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FIITJEE

PHYSICS, CHEMISTRY & MATHEMATICS


Topic: Phy: Current, Electrostatics, Capacitor, Magnetism, Unit dimension, EMI, SHM, AC & Surface Tension (Prop.
Of Matter); Chem: Thermodynamics & Thermochemistry, Solid State, Liquid Solution, Electrochemistry & Transition &
Co-ordiantion Compounds & Maths: QE, Progression and Series, Complex Nos. & Binomial

[ myPAT ]
PART TEST – 4 [PAPER – 2]
DATE: 22/10/2019
Time Allotted: 3 Hours Maximum Marks: 180

 Please read the instructions carefully. You are allotte d 5 minutes specifically for
BATCHES – (ADVANCED)

this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.

INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong
results.

A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
5. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.

B. Filling of OMR Sheet


1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Three Parts.
(i) Section – 1 (1 – 6) – contains six (06) multiple choice questions which have One or More correct answer.
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO incorrect
option is darkened.
Zero Marks: 0 If none of the bubbles is darkened. Negative Marks: 2 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will
result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B) will result
in 1 marks, as a wrong option is also darkened.

(ii) Section – 2 (07 – 14) contains 8 Numerical based questions with answers of the form XX.XX and
each question carries +3 marks for correct answer. There is no negative marking.

(iii) Section - 3 contains 4 Matrix Match Type questions containing statements given in 2 columns.
Statements in the first column have to be matched with statements in the second column. Each
question carries +3 marks for correct answer and – 1 mark for wrong answer.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

FIITJEE Ltd., Plot No. 47, Sector – 12B, Opposite Bal Bhawan International School, Dwarka, New Delhi – 110 075,
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PART – I : PHYSICS
SECTION – 1
(Multi Correct Answer Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE OR MORE THAN ONE may be correct.
1. Two particles of equal mass m and having opposite charges of modulus „q‟ each are placed in
free space at a distance r0 apart. A uniform and constant magnetic field of induction „B‟ is
established everywhere perpendicular to the line joining the particles, and the particles are
released. Then
 0 B2r03
(A) For a collision to occur between them, m 
4
 0 B2r03
(B) For a collision to occur between them, m 
2
(C) If there is no collision, between them, minimum distance between them is
r0  4m 
1  1  
2   0 B2r03 
(D) If there is no collision, between them, minimum distance between them is
 2m 
r0 1  1  
  0 B2r03 

2. In the region z < 0, a conducting medium having x D(a, –a, 0)


resistivity „‟ exists. Current I0 enters the x-y plane C(a, a, 0)
from point „C‟ and a current I0 leaves at D (as
shown in figure). A voltmeter is connected I0 I0
between points „A‟ and „B‟. Then
I  2  1 z
(A) Reading of voltmeter is 0  
  2 2a  B(–a, –a, 0)

I0 5  2 2 
(B) Reading of voltmeter is   y A(–a, a, 0) V
  2 2a 
 I0 a
(C) The value of E at mid point on the line joining AB is  ĵ
 
3
 5a
 I0 a
(D) The value of E at mid point on the line joining AB is  ĵ
 
3
 7a

3. Two balls of charge q1 and q2 initially have a velocity of the same magnitude and direction. After a
uniform electric field has been applied during a certain time, the direction of the velocity of the first
ball changes by 60°, and the velocity magnitude is reduced by half. The direction of the velocity of
the second ball changes thereby by 90°. In what proportion will the velocity of the second ball
change?
2
(A) (B)
3 3
1 1
(C) (D)
3 2 3

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4. One end of a horizontal track of gauge l and negligible resistance, is connected to a capacitor of
capacitance C charged to voltage V0. The inductance of the assembly is negligible. The system is
placed in a homogenous, vertical magnetic field of induction B, as shown in the figure.
A frictionless conducting rod of mass m and resistance R is placed perpendicularly onto the track.
The polarity of the capacitor is such that the rod is repelled from the capacitor when the switch is
turned over.
What is the maximum velocity of the rod?

BCV0 2BCV0
(A) (B)
mB  C
2 2
m  B2  2 C
BCV0 BCV0
(C) (D)
2m  B2 2C m  2B2 2C

5. A solid metal cylinder rotates with angular velocity  about its axis of symmetry. The cylinder is in
a homogeneous magnetic field B parallel to its axis. What is the resultant charge distribution
inside the cylinder?
20 m  B  20 m  B 
(A)    (B)   
e  m e  m
 m  B  20 m  B 
(C) 0    (D)   
e  2m  e  2m 

6. A capacitor in an LC oscillator has a maximum potential difference of 15V and a maximum energy
of 360 J. At a certain instant t = t0 the energy in the inductor is 320 J, at that instant, the
potential difference across the capacitor is V volt?
(A) The value of capacitance is 1.6 F (B) The value of capacitance is 3.2 F
(C) The value of V is 5 Volt (D) The value of V is 10 Volt

SECTION – 2
(Numerical Answer Type)
This section contains 8 questions. The answer to each question is of the form XX.XX. The correct digit
below the question number in the ORS is to be bubbled.

a 2b 4
7. A physical quantity x is calculated from relation x  . If percentage error in a, b, c & d are
c d
a 2b 4
2.43 %, 1.51 %, 3.56 % & 4.26 %. Find out percentage error in x  .
c d

8. The pitch of screw gauge is 1 mm and there are 50 divisions on its circular scale. When nothing is
put in between its jaws, the zero of circular scale lies 4 divisions below the reference line. When a
wire is placed between the jaws, 3 linear scale divisions are clearly visible while 42 divisions on
circular scale coincide with reference line. Determine diameter of wire.

9. A homogeneous beam of protons accelerated through a potential difference v = 500 kv has


–3
circular cross section at radius R = 4 mm. Assuming beam current i = 32  10 A. Find the
surface of beam in kv/m.

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10. What amount of heat will be generated in a coil of resistance 3  due to a charge q = 0.5 C
passing through it if the current in the coil decreases down to zero uniformly during a time interval
2 sec.

11. Figure shows a long straight conductor carrying current i. A wooden


disc of mass m and radius R is placed near it such that conductor
lies in the plane of the disc. The distance between wire and centre
of the disc is 5R. A wire of length R and carrying current i0 is posted i Hinge

on the disc such that the wire is perpendicular to the long straight i0
conductor. The disc is hinged at the centre. Neglecting mass of the
conducting wire, then angular acceleration of the disc at this initial
5R R
 ii
instant is 0 0 (1 – 5 ln k). The value of k is
mR

12. In the figure shown W1 represent the cross section of an infinitely


long wire carrying current I1 into the plane of the figure AB is a line A D
of length L and the wire W1 is symmetrically located with respect to
B  
the line. The line integral  B  dl along the line from A to B is equal
A w1 w2
to a0 where a0 is a positive number. Another long wire W2 is 
l1 l2
placed symmetrically with respect to AB (see figure) and the value of
B  

A
 B  d becomes zero. Consider a line DC to the right of W2. The d d
line is parallel to AB and has same length. The two wires fall on B C
D  
perpendicular bisector of both lines. If  B  d  2a0 with both wires
C

I2
W1 and W2 present, calculate the ratio of current in the two wires.
I1

13. A current carrying loop is in the shape of an


equilateral triangle of side length a  3 3. Its mass     
is M and it is in vertical plane. There exists a uniform
A B
horizontal magnetic field B in the region shown. The     

3 B
loop is in equilibrium for y 0  a. The loop is
4     
displaced slightly in its plane perpendicular to its
side AB and released. Find time period of its y
oscillations. Neglect emf induced in the loop.
Express your answer in terms of a and g. C

14. A charged particle of mass m and charge +q is projected on a rough horizontal x-y plane, where

both electric rod magnetic fields are acting in the region and are given by E  E0kˆ and

ˆ The particle enters into the field at (a0, 0, 0) with velocity v  1jˆ (m/s). If coefficient of
B  B k.
0
friction between the particle and plane is b, the length of path travelled by the particle when it
km
comes to rest is . The value of K is
(mg  qE)

FIITJEE Ltd., Plot No. 47, Sector – 12B, Opposite Bal Bhawan International School, Dwarka, New Delhi – 110 075,
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SECTION – 3
(MatrixMatch Type)
This Section contains 4 questions. Each question has four statements (A, B, C and D) given in Column
I and five statements (p, q, r, s and t) in Column II. Any given statement in Column I can have correct
matching with ONE or MORE statement(s) given in Column II. For example, if for a given question,
statement B matches with the statements given in q and r, then for the particular question, against
statement B, darken the bubbles corresponding to q and r in the ORS.

15. Homogeneous plank with given dimensions is pulled in following ways. Match with the developed
elongation given in column-II
Column I Column II
3FL
(A) F (p)
L 2Ay
2FL
(B) F 2F (q)
L Ay
FL
(C) 2F F 3F (r)
L/2 L/2 2Ay
5FL
(D) F 2F 3F (s)
2Ay
L/2 L/2
(A) (A) – r; (B) – p; (C) – s; (D) – q (B) (A) – q; (B) – p; (C) – s; (D) – r
(C) (A) – r; (B) – s; (C) – p; (D) – q (D) (A) – r; (B) – r; (C) – s; (D) – s

16. Two identical capacitors are connected in series, and the combination is + –
connected with a battery as shown. Some changes in the capacitor 1 are
now made independently after the steady state is achieved, listed in
Column-I. Some effects which may occur in new steady state due to these
changes on the capacitor 2 are listed in column-II. Match the changes in
capacitor 1 in column-I with corresponding effect on capacitor 2 in Cap.1 Cap.2
column-II.
Column I Column II
(A) A dielectric slab is inserted (p) Charge on the capacitor increases
(B) Separation between plates increased (q) Charge on the capacitor decreases
(C) A metal plate is inserted connecting both plates (r) Energy stored in the capacitor increases
(D) The left plate is grounded (s) No change is occurred
(A) (A) – r; (B) – q; (C) – r; (D) – s (B) (A) – p; (B) – q; (C) – p; (D) – s
(C) (A) – p, r; (B) – q; (C) – p, r; (D) – s (D) (A) – p, r; (B) – s; (C) – p, r; (D) – q

17. In each situation of column-I, a circuit involving two non-ideal cells of unequal emf E1 and E2
(E1 > E2) and equal internal resistance r are given. A resistor of resistance R is connected in all
four situations and a capacitor of capacitance C is connected in last two situations as shown.
Four statements are given in column-II. Match the situation of column-I with statements in
column-II.
Column I Column II
(p) Magnitude of potential difference
(A) R across both cells can never be same
E1, r E2, r

(q) Cell of lower emf absorbs energy, that


(B) R is, it gets charged up as long as current
E1, r E2, r flows in circuit

(r) Potential difference across cell of lower


R C
(C) emf may be zero
E1, r K E2, r

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(s) Current in the circuit can never be zero


R C
(D) (even after steady state is reached)
E1, r K E2, r

(A) (A) – p, q; (B) – p, r; (C) – p, q; (D) – p, r (B) (A) – p, s; (B) – p, s; (C) – p, q; (D) – p, r
(C) (A) – p, q, s; (B) – p, s; (C) – p; (D) – r (D) (A) – p, q, s; (B) – p, r, s; (C) – p, q; (D) – p, r

18. Match the statements in Column I with the results in Column II.
Column I Column II
(A) A variable resistor is connected across a (p) First increases for some time
non-ideal cell. As the resistance of the and then decreases
variable resistor is continuously increased
from zero to a very large value, the electric
power consumed by the variable resistor:
(B) A circular ring lies in space having uniform (q) Find decreases for some time
and constant magnetic field. Initially the and then increases
direction of magnetic field is parallel to
plane of the ring. Keeping the centre of ring
fixed, the ring is rotated by 180° about one
of its diameter with constant angular speed.
For the duration the ring rotates, the
magnitude of induced emf in the ring:
(C) A thin rod of length 1 cm lies along principal (r) Is always constant
axis of a convex lens of focal length 5 cm.
One end of rod is at a distance 10 cm from
optical centre of the lens. The convex lens
is moved (without rotation) perpendicular to
initial principal axis by 5 mm and brought
back to its initial position. The length of the
image of the rod:
(D) A bulb (of negligible inductance) and a (s) Increases or may increase over
capacitor in series are connected across an some time interval
ideal AC source of constant peak voltage
and variable frequency. As frequency of AC
source is continuously increased, the
brightness of bulb:
(A) (A) – p; (B) – q; (C) – p, s; (D) – s (B) (A) – p, s; (B) – q, s; (C) – p, s; (D) – s
(C) (A) – s; (B) – q, s; (C) – s; (D) – s (D) (A) – p; (B) – q; (C) – p; (D) – s

Rough work

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PART – II : CHEMISTRY
SECTION – 1
(Multi Correct Answer Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE OR MORE THAN ONE may be correct.
1. Which of the following statement(s) is/are correct?
(A) For ideal gas in an isothermal reversible expansion, heat can be converted into work 100%
(B) In adiabatic reversible expansion, minimum cooling effect is obtained for monoatomic gas.
(C) When two gases are present in equal moles under similar condition of pressure and
temperature, on their mixing entropy change will be maximum.
(D)  dGT,P  O is condition of spontaning for a process occurring at constant temperature and
pressure.

2. Select the correct statements


3
(A) Fe  C2O4 3  is optically active even though it has simple axis of rotation other than one
fold
4
(B) In the complex ion, Fe  CN6  the total number of valence electrons around Fe and formal
charge on Fe are respectively 18 and –4.
3
(C) Fac and Mer geometrical isomerism is not possible in Co  en3  , where en is
H2N  CH2CH2NH2
(D) All of above

3. Which of the following statement are correct


(A) If a body centred cubic lattice is mode up of hollow sphere of B in which a sphere of solid A
having radius half of B are present then ratio of total volume of sphere of B unoccupied by A is a
unit cell and volume of unit cell is 7 3 64
(B) If distance between next to next nearest neighbour in FCC unit cell is 4.8Aº then distance
between corner to its nearest tetrahedral void will be 1.7Aº  1.5  1.2and 3  1.7 
 
(C) If distance between two nearest parallel planes in graphite is 3.4Aº then density of graphite
will be 1.37 gm/cc  3  1.7 
 
 2 
(D) In the configuration shown, the size of the smallest circle is   1 times the size of the
 3 
highest circles.

4. For which of the compound(s) conductivity (k) and molar conductance (m) both charge on
dilution
(A) HCl (aq) (B) CH3COOH aq
(C) AgCl (saturated solution (D) NaOH(aq)

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5. The enthalpy of reaction at 273 K is –3.75 kJ. What will be the enthalpy of reaction at 373 K is
CP is assumed to be zero.
(A) 3.75kJ (B) zero
373
(C) 3.75  kJ (D) 3750J
273

6. Set of orbitals which is/are used by central metal during formation of MnO4 .
(A) S (B) dxy , dyz , dxz
(C) px ,p4 ,d2 (D) dx2  y2 ,d22

SECTION – 2
(Integer Answer Type)
This section contains 8 questions. The answer to each question is a single-digit integer, ranging from 0
to 9. The correct digit below the question number in the ORS is to be bubbled.
7. If an ideal binary solution of two volatile components A and B are in equilibrium with atmospheric
pressure at T Kelvin. Find PAº 1  PBº  in atmosphere. If the mole fraction of more volatile
component in solution is 0.5.

1 atm

8. A perfect diatomic gas at 500 K undergoes following steps of process


(a) An isochoric change of state from (0.5 atm, 80 litre) to (1atm, 80 litre)
(b) An isobaric change from (1 atm, 80 litre) to (1 atm, 20 litre). If all processes are irreversible
than calculate the magnitude of entropy change (in J/K) of surrounding for entire process.
[use ln = 0.7, R = 0.08 atm-litre/K-mole, 1 lit-atm = 100 J)

9. When zinc is refined by electrolysis, the desired half reaction at the cathode is
Zn2aq  2e   Zn  s 
A competing reaction, which lowers the yield, is the formation of hydrogen gas
2H aq  2e  H2  g
 
If 91.26% of the current flowing results in zinc being deposited, while 8.74% produces hydrogen
gas, how many litres of H2 , measured STP, form per kilogram of zinc? [Zn = 64)

10. 1342 gm of 1.0 molal sucrose (M.W = 342) solution in water is cooled to –3.0ºC. What weight of
ice (in gm) would be separated out at this temperature? Given that the amount of ice that
separates out on cooling a solution containing 50 g of glycol OH  CH2CH2  OH in 0.2 kg water
to –10ºC is 50 gm. [Assume ideal conductive]

11. In the cell reaction


(i) Au   Au3   3e G  n1FE1
(ii) 3Au  3e 
 3Au G2  n2FE2
Overall 3Au   Au3   2Au G3  nFE
reaction
What should be the value of n here?

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12. Consider the following unit cell structure of graphite. Find out density of graphite.
 3  1.7  N
A  6  1023 

º
3.4A

º
2.46A
a  lattice parameter

d  C  C bond length

a  2 d cos 30º
 3d

d
d  1.42A
º
x y

a  2.46A
º
120º

13. How many of following statements are correct?

a. One type of unit cells are possible for the crystallographic dimension as a  b  c and
      90.
b. Number of next neighbours of Cs  ion in CsCl structure is 6Cs  ions.
c. A crystal has A ions at the cube corners and B
ions at the edge centres. The coordination B

numbers of A and B are respectively 6 and 2.


3+
A

coordination
no of A = 6.

d. Distance between cation and its next-neighbour in ZnS (zinc blande) is 1 4 of the length of
body diagonal.

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e. In the configuration shown the size of the


 2 
smallest circle is   1 times the size of
 3 
the biggest circles.

f. In the unit cell of HCP structure, the three


atoms shown in layer B are completely inside
the unit cell. Layer A
Layer B
Layer C

g. Six fold axis of symmetry is present in hexagonal close packing.

h. A rhombohedral unit cell is shown. Its volume


3
is a 3 A 3 , where side length is A 60
120
2
a
60 120

60
120 60a
a

14. For each of the following processes, state which of the quantities ∆U, ∆H, ∆S, ∆A, and ∆G are
equal to zero( Give your answer as sum of numbers for each option- like for one quantity your
answer is 1 for two your answer is 2, like wise, than add all numbers to give final answer)
a. Isothermal reversible expansion of an ideal gas.
b. Adiabatic reversible expansion of a nonideal gas.
c. Vaporization of liquid water at 80 °C and 1 bar pressure.
d. Vaporization of liquid water at 100 °C and 1 bar pressure.
e. Reaction between H2 and O2 in a thermally insulated bomb.
f. Reaction between H2SO4 and NaOH in dilute aqueous solution at constant temperature and
pressure.

SECTION – 3
(MatrixMatch Type)
This Section contains 4 questions. Each question has four statements (A, B, C and D) given in Column
I and five statements (p, q, r, s and t) in Column II. Any given statement in Column I can have correct
matching with ONE or MORE statement(s) given in Column II. For example, if for a given question,
statement B matches with the statements given in q and r, then for the particular question, against
statement B, darken the bubbles corresponding to q and r in the ORS.
15. Match the column
Column-I (Compound) Column-II (Dissolves ln)
(P) Ag2O (1) Aq.NH3
(Q) Ag2S (2) KCN
(R) AgCl (3) HNO3
(S) Ag2CrO4 (4) Na2S2O3
K sp  AgCl  10 10
, K sp  Ag2S  10 , K sp  Ag2CrO4   1012
51

Codes:

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P Q R S
A 4 1 1 2
B  2 2 2 1
C 1 3 4 1
D  3 4 3 4

16. Match the column


List-I (Complex) List-II (Possible number of
geometrical isomers)

(P) CrCl2 NO2 2 NH3 2  (1) 2

(Q) CO NO2 3 NH3 3  (2) 0


(R) PtCl NO2 NH3 Py  (3) 5

(S) PtBrCl  en (4) 3


Codes:
P Q R S
A 3 1 1 2
B  3 4 1 2
C 3 2 2 4
D  3 1 4 2

17. Match the column


List-I (Ion involved) List-II (Complexing agent)
(P) Ni2 (1) Sodium thiosulphate
(Q) Ag (2) Sodium nitroprusside
(R) Cu2 (3) Ammonia
(S) 2 (4) Dimethylglyoxime
S
Codes:
P Q R S
A 3 1 4 2
B  4 3 1 2
C 4 3 2 1
D  4 1 3 2

18. Match the column


Column-I Column-II
(P) Cubic (1) Have-2 fold axis of symmetry
(Q) Orthorhombic (2) Have all axial angles identical
(R) Tetragonal (3) Have all edge length identical
(S) Rhomohedral (4) More than one types of Bravias lattices
are found
Codes:
P Q R S
A 1 1 1 1
B  2 2 2 2
C 3 3 3 3
D  4 4 4 4

Rough work

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PART – III : Mathematics


SECTION – 1
(Multi Correct Answer Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE OR MORE THAN ONE may be correct.

1. If Sn  2(w  1)(w 2  1)  3(2w  1)(2w 2  1)  4(3w  1)(3w 2  1) ....n terms then the correct
statements is/are n  3 (w is non-real cube roots of unity)
(A) Sn cannot be a prime number (B) unit digit of S24 is 4
(C) Sn is always divisible by n (D) Sn is an increasing sequence

Given that 1  x   c 0  c1x  c 2 x 2  .....cn xn and the series


n
2.
S1  c0  c3  c 6  .....
S2  c1  c 4  c7  .....
S3  c 2  c5  c8  .....
Are continued as for as possible then which of following is/are incorrect.
1 (n  1)  1  n  
(A) S1  2n  2cos (B) S1  2n  2cos   
3 3  3  3 
1 n (n  2)  1 n (n  2) 
(C) S2   2  2cos (D) S3  2  2cos
3 3  
3 3 

n 1
 k 
3. If S(n)   ( 1)k cosn   , then choose correct options.
k 0  n 
101 100 100 100
(A) S(101)  100 (B) S(100)  100 (C) S(100)  99 (D) S(101) 
2 2 2 2101

30 r
30
Cr (2r  1)
4. Let S  
r 1
30
Cr (30  r)

 
30
K
2
30
Cr
r 0

 
60
G     1
r 2
60
Cr
r 0

Then which of following is/are correct.


(A) G  S  1 (B) SK  SG  0 (C) K  G  2S  2 (D) K  G  2S  2

8 16 24
5. Let Sn be the sum of n terms of series    ..... Then which of following is/are correct.
5 65 325
56
(A) lim Sn  2 (B) The seventh term of series 
n 9604
288 287
(C) Value of S8  (D) Value of S8 
145 145

6. The letters of the word “CALCULUS” are arranged in all possible w ays. Then the number of
words in which
(A) 2C‟s are separated is 3780.
(B) 2C‟s and 2L‟s are separated is 2880
(C) 2C‟s are separated but 2L‟s are together is 900.
(D) 2C‟s and 2L‟s are together is 360.

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SECTION – 2
(Numerical Answer Type)

This section contains 8 questions. The answer to each question is of the form XX.XX. The correct digit
below the question number in the ORS is to be bubbled.

7. Consider a 7-digit telephone number 336 – 7624 which has property that the first three-digit
prefix, 336 equals the product of the last four digits. How many seven-digit phone numbers
beginning with 336 have this property other than 336 – 7624.


1 n
 2e  e 1
 n!  (k  1) 2
1
(k 1)x
8. If the sum of following infinite series dx  is , then 
n0 k 0
0
  log2 

9. a, b, c are cube root of p(p  0) . Then for any permissible value of x, y, z which is given by
xa  yb  zc
xb  yc  za
 
 a12  2b12   2 [x]  [y]  [z]   0

Where  is cube roots of unity and a1, b1 are real positive number and b1is prime number. Find
the value of [x  a1 ]  [y b1]  [z] . Where [ ] GIF.

10. Let A  a  R | The equation (1  2i)x3  2(3  i)x2  (5  4i)x  2a2  0 } has at least one real
roots. Then value of a 2

z2 4 20 
11. If z lies on the locus  2 and by transformation  z    i  a new locus is formed
zi  9 
3

then the greatest value of || is


2
3

m  n then m2  n2  
12. p(x) be a 5-degree polynomial with integer coefficients, p(x) = 0 has at least one integral root. If
p(2) = 13 and p(10) = 5, let  is the integral root p(x) = 0 then find the sum of all the digits of  (or
 itself if < 10)

13. If sum of the rational solutions of the set of equations is p


x2  y2  z2  45
 y  z   z  x   x  y   18
3xyz  x3  y3  z3  67 , Then the value of |P| is

14. Let A  2 , B  2i and C  4  be three points lying on the Argand plane. Now a point P is taken
on the circumcircle of the triangle ABC such that PA.BC = PC . AB, (where P, A, B, C are in
2
order). If z is the complex number associated with the mid-point of PB, then the value of |z| is.
( is a non-real cube root of unity)

SECTION – 3
(MatrixMatch Type)
This Section contains 4 questions. Each question has four statements (A, B, C and D) given in Column
I and five statements (p, q, r, s and t) in Column II. Any given statement in Column I can have correct
matching with ONE or MORE statement(s) given in Column II. For example, if for a given question,
statement B matches with the statements given in q and r, then for the particular question, against
statement B, darken the bubbles corresponding to q and r in the ORS.

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15. Match the following:

Column I Column II
(P) If  n  210, Then  n2 is divisible by the greatest prime (1) 16
number which is greater than
(Q) Between 4 and 2916 is inserted odd number (2n+1) G, m‟s (2) 10
th
then the (n+1) G.M is divisible by the greatest odd integer
which is less than
(R) In a certain progression four consecutive terms are 40, 30, 24, (3) 34
20. Then the integral part of progression is more than
(S) 4 7 10 a (4) 30
1   2  3  .....  where H.C.F (a, b) is less than
5 5 5 b
(5) 0

(A)P 1,2,3; Q1,2,3,4,5; R1,2,5; S3,4 (B) P 1,2,3,4,5; Q1,2; R1,2,3; S5
(C)P 1,2,3,4,5; Q3,4; R1,2,5; S3,4 (D) P 3,4; Q1,2,3,4,5; R1,2,5; S3,4

16. Match the following

Column I Column II
(P) If z  2i  z  7i  k then locus of z is an ellipse if k = (1) 7
0
(Q) 2z  3 2 (2) 8
If  k, then locus of z is a circle if is a
3z  2 3
3
point inside circle and is outside the circle if
2
k=
(R) If z  3  z  4i  k then locus of z is a hyperbola if k (3) 2
is
(S) k (4) 4
If z  (3  4i)  az  az  b where a  3  4i .
50
Then locus of z is Hyperbola with k =
(5) 5
(A) P 1,2; Q 1,2,3,4,5; R 1,2; S 3,4 (B) P 1,2,3,4,5; Q 1,2; R 3,4; S 1,2
(C) P 1,2; Q 1,2,3,4,5; R 3,4; S 4,5 (D) P 1,2; Q 1,2,3,4,5; R 3,4; S 1,2

n 7
17. Let Sn   r!, then for n > 7 (Given  r!,  4340 ). Match the following List – I and List – II
r 1 r 1

List I List II
(P)   S   (1) 2 - 5
tan1  tan  Sn  8  n   1 
   8  
(Q)   S   (2) 5 – 2
cos1  cos  Sn  8  n   1 
   8  
(R)   
 1 
tan (3) 2x + 2
  n2   n  
The value of  lim  2    2 is
 n  n  1  
n 
(S) ln2i  ln  n  (4) 2x +1
If lim   lnk, then ek + 2 is
n n
i 1

(A) P2; Q1; R4; S3 (B) P2; Q4; R1; S3
(C) P1; Q2; R4; S3 (D) P2; Q1; R3; S4

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18. Match List – I with List - II

List – I List - II
(P) No. of possible 4 digit no. of the form a1a2a3a4 such (1) 62
that a1> a2  a3 > a4
3 8 6
(Q) No. of divisor of n = 2 × 7 × 5 of the form 4+2, (2) 510  5 C159  5 C2 58  5 C3 57
1
 5 C4 56  5 C5 55
(R) If f : {x1,x2 ,x3 ,x4 .......x10 }  {y1,y2 ,y3 ,y 4 ,y5 } then (3) 330
no. of possible function in which f (xi) yi
(S) Number of triangles can be formed by joining the 3 (4) 120
vertices of a convex polygon of 35 diagonals

(A) P1; Q2; R2; S4 (B) P1; Q1; R2; S3
(C) P4; Q1; R2; S3 (D) P3; Q1; R2; S4

Rough work

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FIITJEE INTERNAL TEST


[ myPAT ]
PART TEST – 4 [PAPER – 2]
DATE: 22/10/2019
ANSWERS KEY
PART – I
PHYSICS
SECTION – 1
1. A, C P120303
2. A, C P120202
3. C P120102
4. A P120403
5. A, B P120106
6. B, C P120208
SECTION – 2
7. 16.59 P110101
8. 03.76 P110104
9. 14.40 P120102
10. 00.50 P120205
11. 01.20 P120301
12. 02.41 P120302
13. 09.14 P111104
14. 00.50 P120304
SECTION – 3
15. A P111101
16. C P120110
17. D P120112
18. B P120205

PART – II
CHEMISTRY
SECTION – 1
1. A, C, D
2. A, B, C, D
3. A, B
4. A, B, D
5. A, D
6. A, B
SECTION – 2
7. 2
8. 74 J/K
9. 33.6 litre
10. 380 gm
11. 2
12. 2.20g/cc
13. 3
14. 5
SECTION – 3
15. C
16. D
17. D
18. B

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MATHEMATICS
SECTION – 1
Section-1
1. A, B, D
2. A
3. A, C
4. A, B, D
5. A, C
6. A, B, C, D

SECTION – 2
7. 83
8. 0.50
9. 6
10. 18
11. 61
12. 6
13. 1
14. 0
SECTION – 3

15. C
16. D
17. A
18. D

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HINTS & SOLUTIONS


PHYSICS
SECTION – A
1. A, C
In x direction
r0 r
 x
2 2
In y direction qvB  V
dv y
qv xBcos   m 
dt (x, y)
t Vy

qB Vx dt  m  dVy r
0 0

qB
qBx  mVy  Vy  x r0
m
By Conservation of energy
kq2 kq2
   mv 2
r0 r
1 1 
kq2     m Vx2  Vy2  
 r r0 
At minimum dist.
Vx  0
1 1 
kq2     mVy2
 r r0 
 r  r  q2B2 2
kq2  0  x
 r  r0  m
From these equation
2km
2x 2  r0 x  2  0
B r0
Where, r0 – r = 2x
2. A, C
I
J 0 2
2r
I
E  02
2r
2 2a
VAB   
2a
E.dr

3. C
For q1
V Exq1
cos60  V  t
2 m
V Eyq1
sin60  t
2 m
For q2
Exq2
0V t
m
Ey
V  q2 xt
m
4. A
BV0
Initial acceleration a 
mR

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Qmin
Bv max 
C
dQ
ma  B
dt
mvmax  B(Q0  Qmin )
BCV0 B2 2C2 V0
From these equation vmax andQ 
m  B2  2 C m  B2  2 C
min

5. A, B
eE  erB  mr2 r r
 m2 
E  B  r  Kr,
 e 
Electric flux of magnitude 2LE(r) enters the shell and a flux of
2(r  r)LE(r  r) leaves it. E
L
K(r  r)2(r  r)L  Kr2rL  (1/ 0 )2rrL
From this we obtain
2 m  eB 
 0  
e  m 
6. B, C
1 360  106  2
CV02  360  106  C  F
2 225
When energy stored in capacitor is 40 J, then let potential difference across the capacitor is V
volt, so
1 1 360  106  2
CV 2  40  106    V 2  40  106
2 2 225
40  106  225
 V2 
360  106
 V = 5 volt
SECTION – 2
7. 16.59
x  a 4b c 1 d 
  2   
x  a b c 2 d 
 1 
 2  2.43  4  1.51  3.56   4.26  %
 2 
= [4.86 + 6.04 + 3.56 + 2.13]
= 16.59 %
8. 03.76
1mm
Least count   0.2 mm
50
Positive error of instrument = (4  0.02) = 0.08 mm
Linear scale reading = 3  1 mm = 3 mm
Circular scale reading = 42  0.02mm = 0.84 mm
So measured reading = 3 + 0.84 = 3.84 mm
True reading = 3.84 – 0.08 = 3.76 mm
9. 14.40
i
E
2 0 rV
1
mV 2  eV
2
10. 00.50 Jule
 t 
i  I0  1  
 t 

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2q
I0 
t
2q  t 
i  1 
t  t 
t
H   I2Rdt
0
11. 01.20
I (dx)0i
dF  0
2x
d  (dF)(x  5R)
12. 02.41
Current in W2 must be outward
B  
In the field of I1 we have  B1d  a0
A
B  
In the field of I2 we have  B d  a
A
2 0

For CD
D    I1 
 B d  a  I
C
1 
2 

D    I2 
 B d  a
C
2 0  
 I1 
13. 09.14
a
For equilibrium I   B  Mg
2
dy2   3  
M 2  Mg  I 2  a  y  tan30 B
 
dt   4  
2IB

3M
14. 00.50
1
()(qE0  mg)S  m(1)2
2
SECTION – 3
15. A
Calculate tension at any point on the rod
Using this tension calculate extension in small element of length dx
From this calculate total extension
16. C
(A) By inserting dielectric slab, capacitance of 1 increases thereby increasing charge on capacitor
2 as more charge is flown through the battery. Energy stored in capacitor also increases.
(B) By inserting separation between the plates, capacitor C 1 decreases. Charge on C2 also
decreases.
(C) By shorting capacitor 1, only capacitor 2 remains in the circuit. Potential difference across C 2
increases thereby increasing charge on 2 as well as energy stored.
(D) By earthing plate of capacitor 1 potentials will change but there will be no potential difference
change, making no overall change in the circuit.

17. D
E1  E2  E1  E2 
(A) Ei  ir  E2  ir or i  
2r  2r  R 
Hence potential difference both cells cannot be same.
For potential difference cell of lower emf to be zero E2 + ir = 0 which is not possible.
 E1  E2
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(B) For potential difference across cell of lower emf to be zero


E2  ir  0 and E1  i(r  R)  0
E1 E
or  2
r R r
E1  E2
(C) Situation is same as in (a) except current decreases from to zero
2r  R
E  E2
(D) Situation is same as in (b) except current decreases from 1 to zero.
2r  R
18. B
(A)
P

R
(B) f  BA sin t
d
emf   Ba cos t
dt
(C) As the lens is moved up, the projection of length of image on principal axis remains same, but
its slant with principal axis increases. This increase is due to the fact that lateral magnification of
each point of image of rod is different. Hence as lens moves up the size of image increases and
when it moves down the size of image decreases.
(D) As frequency of AC source increases, reactance of capacitor decreases. Therefore the bulb
glows more brighter.

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CHEMISTRY
1. A, C, D
2. A, B, C, D

O O

Fe 
 C2 Axis
Sol.
O O

O
3. A, B
(A) If size of sphere is is 2r and sphere A is r. Volume left unoccupied in sphere B is
4 4
   2r   r 3
3

3 3
4 3
 7  r
3
In BCC there are two effective sphere of B
4 4
2  7  r 3 2  7  r 3
So, = 3  3
a3
 
3
8r 3

= 7 3 64

3
(B) Next tonext  a Next Nearest  a
2

3
Distance from corner atom to tetrahedral void is
4
On solving a  4A
º

4. A, B, D
5. A, D
From Kirchhoff‟s equation
H2  H1
 CPº
T2  T1
H2  H1  3.75kJ1
H2  H1  3.75kJ1
6. A, B
Hybridisation of Mn in MnO4 is d3 s.
7. 2
Ptotal  1atm
Ptotal  PAº  0.5  PBº  0.5
PAº  PBº  2
8. 74 J/K
State  1 State  2 State  3
0.5atm 1.0atm 1atm
80litre 80litre 20litre
500K 1000K 250K
1mole 1mole 1mole

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q  5
 nCV T  1 R 1000  500
sys step 1
2
250
 R
2
2500
 qsys   2
 Ssurr. Step 1      R
 T  1000
2.5
 R
2
q  sys Step  2  n CP T
7 5250
 1 R 250  1000   R
2 2

5250
 qsys  R
21
 Ssurr. Step2      2  R
 T  250 2
2.5 21 18.5
 S surr.    R  R  R
2 2 2
= 74 J/K.
9. 33.6 litre
10. 380 gm
TF  KF  molality
10  150  103  62
Kf   1.86
50
1342 gm of 1 molal sucrose solution = 342 gm of sucrose in 1 kg of H2O
1
3.0  1.86 
W  103
WH2O  620gm
Wice  1000  620  380gm.
11. 2
12. 2.20g/cc
Volume of unit cell = base area  height
Area = 2  equilateral triangle
3 2 3
 
2
2 a  2  2.46  108 cm2
4 4
3
  2.46   6.8  1024 cm3
2
Volume =
2
There are 4 effective no of atoms in each unit cell
4  12
density 
3
  2.46   6.8  1024  6  1023
2

2
8  4  3  10
=
 2.46 
2
 6.8  6
544
  2.20
246.9
13. 3
1. False

2. True

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C.N of cation charge of cation 3


3. True   3 –
C.N of anion charge of anion 1 B
Now Co-ordination no. of A is as
3+
shown so of B is 2. A

coordination
no of A = 6.
4. False

5. False

6. False

7. True

8. False Using vector algebra, calculate box product of vectors along three sides of
a3
given unit cell and volume is
2

14. 5
(a) 2, isothermal reversible expansion of an ideal gas U & H are zero
(b) 1, S will be zero
(c) 0
(d) 1, G is zero, the system will be at equilibrium
(e) 1, U will be equal to zero
(f) 0

15. C
Ag2S is not soluble in aq. NH3 or Na2S2O3 .
16. D
17. D
18. B

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MATHEMATICS
1. A, B, D
tn  (n  1)(nw  1)(nw 2  1)
tn  n3  1
 n(n  1)2 
Sn  n   1
 4 
2. A
2n  c0  c1  ....cn ...(1)
(1  w)  c 0  c1w  c 2 w  ....cn wn
n 2
..(2)
(1  w )  c0  c1w  c 2 w  ....cn w
2 n 2 4 2n
..(3)
S1  (1)  (2)  (3)
S2  (1)  w 2 (z)  w(3)
S3 (1)  w(2)  w 2 (3)
3. A, C
n
 kni 
ki

n  k  e n 
n 1 n 1
k e
S(n)   ( 1) cos     ( 1)
k

k 0  n  k 0  2 
 
n 1 kn
  ( 1)k n 1  x 2k 
x n

k 0 2
i
Let e n  x
(n 1)
( 1)2k  n n 
S(n)  
k 0
n  
2  r 0
Cr x 2kr 

1  n  n1 2kr  
n 1
   Cr   x  
2n  r 0  k 0 
1  n1 n 

2n  r 1

 Cr 1  x2r  x 4r  ..... nc0 n n

Cn 

1  n1  1  x 2nr   n n
 n  nCr  2r  
 
2  r 1  1  x  2n 2n
n
 n 1
2
4. A, B, D
30  r 30  r
30
Cr (2r  1) 30
Cr  30  r  1 
S   1  30  r 
r 1
30
Cr (30  r) r 1
30
Cr  
30
 30 r C 30 r
C 30  r  1
   30 r  30 r . 
r 1  C r C r 30  r 
 (30  r) 29 r 
30  30  r Cr 1
Cr  31  r  
   30  r . 
 30  r  
30
r 1  Cr Cr
 
30
 30 r C Cr 1 
29  r
 nC n  r  1
   30 r  30   n r  
r 1  Cr Cr 1   Cr 1 r 
 C30  1
60

k  60C30
5. A, C
8r 8r
tr  
4r  1 (2r  2r  1)(2r 2  2r  1)
4 2

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6. A, B, C, D
7. 83
336  24.3.7
Now a seven digit telephone of the form 336 d1d2 d3 d4 such that d1d2 d3 d4  336 where
di  1,2,......9
d1d2d3 d4  7  3  2  8  4!
4!
7344 
2!
7618  4!
7246  4!
4!
Total ways = 3 4!  84
2!
Other than 336 - 7624 84 - 1 = 83
8. 0.50
9. 6
xa  yb  zc
 (a12  2b12 )  [x]  [y]  [z] 
xb  yc  za
Now let a  t,b  t c  t2
xa  yb  zc
1
xb  yc  za
a12  2b12  1  a12  2b12  1 (odd)
(2n  1)2  2b12  1  b12  2n(2n 1) (even)
So, b1  2,a1  3
[x]  [y]  [z]  1  a12  2b12
So, [x  a1]  [y b1]  [z]  6
10. 18
A  1  2i x3  2(3  i)x2  (5  4i)x  2a2  0
Let the real root be 
Then (1 2i)3  2(3  i)2  (5  4i)  2a2  0
Equation imaginary part zero
3  62  5  2a2  0
   a  0
  1: a   6
  2a   3

a  6     6    3     3   0
2 2 2 2
So, 2
  18
11. 61
12. 6
p  x    x  l  ax 4  bx3  cx2  dx  e 
Where a, b, c, d, e must be integer
[Note : we are going to following Dirisbion method we will get integral are of quotient
also]
Let q  x   ax4  bx3  cx  dx  e
p  2   2  l  q  2  13
 13  1 13 or 13  1 or  1 13 or  13  1  2  l  13,  13, 1 or  1
 l  11, 15,  1, 3
p(10) = 5
 10  l  5,  5, 1 or  1  l  5, 15, 9, 11
l = 15 (is the only possibility)
 1 + 5 = 6.

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13. 1
p   x, q   xy, r  xyz
p2  2q  45
pq – r = –18
p3 – 3pq = – 67
Solve the cubic in p to get the rational root p = –1 for equation
p3  135p  134  0
p 1
14. 0
Applying rotation formula at P and B we get,
p  4 2i  2
  1  p  2i  2  2i  4   2  2i  4   4  2i  2 
p  2 2k  4
2i  8i  82 2 i  4i  42 
p   i  2k
4i  2  4  42  i  4i
So, z = p  b  0  z  0.
2

2
15. C
16. D
17. A
(P) and (Q)
Sn  1! 21 3!.....7! 8! (where l is an integer)
Sn  4340  8!
 Sn 
Also, 8   4336  8!
 8 
S 
Sn  8  n   4
8 
 1 
tan 
 n2   n
(R) L  lim  2 
n   n  1 

 1   n 
2
lnL = lim tan   ln  n2  1 
n
 n
 n2 
ln  2 
lnL  lim  n  1 
n   1 
cot  
 n
Now use L „hospital rule and after solving, we get L = 1
 2! 
n  ln  1 2
(S) lim   n    ln2xdx   xln2  xln x  x 0  ln
1

i 1  n 
n  e
0

18. D
(P) no. of digits of form a1  a2  a3  a4  10C4  1
no. of digits of form a1  a2  a3  a4  10C3  1
no. of digits = 10 C4  10C3  330
(Q) 4+2 = 2 (2+1) = 2 × odd no
 no. of division = (8+1)×(6+1)-1 = 62

(R) Let Ei is the set which contains all possible function in which xi = yi from inclusion
exclusion
n(UEi )   nEi    n Ei  E j    n Ei  E j  Ek   ..........

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n Ei   59 n Ei  E j   58 n Ei  E j  Ek   57. &so on


n UEi   C15  C2 5  C3 5  C4 5  C5 5
5 9 5 8 5 7 5 6 5 5

no. of desired fn. = 510-n (UEi).


(S) Let the sides of polygon are n.
So no. of diagonals n C2  n  35
 n= 10
 no. of triangles can be formed is = 10
C3  120

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