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Surface Active Element Effects On The Shape of GTA, Laser, and Electron Beam Welds
Surface Active Element Effects On The Shape of GTA, Laser, and Electron Beam Welds
ABSTRACT. Laser and electron beam surface. materials, the surface tension will be
welds were passed across selenium- Small concentrations of surface active greatest at the toe (edge) of the weld
doped zones in 21-6-9 stainless steel. The elements (that is, elements which segre- pool and lowest in the hottest part of the
depth/width (d/w) ratio of a defocused gate preferentially to the surface of the weld pool near the center under the arc.
laser weld with a weld pool shape similar liquid metal) affect weld pool shape by The surface tension gradient, therefore,
to a CTA weld increased by over 200% in altering surface tension gradients on the produces fluid flow outward from the
a zone where 77 ppm selenium had been weld pool surface and thereby changing center of the weld pool surface as indi-
added. Smaller increases were observed the magnitude and/or direction of fluid cated schematically in Fig. 1A. This fluid
in selenium-doped zones for a moderate- flow in the weld pool. In addition, impu- flow pattern efficiently transfers heat
ly defocused electron beam weld with a rities which are not surface active may from the hottest part of the weld pool
higher d / w ratio in undoped base met- affect weld pool shape. This can occur if (under the arc) to the toe of the weld and
al. they react with surface active impurities thereby produces a relatively wide and
When laser or electron beam weld (also present in the weld pool) to form shallow weld.
penetration was by a keyhole mecha- compounds which are not surface active, The addition of surface active ele-
nism, no change in d / w ratio occurred in and thus prevent the surface active impu- ments to molten metals can drastically
selenium doped zones. The results con- rities from influencing surface tension gra- change the temperature dependence of
firm the surface tension driven fluid flow dients. the surface tension so that, for a range of
model for the effect of minor elements In the absence of significant concentra- temperature above the melting point, the
on GTA weld pool shape. Other experi- tions of surface active elements, the sur- surface tension increases with increasing
mental evidence bearing on the effect of face tension of molten metals and alloys temperature. In this case, the surface
minor elements on GTA weld penetra- decreases with increasing temperature tension is highest near the center (hotter)
tion is summarized. (Ref. 13). For GTA welds in such region of the weld pool. Fluid flow will be
Introduction
Many studies have reported variations
in the shape of GTA weld fusion zones in
stainless steels and other materials with
changes in the concentration of one or
more impurities in the base metal (Ref.
•=53;
1-12). A mechanism for the effect of
small concentrations of certain impurities
on GTA weld pool shape has recently ®
been presented (Ref. 11). It was pro-
posed that fluid flow in the GTA weld
pool is generally the major factor deter-
mining fusion zone shape and that the WELDING
dominant force driving fluid flow under DIRECTION
many welding conditions is a surface
tension gradient. Surface tension gradi-
ents exist on a weld pool surface,
because the surface tension is tempera-
ture dependent and there are substantial
temperature gradients on a weld pool
Cr 17.48
\: 9.6
Si 0.67
C 0.04
P 0.17
Mn 1.26
Mo 0.24
Cu 0.20
S 0.022
Se 0.25 500 u m
Fe Balance
Se Increase from
Weld type Zone content, ppm d/w undoped zone, %
Ik -A
A mm /*
Fig. 4 - Cross section of defocused, decoupled . »' 1 • "a*
•
"/
laser weld with focus above plate surface in a Fig. 5 — GTA weld cross section in an undoped
selenium-doped electron beam melted zone in electron beam melted zone in 21-6-9 contain- Fig. 7 — GTA weld cross section in an undoped
21-6-9; fusion zone boundary outlined for ing 30 ppm S; fusion zone boundary outlined electron beam melted zone in 21-6-9; fusion
clarity for clarity zone boundary outlined for clarity
74-sl M A R C H 1983
Fig. 9 - Cross section of a defocused electron Fig. 10 — Cross sect/on of a defocused electron
Fig. 8 - GTA weld cross section in a tellurium-
beam weld in an undoped, beam melted zone beam weld in a selenium-doped, beam melted
doped electron beam melted zone in 21-6-9
in 21-6-9; fusion zone boundary outlined for zone in 21-6-9; fusion zone boundary outlined
containing 62 ppm Te; fusion zone boundary
outlined for clarity clarity for clarity
width changed in the doped zones. The welds. A considerably smaller change in (mostly on stainless steels). These obser-
peculiar cross section of this weld is d / w ratio occurred when a defocused vations are summarized below and dis-
shown in Fig. 12. It is unclear that the d / w electron beam crossed selenium-doped cussed in terms of the dominant mecha-
ratio for a weld of this shape has any zones. The d / w ratio for this weld was nism determining weld pool shape being
significance, and it is not listed in Ta- fairly high in undoped base metal; conse- fluid flow driven by surface tension gradi-
ble 3. quently, d / w increases in selenium ents. Other mechanisms are consistent
Finally, no change in the d / w ratio of doped zones were correspondingly with one or more of these observations.
the uncoupled laser weld with the focus smaller. However, it appears at present that only
below the plate surface occurred when When laser and electron beam pene- the surface tension driven fluid flow
the weld crossed selenium-doped zones. tration was by a keyhole mechanism, mechanism is consistent with the entire
A representative cross section of this selenium doping at the low concentra- set of observations.
weld in the undoped, beam melted zone tions (<80 ppm) tested had little effect on Sulfur, oxygen, selenium, and tellurium
is given in Fig. 13 and the d / w ratios weld shape. It is generally believed that are surface active and are either known
achieved are listed in Table 3. surface tension forces are important in (S and O) or expected (Se and Te) to
determining the depth and stability of the produce a positive temperature coeffi-
Discussion keyhole. The important parameter may cient of surface tension in iron at very
be the magnitude of the surface tension, low concentrations. The model, there-
The surface tension driven fluid flow rather than surface tension gradients aris- fore, predicts, solely on the basis of the
model predicts that minor elements will ing from the temperature dependence of available surface tension data, that all
similarly affect the shape of GTA weld the surface tension. Small concentrations these elements will increase GTA weld
pools and weld pools created by some of surface active elements alter the mag- penetration in steels; all of them have
heat sources other than a gas tungsten nitude of the surface tension as well as been shown to substantially increase
arc, provided that the input energy den- the temperature dependence. However, penetration in 21-6-9 (Ref. 12). Sulfur has
sity is low enough that a keyhole is not the change in the magnitude of the sur- also been shown to increase penetration
formed. A dramatic increase in weld d / w face tension may be too small to affect in Type 304 stainless steel (Ref. 15). Fur-
ratio was observed when a defocused, the keyhole. thermore, the concentrations required to
decoupled laser weld with the focus Any proposal which seeks to explain substantially affect weld shape are so
above the plate was passed across seleni- the effects of trace impurities on the small that significant alteration of bulk
um doped zones in 21-6-9. The changes shape or penetration of CTA welds must properties (such as viscosity or thermal
observed in d / w ratios were comparable account for, or be consistent with, quite a conductivity) of the weld pool or base
to those observed previously for GTA number of experimental observations metal is highly unlikely. For example, only
76-sl M A R C H 1983
o t h e r forces are d o m i n a n t . For e x a m p l e , Albuquerque Operations Office, whose vacuum and inert-atmosphere-melted Zirca-
as t h e w e l d current is increased, so is the s u p p o r t is gratefully a c k n o w l e d g e d . T h e loy-2. Welding journal 36(7):335-s to 341-s.
m a g n i t u d e of the Lorentz f o r c e ; thus at electron b e a m w e l d i n g w a s d o n e by V. J. 10. Heiple, C. R., and Roper, ]. R. 1981.
Effect of selenium on GTAW fusion zone
high w e l d currents t h e Lorentz f o r c e may Lusero and R. T. Kettl. T h e laser w e l d i n g
geometry. Welding journal 60(8): 143-s to
d o m i n a t e surface tension forces in deter- w a s p e r f o r m e d b y W . B. Estell at Sandia
145-s.
mining fluid f l o w in the w e l d p o o l . L i v e r m o r e Laboratories. T h e extensive 11. Heiple, C. R., and Roper, ]. R. 1982.
metallography w a s d o n e b y P. A . Kneale. Mechanism for minor element effect on GTA
Conclusion Their help w a s greatly a p p r e c i a t e d . fusion zone geometry. Welding journal 61
(4):97-s to 102-s.
T h e a d d i t i o n of small c o n c e n t r a t i o n s of References 12. Heiple, C. R., and Roper, ). R. 1982.
a surface active element (Se) t o 21-6-9 Effects of minor elements on GTAW fusion
stainless steel dramatically increased the 1. Bennett, W . S., and Mills, C. S. 1974. zone shape. Trends in welding research in the
CTA weldability studies on high manganese United States, ed. S. A. David: pp. 489-520.
d / w ratio of a severely d e f o c u s e d ,
stainless steel. Welding journal 53 (12):548-s to Metals Park, Ohio: Am. Soc. for Metals.
d e c o u p l e d laser w e l d . Similar, b u t small- 553-s.
er, shape changes w e r e o b s e r v e d w i t h a 13. Allen, B. C. 1972. The surface tension of
2. Heiple, C. R., Cluley, R. )., and Dixon, liquid metals. Liquid metals — chemistry and
defocused electron beam w e l d . The R. D. 1980. Effect of aluminum on CTA weld physics, ed. S. Z. Beer: pp. 161-212. M. Dek-
shape changes in the laser w e l d particu- geometries in stainless steel. Physical metallur- ker, Inc.
larly w e r e v e r y similar t o those o b s e r v e d gy of metal joining, eds. R. Kossowsky and
14. Park, K., and Walter, W . F. 1979. Metal
previously f o r G T A w e l d s w h e n surface M. E. Clicksman, pp. 160-165. The Metallurgi-
reflectance changes during intense laser irradi-
active elements, including Se, w e r e cal Society —AIME.
ation. Applications of lasers in materials pro-
a d d e d t o 21-6-9. 3. Makara, A. M „ et al. 1977. The effect of cessing, E. A. Metzbower, ed., pp. 21-31.
refining on the penetration of metal in arc Metals Park, Ohio: American Society for Met-
T h e o b s e r v a t i o n that Se p r o d u c e s sim-
welding. Automatic Weld. 30(9): 1-3. als.
ilar shape changes in G T A w e l d s and a 4. Savage, W. F., Nippes, E. F., and Good-
d e f o c u s e d laser w e l d strongly supports 15. Heiple, C. R., Stagner, R. J., and Aden,
win, G. M. 1977. Effect of minor elements on R. |. 1980. Unpublished research.
the surface tension d r i v e n fluid f l o w fusion zone dimensions in Inconel 600. Weld-
16. Fihey, ). L, and Simoneau, R. 1982.
m o d e l f o r t h e origin of m i n o r element ing lournal 56(4): 126-s to 132-s.
Weld penetration variation in GTA welding of
effects o n G T A w e l d p e n e t r a t i o n . Clearly 5. Oyler, G. W., Matuszesk, R. A., and Carr, some 304L stainless steels. Int. conf. on weld-
electromagnetic a n d possible impurity- C. R. 1967. Why some heats of stainless steel ing tech. for energy applications, Catlinburg,
arc interactions play n o role in the d e f o - may not weld. Welding journal 46(12):1006- Tenn.
1011.
cused laser w e l d ; h o w e v e r , surface t e n - 17. Brimacombe, |. K., and Weinberg, F.
6. Martin, D. C. 1955. loining and finishing 1972. Observations of surface movements of
sion effects are likely t o b e similar in the
of zirconium. The metallurgy of zirconium, liquid copper and tin. Metall. Trans. 3:2298-
t w o types o f w e l d pools. eds. B. Lustman and F. Kerze, |r.: pp. 307-320. 2299.
Negligible changes in w e l d p o o l p e n e - New York: McGraw-Hill.
18. Mills, G. S. 1977. Analysis of high man-
tration or shape o c c u r r e d w h e n laser o r 7. Linnert, G. F. 1967. Weldability of austen- ganese stainless steel weldability problem.
e l e c t r o n b e a m w e l d s crossed S e - d o p e d tic stainless steel as affected by residual ele- Welding journal 56:186-s to 188-s.
zones, if w e l d p e n e t r a t i o n w a s by a ments. Effects of residual elements on proper-
19. Mills, G. S. 1979. Fundamental mecha-
k e y h o l e m e c h a n i s m . Surface tension gra- ties of austenitic stainless steels, publication no.
nisms of penetration in GTA welding. Welding
418:105-119. Philadelphia: Am. Soc. for Test-
dients, t h e r e f o r e , appear t o play a minor journal 58:22-s to 24-s.
ing and Materials.
role, if any, in d e t e r m i n i n g the d e p t h a n d 20. Mosio, T., and Leinonen |. 1980. The
8. Patton, B. E. et al., 1974. The weldability influence of minor elements on the welding
stability of the k e y h o l e .
of structural steels after refining by remelting. arc and penetration in austenitic stainless steel
Automat. Weld. 27(6):1-4. welding. Arc physics and weld pool behavior:
Acknowledgments 9. Ludwig, H. C. 1957. Arc welding of pp. 285-87. Cambridge, England: The Welding
This w o r k w a s p e r f o r m e d u n d e r c o n - Institute.
tract for t h e U.S. D e p a r t m e n t of Energy,
T h e V a r e s t r a i n t T e s t , o r o n e of i t s v a r i o u s m o d i f i c a t i o n s , is t h e m o s t u t i l i z e d w e l d a b i l i t y t e s t f o r
e v a l u a t i o n of h o t c r a c k i n g s e n s i t i v i t y . T h i s m o n o g r a p h p r e s e n t s t h e e x p e r i e n c e of s e v e r a l r e s e a r c h e r s in
t h e i r u s e of t h e V a r e s t r a i n t T e s t . It is n o t i n t e n d e d t o b e a s t a n d a r d i z a t i o n d o c u m e n t , b u t a u t i l i z a t i o n
guide.
P u b l i c a t i o n o f t h i s r e p o r t w a s s p o n s o r e d b y t h e S u b c o m m i t t e e o n H e a t R e s i s t a n t A l l o y s of t h e H i g h
A l l o y s C o m m i t t e e of t h e W e l d i n g R e s e a r c h C o u n c i l .
T h e p r i c e of W R C B u l l e t i n 2 8 0 is $ 1 0 . 0 0 p e r c o p y , p l u s $ 3 . 0 0 f o r p o s t a g e a n d h a n d l i n g ( f o r e i g n —
$ 5 . 0 0 ) . O r d e r s s h o u l d be s e n t w i t h p a y m e n t t o t h e W e l d i n g R e s e a r c h C o u n c i l , 3 4 5 East 4 7 t h St., N e w
Y o r k , NY 1 0 0 1 7 .
W E L D I N G RESEARCH S U P P L E M E N T I 7 7 - s