SOLUTIONS PDF

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✓ the most opproprmte answer fr· om· .
sc1cct f I · given olternati ves
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. .
is . . sub question
, . • .
he molar mass of oxahc ac1d
1. T
a. 126 u �- 126 g/mol
c. 12.6 u . . d. 12.6 g/mol
.
pr ep are l M so1 � tmn of � xahc acid
2· To .
/4 126 g of oxahc acid dissolve in distill d . .
acid d issol ve i di � wat ; and d1�u ted to I L
b. 12.6 g of oxalic n stit ed
r

wa er and d� lute d to 1 L
c. 1.26 g of oxalic acid dissolve in disf.1 lled wa ter and dtl t
d t0 1 L
d. 0.126 g.of ·11·.
oxoHc acid. dissolve in distill
· · ed w ae· 1 . .
ra d d�I e-
. · . n tu ted to .IL
W a ter of crysta 1zatlon present m oxahc acid is/or . .
e..........
3.
a. 1 . ·. ·.• ...-b • 2 c. 3 .
. used to prepa d. 5
. o xa lic acid 1s re stand ard solut ion bec-au se it is 0
. 4
a. substance . "45' . primary standard s�b���-�ce
... .
c. se co nda ry standard substanc e ·. d· tertiary· stan · , dard . . su b s,ta nee
. . .. .
5. Th eq u anti ty of oxali c acid requi red to prep· are o • I. M . · o f oxa 1-tc act
. ' 100· mL s·ta n d1 ard so 1utlon . ·a
is
a. 126 g, b. 12.6 g �.1.26 d. 0.12?_9
[Sii'1!t ODS'3/er qu�tl�n�J
. ._ -
J. Calculate the molar mass of oxalic acid. (H o � · ·· ·
1

=1 C � ·12
16)
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:t: d

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2. Why heating is �equir�d in ox�lic acid and potos�iu��rmangonote titration? · .
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··
3. Why one test tube of dilute sulphuric o�id is required in per-mongcinote
· tit_rotion?
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4. What is the oxidation state of carbon atom in oxalic acid. ofter com�letion_ ':{ red.ox titrotio�?
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Table:
vation
Obser

PIiot reading Durette reodJng· fn mL

Durette level
l II III
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Initial
to 0.0 0.0
0.0

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mL

Calculation
: From above chemical equation

2KMn0.i +
JOFeSOiN
H )
4 1 SO
4 + 8H

2
SO
4 -+ �SO
4 + 2MnSO

4 + 5Fez(SOJ
+
3
lO(NH

1
_ mo Jes
IO moles JiS()
·

x 158
.

lO moles
·

.·.
":'
of moh
r's salt (mo�ar
moss of KMn
0

4 = 158 g)

1000 mL I0M Mohr'

s salt= ·
316 g ofKM

4
nO

.
.
. lO mL
0.1
M
•
316><
10x0
.l

x
Moh
r s sa
lt
=
lO
00
IO

= 0.03
16
g of
K.Mno4
.-. Hen
ce
..... (
x)
CB
R · .
mL
of

4
KM
nO
so I
ution
cont
_ ains
= 0.03
16 g ofK.MnO
�

x
:.
100
0 ml �
of
KM

4
nO 0.
co 031
ntai _ 6
n� 10
00

158
. (
.7:.� )
.. x
CB
R x

log calcw
He
nc
e y
mol
arit

=-
of
K

l
M
. for
n0 Space

j
4'" the .
solu
tion i
s
0,0
3 ( 6
x 10
00

158
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...
. x
CB
R
x

0.2
-
.. (
7S. )
x
C
B
R-

2.6
Res

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ult: Tl

J<Mno
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ic ...
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ar
it
y
of

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lu

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on
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rk

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Oll

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Select' ( ✓] the must appropriate ,onswer from giv en _ al tern
_ ohv . cs
of each sub _ n. .
. -. que stio
1. The indicator used 111 Redox titration is-----
a. . phenolphthalein b· 11-- lctl 1y I orongc
c. meth ylen e blue c. I . potass1l .· m1
__ pcr
_ _ mongon
at.e
2. Sele cl the titrant used in redo . titrati on
a. oxalic acid , h. 1·.A.S 1,,-·�c. KMnO" . d. H2 SO4
.d . tc . ..
3. The ox1 _atm n sta -
_ ,
.. o
- 1· M nm. K Mn O -1
m rcdo x
' tit mt1· r - 1..1trat10n 1s +7 • ·the- •ox·,d-- at1·- on ,st•atc
·011 b c,orc
.
of Mn after •compkuon of t1tratton is----�
, • •

, . '.2 b. + 3 . C. +4 d. +7
__
4. The oxidation stotc oflron in Mohr' salt is +2 the oxidat • ion · st a te o f 1 ron o fl.e- r comp
. _ ._ . - - _ ·i, ctton
• of
t1trottOll IS----:-
· a. +l b. +2 v-e. +3 d. +4 ·
5. The role of Mn 2 ion during oxidatio -
n reduc
.
tion titroHon of KMn• o4 b.Y OXO - ·d ·IS-·-�-
- 1 ·lC- UC!
vO· catalyst b; reductant c. oxidant d. react.ant
:.:�bor.t•.onswer�questlons·'�i ;
.. , ' 1 • ....,.. $ • • ' :.-·.

1. ,vho.t specific na�e is given to the �erm·onganate - titrotions?

.
1 • ......................................................... ............................................................
�l..-_......
Ans......... .... ..................
1

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2. \Vb) heating �s not required in RA.S. ond potassium· ·parmangonate titration?·

: �

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3. Why is dilute sulphuric ocid added while preponng o standard :�olution_ o f Mohr's salt?
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4. Calculate the molar moss of Mohr�s salt (Fe = S6, S == 32, N = 14, H :;:: 1, 0 = 16)
"' ""' • •

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. :
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An< ....... . f.o/-1-0- ....
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·
 : Chemical kmet,cs 15 thc study of the rates of the chemico,I reactions and the factors which
Theory
ate
affect these r
of rcadion: Rate of rea�tion can be measured i11 terms of either decrease in concentration
Rote _
reactants or 111crcosc m concentration or any one of the products per unit time.
of any one of the _
factors which affect the rate of the reaction ore co11ccntratio11, temperature and catalyst.
Sodium thiosulphate reacts with hydrochloric acid and produces a colloidal solution of
the solution translucent. The reaction occurs as follows :
sulphur which makes
Na S 2 OJ (aq) + 2HCl(oq) --- 2NaCl(oq) + J-1 2 O(/) + SOig) + S(s)J.
Ionic fom1 of the above reaction is written as:
+
S 2O/(aq) + 2H (aq)----+ H:P(I) + SOiCg) + S(s).,l,
The prope1ty of the colloidal solution of sulphur to make the solution translucent is used
to study the rate of precipitation of sulphur. The rote of precipitation of sulphur increases with
incrca c in the concentration of the reacting. species or with increase in the temperature of the
system. With increase in the concentration of reactants, the number of molecular collisions per unit
time between the reacting species increases and consequently, the chances of product fonnation
increase. This result increase in the rate of precipitation of sulphur. Similarly, on increasing the
temperature, the kinetic ·energy of the reacting species increases. So the number of effective
collisions that result in the formation of products increase leading to a foster rat� of reaction.

■ � .. ... ...

Aim: To study the effect ofconcentrotion on the rate ofreaction_between sodium thiosulphote and
hydrochloric acid.
Theory : Law of mass action states th?t rate of o chemical reaction is directly proportional to the
- product of active mosses (molar concentrations) of reactants. The rate of reaction between sodium
thiosulphate and hydrochloric acid depends on the concentration of reactants. As the concentration
of reoctonts increses, the rate of re:action also increases. The balanced chemical reaction is,
Na2 S 2 O3 (aq) + 2HC1(aq) � S(s),J, + NaCI(aq) + SOig) + H2O(/)
Sulphur fanned during the reaction is.1nsoluble and forms milky non transparent opaque
colloidal solution. The time required to produce enough sulphur, so that cross mark on the paper
kept below the conical flask can not be seen, when obsexved from top and hence rote of reaction be
calculated.
Apparatus: Burette (50 mL), conical flask (250 mL}, _stop watch, plane paper with cross mark,
measuring cylinder ( l 0 mL), etc.
'.Chemicals: 0.1 M Na S 0 3, 1 M HCI, distilled water.
2 2
Diagram:

/ Conical flask �
No,S,O,+HCI
lit

Co11Cenir-&1jonof Nil,S,O,

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 em as A, B' c •
and label th
rocedure: I1 with water D re
8li q
mL ), was 1
o I flasks (250 L 0. l M Na S O in th e fl
I. Toke fo ur conic 30 40 and 50 m
2 2 3 o sl(9
y 20 ,
2. Using 50 ml burettc to
k e e xac tl •
::: :·
.t\Q;illl
Ba
d w at e rtoflasksA ' n d
D respectively. 18 C1StlI. ·11 -
e C res
m l bu r c tl c mid 2 8, I 8 � • ;';'
Pe( · ,, · ·, .
0
nc

3. Using another 5 wat e r lll 11 as

k O
n of disl i llcil to the flask Ac� .
)
(There is no additio dd 2 ml I M HCl
de r o
dng cylin , mediate! ntoin·
f IO ml n1cosu e stop watch im
4. With th· help o wa te . S tar t th J
an d 2 8 m l distilled r
nil 0. \ M No I SO . ) and view the }·l
on o paper having cross mark cros
an d k ee p th e co nical llosk ·· '
hak e co ni ca l flask.
from top o f th
through reaction ,nixtutc
e stop watch im me ,
5
.

r jus t be co1rc invisible sto th d IOtd

When the crosst nork on the pape
p

onds.
record t he ti1ne required in sec
I sks B • C and D St·multa-
e exp eri men t by ad di ng 2 mL I M HC to fla
7- Repeat th mark on the a e . neoos11.
·
stop wat ch reco rd the time required, when cross
'."mg D p p r JUSI :· •
cross mark for flasks B, C and )
mVISib\e. (U • some paper having .�
.
Ob en•otion Tobie:

i · O.lM
i
No,_S,,0
n �
mL
3

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