KE «3 tea quan (13) sana to Eguion (7) B12 Dinciave adoption Aroumin the avrg aa molec 2a the sie * which oxcurs aeons J. (g) + 2) #424 oy tah the soto and sopton es ae estes Yous Kapa ~ OY 5) Fan = By 16) ‘The dssviaton of asus oer on Wo sites simultaneous Agua. we have aryl = 0° = habe e un Since k= une Reananging we determine the ation of SEO ites due o sso whee os YEP ion for dnscitve whption dre Langimsir equ 33, Adsorption of m-molecules (Going oa. adsorption-desoeption of several molecules. reastants or products. we ave sirilar ‘iuation, as shoven ia the following scheme: | surtoce (aa “Then. the ftion aie sites is: AW, Opn 9)wher an Hr ate the foetions ees ies by teat Mad prot Respective the anion al desorption rte are slr the ates present uations 2a 3. Foca component and cosiing the civ como ire et he Fhe aK ee 0, = Ket co 4, Ken LA=(K Pt KPa Ke Paton ew ‘hus as you have in equation (7) Eksp ay BOTT km And since dane en Then. on \ OTEK “Therefore, we ctn determin the faction of ossuped sits ofeach component from Equation (19) sine 4 8, es) “Thus, forexample, for component. eg: Ky. TET 2) TR pe Kir Bio) ane ofthe components is dissociated we subsite te comesponding fem by SqueFE oo For example, fs dissociated then en ‘These expressions of occupied faetion ses by asosated or dsoviaied moleeles are imponant forthe determination ofthe aopion and the desorption rates. a5 shown inEquations 2 and 3, Moreover they are als important fr te detenminatonof the eaton as ‘cecuring simultaneously with adsorption and desorption. 32, Other chemisorption modes ‘The Langmuir adsorption mode! fs because + Notall sites are active. + The adsorption enthalpy depends on the surlac coverage degre, Adsrbed meses my interfere onthe adsorption of neighbouring sites “The dapondence ofthe surface coverage with th heat of adsorption was secounted on 0 ‘ter models, The Freundlich model presente coverage sure 4p" em) ‘where and mare constants and assume values higher than one. reundic’s equation was “orginally itrodoced as an empiialeoration rom experimental dat, However. it can Be <éerved theoretically with folowing considerations “The hea of adsorption decreases logarithmically with he sare coverage BH, = Ane (9) wher asus values varying hetween 0.2 and 08 “Tembin's mods! asumes deresing Hine lationship ofthe heat f adsorption with the surf coverage: AH, =A 01-8) 0) “here Ady isthe ntl het of adsion, The degre of surface coverages inthiscase ven 1s allows ar AT an o- emer 6D wheres the constant relate othe enthalpy adsorption and is corsa ‘Noteworthy sha despite oll finan the Langmuir models sein majo for kiss models