03-12-2021 Online Jee Advanced Question Revesion Model P+ C + M

Name ................................
ONLINE JEE ADVANCED REVISION MODEL

Batch.................... Roll No. ...............
UNIT 1
03-12- 2021
21W
/JEE ADV./TP/[I1] PHYSICS+ CHEMISTRY+ MATHS Batch : Lt 22 All Residential & Hybrid
Time : 3hrs Max. Mark : 225

PHYSICS
Section I - Straight objective type (3, –1)
1.
2.
3.
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/JEE ADV./MOD/[I1] 2 I/MODEL
4.
5.
Section II - One or more than one correct (4, -1)

Full marks: +4- If only the bubble(s)corresponding to all the correct options(s) is(are) darkened.
Partial Marks:+1 - For darkening a bubble corresponding to each correct option
6.
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7.
8.
9.
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10.
Section III - Integer type question (4, 0)

The answer to each question is a single digit integer ranging from 0 to 9 both inclusive.Each
questions carries +4 marks for correct answer 0 marks for each wrong answer.
11.
12.
13.
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14.
15.
Section IV- Numerical type question (4, 0)

The answer to each question is a NUMERICALVALUE. Each questions carries +4 marks for correct answerand 0 marks for
all other cases. For each question, enter the correct numerical value (in decimal notation, truncated/rounded-off to the
second decimal place; eg. 6.25, 7.00, 30.27, 127.30, 0.60)
16.
17.
18.
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19.
20.
CHEMISTRY
Section I - Straight objective type (3, –1)
21. 17.00 mg of a compound made of C, H and O was burned in excess of oxygen and it was found that
49.50 mg of CO2 and 13.50 mg of H2O were produced. The minimum number of atoms in 1 molecule of
the compound is :
A) 19 B) 20 C) 21 D) 22
22. The smallest anion is :
A) F B) O2 C) H D) Cl
23. The IUPAC name of the following compound is
C
OMe
Br
A) 3-bromo-1-methoxycyclohexanone B) 4-bromo-1-methoxycyclohexanone
C) methyl-3-bromocyclohexanoate D) methyl-3-bromocyclohexanecarboxylate
24. What is the principal quantum number of the highest energy level for which the lines in the Balmer series of
emission spectra of atomic hydrogen will just be resolved by a spectrometer of resolving power

 8 103 ?
d
A) 30 B) 40 C) 50 D) 60
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25. The IUPAC name of the following compound is
H C CH CH CH2 COOH
CH3 CH3
A) 1-formyl-2,3-dimethylpentan-5-oic acid B) 5-formyl-2,3-dimethylpentanoic acid

C) 4-formyl-3-methylpentanoic acid D) 2-(carboxymethyl)-3-formylbutane
Full marks: +4- If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
26. Which of the following statements are correct ?
 2
A)  O(g)  2e  O(g)  is an endothermic reaction
 1
B)  O(g)  e  O(g)  is an exothermic reaction
C) IE1 of Al < IE1 of Si

D) f- orbitals provide the largest screening effect for a given n value
27. The following wave function of an H-like species refers to nth excited state. The possible value(s) of
n is/are :
Zr
1 3/ 2
 Z  2  Zr  e2
4 2
A) 1 B) 2 C) 3 D) 4
28. Which of the following is (are) the correct IUPAC name(s) of the compound :
O O O
CH3 C C C CH3
A) 1,2,3-trioxopentane B) 1,2,3-triformylpentane
C) Pentane-2,3,4-trione D) 1,3-dimethylpropan-1,2,3-trione
29. Which of the following statements are correct ?
A) Spin-magnetic moment of an atom is given by   n  n  1 B.M., where n is the number of unpaired

electrons.
B) Lyman series of hydrogen atom lies in visible region of electromagnetic spectrum.
C) The wavelengths of different series in hydrogen spectrum do not overlap.
D) Bohr’s model of hydrogen atom could not explain Zeeman effect.
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30. Select the incorrect statements :

A) Over a boundary surface, value of probability density is constant for an orbital.
B) Probability of finding an electron is 100 % in an orbital.
C) Number of angular nodes in an orbital is n-  -1.

D) For 1s orbital, the probability density of finding an electron is minimum at the nucleus.
The answer to each question is a single digit integer ranging from 0 to 9 both inclusive. Each
31. How many of the following statements are correct ?
a) The highest principal quantum number (n) of any electron in ground state of Palladium (Z = 46) is 4.
b) Not considering the electronic spin, if the degeneracy of ground state of H atom is 1, then that of the 3rd
excited state of H ion is 2.
c) A maximum of two electrons in an atom can have the same set of four quantum numbers.
d) The extra stability of half-filled and completely-filled subshell is due to their smaller exchange energy.
e) Caesium is a solid at 50 degree Celsius.
f) I E1 of N > IE1 of O
32. How many of the following orbitals are degenerated with 4pz orbital in a single electron atom in absence of
electric and magnetic field ?
[3px, 3py, 3pz, 4s, 4px, 4py, 4dxy, 5s, 5pz]
33. How many of the following are matched with their correct IUPAC names ?
COOH
a)  Cyclopropanecarboxylic acid
CHO
Br
b)  1-bromo-3-methylcyclohexane-2-carbaldehyde
CONH2
c)  Cyclohexanecarbamide
F
F
d)  2,3-difluorocyclohexene
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Cl
e)  1-fluoro-2-bromo-4-chlorocyclohexane
Br
F
34. How many of the following orbitals have nodal planes :
3d , 4d , 4d , 3s, 2pz , 4p y , 5s, 5d 2 , 1s 

xy z2 x 2  y2
 z 
35. A mixture of MO and M2O3 when heated in air, gains 36.50 % in weight. Both MO and M2O3 gets
converted to M2O7 when heated in air. The molar mass of M is 64 g. What is the percentage of MO
present in the original mixture ?
The answer to each question is a NUMERICAL VALUE. Each questions carries +4 marks for correct
answer and 0 marks for all other cases. For each question, enter the correct numerical value (in decimal
notation, truncated/rounded-off to the second decimal place; eg. 6.25, 7.00, 30.27, 127.30, 0.60)
36. The binding energy of an electron in the ground state of He atom is 25 eV. Find the energy (in eV) required
to remove both the electrons. (Given that the total energy of the electron in the ground state of an H atom
is -13.6 eV)
1
37. Mole fraction of solute in a solution (originally) is . Now if 50 % of the solute molecules dissociate into
n
4
two pairs and remaining 50 % get dimerised, new mole fraction of solvent = , find the value of n.
5
38. If the radiation corresponding to the second line of “Balmer series” of Li 2 ion, knocked the electron
from the 1st excited state of H atom, what is the kinetic energy of electron in eV ? (Given that the energy
of an electron in the ground state of H atom is - 13.6 eV)
39. The molar mass (in g/mol) of the compound with the IUPAC name “Hexachlorobenzene” is : (Atomic
masses : H = 1, C = 12, Cl = 35.5)
40. The number of elements (whose atomic numbers are listed) among the following, which lie in s-block, is :
i) Z = 40 ii) Z = 31 iii) Z = 24 iv) Z = 88
MATHEMATICS
Section I - Straight objective type (3, -1)
 x  b  x  c    x  c  x  a    x  a  x  b  , a  b  c
41. Consider the function f  x  
 b  a  c  a   c  b  a  b   a  c  b  c 
Then the number of solutions of f(x) = 1 is:
A) 1 B) 0 C) infinite D) 2
42. Z1, Z2 and Z3 are such that Z12  Z 22  Z32  Z1 Z2  Z2 Z3  Z3 Z1 and 2Z1  Z2  Z3  8 3
Then area of triangle formed by Z1Z2 and Z3 is
A) 16 3 B) 12 3 C) 8 3 D) 9 3
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43. The inequality cos Z  sin Z  0 represents
A) region between concentric circles B) region between straight lines with slope 
C) region between a sine curve and x axis D) region between rectangles with same centre
2
44. Sum of the roots of the equation  x   x  2x  3  0 is.
A) 2 B) 4 C) -2 D) -4
45. What is the value of ‘a’ for which g  x   a  x  1 and f  x    x  4  x  6  has exactly 3 roots.
A) 8  45 B) 6  35 C) 6  35 D) 8  45
Full marks: +4- If only the bubble(s)corresponding to all the correct options(s) is(are) darkened.
 z1  z 2 
. Then arg  z  z  can be
2020
46. z1, z2, z3 z4 are any four different roots of the equation z 2020   z  2020 
 3 4
A) 0 B)  C)  / 2 D)  / 4
47. Consider the region of complex numbers Z given by the set S where
  z z  10   10  
S  Z  0 :0  Re    1, 0  lm   1, 0  Re   1,0  lm    1 Then which is/are correct
  10   10  z z 
25
A) The area of the region is  6   square units
2
B) Minimum value of Z equals 5 2
C) Maximum value of Z  10i equals 10 2
 z  10 
D) arg is  only for two values of Z.
 z  10i 
48. Let p and q are complex numbers such that p  q  1 . If Z1 and Z2 are the roots of Z2  pZ  q  0 ,
then which of the following is/are correct?
A) z1  1 and z 2  1 B) z1  1 and z 2  1
C) z1 z 2  1 D) Exactly one among z1 and z 2  1 .
49. Let arg  Z  2i   3  / 4, arg

 z  3  3 2  3i   
describe two curves in the complex plane. Then
 z  3  3 2  3i   2
which of the following statements are WRONG:

A) They have exactly one point of intersection B) They do not intersect
C) They intersect at 1 + i or (1,1) D) They intersect exactly at two points
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50. m and n are real roots of ax 2  bx  c . The roots of equation
m n
 4a  2b  c  x 2   4a  b  2c  x   a  b  c   0 are of the form
m 
and
n 
.
 m   and n    Then:
A)   1 B)   2 C)     4 D)     2
The answer to each question is a single digit integer ranging from 0 to 9 both inclusive.Each
1 i
51. Let Z  then the value of  Z1  Z 4  Z9  ......Z144  is kZ. Find the value of k.
2
33 4
52. ,  are roots of x2-3x+4=0 then find the value of 2
   2  ?
 4
53. What is the value of ‘t’ such that one root is the square of the other root of the equation
X 2   t 2  5t  16  x   t 3  7t 2  25t  39   0 ?
54. Let f(x) be a quadratic equation with real coefficients and f  0   f  2   f  4   f  6   4 . Then value
of f  3  
55. a cos  sin 3   b sin 4  csin 2  0 . Then find the value of a+b-c. (a,b and c are smallest possible
positive integers.
1
z
(hint: sin  z where
z  e i )
2i
The answer to each question is a NUMERICAL VALUE. Each questions carries +4 marks for
correct answer and 0 marks for all other cases. For each question, enter the correct numerical
value (in decimal notation, truncated/rounded-off to the second decimal place; eg. 6.25, 7.00,
30.27, 127.30, 0.60)
56. If complex numbers a,b and c are the vertices of a triangle ABC (acute angled) taken in anticlockwise
direction and d is the circumcentre. Then  d  a  *sin 2A   d  c  *sin 2C  2k sin 2B . Find the value
d  b d  b
of k.
2
57. If r1 and r2 are the maximum and minimum distances of a point on curve 10 Z  3i  Z2  Z2   16  0
and origin then r1  r2  ?
58. Find the radius of the circumcircle formed by the complex numbers 3  4i, 2 6  i and 2  21 .
2i
59. If Z1 and Z2 are two complex numbers such that Z12  Z 22  Z1  Z 2  , Then value of Re  Z1   ?
3
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60. Let a,b,c and m  R  . The maximum possible value of m (INDEPENDENTof a, b and c) for which
atleast one of the following equations: ax 2  bx  cm  0, bx 2  cx  am  0, cx 2  ax  bm  0 have real
roots is:
Name ................................
ONLINE JEE ADVANCED REVISION MODEL
Batch.................... Roll No. ...............
UNIT 1
03-12- 2021
21W
/JEE ADV./TP/[I1] PHYSICS+ CHEMISTRY+ MATHS Batch : Lt 22 All residential & Hybrid
PHYSICS
1. A 7NSD  10VSD
 IVSD  .7NSD  .7mm
from given data the vernier reading looks like
from figure x = y -z= 3 × 1mm -4×.7 mm = 3- 2.8 = .2mm

 L  9  .2  9.2mm
mdv mvdv
2. B   bv 
dt dx
x 0
  bdx   mdv  bx  mvo ; mvo
x
0 v0 b
3v20  u2 sin  
3. C Range for Ist projectile is R1   
2g  g 
3V02  1  3v 20  1 
but R 2  e1R1   ; R 3  e1e 2 R 1   
2g  4  2g  9 

3v 20  1 1 
  Ri  1    ...... 
i 1 2g  4 9 
x 3 x5
We know sinx = x    ........
310 510
also roots of their equation are 0, , ,  2 ........
 x 2  x 2  x2 
 we can write sin x  x  1  2 
1  2 
1  2 
........
   4  9 
 1 1 1 
from this coefficient of x3 is   2  2  2  ....... 
  4 9 
2
1  1 1 1   1 1  
    2  2  2  ....   ;   1    .....  
6   4 9   4 9  6
This is a very famous and beautiful equation.
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4. D
mg sin   F cos   f
mg cos   Fsin   N
Fcos   mg sin   f
Clearly for any given  F is minimum when f is max  f  N
 Fcos   mg sin   mg cos   F sin 
mg  sin    cos  
F
cos    sin 
mg  sin    cos   1   2
 F min 
1  2
5. B 2v 20
voT 
g
2v
T o
g
1 2Vo 1 4v02
 VB T  gT 2   h ; VB  g 2  h
2 g 2 g
dh 2V0  dh  dh gh
VB  ;   Vo    h ;   Vo
dt g  dt  dt 2Vo
gt 2V gt
 he  Vo  o e 2Vo  C
2Vo g
t 0 h0
 gt
2V02  2V

h  1  e o 
g   

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6. A,C
F.B.D of A
for equillibrium f  mg sin 
when  is max f is max  f  s N
s mg cos   mg sin 
h
s  tan   ; h  s R
R

Work required = mgh com  ms 2 R 4g
12
System is in unstable equillibrium due to maximum potential energy.
7. B,C
Consider the trajectory of the sailor at any instant when he is at any instant when he is at (x,y) , set
distance from P = r1, distance to line x = 100 is r2, then clearly.
dr1 dr2
4  4 cos   
dt dt
r1 r2
Integrade   dr   dr
1 2  r1  r2
100 100
 trajectory is a parabola with focus P and directerix x= 100

2
ie,  y  100   200  50  x 
8. A, D Equate LHS and RHS dimension x is dimensionless in ex, unless otherwise specific.
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9. A, C
at x, y) we draw the enlarged figure
2
2 2  dy 
Clearly dl   dx    dy  ; dl  dx 1   
 dx 
but dl  udt  u is cons tan t 
 dy 
 udt  dx 1  cos 2 x   cos x 
 dx 
dt 1
  t1  x   1  cos 2 x
dx u
3
  dy 2  2
 1    
u2  dx  
a , R
R d2y
dx 2
10. A, B, C, D
Where a body breaks off a plane, it means that the contact loses and hence equate normal force
zero in these situation.
xy  z
11. 6  ; log   log  xy  2   log  xz  y 
xz  y
1 1 1
d   xdy  ydx  dz   2  zdx  xdz  dy 
2 xy  2 x y
Substitute value for x, y, z
1 1 3dy  3dz 3
 2dy  4dx  dz    4dx  2dz  dy     dy  dz 
4 4 4 4
to maximize put dy = .04, d2 = .04
100d
 6

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12. 1
by shifting origin eqn. of trajectory

hy   x 2 ; x  ky
VB 2 kh 2
  
VSH 2kh  kh 2 1
By a little math and logic, rigorous calculations on be simplified.
13. 8
Consider a small element in the belt.

d Rdv 2
2T N ; N  Td  v 2 d
2 R
 
2 2
  T  V  cos d
2
  N cos  
 
2 2
 Fne    8  4   2  8N
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14. 5
dx
 u cos   Vr  u cos   ky
dt
y t
dy
 u sin  ;  dy   u sin  dt
dt 0 0
dx
y  u sin t ;   u cos   ku sin t
dt
T
0 2
 dx 
0
 u cos   ku sin  t dt
0
by symmetry drift will be zero at mid point at time T/2

u cos T ku sin T x 4 cot  4
  ; T  5
2 4 2 k 0.8
15. 9 Let coofficient of friction be  then, at angle  we have
dt  2Rg.sin d  rRg cos d   1

2
 dT  0    1  net tension is 0
0
also from (1)

dT
 Rg  sin   cos  
d
dT
  0 when   45o
d

4
 Tmax   Rg  sin   cos   
0

2  1 Rg
 T max   
2  1  .9  10   
2 1  9
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16. 6.6 Rs average = 5

.2  .2  .2  .2  0 .8
 R s average  
5 5
Rs .8 M .4
 ; 
Rs 25 M 4
C 1  M Rs  1  .8 
Clearly       .1  
C 2 M Rs  2  25 
C 1  .8  100  1
 100   10    10  4  .8   5  1.6  6.6
C 2 25  2
17. 2.82 - 2.83
gx 2
2 
Equation of projectile is y  x tan   1  tan 2     1
2u
dy
for a particular x, maximum y is when d  tan    0
u2 u 2 8x 2
 tan  
gx
;  y max  
2g 2u 2
 put tan  in 1 
u 2 gx 2
 can on can hit when y  
2g 2u 2
Put y = 250 , u = 100, g = 10
1000 2
  500 2  x  500 2 ;  T  2 2
500
18. 1.55 - 1.56
dp 2  7  t 14t
Force in S1   
dt 9 9
14
at t = 1 F 
9
as force is frame independant
14
F in S2 = F in S1 =
9
 a2  b2  5  32  dI
19. 10 I   80 ; as actual I  80, is positive error
2 2 I
da
also a = 4  .4, b  4 but a  b ;  is negative error
d
dI dm 2ada
also we have  
I m a 2  b2
positive negative
dm
for equality is positive and to maximize the error da = 0 (negative term = 0)
m
dI dm .5 dI
    .1 ; 100  10%
I m 5 I
21W
20. 7.77 - 7.78
T    90 T  45
aA  
9 9
27  45 180  T
aB  ; ac 
9 18
 T.a  0
2T a B  Ta A  Ta c
4T  90 T  45 180  T 5T  135 180  T 450
   ;  T
9 9 18 9 18 11
450
but putting T   a A   ue  not possible 
11
uT  90 180  T
 a A 0 ;  
9 18
 T  40
140 70
a c  
18 9
CHEMISTRY
12
21. D Mass of carbon =  49.50  13.5 mg
44
2 13.5
Mass of hydrogen =  13.5  mg
18 9
 13.5  135
Mass of O = 17  13.5    17   2 mg
 9  9
 13.5 
13.5  
9  2
Number of moles : C : H : O is : :  9 :12 :1
12 1 16
Empirical formula is C9H12O1  minimum 22 atoms
22. A The smallest anion is F and not H . The radius order of anions is F  Cl   Br   H   I .
e
The exception in the size of H is because this is the only anion with ratio = 2.
p
23. D
21W

24. B Since  8  103 , n is very large.
d
Let  n denote the emission wavelength of n  2 (Balmer series)
hc 1 1 
 13.6   2 
n 4 n 
hc 1 1 
 13.6   
 n 1  4  n  1 2 
 
 1 1   1 1 
hc     13.6  2  
2

 n 1  n   n  n  1 

     13.6  2n  1
 hc  n 2 n 1     n   n 1 
  n2 n 1 2
 n   
hc.  13.6  2n   n 1  n 
 . n  2n  1  2n 
n n4  
hc   13.6  2 hc
  
n n3 1 1 
13.6   2 
4 n 
 2
   1 1  1 
n 1  4  2   4 
n3  
4  n  
 n 3  8  8 103    d 
 n  40
25. C When a functional group is treated as a substituent (ie, if a functional group with a higher priority
is already present), its C-atom does not form part of the parent carbon chain (exception : ketone
groups as substituents)
26. A, B, C s-orbitals provide the largest screening effect for a given n value.
27. A The wave function is independent of angle, which implies that it belongs to the spherically sym-
Z
metric s orbital. Further, it has only one radial node at r  which means n -  - 1 = 1
2
 n = 2 (as  = 0). So, it is 2s orbital, which is the first excited state. So, here n = 1.
28. C Ketone group is not a ‘substituent’ here. So, option (A) is wrong. (Ketone is the only functional
group here).
21W
29. D Option (A)    n  n  2  B.M
Option (B)  Lyman : UV region

Option (C)  For hydrogen spectrum :
Lyman & Balmer  No overlap
Balmer & Paschen  No overlap
Paschen & Brackett  Overlaps
All subsequent series overlap

Option (D)  True
30. B, C, D
(A)  True
(B)  It is about 90 to 95 % for an orbital.
The probability is 100 % only it we consider the whole infinite space.
(C)  No. of angular nodes = 
(D)  Let the radial wave function be denoted by R.
For s orbitals,
the radial probability density R2 is maximum at the nucleus (r = 0). But, the radial probability,
which is 4r 2dr.R 2 is zero when r = 0.
31. 2 a & f are correct
(a) pd   Kr  4d10 5s0
(b) Energy of an electron in a single electron system depends only on the value of n.
But, energy of an electron in a multiple electron system depends on both n &  .
So, the third excited state in H atom refers to n = 4.
But, the third excited state in an H ion refers to 3s (1s < 2s < 2p < 3s). Since the s subshell has
only 1 orbital, degeneracy is 1.
(c) See Pauli Exclusion Principle
(d) It is due to their larger exchange energy
(e) The melting point of Cs is 302 K [see NCERT]
(f) True
32. 4 Energy depends only on the value of n (single electron system). So, 4s, 4px, 4py & 4dxy only.
33. 1 (a)  correct
(b)  2-Bromo-6-methylcyclohexane-1-carbaldehyde
(c)  Cyclohexanecarboxamide
(d)  1,6-difluorocyclohexene
(e)  2-Bromo-4-chloro-1-fluorocyclohexane
21W
34. 4 d orbitals do not have nodal planes. They have nodal “cones”. So, the correct orbitals are
z2
3d xy , 4d x 2  y 2 , 2p z , 4p y .
35. 1 Let the total mixture be of mass 100 g.
MO  x g Molar mass of MO  80
M 2O3  100  x  g Molar mass of M 2O3  176
Finally we get  M 2O7  136.5 g Molar mass of M 2O7  240
The no. of M atoms is conserved.

So,
(amount of M in MO) + (amount of M in M2O3) = (amount of M in M2O7)
x 100  x   2 136.5  2
 
80 176 240
 x 100  x  1 273
    
 10 11  8 240
273
1000  x   880
240
 x 1 g
1
Percentage of MO =  100  1%
100
36. 79.40 When one electron is removed, the remaining atom is hydrogen - like atom with Z = 2.
So, total energy needed = 25 + (13.6 × 22) = 25 + 54.4 = 79.40 eV
37. 6.00 Let moles of solute = a
Moles of solvent = b
a a 1 5a
New no. of moles of solute = 2  
2 2 2 4
b 4
Now,   b  5a
5a 5
b
4
a a 1 1
So,   
a  b a  5a 6 n
So, n = 6
1 1  1
38. 19.55 KE  13.6  9     13.6   
 4 16  4
13.6  23
  19.55 eV
16
21W
Cl
39. 285.00
Cl Cl  6 C, 6 Cl
Molar mass  6   35.5  12   285
Cl Cl
Cl
40. 1.00 Z = 88 only

MATHEMATICS
f x 
 x  b  x  c    x  c  x  a    x  a  x  16 
41. C
 b  a  c  a   c  b  a  b   a  c  b  c 
f  a   f   b   f  c   1
 The quadratic equation f  x   1  0 has 3 roots
 f  x   1  0 has  roots, ie f(x) =1 is an identity on x
42. A It for 3 complex numbers z 1 , z 2 & z 3
z12  z 22  z32  z1z 2  z 2 z 3  z 3 z1
The complex numbers z1 , z 2 & z 3 are vertices of an equilateral triangle.

z2
z1 z3
 Deduced from the relation 

  
 z 2  z1  ei 3 taken in cyclic order 
 z3  z1 
 z 2  23 
And 2z1  z 2  z 3  8 3 ;  2 z1    8 3
 2 
z 2  z3
a a
3 2
2
z1
3a
 2  8 3 ; a= 8
2
3 2
Area = 8  16 3
4
21W
43. A cos | z |  sin | z | 0
cos | z | sin | z |  
 0  sin  | z |    0
2 2  4
   3   2 11 
|z| t  0,   v  2,3  ........ ; | z | t  ,  v ,  ........
4  4 4   4 4 
|z| cannot be negative
 3   7 4 
 | z |  0,  v  , 
 4   4 4 
 The inequality cos | z |  sin | z | 0 represents region between concentric circles.
2 3 11
4
4 4
44. C  x 2  x  2x  3  0 ;  x 2  x   x   2x  3  0
 x 2   x   3x  3  0 ;  x 2   x   3 1  x 
2
f  x   x  x
solving wing graphical method
g  x   3 1  x 
x=-3
x=1
21W
45. D
For having exactly 3 roots

y = a(x - 1) should be a tangent to y - 1(x-4) (x-6)
ie., a  x  1    x 2  10x  24  has only 1 root
ax  a   x 2  10x  24
x 2   a  10  x   24  a   0
 only 1 root D = 0
2
 a  10   4  24  a   0
a 2  20a  100  96  4a  0
a 2  16a  4  0
196  16
a  8  8  45
2
From graph, we can say 8  45 is extraneous root.
a  8  45
2020
46. A,B Z 2020   z  2020 
2020 2020
taking modulus. z  z  2020
 z   z  2020
 Modulus is always positive or 0
z  z  2020
z satisfies a line parallel to y axis with x = -1010.
 All the 2019 roots of the above equation are of the form -1010 + ki where k 
z1  z 2 k1  k 2
 for any four of them z  z  k  k 
3 4 3 4
 z1  z 2  k1  k 2
arg  z  z   0 or  according to whether k  k is +ve or -ve.
 3 4 3 4
21W
 z
47. A,B,C 0  Re    1  x   0,10
 10 
 z 
0  lm    1  y   0,10
 10 
 10   10 
0  Re    1  0  Re   1
 z   x  iy 
 10   10  x  iy   10x
Re    Re  2 2 
 0 2 1
 x iy   x y  x  y2
0 10x  x 2  y 2  1 x 2

 y 2 is always  ve 
 10   10 
0  lm    1  0  lm  1
 z   x  iy 
 10   10  x  iy  
lm    lm  2 2 
 x  iy   x y 
10y
 0 1 0 10y  x 2  y 2   2 
x 2  y2
2
From (1) x 2  y 2  10x  0  x  5  y 2  25
2
From (2) x 2  y 2  10x  0 x 2   y  5   25
(10i)
z min  5 2
z  10i max  10 2
Area of region = Big square - small square - 2 quarter circle.
25 25 25
 100  25  2  75   6  
4 2 2
21W
48. A z 2  pz  q  0
z1  z 2  p and z1z 2  q
p  q 1
 z1  z 2  z1z 2  1
but z1  z 2  z1  z 2
 z1  z 2  z1  z 2  1  z1 z 2
let z1  z 2 ; z1  z 2  1  z1 z 2  0
z1  01
  z1  1 z 2  1  0  z1  1  0
 z2  1
For z 2  z1 also z 2  1& z 2  1
3
49. B,C,D arg  z  2i    (arc)\
4

 z  3  3 2  3i
arg 
     semi circle 

 z  3  3 2  3i
   2
3  3 2, 3 (3,3) 3  3 2,3
finding pts of intersection

 only 1 pt of intersection.
y=3
x=-1
x  33 2
21W
50. A,B  4a  2b  c  x 2   4a  b  2c  x   a  b  c   0
a  4x 2  4x  1  b  2x 2  x  1  c  x 2  2a  1  0
2 2
a  2x  1  b  2x  1 x  1  c  x  1  0
2
  x  1
2
 2x  1   2x  1 
a    b c  0
 x 1   x 1 
m and n are root of ax 2  ba  c  0
2x  1
m  mx - m = 2x + 1
x 1
(m - 2)x = m + 1
m 1
x   1,   2
m2
i
1 i
51. 6 Z  Z  e4 Z4  e i   1
2
Z  Z4  Z9  Z16  Z25  Z36  Z49  Z64  Z81  Z100  Z121  Z144

 Z   1  Z  1  Z   1  Z  1  Z   1  Z  1  6Z
33 4
52. 1 2
   2  ?
 4
 2  3  4  0,  2  4  3 Also  2  3  4  0
33 33
2
  2
  4 3
2
  2  2  4  4  2  3  4     
4 2
  2       2
33 4 2
2
    2    2  2        2  9  24  1
 4
53. 2 x 2   t 2  5t  16  x   t 3  7t 2  25t  39   0
let roots be  & 
    t 2  5t  16   t 2  4t  13    t  3 
  t 3  7t 2  25t  39   t 2  4t  13   t  3 
   t 3   t 2  4t  13
2    t 2  6t  9  t 2  4t  13 ; 2t  4  t  2
 2   has no real roots  t  2

21W
54. 5 f  0  f  2  f  4   f  6   4
 f  0  f  6  4 f  2   f  4   4
0 6
y=4
2 4
y=-4
 f  x   x  x  6  4
f  x   x 2  6x  4  f  3   5
1
z
55. 7 sin   z
2i
1
z  cos   i sin   cos   i sin 
z
1 1
z z
z  sin  z  cos 
2i 2
3 2
 1  1   z 2  1  z  1 
 z  z  z  z   
z 2  z

cos  sin 3      
 2  zi  16i3
  
 1  1 
16 i3 cos  sin 3    z 2  2  z 2  2  2 
 z  z 
z  cos   i sin  z 2  cos 2   i sin 2 
1
z2 
 z 2  sin 2 
zi
2
 1   1 
16 i cos  sin    z 4  4   z 2  2   2 i sin 4  2  2 i sin 2 
3 3
 z   z 
8i 2 cos  sin 3   sin 4  2sin 2   8cos  sin   sin 4   2sin 2   0 a+b+c=7

21W
56. 0.50
c
b
d a
taking rotation al d  e i 2C  cos 2C  i sin 2C
db
dc
 e i 2A  cos 2A  i sin 2A
db
da* d  c*
 sin 2A  sin 2C
db db
  cos 2C  i sin 2C  sin 2A   cos 2A  isin 2A  sin 2C
 cos 2Csin 2A  cos 2A sin 2C  sin  2A  2C 
 sm  2  A  C    sm  2    B    sin  2  B 
1
 smB; k
2
57. 3 Put z = x + iy
10  x 2  y 2   3i  x 2  y 2  2ixy  x 2  y 2  2 ixy   16  0
10x 2  10y 2  12xy  16  0
5x 2  5y 2  6xy  8  0
Let x  r cos  and y  r sin 
5r 2 cos 2   5 r 2 sin 2   6r 2 sin  cos   8  0
r 2 5 cos 2   5sin 2   6 sin  cos    8  0
8
r2 
5  3sin  2 
2 8 2 8
rmin  1 rmax  4
53 53
rmin  1; rmax  2 r1  r2  3
58. 5 All the complex nos. 3 + 4i, 2 6  i and 2  2i have modulus 5.

 they represent a with circumcentre at origin and radius = 5
21W
2i 2 4
59. 0.70-0.71 z1  z 2   z1  z 2  
3 3
4
z12  z 22  2z1z 2 
3
2i 4 2 i
 2z1z 2  ; z1z 2 
3 3 3 3
z1 + z2 = Purely imaginary.
 z1  x  iy and z 2   x  ik
z1z 2   x  iy   x  i k    x 2  i kx  i xy  ky
2 1 1
  x 2  ky    A  and kx  xy  ky  1
3 3 3x
2i 2
z1  z 2  i  y  k   yk    2
3 3
2 1 1 1
(1) + (2)  2k  3  3x k 
3 2 3x
 2  1  y
1

1
2 3 2 3x
Putting k and y in (A)
1 1
 12x 4  4x 2  1  0  x   x 
2 2
60. 0.25 If at least one of the equations has real roots, then D1  D 2  D3  0
b 2  4 acm  c 2  4abm  a 2  4 cbm  0
a 2  b 2  c 2  4  ab  bc  ca  m
a 2  b2  c2 a 2  b2  c2
m minimum value of 1
4  ab  bc  ca  ab  bc  ca
1
 m
4

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ONLINE JEE ADVANCED REVISION MODEL

Time : 3hrs Max. Mark : 225

Section II - One or more than one correct (4, -1)

Section III - Integer type question (4, 0)

Section IV- Numerical type question (4, 0)

25. The IUPAC name of the following compound is

A) 1-formyl-2,3-dimethylpentan-5-oic acid B) 5-formyl-2,3-dimethylpentanoic acid

C) IE1 of Al < IE1 of Si

A) Spin-magnetic moment of an atom is given by   n  n  1 B.M., where n is the number of unpaired

30. Select the incorrect statements :

C) Number of angular nodes in an orbital is n-  -1.

34. How many of the following orbitals have nodal planes :

3d , 4d , 4d , 3s, 2pz , 4p y , 5s, 5d 2 , 1s 

Then area of triangle formed by Z1Z2 and Z3 is

43. The inequality cos Z  sin Z  0 represents

B) Minimum value of Z equals 5 2

C) Maximum value of Z  10i equals 10 2

C) z1 z 2  1 D) Exactly one among z1 and z 2  1 .

49. Let arg  Z  2i   3  / 4, arg

which of the following statements are WRONG:

50. m and n are real roots of ax 2  bx  c . The roots of equation

and origin then r1  r2  ?

from figure x = y -z= 3 × 1mm -4×.7 mm = 3- 2.8 = .2mm

 trajectory is a parabola with focus P and directerix x= 100

at x, y) we draw the enlarged figure

but dl  udt  u is cons tan t 

by shifting origin eqn. of trajectory

Consider a small element in the belt.

by symmetry drift will be zero at mid point at time T/2

also from (1)

16. 6.6 Rs average = 5

20. 7.77 - 7.78

Let  n denote the emission wavelength of n  2 (Balmer series)

29. D Option (A)    n  n  2  B.M

Option (B)  Lyman : UV region

All subsequent series overlap

31. 2 a & f are correct

(a) pd   Kr  4d10 5s0

The no. of M atoms is conserved.

40. 1.00 Z = 88 only

 The quadratic equation f  x   1  0 has 3 roots

 f  x   1  0 has  roots, ie f(x) =1 is an identity on x

42. A It for 3 complex numbers z 1 , z 2 & z 3

z12  z 22  z32  z1z 2  z 2 z 3  z 3 z1

The complex numbers z1 , z 2 & z 3 are vertices of an equilateral triangle.

 Deduced from the relation 

43. A cos | z |  sin | z | 0

For having exactly 3 roots

ie., a  x  1    x 2  10x  24  has only 1 root

From graph, we can say 8  45 is extraneous root.

0 10x  x 2  y 2  1 x 2

For z 2  z1 also z 2  1& z 2  1

finding pts of intersection

Z  Z4  Z9  Z16  Z25  Z36  Z49  Z64  Z81  Z100  Z121  Z144

let roots be  & 

 2   has no real roots  t  2

z  cos   i sin  z 2  cos 2   i sin 2 