Professional Documents
Culture Documents
Jan 2018 P1C
Jan 2018 P1C
Jan 2018 P1C
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Answer ALL questions.
Use the Periodic Table on page 2 to help you answer this question.
(a) Give the symbol of the element that has an atomic number of 14.
(1 I
(b) Give the symbol of the element that has a relative atomic mass of 14.
(1 l
(c) Give the number of the group that contains the noble gases.
(1)
(d) Identify the group whose atoms form ions with a charge of+ 1.
--
(1 l
D
2
7
--
.8 (e) Identify the group whose atoms form ions with a charge of -1 .
-
• E
E ,
0 C (1)
' z"
j
-
B 2
6 --
po
C
7
(Total for Question 1 = 5 marks)
Turn over
- -
-
2 The diagram shows the arrangement of particles in the three states of matter.
Each circle represents a particle.
0
0
X y z
(a) Use the letters X, Y and Z to give the starting and finishing states of matter for
each of the changes in the table.
I
ethene to poly(ethene) 1 z
(b) Which of these changes takes place when solid iodine is heated to form iodine gas?
- (1 l
--
A crystallisation
B evaporation
-
C melting
r1' D sublimation
-
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(c ) The stude nt repeats the experiment using hot water instead of cold wate r.
3 A st udent places a few purple crystals at the bottom of a bea ker containi ng some cold wa ter.
Ii) State how the change in the appearance of the wate r differs when hot water
The crysta ls start to dissol ve. is used instead of cold water.
(ii) Exp lain, in terms of particles, why the change d iffers w hen hot water is used
instead of cold water.
cold water
12
pu rple crystals l fl. Lo1C ..J.00..l.e..L,.Jh.L()C\ 1 tic \es ..sp!.filLCI_ ~P'~ - q__w c k l',! . _ _
.;:
(a) State how the appea rance of the crystals and the water change as the crystals dissolve. ·o w
0 <t:
121 .,:
B =6 marks)
'3e ls
... ~ :-
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(Total fo r Quest ion 3
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4
!he maxim um mass of a solid that dissolves in 100g of water at a given temperature (b) Extend yo ur curve to find the solubi lity of potassiu m nitrat e at l 0 °C.
1s ca lle d its solubility.
Th e table g ives the solu bility of potassium nitrate at six different temperatures. 0
0
"'
w
<X
"' 33
2
...,0 solubility= g pe r 100 g of wate r
Temperat ure in °C
I 20 I 30 40 50 60 70 :;:
"'
:;
(c) Use you r graph to find t he max imum mass of potass iu m nitrate that cou ld
dis so lve in 50 g of water at 35 °C.
Solubility in g per 100 g of water 41 52 m
(a) Plot the points o n the grid and draw a curve of best fit.
65 83 106 135
...,2
:r
in
12)
I
I 140
131 :,,
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:,,
I
I
130
I 120
maximu m m ass =
(Total for Question 4 = 7 marks)
,S'Q __ ----- 9 \
I
11 0
I 100
90
---i--
I
I
I
,
solubili ty in g I
pe r 100 g of water
80
70 I
I
/
60
/
50
40
80
temperat ure in °(
jkerosene - ~-----~
,-::---:-----./ fuel for aircraft /
heat in gas X
potassium chloride
~ - / fuel for lorries / solid
I d.1
cru eo, _ . . ~ _ . , , /
/ fueloil /
fuelforships
I
I !bitumen
-
(a) Describe what is done to the crude oil before it enters the fractionating column.
(21
gas x
Give the names of gas X, colourless solution Y and acid Z.
. chlo, _i 0.e. .
(3)
I (d) Name the fraction that con tains the largest molecules.
(1)
I
I
observation
f (e) State the physical property that allows the different fractions to be collected at (Total for Question 6 = 7 ~ks)
different heights in the column .
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P53275A0 1 032 P53275A01132
- 7
Co pper p yrit es is an ore o f co pp er th at contain s copper, iron and sulfur.
(c) Sulfur dioxide di ssolves in water to form an acidic solution.
(a) Th e p erce nt age co mposition by mass of copp er pyrites is
(i) Id e ntify th e ion that causes thi s solution to b e ac idic.
Cu 34.60% Fe 30.52 % 5 34.88%
C u. ~e s.,
Ill
o":l gen.
(ii) Wri te a chemica l equation for the reaction t hat occurs in stage 2.
11 )
C l..('3 + o ----'7 c,, ' so
'
12
He repeats the experiment four times, using a different metal each time.
The table shows his results.
iron 3.0
The student measures the te mperature before adding the zinc. calcium 10.S
After a dding the zinc, he stirs the mixture and measures the highest temperature reached.
The diagram shows his results. (i) State three factors that the student should keep constant in each experiment.
131
1. -tile voµme ol -I~ ad.Ct
(ii) Using information from the table, state the relationship between the reactivity
of a metal and the temperature rise.
\1)
before after
(iii) State why there is no temperature rise when gold is added to the acid.
",:,J
(a) Use th e readings to complete the table, giving all values to the nearest 0.5 °C. 111
(2)
14
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9
The ion s present in ionic compounds ca n be identified using simple tests.
(b) (i) In the test s, com pound Y gives a blue flame and produces a yellow colour
some cations (positive ions) can be identified using a flam e test when methyl o range is added.
solm~ anions (negative ions) can be identified by observing reactions in A student concludes that co mpound Y is tantalum hydroxide.
so ut,ons o f the compound s
Give two reasons why this conclusion may not be correct.
Table 1 shows th e flame test colo urs for fou r cations.
2,
Tabl e
2
Table 1
shows the resu lts of three tests used to identify anions in solution.
.
UV
tt
ad cl ½ dlOC.\\1:c:,t,c Qcid . .
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Anion
Test and Result ' :i:
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~. (c) An aqueous solution contains either carbonate ions or hydrogencarbonate ions.
Hydrochloric Magnesium chloride Methyl orange
w
·z.... Using only information from the tables, explain how you could decide if the solution
I- '
acid added solution added added 0:
t ca rbonate J:
:s: contains carbonate or hydrogencarbonate ions.
,,,,.
effervescence white precipitate forms yellow . V\-.
I- ',
0 13\
2
ch loride no ch ange no change 0 Ac\c\ mo..gn <?s•ufY1_c\\\c:,,,de solu\ic::(l , _T\' ,Js 9- CO\'o_o <J..a.le iOI\ ,
------- - - - - - orange .~ 0
hydrogencarbonate effervescence no change yellow
·11 Q.,"<?S o_ u::,n:w p,ec.-. p a.1.e . 1\-\e1e ,s n,o c.'n.ofl <;i E' eo"t,
hydrogensulfate
hydroxide
n o change
no change
no change
yellow
Table2
I 0
0
2
I!
Use the information in the tables to a nswer these q uestions. 0
(a) In th e tests. compo und X gives a red flame and produces effervescence whe (Total for Question 9 - 8 marks)
hydrochloric acid is added. n
16
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(i) Th e result for 20.00 cm 1 of acid is anomalou s.
10 A st udent u ses th is ap pa ratu s to investigate the h eat en ergy re lease d w h en nitri c acid
is a dd e d to potass ium hydroxid e solution. Suggest two po ssible mistakes, other than misreading th e thermometer, that
th e stud ent might have made to produce the anomalous result.
/ nitric acid 3
odd<?cl less -\-'r\on .scr-<1 of:o..c;d
burett e
polystyrene (ii) Suggest a true value for the temperature when 20.00cm 3 of acid is added.
cup (1\
_::_O
~l 10.00 3
(31
Total volume of acid added in cm' 0.00 20~ 25.00
Q' sO y L\ . \'G ;. 19
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111 Th is q ues ti on 1s about titanium an d it s compo unds.
(b) Titaniurn(IV ) chloride, TiCl 4 , and titanium(IV) oxide, Ti0 7 , are both cova lent co mpounds.
"' S,(\c(> T,c{_1 i S o.. -Z. q_ .V:d.. r\ n.QS s ,01 p1e r<\oiecu.lo , s1ru<.lcne
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ii: O<\O 1-\o,e <.0eoJ, ;n1e1c<1qlQcuJa, force.s.T,0 2 ho s o.
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metal
cations delocalised
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bof\c\,
(i) Stat e why metals such as titanium are good conductors of electricity.
(1)
eoc h dhe , .
(c) (i) A mixture of titanium(IV) oxide and carbon reacts with ch lo ri ne to form
titanium(IV) ch loride and carbon dioxide.
20
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12
A mihxtu.re of carbon monoxide, carbon dioxide and hydrog en is known in industry as
syn t es,s ga s. (c) Reac ti on l ca n be re prese nt ed by a reaction profile diagram .
Synthesis gas is converted to methanol, CH 3OH, by passing it over a heated solid ca talyst.
The equations for the two reactions are
Reaction 1
CO (g) + 2H,(g) = CH, OH(g) 6 H = -91 kJ/ mol
Reaction 2
CO, (g) + 3H, (g) = CH , OH(g) + H,O(g) 6 H = -49 kJ/ mol
L\ ')_
(i) For reaction 1, predict whether using a high or a low temperature would produce
the higher yield of methanol.
(11
prediction Cl-I 0H
0
reason
becCtUSe fuccoorc\ t©r~iori is e~ _f rric
..
(ii) For reaction 2, predict whether using a high or a low pressure would produce
the higher yield of methanol. i (i) Complete the profile by showing the products of the reaction and the
Give a reason for your choice. ! entha lpy change, 6.H, for the reaction.
{2\
h,g"1 ·
(1 1
t .. (ii) Draw an arrow on the profile to represent the activation energy for the
'
prediction forward reaction.
reason Label this arrow E.
; {1)
1
(iii) State the effect. if any, of the catalyst on the entha lpy change for the reaction.
(b) The catalyst increases the rate of both the forward reaction and the backwa rd reaction. 11
Suggest why the catalyst has no effect on the position of equilibrium.
(1)
.. I no d\ec.1
i _ (Total fo r Question 12 = 7 marks)
Tl
·t
,_
w
ii:
t32
0
0
22
0
I J'2c(X)OD, 1. 12., 10
-:i
massofCaO= _l. 1'2.s .L02 unit 9
(b) Slaked lime, Ca(OHh, forms when water is added to calcium oxide.
Give the chemical name of slaked lime. (Total for Question 13 1 o marks)
111
(HJ Calculate th e minimum mass, in grams, of Ca(OH), required to neutra lise the HCI.
-
[M, of Ca[OH), = 74)
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Turn over •
14 The table shows th e di splayed formu lae of six hydrocarbons. O. R, S, T. U and V.
Q
H H H H H H H H
, I I '- / I I I
C= C- C- H C H- C- C- C- H
/ I / '- I I I
H H H- C- -C- H
H H H
cJI,;,
I ,, ----'. c·F
J
T u V
H H H H H H H H H
I I I I I I I / H I I
H- C- C- C- C- H H- C- C- C= C H- C- C- H
I I I I I I '- I I
H H H H H H H H- C- C- H
II ,, Hi
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'f1 B QandU
0 C SandT
0 D Q andT
- / 0 B Qand U
)2( C SandT
-, 0 D QandT
0
0
I (c) Which hydroca rbon is an isomer of U?
(1)
z
0
I 0
0 A
0 B
C T
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R
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Th e fl ow d iagram shows th e m ain stag es in an industrial proces s t o manufa cture ammon ia.
' (f) Th e reac ti o n t o make ammoni a is revers ib le and ca n reach a position of equi libri um .
0 ct Th e gra ph shows th e perce ntage yie ld of ammonia at equ ilib rium, and at different
Gas A 0 w
(o b t ained from air)
Gas B
(made from natura l gas)
;z
0
-<
- cc
ct
VI
te mpe rat ures and p ressures.
:i:
.... 80
::E
;o
z ....w
unreacted gases ii:
-<
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i;; ....3:o ·
l>
;o
z
0 Percentage yield
0 of ammonia
at equilibriu m (% )
am monia
(ii) Find t he pe rce ntage yie ld of ammonia at eq uili briu m, at a p ress ure of
200 atmospheres and a temperature of 450 °C.
I) Name th e ca ta lyst that is use d in the reactor. (1)
I{ c,C'--
(1) ,- o
0 ~,
-; ,
1-\o J
z er
'O <t-;'
'"1 (iii) Suggest why, in t he ind ustri al p rocess, t he percentage yield of ammonia at
Sug gest t w o reaso n s why the unreacted gases a re recycle d. / ::;; :i:: 200 atm osph eres and 450 ° ( is o nly 15%.
,I.XI I--'-,,
(2) ,,3' 11 )
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m 0
):,, (Total for Question 15 = 11 marks)
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16
The min eral rozenite cont ain s crysta l s of h ydrat ed iron(ll) sulfate, FeSO•.xH10 (b) (i ) Ca lcul ate the ma ss of FeSO4 fo rme d after heating to constant mass.
A student wants to find th e va lu e of x.
I~ .'lb · tt!H,
She use s this a pparatus t 0
of iron(II) s ulfate crystals. remove and coll ect the water of crystallisation from a sample
I iron(I I) sulfate c rysta ls
mass of FeSO~formed = g
tube A (ii) Calculate th e mass of water co ll ected in tube B after heating to constant mass.
Ill
I T J II UtubeB
I
heat mass of water collected = g
mass of tube A
\\--ig r_e.o.c-li 01 ; e o+l"1e\ rni c. ~cho.l ecl. ropp;,'( ( ];
- - - - - - -~ I 54t1o)e •$ \'ai med .
I_
m_ as s of tube A an_d Fe5O4 .x_H,O
15.76g
,
-r6 rt'Q ke s ure? -lti a~ a ll -ii\e cv0-1-er- h.a..,; bee"- re N"Lo ~c?CP .
[Total for Question 16 = 8 marks)
30
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