Frecchions of sores / energy O Comlpydion CoHenia + nO. > n Cort nto 4d ex CHS CH2CHy 402 => Coe + Heo CH3 CHaCHss B00 ~> 3000+ WHO @ Halogeraon : ne RH Be Ret Hy ex: CHa ete > CHy-cl 4 nel Crs Cla Chl +e Ho chy che CHa -o) Most stable infertiar) bs f (secondary) CRY-OHa= Cp, He fr noes i Hs aes He CHa-CH-CH + Hel Steendor Seondosey © Vebydeodion of Aliones Akane head scollyst, Mtn + Ha ex: \ . Cis CHaCH2cHs — PE, SOC, cH ~ CH = CH= CH +HNerrencl due Alone NAA Dewallyl 3 hexene or Doma! her 3 ere Gora Ge . Cs — cH = ctl Eee ethyl = 6 6-Heimethy| * 2-hep te ° o &€ 6 6 6 @ sepil2m oy rome fom closest double bor 2 dale pond -> Diene ANA oor, co 3 dedtle land 7 Trene ‘ 4 davble bonds > Sekaane.——2ecthy- it hers. ene era La dient 3. a cual ety 5,6 methyl =1,3,5 hepladriene y % SB popyl “lt hepla diene : ee om Lo tye PAH 3-Beore= Somethy| US “here dene 5. Ane Ys Teopropy] “3,9 -dimelhy! = 13,8 “hep torciene we a eoganyl die bond ~ Cty eroptl = Sung toons elkenyl = desbhe bond (nyt) cn 539 dell = 24 acta diene Ga, eel singe bond 3 oe S methyl ~ Soweyl ~ 13 -Heaw diene,Ci * Seame Trans gpeite He we ~|" wae —T ohn whe os | rang neither | 2-medhyl ~ | prone Win le ‘e a “ee ee 7 teeter eh Sm gh aioe tee igh v v i 2. @ eneens 3 Weey, _ einen = a CHO CAH Sascte d TL E eanfigy ten B ConfigurationSymthesis of Aly! Halide. ), Helagratin RH tx? Z RA HEX or: chs a7 CHa~ch-ch3 4+ C12 4> cs-d-cna + Hel a f ‘ ¢ D From Alkenes x OK “ 2 t a) CH2= CH2a nx —> che~ cHe Addin of Hydager slandes) ex CHa cH =CHa + HBr ©? CHS > CH - cHe 1 el B) CH=CH 4x2 —> cha- Cte on ons ct CHa>CH-cH =CH2 +Cle -> CHa -CH-CH-CH2, ; gy ch Moxkounikov's Rule cHs otls a 1 CHa ~ 0 = CH -cH3 + Hbe -> CHg -C- cH cH3 e-8 Be H Anti- Markov aikors Role only Bc jn dhe presence of Peronides Case os chs Hoon CHy- 6 = CH CHS + HBe MS Chis - C- cr Hs nde 3, From Alkynes Hx eH ; it HE CH ADH —> cH cH cu-cH Vaan rod H x HX Be WY CHE CH+ 2x2 —> CHae -CHxr wt L H-CEe ~chucheCHy 426° -2 H-C-o~ Cth Hy ,oul Gr Br H- CEC - C2 CHiCHs + 2H ~> H-CH2-C Beg ~CHaOAr OryY From other Halide ABs MT MB Ry ay h. ee CHa = elec + Ney Acs oblycuaT 4 Mach YW Rx SKE terme Q- “Ghar F+kx Symtesis of Alkenes ® pale Tadogenakn of Aly aside (re ~ rien 009 Me”) Lv Yoon. neo eee eee Yesett ty 1G = ; ors ws OR. cits CHa — bo ey BRC ty etl se = cH be . Hor © Vebrorivadhon of Vinal dibrorides T= be Ae : : -¢ha- Desc s 17 Be +b 4 Ne Uke ow 4 hes y= cH = CHD fare Clyne eH “EHS? Bea oe @_Wehydradton of Sones Mone eis Avene Oo yi S09% “odecl-tl, +H cage cian cher ors SA (Hs “CH bh tHe ; of Mleahels @ Dehn we hfe, ye 26K Ha + MS Msfoy Hort a? “ow om Wed gg c= CH CHS + HOt Ha SO nr — y: 12 SPy cla - cH = cH CH pak . Hs© Reduchion of Aliy nes or hydeagenostion of Mhynes a “ACEC -A CH (Bb, ee’ cis Lindlor 9. Wiealing Wy H Nie nb = ‘ ww 7 4 Trans R-czc-@ NegNHy po ens. H & ex: Hoe Hucs Ungdlor cry Cl Cy CHa - CEC -cHyCHy SS ‘ese? H W CR ly CHa CEC“ CH Mon 2 CHa tly ce =Cc / N CH3 Hal WW Witting Recneli Hing rr on 5 Se =O 4 Phs? = CHR ——> BA lige 4 Phs? =O Re Ketone & Aldehyde CHa € = CHaCHs + Phsp = CH-CHg = cts detec + PhsPs0 3-methyl -2- penteneReoclons of O Addition 9 \ czee oe XS ey OF Mena, # Alig tddse + He cH -be Hog = NO CHS 4 HT Wo ety clk atl ents He scH on. = CHa Cs Of Hel eH ea ot See tian SE Ne © Orymeresradon = Demereanden 2 wat Nae a cree Mg lok Pee NGO =u be Fhe oy 3 Na Wy ‘on Oca bees i xe ) CHascl-CHly 4Re2 => Ole CH= Hs Be de proce Mechel © jad eodalyle hyreden Se eeZ vino He / Hye cH» CHa + Hyd 252% Cry ~ CH= CH last HOH Heres H 3 b= Bohol Hoe ex. Anti - Malornsher ‘oeat 5 CHy- CH = CHa 4 Os « THE Hi Gl - che ¥ om @ Emerson yee© Codahyhe. Hydrogenadon i: Yerevan, BiPeM, G4 ©. Ondertion gycol a7 Baeyer Reaction — (KMn Oy cold, dilvted) Berd > aie MnO Ha - CH ~CHy -CH3, CHa = OM ~ CHe- CH ooh ante C H ana Dir Seal Kony, Ketones Fcarooriyic. Aid if Wratm cC cuaew ‘ cracls eee Krad r oCRG- CTE - CHy Temte Mls CO + O=C- onts CH CHy- cA cHachs 2 OR genic 20 x 056” w! ‘a : 10” Soy Ons, wv cle $a foc? > tHa.¢20 40.50% PA \ i ‘es 4 ey HO C) Ozomolysis os et Os, Krones ¢ Ndehyds ’ a Sony aS v cH3 « %3~c=0 4 O=¢’ W Sty cHs ors CHe = 6 ae =0 =. 2 — CH -CHs ages CH2=0 +0 FCo CHa chy fe C=O e He Cor CHWs cls 0 CHy- 6 = CH ~CHs ce cHy-C=O4% C-H 1