0 1 1 0 42. (c)
1 0 0 1 1 0 Peak value of recti ied output voltage
0 0 1 1 1 0 = peak value of input voltage – barrier
1 0 1 1 1 0 voltage
0 1 0 1 1 0 = 2 – 0.7 = 1.3 V
1 1 0 0 1 0 43. (d)
0 1 1 1 0 0 ‘NOR’ gates are considered as universal gates,
1 1 1 0 0 1 because all the gates like AND, OR, NOT
can be obtained by using only NOR gates
Output of single three input gate is that of
44. (a)
AND gate
The given Boolean expression can be written as
38. (c)
By doping a semiconductor with some impurity = ( + ). ( . ) = ( ̅. ). ( ̅ + )
atoms increases the conductivity and = ( ̅ ̅). + ( . )
= . +̅ ̅ = ̅
hence decreases the resistivity (as
= 1/ ).
39. (d) Group 5 elements like arsenic are used to 0 0 1
create, N type semiconductors and indium is 1 0 0
0 1 0 For the reaction,
1 1 0 3 →2
45. (a) 1 [ ] 1 [ ]
=− =+
When a junction diode is forward biased, energy 3 2
is released at the junction due to [ ] 2 [ ]
∴ + =−
recombination of electrons and holes. In 3
the junction diode made of gallium 54. (b)
arsenide or indium phosphide the energy The rate expression is derived for slowest step of
is released in visible region. Such a mechanism.
junction diode is called a light emitting 55. (c)
diode or LED. [ ] 1 [ ] [ ]
− =− =
46. (b) 2
The ripple factor for full wave recti ier is 0.482 56. (b)
which is 48.2%. = [ ] ;
47. (b) Maximum efficiency of a full wave rec fier is Also, 100 = [10 ] ;
1 1
× 100% = ;
100 10
∴ =2
48. (d) 57. (d)
The diode will conduct for positive half cycle Rate = [ ]
of . . supply because this is forward Hence ,rate determining step is
biased. For negative half cycle of . . → +
supply, this is reverse biased and does not 58. (c)
conduct. So out put would be half wave ∵ On doubling the concentration of A, the rate of
recti ied and for half wave recti ied out reaction becomes two times.
put ∴ The order of reaction w.r.t. A is 1
220√2 220 ∵ On doubling the concentration of B, the rate of
= = =
2 2 √2 reaction does not change.
49. (b) ∴ the order of reaction respect to B is 0
One atom of pentavalent impurity, donates one ∵ on doubling the concentration of C, the rate of
electron reaction becomes four times
50. (a) ∴ the order of reaction w.r.t. C is 2
AC input should be connected across B and D ∴ the overall order of reaction=1+0+2=3
and DC output would appear across A and 59. (b)
C. For Ist order reaction
2.303 [ ]
REPEATER WT -23 CHEMISTRY SOLUTION = log
[ ]
×
If [ ] = , [ ] = − = 0.80
51. (d)
If the concentration of reactants is increased by , = 10 min
2.303 2.303
then rate constant remains same, , = log = × 0.0969
because change of concentration has no effect 10 0.80 10
= 0.0223
on the rate constant ×
52. (b) If [ ] = , [ ] = − = 0.25
Rate = [NO] [O ] ; 2.303 [ ]
= log
Concentration of each species are reduced by 1/2 on [ ]
increasing volume to two times and thus, rate 2.303
becomes 1/8 times of initial rate. = log
0.0223 0.25
53. (b)
2.303
= × 0.6021 =
0.0223
= 62.18 min 65. (c)
60. (c) Given , =initial concentration =1
The value of irst order rate constant expends on the N=concentration after time =
units of the concentration term used is not the K=6.9 × 10
correct statement. 1
61. (b) =
2
For zero order reaction Or
=[ ] −[ ] 1 1
For / , [ ] = [ ] /2 =1
8 2
∴ / = [ ] − [ ] /2 ∴ =3
[ ] 0.693 0.693
= / = = = 100
2 6.9 × 10
[ ] T= × /
/ =
2 =3× 100
62. (b) =300s
The rate for irst order reaction is expressed as ∴ after 300s it will be reduced to 1/8 of original
→ concentration.
[ ]
Rate= − 66. (b)
Rate=k[A] 67. (d)
And the rate constant (k) is given as Combination of and to give HBr is zero order
2.303 [ ] reaction as the rate of reaction is not affected
= by the concentration of reactants.
[ ]
[ ] + 2HBr
− = 68. (b)
2.303 [ ]
63. (c) For the irst order reaction
For a zero order reaction, = [ ]
→ product
[ ] [A]→concentration of reactant
Rate=− = [ ] =
K→rate constant
− [ ]= . Given that,
Integrating the above equation.
−∫ [ ] = ∫ = 1.5 × 10 min
−[ ] = + I …(i) K=? and [A]=0.5 M
Where, I is integration constant 1.5 × 10 = × 0.5
At = 0, = [ ] . ×
= =3 × 10 min
−[ ] = × 0 + I .
I = −[ ] For irst order reaction,
. .
Put this value in Eq. (i) Half-life period / = =
×
−[ ] = − [ ] =23.1min
or [ ] = − + [ ] 69. (b)
64. (c) 70. (c)
For zero order reaction, / = 100
[ ] = − + [ ]0 0.693 0.693
Where, [A]0= initial concentration=a = =
/ 100
[A]=remaining concentration= − = 0
On putting value of [ ] and [A],we get = 6.93 × 10
71. (d)
These are the characteristics of effective collisions. 82. (a)
72. (c) 83. (d)
For irst order reaction 84. (c)
73. (c) 85. (c)
74. (a) The reaction occurring in two steps has two
If energy of activation for forward and backward activation energy peaks. The irst step, being
reactions are same, reaction is neither fast needs less activation energy. The second
exothermic not endothermic. step being slow, needs more activation energy.
75. (a) Therefore, second peak will be higher than the
/ irst
= , As temperature increases increases
exponentially. 86. (d)
76. (a) 87. (c)
Threshold energy level is a characteristic of a 88. (a)
reaction which may be however lowered, if 89. (b)
catalyst is used. 90. (c)
77. (d) 91. (a)
92. (c)
78. (b) 93. (c)
+ 10 94. (a)
= = 2; 95. (b)
For an increase of temperature to 50℃, . ., 96. (c)
5 times, the rate increases by 2 times, . ., 97. (a)
32 times. 98. (a)
79. (c) 99. (c)
80. (c) 100. (d)
81. (a)