Z. ASTM C1876-19, Bulk Resist

You might also like

Download as pdf or txt
Download as pdf or txt
You are on page 1of 7

This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles

for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

Designation: C1876 − 19

Standard Test Method for


Bulk Electrical Resistivity or Bulk Conductivity of Concrete1
This standard is issued under the fixed designation C1876; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.

1. Scope 2. Referenced Documents


1.1 This test method covers the determination of the bulk 2.1 ASTM Standards:4
electrical resistivity or conductivity of molded specimens or C31/C31M Practice for Making and Curing Concrete Test
cored sections of hardened concrete after immersion in water Specimens in the Field
saturated with a simulated pore solution in order to provide a C39/C39M Test Method for Compressive Strength of Cylin-
rapid indication of its resistance to the penetration of fluids and drical Concrete Specimens
dissolved aggressive ions. C42/C42M Test Method for Obtaining and Testing Drilled
Cores and Sawed Beams of Concrete
1.2 The values stated in SI units are to be regarded as the C125 Terminology Relating to Concrete and Concrete Ag-
standard. No other units of measurement are included in this gregates
standard. If required results obtained from another standard are C192/C192M Practice for Making and Curing Concrete Test
not reported in the same system of units as used by this Specimens in the Laboratory
standard, it is permitted to convert those results using the C1202 Test Method for Electrical Indication of Concrete’s
conversion factors found in the SI Quick Reference Guide.2 Ability to Resist Chloride Ion Penetration
1.3 The text of this standard references notes and footnotes C1556 Test Method for Determining the Apparent Chloride
Diffusion Coefficient of Cementitious Mixtures by Bulk
that provide explanatory material. These notes and footnotes
Diffusion
(excluding those in tables and figures) shall not be considered
C1760 Test Method for Bulk Electrical Conductivity of
as requirements of this standard.
Hardened Concrete
1.4 This standard does not purport to address all of the
safety concerns, if any, associated with its use. It is the 3. Terminology
responsibility of the user of this standard to establish appro- 3.1 Definitions:
priate safety, health, and environmental practices and deter- 3.1.1 For definitions of terms used in this standard, refer to
mine the applicability of regulatory limitations prior to use. Terminology C125.
(Warning—Fresh hydraulic cementitious mixtures are caustic 3.2 Definitions of Terms Specific to This Standard:
and may cause chemical burns to skin and tissue upon 3.2.1 bulk electrical resistivity, n—material property that
prolonged exposure.)3 For specific warning statement see quantifies how strongly the material opposes the flow of
8.1.2. electrical charge when an electric field is applied using
1.5 This international standard was developed in accor- electrodes placed on opposite faces of a test specimen; mea-
dance with internationally recognized principles on standard- sured in units of ohm-meter.
ization established in the Decision on Principles for the 3.2.2 bulk electrical conductivity, n—material property that
Development of International Standards, Guides and Recom- quantifies how strongly the material permits the flow of
mendations issued by the World Trade Organization Technical electrical charge when an electric field is applied using
Barriers to Trade (TBT) Committee. electrodes placed on opposite faces of a test specimen; mea-
sured in units of milli-siemens per meter (mS/m).

1
3.2.2.1 Discussion—Bulk electrical conductivity is the re-
This test method is under the jurisdiction of ASTM Committee C09 on
Concrete and Concrete Aggregates and is the direct responsibility of Subcommittee ciprocal of bulk electrical resistivity.
C09.66 on Concrete’s Resistance to Fluid Penetration.
Current edition approved June 15, 2019. Published Aug. 2019. DOI: 10.1520/
C1876-19
2 4
Annex A in Form and Style for ASTM Standards, www.astm.org/COMMIT/ For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Blue_Book.pdf. contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
3
Section on Safety Precautions, Manual of Aggregate and Concrete Testing, Standards volume information, refer to the standard’s Document Summary page on
Annual Book of ASTM Standards, Vol. 04.02. the ASTM website.

Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States

&RS\ULJKWE\$670,QW O DOOULJKWVUHVHUYHG 7KX'HF*07


1
'RZQORDGHGSULQWHGE\
8QLYHUVLW\RI)ORULGDSXUVXDQWWR/LFHQVH$JUHHPHQW1RIXUWKHUUHSURGXFWLRQVDXWKRUL]HG
C1876 − 19
4. Summary of Test Method shown good correlation with bulk diffusion determined using
4.1 The electrical resistance or conductance of a hardened Test Method C1556 on companion molded cylinders from the
concrete cylindrical specimen conditioned in accordance with same concrete mixtures (4).
this test method is determined on at least two specimens
obtained from cores or cast in cylindrical molds, the ends are 6. Interferences
prepared, the dimensions measured, and then submerged in a 6.1 If this test method is used to compare different concrete
simulated pore solution for at least 6 days, or from time of mixtures, the results can be misleading if certain admixtures
demolding in the case of molded cylinders. While the specimen containing water-soluble ionic compounds, such as calcium
is in the solution, the bulk resistivity or conductivity test device nitrite and calcium nitrate, are present in one of the concrete
is verified over the expected range of resistivity or conductiv- mixtures. Chemical admixtures such as calcium nitrite can
ity. Then the specimen is placed in the test device. In some contribute to a lower electrical resistivity because they increase
testing apparatus, the voltage and current are measured such the conductivity of the pore solution (Note 1). This effect can
that the resistivity or conductivity can then be calculated. In be independent of the overall quality of the concrete because it
other testing apparatus, the resistivity or conductivity is calcu- has been shown in long-term bulk diffusion tests that concretes
lated directly once specimen dimensions are input. with calcium nitrite can perform as well as control mixtures
5. Significance and Use without the admixture and lower conductivity.

5.1 The electrical resistivity of a concrete is the opposition NOTE 1—Similarly, other admixtures containing water-soluble ionic
to the movement of ions under an applied electric field. The compounds might affect the results of this test method. Long-term
chloride ion diffusion tests are recommended if an admixture effect is
electrical conductivity of a concrete is a measure of how suspected. Alternately, this interference can be minimized by expressing
readily the ions in the pore solution can be transported through results as a formation factor (see Appendix X1).
the concrete under an applied electric field (the higher the
conductivity, the greater the rate of transport). The electrical 6.2 Because the test results are a function of the electrical
resistivity or conductivity is a material property that depends resistance or conductance of the specimen, the presence of
upon the pore volume, the pore structure (size and reinforcing steel, metal fibers, or other embedded electrically
connectivity), the pore solution composition, the degree of conductive materials, including some types of aggregates, may
saturation of the concrete specimen, and the specimen’s tem- yield unrepresentative results, as these will result in higher
perature. Concrete mixture characteristics that are known to conductivity than a concrete of similar quality but with no
affect concrete electrical resistivity, as well as resistance to embedded conductive material. The test is not applicable to
chloride ion penetration, include water-cementitious materials specimens containing reinforcing steel positioned longitudi-
ratio, pozzolans, slag cement, the presence of polymeric nally that provide a continuous electrical path between the two
admixtures, air-entrainment, aggregate type, aggregate volume ends of the specimen, and it is not applicable to specimens
fraction, degree of consolidation, curing method, and age. containing discrete metallic fibers.
5.2 The bulk electrical resistivity of concrete is the inverse 6.3 Leaching of ions from the pore solution of concrete is
of its bulk electrical conductivity. Bulk electrical conductivity known to affect measured resistivity or conductivity values.
can also be measured by Test Method C1760, which uses the Even standard curing in water saturated with calcium hydrox-
apparatus described in Test Method C1202. This test method, ide can influence the resistivity of the solution inside the pores
however, uses apparatus specifically designed to measure bulk of the concrete as potassium and sodium hydroxides are
conductivity or bulk resistivity. leached out. As such, concrete cylinders and cores are im-
5.3 The purpose of conditioning in a simulated pore solution mersed in simulated pore solution for at least 6 days prior to
is to bring the specimen to a level of near complete saturation testing.
of the capillary and gel pores. When comparing two different 6.4 The level of saturation of the concrete has a major
concrete specimens, it is important to condition both specimens impact on resistivity or conductivity because the electric
as close as possible to a comparable saturation state, using the current is mainly conducted through the liquid in the pores.
same solution for conditioning, so that values can be compared Achieving full saturation is difficult, so while not perfect, the
in a meaningful way. This is particularly true for using the conditioning procedures used in this test method provide a
measured resistivity or conductivity, along with other methodology for achieving a high and reproducible level of
information, to estimate the diffusivity. saturation without allowing excessive leaching of alkalis.
5.4 The bulk electrical resistivity or conductivity of con- 6.5 Because concrete has a capacitive component, its elec-
crete can provide a rapid indication of its resistance to chloride trical response is characterized by a magnitude and a phase
ion penetration and resistance to penetration of other fluids. difference that is a function of the AC frequency. This may
Resistivity or conductivity measurements have shown good have an effect on the measured test result. The desired quantity
correlations with other electrical indication tests including Test is the magnitude of the impedance that is measured at the
Method C1202 (1, 2, 3).5 Bulk electrical resistivity results have frequency that yields the minimum phase difference between
the applied voltage and the measured current; that is, the
5
The boldface numbers in parentheses refer to the list of references at the end of system is behaving most like a resistor. A number of commer-
this standard. cial devices operate at a single fixed frequency, typically

&RS\ULJKWE\$670,QW O DOOULJKWVUHVHUYHG 7KX'HF*07


2
'RZQORDGHGSULQWHGE\
8QLYHUVLW\RI)ORULGDSXUVXDQWWR/LFHQVH$JUHHPHQW1RIXUWKHUUHSURGXFWLRQVDXWKRUL]HG
C1876 − 19
between 10 Hz and 1 kHz. The degree to which a limited with two conductors made of 18 AWG stranded copper wire
frequency range impacts the result has been found to be no have been found to be satisfactory. The ends of the cables shall
more than 5 % (5). be suitable for connecting to the test device and the plate
6.6 Electrical resistivity or conductivity is temperature electrodes.
dependent, so perform all tests on concrete specimens condi- 7.4 Verification Cylinder, composed of a hollow tube with a
tioned within 62 ºC (5, 6). diameter of 100 mm and length of 200 mm, made of electri-
6.7 The thin sponges, saturated with conductive fluid, that cally non-conductive, rigid material and fitted with electrically
connect the test specimen to the plate electrodes, can provide a conductive stainless steel plates at each end. Inside the hollow
small amount of resistance (7). However, if both electrodes are cylinder, at least five precision resistors with tolerances no
clamped tightly to the test specimen, the resistance is minimal greater than 60.1 % of their nominal value shall be connected
and can be neglected. in parallel between the two end plates and provided with a
switch so that only one resistor is connected at any one time
7. Apparatus (Fig. 1). The resistors shall be distributed over the range of 10
7.1 Bulk Resistivity or Conductivity Test Device, capable of ohm to 100 kohm in order to cover the potential range of
supplying an ac voltage across the entire cross-section of the resistivity values for various concrete mixtures.
specimen, measuring the current passing through the specimen NOTE 4—It is recommended that at least one precision resistor is used
to three significant digits, and measuring the voltage drop per decade, such as 12 ohm, 120 ohm, 1.2 kohm, 12 kohm, and 120 kohm
across the ends of the specimen to three significant digits. The resistors or using other resistors that cover the expected range of concrete
test device shall meet the verification requirements in Section mixtures to be evaluated.
11. 7.5 Sponges, or other alkali-resistant absorbent material
NOTE 2—Several test devices are commercially available, but the with at least the same dimensions as the cross-sections of the
voltage, frequency, and wave form used are different with each device. ends of the test specimen.
Some devices display resistivity or conductivity based directly on speci-
men geometry while others may display the electrical resistance of the 7.6 Specimen Holder, for tests to be conducted horizontally,
specimen. In this test method, different devices may be used as long as sufficiently large enough to support the cylindrical specimen
they meet the verification requirements in Section 11. during testing. The specimen holder shall be made of rigid
7.2 Stainless Steel Electrically Conductive Plate Electrodes, plastic or other similar electrically non-conductive material.
made with at least the same nominal diameter (Note 3) as the
NOTE 5—Two vertically oriented V-notch plates fixed to a base plate
ends of the specimens to be tested and between 6 and 8 mm provides a suitable specimen holder.
thick. Plate electrodes shall be fitted with connectors that allow
connection to the electrical cables. Plate electrodes are permit- 7.7 Non-Electrically Conductive Surface, for tests to be
ted to be larger than the specimen diameter or cross-section. conducted vertically, such as a rubber or plastic base or mat of
at least 3 mm thickness and having a cross-sectional area larger
NOTE 3—Rectangular specimens, such as cubes or prisms, may also be
measured using electrodes of at least the same size as the cross-section to
than that of the plate electrodes. The test device is placed on
be tested. top of this non-conductive mat or base.
7.3 Electrical Cables, for connecting the plate electrodes to 7.8 Ruler, 300 mm to 380 mm in length divided into 1 mm
the test device. Two insulated cables or one insulated cable graduations.

FIG. 1 Schematic of electric circuit inside verification cylinder. Precision resistors are labeled R1 to R5. The switch is labeled S1. The
circuit is connected to plate electrodes at each end.

&RS\ULJKWE\$670,QW O DOOULJKWVUHVHUYHG 7KX'HF*07


3
'RZQORDGHGSULQWHGE\
8QLYHUVLW\RI)ORULGDSXUVXDQWWR/LFHQVH$JUHHPHQW1RIXUWKHUUHSURGXFWLRQVDXWKRUL]HG
C1876 − 19
7.9 Saw, for trimming ends of cores. The saw shall have a rials or their proportions, specimens are permitted to be either
diamond or silicon-carbide cutting edge and shall be capable of 100 mm diameter by 200 mm long molded cylinders or cores
cutting cores without introducing cracks or dislodging aggre- with length to diameter ratio of at least 1. The minimum
gate particles. specimen dimension shall be at least three times the nominal
maximum aggregate size. Obtain two molded cylinders or
8. Reagents and Materials cores for each test.
8.1 Simulated Pore Solution Saturated with Calcium 9.1.1 If testing molded cylinders, prepare specimens in
Hydroxide—Add 7.6 g of dry NaOH, 10.64 g of dry KOH, and accordance with Practice C192/C192M or Practice C31/C31M,
2.0 g of dry Ca(OH)2 to a 1 L container and add deionized whichever is applicable.
water to the 1 L mark. Use reagent grade chemicals conforming 9.1.1.1 Transport field-molded specimens to the laboratory
to the specifications of the Committee on Analytical Reagents in their molds, capped with lids and sealed in plastic bags. If
of the American Chemical Society where such specifications specimens must be shipped, protect them from freezing and
are available.6 from damage in transit or storage.
9.1.2 If testing cores, obtain them in accordance with Test
NOTE 6—Sufficient solution can be made in an 18 to 20 L bucket using
13 250 g deionized water, 102.6 g NaOH, 143.9 g KOH, and 27 g Method C42/C42M.
Ca(OH)2. No correction for purity of reagents is made. 9.1.2.1 After drilling, place cores in separate plastic bags or
NOTE 7—This simulated pore solution has been found to minimize the non-absorbent containers and seal to prevent moisture loss.
potential for leaching of alkalis and calcium hydroxide from the test Maintain cores at ambient temperature. Transport the cores to
specimens and minimize changes to the electrical conductivity of the pore
solution. The conductivity and resistivity of this pore solution has been
the testing laboratory as soon as possible.
found to be 7874 mS/m and 0.127 ohm-m, respectively. Compositions and
conductivities of pore solutions in different concretes and at different ages 10. Specimen Preparation and Conditioning
will vary but it is not practical to match pore solution compositions to 10.1 Specimen Preparation:
those of each concrete being tested.
10.1.1 Remove the molds from molded cylinders, or remove
8.1.1 Bring the simulated pore solution to room temperature transported field-molded specimens from plastic bags, and if
prior to use. necessary, saw cut or grind cylinder ends so that they are plane
8.1.2 Warning—Before using NaOH and KOH, review the and perpendicular to the longitudinal axis for measurement of
following: (1) the safety precautions for using NaOH and length.
KOH; (2) first aid for burns; and (3) the emergency response to 10.1.2 Remove core specimens from plastic bags and saw
spills, as described in the manufacturer’s Material Safety Data cut to obtain specimens with ends plane and perpendicular to
Sheets or other reliable safety literature. NaOH and KOH as the longitudinal axis in accordance with Test Method C39/
well as solutions made with them can cause very severe burns C39M.
and injury to unprotected skin and eyes. Suitable personal 10.1.3 After end preparation, use a ruler to measure and
protective equipment should always be used when making the record two cross-sectional diameters at each end of each
solution and when placing and removing specimens from the specimen, and four specimen lengths taken at 90° to each other.
pore solution. These should include full-face shields, rubber Calculate and record the average diameter (D) and length (L)
aprons, and gloves impervious to NaOH and KOH. Gloves values in meters to the nearest 0.001 m. Calculate and record
should be checked periodically for pin holes. the cross-sectional area in m2. Use the average diameter for
8.2 Conductive Fluid—An electrically conductive liquid is calculating the circular cross-sectional area perpendicular to
applied to sponges and each electrode to ensure electrical the longitudinal axis, to three significant digits.
contact with the surface of the concrete. Follow the apparatus 10.2 Specimen Conditioning:
manufacturer’s instructions regarding the composition and use 10.2.1 After obtaining dimensions, submerge two core or
of a conductive fluid. molded cylindrical specimens in an 18 to 20 L bucket with
NOTE 8—Water saturated with respect to calcium hydroxide has been sufficient simulated pore solution to cover the specimens with
found to be a suitable conductive fluid for saturating the sponges. 35 to 40 mm of solution (Note 9). The simulated pore solution
Alternatively, the simulated pore solution described in 8.1, or a conductive shall be maintained at a temperature of 23.0 6 2.0 °C. Keep
fluid supplied by the manufacturer of the equipment is also suitable. The the specimens submerged for at least 6 days and until time of
use of distilled or deionized water is not recommended due to its low
electrical conductivity. Tap water may be acceptable, if determined to be
testing.
sufficiently conductive, but its use is not recommended. 10.2.2 If more than two specimens are to be conditioned in
one bucket, maintain the same range of volume of solution to
9. Test Specimens volume of specimens as used in 10.2.1.
9.1 Specimen preparation and selection depends on the NOTE 9—The volume of solution surrounding the specimens should
purpose of the test. For evaluation of concrete-making mate- range from two and up to three times the volume of the specimens.

6
11. Verification
Reagent Chemicals, American Chemical Society Specifications, American
Chemical Society, Washington, DC. For suggestions on the testing of reagents not 11.1 Prior to testing concrete specimens on a given day,
listed by the American Chemical Society, see Analar Standards for Laboratory
verify the accuracy of measurements made by the test device
Chemicals, BDH Ltd., Poole, Dorset, U.K., and the United States Pharmacopeia
and National Formulary, U.S. Pharmacopeial Convention,Inc. (USPC), Rockville, over the range of expected values of resistivity or conductivity
MD. using the verification cylinder described in 7.4.

&RS\ULJKWE\$670,QW O DOOULJKWVUHVHUYHG 7KX'HF*07


4
'RZQORDGHGSULQWHGE\
8QLYHUVLW\RI)ORULGDSXUVXDQWWR/LFHQVH$JUHHPHQW1RIXUWKHUUHSURGXFWLRQVDXWKRUL]HG
C1876 − 19
NOTE 10—Use of a verification cylinder allows checking of the bulk 12.4.1 For devices that display conductivity, the difference
resistivity device together with electrodes and sponges saturated with between two successive readings on the same specimen shall
conductive fluid.
not exceed 0.10 mS/m for conductivity equal to or greater than
11.2 Apply conductive fluid to saturate the sponges at each 10 mS/m and shall not exceed 0.05 mS/m for conductivity
electrode of the test device and connect to the end plates of the lower than 10 mS/m.
verification cylinder using the same procedure as that used for 12.4.2 For devices that display resistivity, the difference
testing concrete specimens. Measure the resistance, calculated between two successive readings on the same specimen shall
resistivity, or conductivity values across each of the five not exceed 0.5 ohm-m for readings lower than 100 ohm-m, and
resistors sequentially. Each of the five measured values shall be 1.0 ohm-m for readings equal to or higher than 100 ohm-m.
within 2 % of the certified values provided with the verification Record the average of the final two measurements.
test device except as allowed in 11.2.2. 12.4.3 If the difference between two successive measure-
11.2.1 If verification is not initially achieved, remove the ments exceed the values listed in 12.4.1 or 12.4.2, repeat
verification cylinder, apply more conductive fluid to the measurements until two consecutive measurements do not
sponges, and re-insert the verification cylinder into the test differ by more than these values.
device, using the manufacturer’s recommended procedures. If
the instrument does not read within 2 % of the known values, 13. Calculations
it shall not be used except as allowed in 11.2.2.
13.1 Determine the bulk electrical resistivity in accordance
11.2.2 In cases where not all five verification values are
with the type of test device used:
within 2 % of the certified values, the test device may be used
13.1.1 For devices that measure the current and voltage,
if the range of values obtained on test specimens is between
calculate the bulk electrical resistivity in units of ohm-m using
two verification values that are within 2 % of the certified
Eq 1:
values.
V A
ρ5 · (1)
12. Procedure I L

12.1 Remove the test specimen from the container of pore where:
solution, blot off excess liquid, and transfer to the specimen L = average specimen length, m to the nearest 0.001 m,
holder (see 7.6) or place into a test device designed to hold A = specimen cross-sectional area, m2, to three significant
specimens vertically. To minimize drying of the concrete digits,
surface, do not leave the specimen exposed to air for longer V = voltage, V, and
than 5 min before performing tests. I = current, A.
12.2 Saturate the sponges with conductive fluid and place 13.1.2 For devices that display the electrical resistance of
between the plate electrodes and end surfaces of the specimen. the specimen, calculate the bulk electrical resistivity using Eq
Center the electrodes and sponges on the ends of the specimen 2:
and press the sponges against the end faces of the specimen in ρ 5 RA⁄L (2)
accordance with manufacturer’s instructions.
where:
NOTE 11—To obtain repeatable measurements, sufficient pressure R = electrical resistance of specimen, ohms, and
should be applied to provide firm contact between the electrodes and the A and L = as defined for Eq 1.
specimen. This can be provided using a clamping device, bolts, or use of
a weight of at least 3 kg on top of the top electrode of a vertically oriented 13.1.3 For devices that calculate bulk electrical resistivity
test setup. The mass of a concrete cylinder of 100 × 200 mm nominal using Eq 1, no additional calculation is needed.
dimensions is typically sufficient for use as a weight.
13.2 Calculate the average resistivity for the set of replicate
12.3 Make measurements on the test specimen in accor-
specimens tested in ohm-m and report to the nearest 0.1
dance with the manufacturer’s instructions.
ohm-m.
12.3.1 For test devices with capabilities to measure ac
current at variable frequency, perform tests at 1 kHz, unless 13.3 If required by the specifier of the tests, calculate the
otherwise specified. bulk electrical conductivity by taking the inverse of Eq 1 or Eq
12.3.2 If the test device is designed to display resistivity or 2 and multiplying by 1000 to obtain values in units of mS/m.
conductivity, enter the average specimen dimensions into the
device in accordance with the manufacturer’s instructions. 14. Report
12.4 Record the values after allowing the readings stabilize 14.1 Report the following information:
for 2 to 5 s. For devices that perform the calculations internally, 14.1.1 Source of the core; if removed from a structure,
record the displayed resistivity or conductivity. For devices report the location from within the structure,
that display electrical resistance, record the value of resistance 14.1.2 Identification number of the core or cylinder
in ohms. For other devices, record the voltage in volts, V, and specimen,
current, I, in amperes. Remove the electrodes from the 14.1.3 Type of concrete, including binder type, water-
specimen, reapply the electrodes, and repeat the measurement. cementitious materials ratio, and other relevant data supplied
Make at least two repeat measurements. with specimens, if known,

&RS\ULJKWE\$670,QW O DOOULJKWVUHVHUYHG 7KX'HF*07


5
'RZQORDGHGSULQWHGE\
8QLYHUVLW\RI)ORULGDSXUVXDQWWR/LFHQVH$JUHHPHQW1RIXUWKHUUHSURGXFWLRQVDXWKRUL]HG
C1876 − 19
14.1.4 Description of the specimen, including the average 91-day old concrete mixtures with mean resistivity values
diameter and length to the nearest 0.001 m and the cross- ranging from 66 to 380 ohm-m (7).
sectional area to three significant digits, NOTE 12—The conditioning solution used in the interlaboratory test
14.1.5 Curing history and age of the specimen, if known, program (7) was not the same as used in this test method. Unpublished
14.1.6 If the average of two or more companion cylinders or precision values for tests conducted with the simulated pore solution, as
cores tested at the same age is reported, calculate the average used in this test method, were found not to be greatly affected. Precision
bulk electrical resistivity and report to the nearest 0.1 ohm-m values will be revised when those results are published.
or calculate the average bulk electrical conductivity and report 15.1.1 The single-operator coefficient of variation was
to the nearest 0.01 mS/m, and found to be 4.3 %. Therefore, the results of two properly
14.1.7 The type of test device used, including the operating conducted tests by the same operator on the same concrete
frequency for devices with variable frequency. material at the same age are not expected to differ by more than
12.0 % of their average.
15. Precision and Bias 15.1.2 The multi-laboratory coefficient of variation was
15.1 Precision—A test program was completed with 12 found to be 13.2 %. Therefore, the results of two properly
laboratories using one of the commercially available devices. conducted tests by different laboratories on the same concrete
Tests were conducted on concrete cylinders of 100 × 200 mm material at the same age are not expected to differ by more than
nominal dimensions stored in saturated lime water and using 37.0 % of their average.
thin sponges also saturated with lime water to connect the 15.2 Bias—Because there is no accepted reference material
electrodes to the concrete specimen. Tests were conducted on suitable for determining the bias in this test method, no
seven 28-day old concrete mixtures and twelve 56-day and statement of bias is made.

APPENDIX

(Nonmandatory Information)

X1.1 FORMATION FACTOR degree of hydration, (4) by pore solution extraction and
X1.1.1 Electrical tests of concrete, including Test Method conductivity measurement, or (5) by direct measurement of
C1202 and Test Method C1760, are also influenced by the conductivity with an embedded sensor (8).
conductivity of the pore fluid in addition to the porosity and X1.1.3 The resistivity of the pore solution (ρo) (ohm-m) is
pore connectivity. Only the latter factors, however, are indica- the inverse of pore solution conductivity (S/m). Based on the
tive of the resistance of concrete to fluid penetration. This work reported by Snyder (9), pore solution conductivity can be
interference can be removed by use of the formation factor.
estimated using the on-line calculator by following the link:
X1.1.2 The formation factor is a material property that https://www.nist.gov/el/materials-and-structural-systems-
relates to the pore geometry and connectivity. The formation division-73100/inorganic-materials-group-73103/estimation-
factor can be calculated as the ratio of the resistivity of a bulk pore
body (ρ) to the resistivity of the pore solution in the body (ρo):
F5ρ⁄ρo . The resistivity of the pore fluid can be determined by X1.1.4 If resistivity is measured at a temperature other than
calculation using models based on (1) thermodynamics, (2) a 23.0 6 2.0°C, the measured resistivity must be divided by the
mathematical model (see X1.1.3) based on mixture resistivity of the pore solution at the same temperature in order
proportions, (3) the alkali content of the binder and assumed to obtain the formation factor.

REFERENCES

(1) Hooton, R.D., Charmchi, G., “Adoption of Resistivity Tests for (4) Shahroodi A., Hooton R.D., “Development of Test Methods for
Concrete Acceptance,” ACI Special Publication SP-303, Proceedings, Assessment of Concrete Durability for Use in Performance-Based
Recent Advances in Concrete Technology and Sustainability Issues, Specifications,” Final Report Submitted to Ministry of Transportation
Ottawa, July 2015, pp. 269-279. of Ontario and Department of Civil Engineering, University of
(2) Hooton, R.D., Charmchi, G. and Karkar, E., “Development and Toronto, 2010.
Standardization of Rapid Methods for Assessing the Fluid Penetration (5) Spragg, R., Villani, C. and Weiss, J., “Electrical Properties of
Resistance of Concrete,” Proceedings, XIII International Conference Cementitious Systems: Formation Factor Determination and the
on the Durability of Building Materials, Sao Paolo, Brazil, Sept. 2014, Influence of Conditioning Procedures,” Advances in Civil Engineer-
pp.1111-1117. ing Materials, Vol. 5, No. 1, pp. 24-48, 2016.
(3) Gudimettla, J., and Crawford, G., “Resistivity tests for concrete – (6) Spragg, R., Villani, C., Snyder, K., Bentz, D., Bullard, J.W., and
recent field experience,” ACI Materials Journal, Vol. 113, No. 4, Weiss, J., “Factors That Influence Electrical Resistivity Measurements
2016. in Cementitious Systems,” Transportation Research Record: Journal

&RS\ULJKWE\$670,QW O DOOULJKWVUHVHUYHG 7KX'HF*07


6
'RZQORDGHGSULQWHGE\
8QLYHUVLW\RI)ORULGDSXUVXDQWWR/LFHQVH$JUHHPHQW1RIXUWKHUUHSURGXFWLRQVDXWKRUL]HG
C1876 − 19
of the Transportation Research Board, No. 2342, Transportation (8) Barrett, T., “Improving Service Life of Concrete Structures Through
Research Board of the National Academies, Washington, D.C., 2013, the use of Internal Curing: Impact on Practice,” Ph.D. Thesis, Purdue
pp. 90-98. DOI: 10.3141/2342-11. University, West Lafayette, IN, 2015.
(7) Spragg, R. P., Castro, J., Nantung, T. E., Paredes, M. A., and Weiss, J., (9) Snyder, K.A., Feng, X., Keen, B.D., and Mason, T.O., “Estimating the
“Variability Analysis of the Uniaxial Resistivity Measured Using Electrical Conductivity of Cement Paste Pore Solutions from OH-,
Concrete Cylinders,” Advances in Civil Engineering Materials, Vol. 1, K+, and Na+ Concentrations,” Cement and Concrete Research, Vol.
No. 1, 1-17, 2012. 33, No. 6, 793-798, 2003.

ASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentioned
in this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the risk
of infringement of such rights, are entirely their own responsibility.

This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years and
if not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standards
and should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of the
responsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you should
make your views known to the ASTM Committee on Standards, at the address shown below.

This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,
United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the above
address or at 610-832-9585 (phone), 610-832-9555 (fax), or service@astm.org (e-mail); or through the ASTM website
(www.astm.org). Permission rights to photocopy the standard may also be secured from the Copyright Clearance Center, 222
Rosewood Drive, Danvers, MA 01923, Tel: (978) 646-2600; http://www.copyright.com/

&RS\ULJKWE\$670,QW O DOOULJKWVUHVHUYHG 7KX'HF*07


7
'RZQORDGHGSULQWHGE\
8QLYHUVLW\RI)ORULGDSXUVXDQWWR/LFHQVH$JUHHPHQW1RIXUWKHUUHSURGXFWLRQVDXWKRUL]HG

You might also like