Electrochemistry

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Electrochemistry NEET
Topic-1: Conductance and Conductivity
1. The molar conductance of NaCl, HCl and CH3 COONa at infinite dilution are 126.45, 426.16 and
91.0 S cm² mol−1 respectively. The molar conductance of CH3 COOH at infinite dilution is
Choose the right option for your answer [NEET 2021]
(a) 540.48 S cm² mol−1 (b) 201.28 S cm² mol−1
(c) 390.71 S cm² mol−1 (d) 698.28 S cm² mol−1
2. The molar conductivity of 0.007 M acetic acid is 20 S cm² mol−1 . What is the dissociation constant
Λ0 + = 350 𝑆 𝑐𝑚2 mol−1
of acetic acid? Choose the correct option. [ 0 𝐻 ] [NEET 2021]
Λ 𝐶𝐻3 𝐶𝑂𝑂− = 50 𝑆 𝑐𝑚2 mol−1
(a) 2.50 × 10−5 mol L−1 (b) 1.75 × 10−4 mol L−1
(c) 2.50 × 10−4 mol L−1 (d) 1.75 × 10−5 mol L−1
3. Following limiting molar conductivities are given as [NEET 2019]
𝜆0𝑚 (𝐻2 𝑆𝑂4 ) = 𝑥 S cm2 mol−1
𝜆0𝑚 (𝐾2 𝑆𝑂4 ) = 𝑦 S cm² mol−1
𝜆0𝑚 (𝐶𝐻3 𝐶𝑂𝑂𝐾) = 𝑧 S cm² mol−1
𝜆0𝑚 (in S cm2 mol−1 ) for CH3 COOH will be
(𝑥−𝑦)
(a) 2 + 𝑧 (b) 𝑥 − 𝑦 + 2𝑧
(c) 𝑥 + 𝑦 + 𝑧 (d) 𝑥 − 𝑦 + 𝑧
4. The molar conductivity of a 0.5 mol/ dm³ solution of AgNO3 , with electrolytic conductivity
of 5.76 × 10−3 S cm−1 at 298 K is [NEET 2016]
(a) 0.086 S cm²/mol (b) 28.8 S cm²/mol
(c) 2.88 S cm²/mol (d) 11.52 S cm²/mol
5. Aqueous solution of which of the following compounds is the best conductor of electric current?
(a) Acetic acid, C2 H4 , O2 (b) Hydrochloric acid, HCI [NEET 2015]
(c) Ammonia, NH3 (d) Fructose C6 H12 O6
6. At 25°C molar conductance of 0.1 molar aqueous solution of ammonium hydroxide is 9.54
ohm−1 cm2 mol−1 and at infinite dilution its molar conductance is 238 ohm−1 cm2 mol−1 . The
degree or ionisation of ammonium hydroxide. at the same concentration and temperature is:
(a) 20.800% (b) 4.008% (c) 40.800% (d) 2.080% [NEET 2013]
0
7. Limiting molar conductivity of 𝑁𝐻4 𝑂𝐻 (i.e., Λ 𝑚(𝑁𝐻4𝑂𝐻) ) is equal to: [NEET 2012]
0 0 0 0 0 0
(a) Λ m(NH4CI) + Λ m(NaCI) − Λ m(NaOH) (b) Λ m(NaOH) + Λ m(NaCI) − Λ m(NH4CI)
0 0 0
(c) Λ m(NH4OH) + Λ m(NH4CI) − Λ m(HCI) (d) Λ0m(NH4CI) + Λ0m(NaOH) − Λ0m(NaCI)
8. Molar conductivities (Λ0𝑚 ) at infinite dilution of NaCl, HCI and CH3 COONa are 126.4, 425.9 and
91.0 S cm² mol−1 respectively. Λ0𝑚 for CH3 COOH will be: [NEET 2012]
(a) 425.5 S cm2 mol−1 (b) 180.5 S cm2 mol−1
(c) 290.8 S cm2 mol−1 (d) 390.5 S cm2 mol−1

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9. An increase in equivalent conductance of a strong electrolyte with dilution is mainly due to:
(a) increase in ionic mobility of ions [NEET 2010]
(b) 100% ionisation of electrolyte at normal dilution
(c) increase in both i.e. number of ions and ionic mobility of ions
(d) increase in number of ions
10. Which of the following expressions correctly represents the equivalent conductance at infinite
dilution of Al2 (SO4 )3 ? Given that Λ0Al3+ and Λ0Al3+ are the equivalent conductances infinite dilution
of the respective ions [NEET 2010]
1 0 1 0 0 0
(a) 3 Λ Al3+ + 2 Λ SO2− (b) 2 Λ Al3+ + 3 Λ SO2−
4 4

(c) Λ0Al3+ + Λ0SO2− (d) (Λ0Al3+ + Λ0SO2− ) ×6


4 4
M
11. The equivalent conductance of solution 32 of a weak monobasic acid is 8.0 mho cm2 and at infinite
dilution is 400 mho cm−2 . The dissociation constant of this acid is: [NEET 2009]
−6 −4 −4 −5
(a) 1.25 × 10 (b) 6.25 × 10 (c) 1.25 × 10 (d) 1.25 × 10
12. Kohlrausch's law states that at: [NEET 2008]
(a) finite dilution, each ion makes definite contribution to equivalent conductance of an electrolyte,
whatever be the nature of the other ion of the electrolyte.
(b) infinite dilution each ion makes definite contribution to equivalent conductance of an electrolyte
depending on the nature of the other ion of the electrolyte.
(c) infinite dilution, each ion makes definite contribution to conductance of an electrolyte whatever
be the nature of the other ion of the electrolyte.
(d) infinite dilution, each ion makes definite contriubtion to equivalent conductance of an electrolyte,
whatever be the nature of the other ion of the electrolyte.
13. The ionic conductance of Ba2+ and CI− are respectively 127 and 76 ohm−1 cm2 at infinite dilution.
The equivalent conductance (in ohm−1 cm²) of BaCI2 , at infinite dilution will be: [NEET 2000]
(a) 139.5 (b) 203 (c) 279 (d) 101.5
14. Specific conductance of a 0.1 N KCl solution at 23°C is 0.012 ohm−1 cm2 . Resistance of cell
containing the solution at same temperature was found to be 55 ohm. The cell constant is
(a) 0.918 cm−1 (b) 0.66 cm−1 (c) 1.142 cm−1 (d) 1.12 cm−1 [NEET 2000]
15. Equivalent conductances of NaCl, HCI and CH3 COONa at infinite dilution are 126.45, 426.16 and
91 ohm−1 cm2 respectively. The equivalent conductance of CH3 COOH at infinite dilution would be
(a) 101.38 ohm−1 cm2 (b) 253.62 ohm−1 cm2 [NEET 1997]
(c) 390.71 ohm−1 cm2 (d) 678.90 ohm−1 cm2
16. If 0.01 M solution of an electrolyte has a resistance of 40 ohms in a cell having a cell constant of 0.4
cm−1 , then its molar conductance in ohm−1 cm2 mol−1 is [NEET 1997]
2 4 3
(a) 10 (b) 10 (c) 10 (d) 10
17. On heating one end of a piece of a metal, the other end becomes hot because of [NEET 1995]
(a) resistance of the Metal (b) mobility of atoms in the metal
(c) energised electrons moving to the other (d) minor perturbation in the energy of atoms
18. Which of the following is an insulator? [NEET 1992]
(a) Graphite (b) Aluminium (c) Diamond (d) Silicon.
Topic-2: Electrolysis and Faraday's Law
19. On electrolysis of dil. sulphuric acid using Platinum (Pt) electrode, the product obtained at anode
will be [NEET 2020]
(a) Oxygen gas (b) HS gas (c) SO2 gas (d) Hydrogen gas
20. The number of Faradays(F) required to produce 20 g of calcium from molten CaCl2 (Atomic mass
of Ca = 40 g mol−1 ) is: [NEET 2020]
(a) 2 (b) 3 (c) 4 (d) 1

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21. When 0.1 mol MnO2− 4 is oxidized, the quantity of electricity required to completely oxidise
2− −
MnO4 to MnO4 is: [NEET 2020]
(a) 96500 C (b) 2 × 96500 C (c) 9650 C (d) 96.50 C
22. The weight of silver (at wt. - 108) displaced by a quantity of electricity which displaces 5600 mL of
O2 at STP will be: - [NEET 2014]
(a) 5.4 g (b) 10.8 g (c) 54.9 g (d) 108.0 g
23. How many grams of cobalt metal will be deposited when a solution of cobalt (II)) chloride is
electrolyzed with a current of 10 amperes for 109 minutes (1 Faraday = 96,500 C: Atomic mass of
Co = 59 u) [NEET 2013]
(a) 0.66 (b) 4.0 (c) 20.0 (d) 40.0
24. Al2 O3 is reduced by electrolysis at low potentials and high currents. If 4.0 × 104 amperes of
current is passed through molten Al2 O3 for 6 hours, what mass of aluminium is produced?
(Assume 100% current efficiency and At. mass of Al = 27 g mol−1 ) [NEET 2009]
4 5 4 3
(a) 8.1 × 10 g (b) 2.4 × 10 g (c) 1.3 × 10 g (d) 9.0 × 10 g
25. 4.5 g of aluminium (at. mass 27 amu) is deposited at cathode from Al3+ solution by a certain
quantity of electric charge. The volume of hydrogen produced at STP from H + ions in solution by
the same quantity of electric charge will be [NEET 2005]
(a) 44.8 L (c) 11.2 L (b) 22.4 L (d) 5.6 L
26. In electrolysis of NaCl, when Pt electrode is taken, then H2 is liberated at cathode while with Hg
cathode, it forms sodium amalgam. This is because [NEET 2002]
(a) Hg is more inert than Pt
(b) More voltage is required to reduce H + at Hg than at Pt
(c) Na is dissolved in Hg while it does not dissolve in Pt
(d) Conc. of H + ions is larger when Pt electrode is taken
27. Standard electrode potentials are: Fe2+ /Fe
[E 0 = −0.44]; Fe3+ /Fe2+ [E0 = +0.77]; If Fe2+ , Fe3+
and Fe blocks are kept together, then [NEET 2001]
2+ 3+
(a) Fe increases (b) Fe decreases
Fe2+
(c) Fe3+ remains unchanged (d) Fe2+ decreases
28. On passing a current of 1.0 ampere for 16 min and 5 see through one litre solution of CuCl₂, all
copper of the solution was deposited at cathode. The strength of CuCl2 , solution was
(Molar mass of Cu= 63.5; Faraday constant = 96,500 C mol−1) [NEET 1996]
(a) 0.01 N (b) 0.01 M (c) 0.02 M (d) 0.2 N
29. On electrolysis of dilute sulphuric acid using platinum electrodes, the product obtained at the anode
will be [NEET 1992]
(a) hydrogen (b) oxygen
(c) hydrogen sulphide (d) sulphur dioxide.
Topic-3: Cells and Electrode Potential Nernst Equation
30. Given below are half-cell reactions: 𝑀𝑛𝑂4− + 8𝐻 + + 5𝑒 − → 𝑀𝑛2+ + 4𝐻2 𝑂,
0
EMn 2+ /MnO− = −1.510V
4
1
O2 + 2H + + 2e− → H 2 O
2
EO0 2/H2O = +1.223V
Will the permanganate ion, MnO− 4 liberate O₂ from water in the presence of an acid? [NEET 2022]
0
(a) No, because Ecell cell = −0.287 V
0
(b) Yes, because Ecell cell = +2.733 V
0
(c) No, because Ecell cell = −2.733 V
0
(d) Yes, because Ecell cell = +0.287 V
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31. Find the emf of the cell in which the following reaction takes place at 298 K [NEET 2022]
+ 2+
Ni(s) + 2Ag (0.001 M) → Ni (0.001 M) + 2Ag(s)
0 2.303𝑅𝑇
(Given that Ecell = 10.5V, 𝐹 = 0.059 at 298 K)
(a) 1.385 V (b) 0.9615 V (c) 1.05 V (d) 1.0385 V
0
32. For a cell involving one electron 𝐸𝑐𝑒𝑙𝑙 = 0.59V at 298 K, the equilibrium constant for the cell
reaction is:
2.303RT
[Given that F = 0.059 V at T = 298K ] [NEET 2019]
(a) 1.0 × 102 (b) 1.0 × 105 (c) 1.0 × 1010 (d) 1.0 × 1030
33. For the cell reaction [NEET 2019]
2Fe3+ (aq) + 2I− (aq) → 2Fe2+ (aq) + I2 (aq) 0.24 V at 298 K. The standard Gibbs energy
(Λ G°) of the cell reaction is:
[Given that Faraday constant F = 96500C mol−1 ]
(a) −46.32 kJ mol−1 (b) −23.16 kJ mol−1 (c) 46.32 kJ mol−1 (d) 23.16 kJ mol−1
34. In the electrochemical cell: - [NEET 2003, 2017]
Zn |ZnSO4 (0.01M) || CuSO4 (1.0 M) | Cu the emf of this Daniel cell is E1. When the concentration
of ZnSO4 is changed to 1.0M and that of CuSO4 changed to 0.01M, the emf changes to E2 . From
the followings, which one is the relationship between 𝐸1 and 𝐸2 ? [NEET 2017]
𝑅𝑇
(Given, 𝐹 = 0.059)
(a) 𝐸1 < 𝐸2 (b) 𝐸1 > 𝐸2 (c) 𝐸2 = 0 ≠ 𝐸1 (d) 𝐸1 = 𝐸2
35. The pressure of H2 required to make the potential of H2 electrode zero in pure water at 298 K is:
(a) 10−14 atm (b) 10−12 atm (c) 10−10 atm (d) 10−4 atm [NEET 2016]
36. A hydrogen gas electrode is made by dipping platinum wire in a solution of HCl of pH=10 and by
passing hydrogen gas around the platinum wire at one atm pressure. The oxidation potential of
electrode would be? [NEET 2013]
(a) 0.59 V (b) 0.118 V (c) 1.18 V (d) 0.059 V
37. Consider the half-cell reduction reaction: [NEET 2013]
Mn2+ + 2e− → Mn, E° = −1.18 V
Mn2+ → Mn3+ + e− , E° = −1.51 V
The 𝐸 0 for the reaction 3Mn2 → Mn0 + 2Mn3+ , and possibility of the forward reaction are,
respectively
(a) −2.69 V and no (b) −4.18 V and yes (c) +0.33 V and yes (d) +2.69 V and no
38. Standard electrode potential of three metals X, Y and Z are −1.2 V, +0.5 V and −3.0 V
respectively. The reducing power of these metals will be: [NEET 2011]
(a) 𝑌 > 𝑍 > 𝑋 (b) 𝑋 > 𝑌 > 𝑍 (c) 𝑍 > 𝑋 > 𝑌 (d) 𝑋 > 𝑌 > 𝑍
39. The electrode potentials for [NEET 2011]
2+ − + + −
Cu (aq) + e → Cu (aq)and Cu (aq) + e → Cu(s) are +0.15 V and + 0.50V,
0
respectively. The value of ECu 2+ /Cu will be:

(a) 0.500 V (b) 0.325 V (c) 0.650 V (d) 0.150 V


40. Standard electrode potential for Sn4+ / Sn2+ couple is +0.15 V and that for the Cr 3+ /Cr couple is
– 0.74 V. These two couples in their standard state are connected to make a cell. The cell potential
will be: [NEET 2011]
(a) +1.19 V (b) +0.89 V (c) +0.18 V (d) +1.83 V
41. If the E for a given reaction has a negative cell value, then which of the following gives the correct
relationships for the values of AG° and 𝐾𝑒𝑞 ? [NEET 2011]
(a) ∆G° > 0; K eq > 1 (b) ∆G° < 0; K eq > 1
(c) ∆G° < 0; K eq < 1 (d) ∆G° > 0; K eq < 1

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42. A solution contains Fe2+ , Fe3+ and I − ions. This solution was treated with iodine at 35°C. E 0 for
Fe3+ / Fe2+is + 0.77 V and 𝐸 0 for I2 /2I − 0.536 V. The favourable redox reaction is:
(a) I2 will be reduced to I− (b) There will be no redox reaction

(c) I will be oxidised to I2 (d) Fe2+ will be oxidised to Fe3+
43. For the reduction of silver ions with copper metal, the standard cell potential was found to be +0.46
V at 25°C. The value of standard Gibbs energy, ∆G0 will be (F = 96500 C mol−1 ) [NEET 2010]
(a) − 89.0 kJ (b) −89.0 J (c) − 44.5 kJ (d) −98.0 kJ
44. Consider the following relations for emf of a electrochemical cell: [NEET 2010]
(i) emf of cell = (Oxidation potential of anode)−(Reduction potential of cathode)
(ii) emf of cell = (Oxidation potential of anode) + (Reduction potential of cathode)
(iii) emf of cell = (Reduction potential of anode) + (Reduction potential of cathode)
(iv) emf of cell = (Oxidation potential of anode) + (Oxidation potential of cathode)
Which of the above relations are correct?
(a) (ii) and (iv) (b) (iii) and (i) (c) (i) and (ii) (d) (iii) and (iv)
45. Given: [NEET 2009]
2+ − 0
(i) Cu + 2e → Cu, E = 0.337 V
(ii) Cu2+ + e− → Cu+ , E° = 0.153 V
Electrode potential, E° for the reaction, Cute Cu, will be:
(a) 0.90 V (b) 0.30 V (c) 0.38 V (d) 0.52 V
0
46. On the basis of the following 𝐸 values, the strongest oxidizing agent is: [NEET 2008]
[Fe(CN)6 ]4− → [Fe(CN)6 ]3− + e− ; E° = −0.35 V
Fe2+ → Fe3+ + e− E° = −0.77 V
− 2+
(a) [Fe(CN) 6 ]4 (b) Fe (c) Fe3+ (d) [Fe(CN6 )]3−
47. The equilibrium constant of the reaction: Cu(s) + 2Ag + (aq) → Cu2+ (aq) + 2Ag(s);
𝐸 0 = 0.46 V at 298 K is [NEET 2007]
10 10 15 10
(a) 2.0 × 10 (b) 4.0 × 10 (c) 4.0 × 10 (d) 2.4 × 10
0 0
48. If EFe 2+ /Fe = −0.441𝑉 and E Fe3+ /Fe2+ =+0.771V, the standard EMF of the reaction
Fe + 2Fe3+ → 3Fe2+ will be [NEET 2006]
(a) 1.653 V (b) 1.212 V (c) 0.111 V (d) 0.330 V
49. A hypothetical electrochemical cell is shown below A|A+ (xM) || B+ (yM) | B
The emf measured is +0.20 V. The cell reaction is [NEET 2006]
+ − + −
(a) A + e → A; B + e → B (b) The cell reaction cannot be predicted
(c) A + B + → A+ + B (d) A+ + B → A + B+
50. The standard e.m.f. of a galvanic cell involving cell reaction with 𝑛 = 2 is found to be 0.295 V at
25°C. The equilibrium constant of the reaction would be [NEET 2004]
−1 −1 −1
(Given F = 96500C mol ; R = 8.314J K mol )
(a) 2.0 × 1011 (b) 4.0 × 1012 (c) 1.0 × 102 (d) 1.0 × 1010
51. On the basis of the information available from the reaction
4 2
Al + O2 → 3 Al2 O3 , ∆G = −827 kJ mol − ¹ of O2 . The minimum e.m.f required to carry out an
3
electrolysis of Al2 O3 is (F = 96500 mol−1 ) [NEET 2003]
(a) 8.56 V (b) 2.14 V (c) 4.28 V (d) 6.42 V
52. Which reaction is not feasible? [NEET 2002]
(a) 2KI + Br₂ → 2KBr + I₂ (b) 2KBr + I2 ⟶ 2K + Br₂
(c) 2KBr + Cl2 → 2KCl + Br2 (d) 2H2 O + 2F2 → 4HF + O₂
53. Cu(aq) is unstable in solution and undergoes simultaneous oxidation and reduction according to the
reaction: 2Cu+ (aq) ⇌ Cu2+ (aq) + Cu(s) choose correct 𝐸 0 for above reaction if E 0 Cu2+ /
Cu 0.34 V and E 0 Cu2+ /Cu+ = 0.15 V [NEET 2000]
(a) −0.38 V (b) +0.49 V (c) +0.38 V (d) −0.19 V
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0
54. What is the Ecell for the reaction Cu2+ (aq) + Sn2+ (aq)+⇌ Cu(s) + Sn4+ (aq) at 25°C if
The equilibrium constant for the reaction is 1 × 106 ? [NEET 1999]
(a) 0.5328 V (b) 0.3552 V (c) 0.1773 V (d) 0.7104 V
55. Foe the cell reaction, Cu2+ (C1 , aq) + Zn(s) = Zn2+ (C2 , aq) + Cu(s) of an electrochemical cell, the
change in free energy, ∆G, at a given temperature is a function of
(a) In (C1 ) (b) In (C2 /C1 ) (c) In (C2 ) (d) In (C1 + C2 )
56. Without losing its concentration ZnCl2 solution cannot be kept in contact with [NEET 1998]
(a) Au (b) Al (c) Pb (d) Ag
57. 𝐸 0 for the cell, Zn | Zn2+ (aq) || Cu2+ (aq)|Cu is 1.10 𝑉 at 25°C. The equilibrium constant for the
cell reaction: Zn + Cu2+ (aq) ⇌ Cu + Zn2+ (aq), is of the order of [NEET 1997]
−18 −37 18 37
(a) 10 (b) 10 (c) 10 (d) 10
58. Standard potentials (E) for some half-reactions are given below: [NEET 1997]
4+ − 2+ 0
(1) Sn 2e → Sn ; E = +0.15 V
(2) 2Hg 2+ + 2e− → Hg 2+ 0
2 ; E = +0.92 V
(3) PbO2 + 4H + + 2e− → 2p2+ + 2H₂O; E 0 + 1.45 V
Based on the above, which one of the following statements is correct?
(a) 𝑆𝑛4+ is a stronger oxidising agent than 𝑃𝑏 4+
(b) 𝑆𝑛2+ is a stronger reducing agent than 𝐻𝑔2+
(c) 𝐻𝑔2+ is a stronger oxidising agent than 𝑃𝑏 4+
(d) 𝑃𝑏 2+ is a stronger reducing agent than 𝑆𝑛2+
59. The correct relationship between free energy and equilibrium constant K of a reaction is
(a) ∆G0 = −𝑅𝑇 𝑙𝑛 𝐾 (b) ∆G = RT ln K [NEET 1996]
(c) ∆G0 = RT ln K (d) ∆𝐺 = −RT ln K
60. An electrochemical cell is set up as: Pt; H2 (l atm) | HC1(0.1 M) || CH3 COOH (0.1 M) H₂ (l atm);
Pt. The e.m.f of this cell will not be zero, because [NEET 1995]
(a) the temperature is constant
(b) e.m.f depends on molarities of acids used
(c) acids used in two compartments are different
(d) pH of 0.1 M HCl and 0.1 M CH3 COOH is not same
61. If 0.5 A current is passed through acidified silver nitrate solution for 100 minutes. The mass of
silver deposited on cathode, is (eq.wt. of silver nitrate =108) [NEET 1995]
(a) 2.3523 g (b) 3.3575 g (c) 5.3578 g (d) 6.3575 g
62. The standard reduction potentials at 25℃ of Li+ /Li, Ba2+ /Ba, Na+ /Na and Mg 2+ /Mg are
−3.03, −2.73, −2.71 and −2.37 respectively. Which one of the following is the strongest
oxidizing agent? [NEET 1994]
+ + 2+ 2+
(a) 𝑁𝑎 (b) 𝐿𝑖 (c) 𝐵𝑎 (d) 𝑀𝑔
Topic 4: - Commercial Cells and Corrosion
63. A device that converts energy of combustion of fuels like hydrogen and methane, directly into
electrical energy is known as: [NEET 2015]
(a) Electrolytic cell (b) Dynamo (c) Ni-Cd cell (d) Fuel cell
64. A button cell used in watches functions as following
Zn(s) + Ag 2 O(s) + H2 O(l) ⇌ 2Ag(s) + Zn2+ (aq) + 2OH − (aq)
If half-cell potential are: Zn2+ (aq) + 2e− → Zn(s); E 0 = −0.76V
Ag 2 O(s) + H2 O(l) + 2e− → 2Ag(s) + 2OH − (aq); E 0 = 0.34V
The cell potential will be: [NEET 2013]
(a) 0.42 V (b) 0.84 V (c) 1.34 V (d) 1.10 V

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| DAV Basundhara | DAV Tensa | DAV Kalinga| DAV ITPS Banharpali
Classroom Helpline No.: 8093626300, 9853705762, 8210001633 |
65. Standard free energies of formation (in kJ/mol) at 298 K are −237.2, −394.4 and −8.2 for
0
H2 O(l), CO2 (g) and pentane (g), respectively. The value of Ecell for the pentane-oxygen fuel cell
is: [NEET 2008]
(a) 1.986 V (b) 2.0968 V (c) 1.0968 V (d) 0.0968 V
66. The efficiency of a fuel cell is given by [NEET 2007]
∆𝐺 ∆𝐺 ∆𝑆 ∆𝐻
(a) ∆𝑆 (b) ∆𝐻 (c) ∆𝐺 (d) ∆𝐺
67. In the silver planting of copper, K[Ag(CN)2 ] is used instead of AgNO3 . The reason is [NEET 2002]
(a) A thin layer of Ag is formed on Cu
(b) More voltage is required
(c) 𝐴𝑔+ ions are completely removed from solution
(d) Less availability of 𝐴𝑔+ ions, as Cu cannot displace Ag from [𝐴𝐺(𝐶𝑁)2 ]− ion
68. The most convenient method to protect the bottom of ship made of iron is [NEET 2001]
(a) Coating it with red lead oxide (b) White tin plating
(c) Connecting it with Mg block (d) Connecting it with Pb block
69. The most durable metal plating on iron to protect against corrosion is [NEET 1994 ]
(a) nickel plating (b) copper plating (c) tin plating (d) zinc plating

Answers
1. (c) 2. (d) 3. (a) 4. (d) 5. (b) 6. (b) 7. (d) 8. (d) 9. (a) 10. (c)
11. (d) 12. (d) 13. (b) 14. (b) 15. (c) 16. (d) 17. (c) 18. (c) 19. (a) 20. (d)
21. (c) 22. (d) 23. (c) 24. (a) 25. (d) 26. (b) 27. (a, b)28. (a) 29. (b) 30. (d)
31. (N) 32. (c) 33. (a) 34. (b) 35. (a) 36. (a) 37. (a) 38. (c) 39. (b) 40. (b)
41. (d) 42. (c) 43. (a) 44. (a) 45. (d) 46. (c) 47. (c) 48. (b) 49. (c) 50. (d)
51. (b) 52. (b) 53. (c) 54. (c) 55. (b) 56. (b) 57. (d) 58. (b) 59. (a) 60. (d)
61. (b) 62. (d) 63. (d) 64. (d) 65. (c) 66. (b) 67. (d) 68. (c) 69. (d)

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