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(1964-1) Criteria For The Break-Up of Thin Liquid Layers Flowing Isothermally Over Solid Surfaces
(1964-1) Criteria For The Break-Up of Thin Liquid Layers Flowing Isothermally Over Solid Surfaces
(1964-1) Criteria For The Break-Up of Thin Liquid Layers Flowing Isothermally Over Solid Surfaces
Abstract-The conditions under which a thin liquid film will tend to completely wet a solid surface
over which it is flowing are studied theoretically. Two (very similar) criteria are suggested; one is
based on a force balance at the upstream stagnation point of a dry-patch, the other on the minimum
total energy rate in a transversely unrestrained stream.
The criteria have been applied to vertical gravity flow of laminar films and to both laminar and
turbulent films motivated only by shear forces at the free liquid surface. These latter examples are of
special interest with regard to the bum-out in two-phase gas-liquid flows.
Comparisons with experimental evidence appear promising but more detailed ex~rimentation is
clearly needed.
2. STABILITY CRITERIA
2.1 Criterion from force-balance at the upstream
point of a dry patch (bl Cross SectxJn
(a) Pian “lew
along E G J (magnlfiedl
Consider a film of liquid flowing uniformly
over the surface of a flat plate, for example the FIG. 1. Dry patch formation in liquid layer flowing
flow due to gravity down an inclined plane. If over a solid surface.
the flow rate is reduced sufficiently the stream
will break away from the edges of the plate or the X-Z plane curvature will be ignored com-
else disrupt over the central area giving rise to pared with those arising from the curvature in
one or more dry patches. An idealized case is the y-z plane.
depicted in Fig. l(a) where a (transversely) If the dry patch is stable, the surface tension
uniform stream with mean velocity P flows forces along GSGpmust balance the fluid pressure
onto the upper edge A6 of a rectangular plate over G,G,. Under the assumptions implied in
ABCD, and a dry patch FGHJ is formed cen- Fig. 1, the fluid pressure on the inner surface
trally. The specific flow rate (mass flow rate per of G,G, exceeds that on the outer surface owing
unit width) of the liquid leaving the plate across to the conversion of fluid. kinetic energy into
DF and HC is clearly greater than that of the static pressure. Considering EG as a stream
liquid entering across AB, and the precise shape tube of transverse width dX, in an element E,
of the dry patch may be connected with the G, the velocity W(y) at E, is gradually reduced
minimum stable film over DF and HC. Consider to zero at G, resulting in an excess static
the forces acting near the point G, the upstream pressure at G of
stagnation point of the liquid stream. Figure AP (Y) = P/Z C~(YP (1)
l(b) shows a cross-section through the central
stream surface EG, and it is assumed in I(b) that The force TW along G,G, due to this resolved
the stream maintains a uniform thickness up to in the z-direction will be TW where
G, where the meniscus begins. Near the point G, sac
the curvature of the edge of the stream in plan TW = dX S P[WY)I~/~
dy (4
view will in general be very small in comparison 0
with the curvature of G,G,, in the flow direction The restraining force due to surface tension is
and so the surface tension forces arising from
T, = dX . u . (1 - cos 0) (3)
* These ideas were originally put forward by the
authors in Nuclear Research Memorandum Q.5, Queen where 0 is the surface tension and 8 the contact
Mary College, London, September 1961. angle [see Fig. l(b)].
CRITERIA FOR THE BREAK-UP OF THIN LIQUID LAYERS 1005
Thus the point G will be in neutral equilibrium stream giving a minimum width at MG followed
if by an expansion (to H-l) and finally a stable
width X over the region LHJK.
u (1 - cos 0) = “s p/2 [ W(y)]2 dy (4) We suggest that the film will attain a stable
0
width X such that the sum of the kinetic energy
It is possible that 0 and hence the critical film flow across a plane such as NR plus the surface
thickness and minimum wetting rate will depend energy flow will be a minimum. Qualitatively it
on whether the experiment is performed by is clear that a very wide and shallow layer would
gradually increasing a flow from the completely have a large surface power and a low kinetic
dry condition or gradually decreasing the flow power whilst a high kinetic power with a low
from a fully wetted condition, surface power would result from a deep and
Equation (4) is interesting in its simplicity and narrow stream.
its strong dependence on contact angle, the left- Thus taking a cross-section of the stable
hand side of the equation being capable of values stream such as is shown in Fig. 2(b) the rate of
ranging from zero to 20. kinetic energy flow Ew is
Liquid is
3. LAMINAR FILM FLOWING VERTICALLY
introduced UNDER GRAVITY
onto surface
ABCD In a uniform laminar film moving steadily
throuqh Slot
EF under gravity over a vertical flat surface, the
A
velocity w at a distance y from the wall is given
by
w=-Z(y2-2yS) (8)
Liquid meon velocity iS v downstream of LH The flow rate per unit width of plate M/X is
given by
(bl
M/X = gp2 63/3/L (9)
Elevation of NPOR
knlorged in the
y - dtirectionl
3.1 Minimum thickness from force criterion
Using equations (4) and (8) we find for the
critical thickness :
6, = 1.72 [u(l - cos B)/p]1’5. [p/pg12’5 (10)
Liquid velocity is IV(y) through element e 0,
giving a minimum wetting rate of
FIG. 2. Flow of a laterally unrestrained liquid layer
on a plane surface. M/XC = 1.69 (ppplg)l’5[O(1 - cos @]3’5 (11)
1006 D. E. HARTLEY and W. MURGATROYD
3.2 Minimum thickness from power criteriorl In reference 3, Bressler shows flow rates and
We are interested in the case where the flow film thicknesses for water at IOO’C on a steel
is just sufficient to cover the surface of width X, plate. Table 2 compares the minimum rates with
hence if a given flow rate is taken for a given those calculated from the power criterion.
width of plate, equation (7) may be expressed
in terms of one constant and one variable-say Table 2. Minimum wetting rafe and film thicknesses J&
the film thickness, as variable. water flowing over a vertical steel plate
Employing equations (7), (8) and (9) and
differentiating with respect to S in equation (7) Quantity Measured [3] Estimated
we obtain for the critical thickness:
Minimum wetting
6, =:--1.34 (u/p)“5 (p/pg)‘.”
rate (Ib/ft h) 103 166
(12)
Minimum film
The minimum wetting rate is then thickness (in) @0075
OGO63
Thus the critical film thicknesses and flow Norman and McIntyre [4] measured minimum
rates derived from the two criteria are almost wetting rates on the inside of a 1 in diameter
identical except that the force criterion includes smooth copper pipe with various temperatures
an effect of contact angle whilst the power both of the water and of the tube metal surface.
criterion does not. The isothermal results [4, Fig. 41 are very
different from those estimated by the present
formulae, as shown in Table 3, although the
3.3 Comparisons with experimental data minimum wetting rates measured with the wall
Experimental data are available from three at 100°C are very close to the estimates for
sources [2, 3 and 41, but in none of these works isothermal conditions.
were contact angles measured, it is therefore only
possible to compare them with the power Table 3. Minimum wetting rates for water flowing iuside
criterion. n 1 in diameter smooth copper pipe
Dukler and Bergelin [2] describe experiments
on water films flowing down a vertical plate of Water mean Surface M.W.R. M.W.R.
polished stainless steel. They were not especially temperature temperature measured [4] estimated
interested in minimum wetting rates, but it is (“C) (“C) (Ib/ft h)
reasonable to assume that their smallest re- 30 30 25 244
corded film thicknesses were in fact the smallest 30 100 250
that they could produce. Water was used at 77°F 45 45 25 223
and Table 1 shows a comparison between the 45 100 225
60 60 25 206
smallest measured values and those estimated
60 110 158
from equations (12) and (13). 75 75 25 192
75 100 I25
Table 1. Minimum wetting rate and j&n thicknesses for
water flowing over vertical stainless steel plate
A --zz_
Thus of the three sets of data, one agrees well
Quantity Measured [2] Estimated with the power criterion (Table l), the second
gives an estimate of M.W.R. which is 60 per cent
Minimum wetting too big, and in the third series the estimates
rate (lb/ft h) 261 248
_~___________~_ from minimum power are about ten times too
Minimum film great. It is not possible from these comparisons
thickness (in) 0.012 0.0121 to evaluate the applicability of the power
z_ ~- -_ -ET- ____ criterion in general. One would expect there to
CRITERIA FOR THE BREAK-UP OF THIN LIQUID LAYERS 1007
be considerable contact angle changes for a 4.1 Minimum thickness from force criterion
subcooled liquid in contact with a surface whose Applying equation (4) to the profile of equa-
temperature is increased up to the saturation tion (14) leads directly to the relation:
temperature of the liquid.
The force criterion, equation (ll), has been
6, = 1.82 [u (1 - cos O)/pJ”s (+)“‘a (17)
used to deduce the contact angles which would
give agreement with the data already discussed.
The results of this analysis are shown in Table 4. and the minimum wetting rate is
Table 4. Contact angles to give [M/X], = 3.30 (pP/~)“” [u (1 - cos 0)]“3 (18)
agreement between test data and
force criterion
.~___ The equations (17) and (18) exhibit similar
Test Contact angle
forms to equations (10) and (11).
4.4 Minimum wetting conditions from power Table 5. Minimum wetting rates for annular air/water JIbw
criterion, with surface shear dependent onfilm in 11 in bore pipe. T-70°F; p-1.57 psia
thickness
Consider the two-phase annular flow in a Ret 2 x 104 6 x 104 2 x 105
vertical channel, and in which most of the liquid
WAG W/s) 29 86 286
is flowing in a film on the wall(s) and the vapour
(or gas) occupies the central part of the channel. k W/h) 72.5 217.5 725
According to Roberts [71the friction factor may
be written as l/2 pc:Wg2 (Ibl/ft*) 32.7 294 3270
-
& (in) 0.0195 oQo75 0.0023
,~TP= fc + 1.42 [a/D - S/Ret . (2/fc>“2] (21) ____~___~ -- ___--
f TPC 0.0112 0.0064
and the shear stress at the surface of the liquid 44 0.39 0.018
P @lr
layer is ______~___ -----
ML~ (lb/h) 74 42
75 =fTP . 112 * PG w,z, (22)
w+ = 5 logY+ - 3.05, S < Y+ < 30 (25b) (c) for a fully turbulent film (S,+ > 30)
w+ = 5.5 + 2.5 logy+, y+ > 30 (25~) + 15.25 S: - 1084 = 2a (1 - cos O)/,W,. (31)
which is in fact the same equation as obtained and values are given for G in Table 8 for
for a laminar film in section 4 but with rearranged s+ = 0 to s+ = 100.
parameters.
(b) for a film in the transition zone (5 < S,+ < 5.4 Minimum thickness from power criterion
B. Shear stress dependent on $lm thickness.
30)
Where the shear stress is dependent on the
25 S,+log2 S; - 80.5 S$ log S,+ liquid film thickness, as in the case of the two-
phase gas/liquid flows, the criterion becomes
+ 89.8 S,+ - 83.3 = 2 6 (1 - cos 0)/p W, (30) more complex.
1010 D. E. HARTLEY and W, MURGATROYD
sc+ 50 34 26
- --
6 (in) oaO355 0 W163 omO97
ML (lb/h) 150 87 59
MG 57 114 171
ML 54 41 36.5
where
I1 (6’) = i W+ dy+ (42~)
0
A (S+) E (I+‘$)3 “s W+ dyf
8 Is@+) = T(W+)sdy+ (42d)
- W; “j, W+)3 dy+ (41a) Equations (40) and (41) are the same as
0 equations (39) but are written in a way more
8+ convenient for computation. The functions of
S+ are given in Table 8.
W+ dy+ Solution of the equations for the case outlined
f
0 at the start of this section leads to the results
WW shown in Table 7.
1012 D. E. HARTLEY and W. MURGATROYD
Sf W+ I, A B G
Table 8-continued
3 G
The critical liquid flow rates are less than those similar in form to those obtained from minimum
from equation (43) but the trend with increasing power considerations in liquid streams not
steam flow rate is the same. restrained laterally.
For water flowing down a vertical surface
6. DISCUSSION under gravity, the power criterion calculations
Considerations of the forces acting at a agree well with measurements of Dukler and
break-point in a liquid film lead to theoretical Bergelin (Table 1) and moderately well with
values of the minimum wetting rates which are those of Bressler (Table 2). There appear to be
1014 D. E. HARTLEY and W. MURGATROYD
APPENDIX
REFERENCES
J. A.R. BENNETT, J.G. COLLIER, H.R.C. PRATT and
J. D. THORNTON,Heat transfer to two phase gas-liquid
systems, Part I. Steam-water mixtures in the liquid-
dispersed region in an annulus. AERE Report R3159
ACKNOWLEDGEMENTS (1959). Also Trans. Inst. Chem. Engrs 39, 113-126
The authors thank Mr. P. M. C. Lacey, Dr. G. F. (1961).
Hewitt, and Mr. J. G. Collier, of A.E.R.E. Harwetl, for A. E. DIJKLER and 0. P. BERGELIN,Characteristics of
their co-operation in connection with this paper, and the flow in falling liquid films, Chem. Engng Prog. 48,
Director, A.E.R.E., Harwell for permission to publish it. 557-563 (1952).
CRITERIA FOR THE BREAK- UP OF THIN LIQUID LAYERS 1015
3. R. BRESSLER, Experiments on the evaporation of thin persed flow regions, Part B. Film thickness and
Iiouid films. Z. Ysr. Dtsch. inc. 100.630-638 (1958). entrainment data and analysis of pressure drop
4. VV.S. N~&N and V. McIN&, hat transfer to a measurements. AERE Report R3455 (1960). Also
liquid film on a vertical surface, Trans. Inst. Chm. Trans. Inst. CZtetn.Engrs 39, 127-237 (1961).
ERgi 38, 301-307 (1960). 7. D. C. ROBERTS, A correlation of adiabatic pressure
5. D. A. CHARVONIA, A study of the mean thickness of drop data for two-phase annular flow in vertical
the liquid film and the characteristics of the interfacial channels. Postgraduate diploma thesis, Queen
surface in annular, two-phase flow in a vertical tube, Mary College, Nuclear Engineering Laboratory
including a review of the literature. Purdue University, (1960).
Ph.D. Thesis (1959). 8. W. MURGATROYD, Some aspects of the high pressure
6. J. G. C~LL.IERand G. F. HEWITT, Data on the vertical wetted wall evaporator. AERE Memorandum X]M
Aow of air-water mixtures in the annular and dis- 124 (1954).
R&arm&-Les conditions, sous lesquelles un film liquide mince tendra a mouiller compl&tement une
surface solide sur laquelle il coule, sont Btudieees theoriquement. Deux criteres (tres semblables) sent
sugg&es; l’un est base sur un bilan de forces au point d’arr& amont dune partie &he, I’autre sur le
debit minimal d’ctnergie totale dans un tlcoulement non borne lat=&ralement.
Les crit&res ont et& appliqutJs 8 Weoulement vertical par gravitb de films laminaires et a la fois a
des films laminaires et turbulent mus seulement par des forces de cisaillement a la surface libre du
liquide. Ces demiers exemples sont dun in&et special eu egard a la calefaction dans des ecoulements
diphasiques du type gaz-liquide.
Des comparaisons avec l’txp&ience apparaissent pleines de promesses mais on a besoin Cvidem-
ment dune experimentation plus detailk+e.
Zusammenfassung-Die Bedingungen, unter welchen ein diinner Fllissigkeitsfilm, der iiber eine feste
Oberfkiche flies&, diese vollst~dig benetzt, werden theoretisch untersucht. Zwei (sehr lihnliche)
Kriterien werden vorgeschlagen; das eine beruht auf dem ~te~eichge~cht am oberen Staupunkt
eines Trockenbereiches, das andere auf der minimalen Gesamtenergieiinderung in einem seitlich nicht
gefilhrten Strom.
Die Kriterien wurden fiir senkrechte Strbmungen unter dem Einfluss der Schwerkraft angewandt,
sowohl auf laminare Filme als such auf laminare und turbulente Bewegungen, die allein von ZBhig-
keitskrliften an der freien FliissigkeitsobertWhe herrtihren. Letztere Beispiele sind besonders fib den
burn-out in Gas-Fhissigkeitsstr&nen interessant.
Vergleiche mit ex~rimentelIen E~~inun~n sind vieive~p~hend, jedoch sind weitere, ins
einzelne gehende Versuche erforderlich.