© scanned with OKEN ScannerI t standard con the change in the enthalpy fae fllowng reaction is ~109 kd mol! ata) 2HBr a) nat bond energy of Hp and Brp is aoe rae ‘and 192 kJ mot, respectively, what : the bond energy (' kJ mot) of HBr? is [NEET-2020 (Phase-2)] (t) 259 2368, @) 736 (4) 518 i 4 stain reaction A}H is 30 kJ mot" at 450 kK, an of AS (in ‘JK mol") for which the same be spontaneous at the same [NEET-2020 (Phase-2)] (2) 70 +i 1) temperature is (1) -70 ) 3 4 n ideal gas expands isothermall 40° m? to 10 m® at 300 K against a pressure of 10° Nm. The work done or |EET-20° ‘Thermodynamics aE 4 change in entropy is negative? INEET-2019] 13. In which (1) Evaporation of water (2) Expansion of a gas at constant temperature (3) Sublimation of solid to gas (4) 2H(g) > H,(9) . The bond dissociation energies of X,, Y, and XY are in the ratio of 4 : 0.5 : 4. AH for the formation of XY is -200 kJ molt. The bond dissociation energy of X, will be [NEET-2018] (1) 200 kJ molt (2) 100 kJ molt (8) 400 kJ mot (4) 800 kJ mol Ssh © scanned with OKEN Scanner174) Thermodynamics 19. The heat of combustion of carbon to CO, is 3935 kulmol. The heat released upon formation of $5.29 of CO, from carbon and oxygen gas is [Re-AIPMT-2015] (1) -630 ky (2) 3.15 ks (@) -315 ks (4) +315 ks 20. For the reaction, X,0,(1) -» 2x0, (g) AU = 2.1 k cal, AS = 20 cal Kt at 300 K Hence, AG is (1) 27 kcal 2) -2.7 kcal (8) 93 kcal (4) -9.3 kcal 21. In which of the following reactions, standard reaction entropy change (AS*) is positive and Standard Gibb’s eneray change (AG*) decreases sharply with increasing temperature? [AIPMT (Prelims)-2012) [AIPMT-2014] ) Mats) + 50,0) mao(s) 1 (2) FC oraphite + F0u0)-»5 C ~ NEET log, ‘ Lomi ga 5 of two monoatomic gases, 24, eee ete and pressure are msgs “ ata om heats (C/G) ofthe msgs, i ly TAPHT Maing 1) 0.83 2) 1.50 4] - a3 (4) 167 Which of the following ‘i correct oad for fey asunder a ansion of an ideal g: bw labat, condtion? eae (1) q=0, AT <0,w#0 2) q=0,AT 40, w=0 @) q#0/aT=0,w=0 (4) q=0, AT=0,w=0 : enthalpy change for the transition of ja, = aa to steam is 30 kJ mol at 27°C, the eng, for the process would be shange for IAIPMT (Prelims) (2) 10 J mol K-1 (4) 0.1. J molt K+ 25. (1) 100 J molt Kt (3) 1.0 J mol K+ Enthalpy change for the reaction, 4 H., + 2 is -869.6 kJ. The dissociation energy of H “i - bond is. (#2174 kd [AIPMT (Prelims)-2011) 2) 4348 kJ (4) + 434.8 kJ the following process AH(kJ/mol) +150 125 [AIPMT (Mains)-201t] (2) 325 kJ/mol (4) ~175 kJ/mol © scanned with OKEN Scannerce (Equations) with Listtl (Type of ad select the correct option usy List teqvations) (ype of proces: . 2a () _Non-spontaneous, = Satin (i) Equilibrium @ (ii) Spontaneous and endothermic ‘Spontaneous: [AIPMT (Mi as (1) 64P, (2) P, (3) 16P, (4) 32P, ». The values of AH and AS for the reaction, Cyaraphie) * CO(9) > 26019) are 170 kJ and 170 JK ly. This reaction ‘will be spontaneous at [AIPMT (Prelims)-2009] © scanned with OKEN Scanner176 Thermodynamics 40. Consider the following reactions ()_H'(aq) + OH> (aq) = H,0(!); AH X, kd mot 1 (i), HQ) + 5.0,(9) = H,0(); AH = -X, kd mot" (ii) CO,(@) + H,(@) = CO(g) + H,0(); AH =X, kJ mol (™) C,H,(g) + 30,00) = 200(g) + H,0(\); AH = 4%, kd mot Enthalpy of formation of H0(|) is IAIPMT (Prelims)-2007] (1) *X, kd mort (2) ~X, kJ mot @) +X, kd mot (4) ~X, kJ mot 41. Given that bond energies of H-H and Cl — Cl are 430 kJ/mol and 240 ki/mol respectively and AH of HCI is -90 kJ/mol. Bond enthalpy of HCl is IAIPMT (Prelims)-2007] (2) 2909 kJ mot (1) 245 kJ mort (8) 380 kJ mor Identify the corre energy for a temperature and 44, 45. 47. NET Leveiy)) The enthalpy and entropy change for the reacts, Br,(l) + Cla) > 28rC\(9) are 30 kJ mot! and 105 JK mol" respective, The temperature at which the reaction will be j, [AIPMT (Prelims)-2006) equilibrium is (1) 285.7 K (2) 273K (3) 450 K (4) 300K The enthalpy of combustion of H,, cyclohexene (CHq) and cyclohexane (CH,2) are ~ 241, 389) and 3920 kJ per mol respectively. Heat of hydrogenation of cyclohexene is [AIPMT (Prelims)-2009) (2) +121 kd per mol (1) ~ 121 kJ per mol (4) — 242 kJ per mol (8) +242 kJ per mol A reaction occurs spontaneously if [AIPMT (Prelims)-2005, (1) TAS < AH and both AH and AS are +ve (2) TAS > AH and both AH and AS are +ve (@) TAS = AH and both AH and AS are +ve (4) TAS > AH and AH is +ve and AS is -ve Which of the following pairs of a chemical reaction is certain to result in a spontaneous reaction ? [AIPMT (Prelims)-2005, cothermic and decreasing disorder jothermic and increasing disorder ic and increasing disorder dical Ent. Exams. 2005 following values of AH, s and endothermic? © scanned with OKEN ScannerecritevertD } ‘hree thermochemical equations are given below. i (i) Cierspnte) * O29) > CO,(g); AH® = x kJ molt A (i) Cigapnte) * 5 O29) > COG); AH? = yk mort 0019) * 5 0,(9) > CO,(g); AH? =ZkJ mol ii) 2 ased on the above equations, find out which of the relationship given below is correct: (i) x=y-z (2) z=x+y @) x=y+z (4) y=22-x |. Following reaction occurring in an automobile 2CHre(9) + 250,(9) > 16C0,(g) + 18H,0 (g). The sign of AH, AS and AG would be (ong (2) +,4,- 1 45+ (4) 2, When 5 litres of a gas mixture of methane and propane is perfectly combusted at 0°C and 1 atmosphere, 16 litre of oxygen at the same temperature and pressure is consumed, The ‘amount of heat releas bustion in kd n (Hom (CH4) = s) "2 2250 kd mot ) ae 5] (1) 22 (3) 317 33. If enthalpie H,0() at and ~28 combusti () #1424 (8) - 441 * ora 1) AH as ) On 57, Thermodynamics [FANN 'dentify the correct statement regarding entropy (1) Atabsolute zero of temperature, the entropy of all crystalline substances is taken to be sero (2) At absolute zero of temperature, the entropy Of a perfectly crystalline substance is +ve (8) At absolute zero of temperature, entropy of a Perfectly crystalline substance is taken to be zer0 (@) At 0°C, the entropy of a perfectly crystaline Substance is taken to be zero One mole of an ideal gas at 300 K is expanded tsothermally from an initial volume of 1 litre to 10 litres, The AE for this process is (R= 2 cal. Mot 'k-1) (1) 1381.1 cal 2) Zero 8) 1637 cal (4) 9Latm In the reaction : S + 3/2 0, > SO, + 2x keal and SO, + 1/2 0, > SO, + y kcal, the heat of formation of SO, is PB (1) (x+y) 2) &-y) @) &+y) @) yan latent heat of fusion of a compound is |. Entropy change is @) 10.77 Jimotk (4) 0.977 Jimol-k AE = RT +2RT (4) AH= AE—2RT n reaction, 2H,0, (I) >2H,0 (!) fomatanattiori arated ae mal respectively, is +196 kuvmot jek apa - Den CO) 248 tinal ‘is heated at constant volume cd from 298 to 308 K. Heat is $00 J. Then which statement et © scanned with OKEN Scannera 178 NE 1978) Thermodynamics Mery (1) Nya) + Ox(9) > N203(9) (2) CH,(g) + 2CL(9) > CHL) + 2Helg) 1 83. Enthelpy of CH, + £0, — CH\OH js negative, If (a) Xela) + 2Fx(9) > XeF (9) enthalpy of combustion of CH, and CH,OH are x and y respectively. Then which relation is correct? (4) 20019) + Ox(9) > 2€0,{9) SS ai and standard ent dard enthalpy roy @ x © >0 entropy change (R = 2 cal/mol k) (3) ASsymtom > 0 Only > 0 only ne Oe (4) AS. rourings / ae nee 73. The work done during the expansion ofa gas, a volume of 4 dm? to 6 dm? against a consis, external pressure of 3 atm is (1 L atm = 10139. (2) -608 J @) -304J 67. Heat of combustion for C(s), H,(g) and CH,(g) are -94, —68 and -213 kcal/mol, then AH for C(s) + 2H,(g) > CH,(g) is (1) -17 kcal @Q - (3) -170 kcal (4) 68. For the reaction © scanned with OKEN Scanner