Câ u 1: Đố t chá y hoà n toà n 3,6 gam ankan X, thu đượ c 5,6 lít khí CO2 (đktc).

Cô ng thứ c phâ n tử củ a X là :
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Câ u 2: Ankan X có phầ n tră m khố i lượ ng cacbon bằ ng 82,76%. Cô ng thứ c phâ n tử củ a X là :
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Câ u 3: Số liên kết sigma trong phâ n tử propan là :
- Cô ng thứ c cấ u tạ o củ a propan là : CH3 – CH2 – CH3
 Trong propan có 8 liên kết sigma (C-H) và 2 liên kết sigma (C-C)
 Tổ ng số liên kết sigma là 10.
Câ u 4: Hợ p chấ t X có CTCT thu gọ n nhấ t: :( CH3 – CH2 – CH(CH3) – CH3 )
Tổ ng số liên kết sigma trong phâ n tử trên là :
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Câ u 5: Ankan hò a tan tố t trong dung mô i nà o sau đâ y:  Benzen
Chấ t nà o sau đâ y thuộ c loạ i hidrocacbon no, mạ ch hở ?  Etan
Phâ n tử metan khô ng tan trong nướ c vì lí do nà o sau đâ y?  Phâ n tử metan khô ng phâ n cự c
Vớ i CTTQ củ a cá c ankan: CnH2n+2 , khi n từ 4 trở xuố ng thì ankan ở thể khí
khi n từ 5 – 18 thì ankan ở thể lỏ ng
khi n từ 19 trở lên thì ankan ở thể rắ n
Câ u 6: Trong số cá c ankan đồ ng phâ n củ a nhau, đồ ng phâ n nà o có nhiệt độ nó ng chả y cao nhấ t?
 Đồ ng phâ n mạ ch thẳ ng
Câ u 7: Cho biết nhiệt độ sô i củ a chấ t X là 360C, chấ t Y là 280C, chấ t Z là 9,40C. Vậ y X,Y,Z là chấ t nà o sau đâ y:
neopentan, isopentan, n-pentan?
 X là isopentan, Y là neopentan, Z là n-pentan
Câ u 8: Cho cá c chấ t sau: etan(1), propan(2), butan(3), isobutan(4). Dã y gồ m cá c chấ t có nhiệt độ sô i tă ng
dầ n là :
 1–2–4–3
- Cà ng nhiều mạ ch phâ n nhá nh thì nhiệt độ sô i/nó ng chả y cà ng cao.
Câ u 9: Mộ t loạ i xă ng chứ a 4 ankan vớ i thà nh phầ n số mol như sau: heptan (10%), octan(50%), nonan
(30%), và đecan (10%). Khi dù ng loạ i xă ng nà y để chạ y độ ng cơ ô tô và motor cầ n trộ n lẫ n hơi xă ng và
khô ng khí (O2 chiếm 20% về thể tích) theo tỉ lệ thể tích như thế nà o để phả n ứ ng xả y ra vừ a hết?
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Câ u 10: Phả n ứ ng đặ c trưng củ a ankan là gì?  Phả n ứ ng thế
Cá c ankan khô ng tham gia phả n ứ ng cộ ng
Câ u 11: Khi cho 2-metylbutan tá c dụ ng vớ i Cl2 theo tỉ lệ mol 1:1 thì tạ o ra sả n phẩ m chính là :
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Câ u 12: Cho tấ t cả ankan thể khí, điều kiện thườ ng tá c dụ ng vớ i Cl2 theo tỉ lệ mol 1:1 thì tạ o ra bao nhiêu
dẫ n xuấ t monoclo tấ t cả ?
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Câ u 13: Khi cho isopentan tá c dụ ng vớ i brom theo tỉ lệ mol 1:1, sả n phẩ m chính thu đượ c là :
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Câ u 14: Cho isopentan tá c dụ ng cớ i Br2 theo tỉ lệ 1:1 về số mol trong điều kiện á nh sá ng khuếch tá n thu
đượ c sả n phẩ m chính monobrom có CTCT là :
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Câ u 15: Cho neo-pentan tá c dụ ng vớ i Cl2 theo tỉ lệ mol 1:1, số sả n phẩ m monoclo tố i đa thu đượ c là :
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Câ u 16: Cho isopentan tá c dụ ng vớ i Cl2 theo tỉ lệ số mol 1:1, số sả n phả n monoclo tố i đa thu đượ c là :
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Câ u 17: Cho propan tá c dụ ng vớ i clo có á nh sá ng vớ i tỉ lệ số mol 1:1 thì thu đucợ số dẫ n xuấ t halogen tố i
đa là :
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Câ u 18: Ankan X có CTPT là C5H12 , khi tá c dụ ng vớ i clo tạ o đượ c 4 dẫ n xuấ t monoclo. Tên củ a X là :
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Câ u 19: Cho ankan X có CTPT là C6H14 , biết rằ ng khi cho X tá c dụ ng vớ i clo theo tỉ lệ mol 1:1 thu đượ c 2
sả n phẩ m thế monoclo. CTCT đú ng củ a X là :
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Câ u 20: Hidrocacbon mạ ch hở X trong phâ n tử chỉ chứ a liên kết sigma và có 2 nguyên tử cacbon bậ c III
trong mộ t phâ n tử . Đố t chá y hoà n toà n 1 thể tích X sinh ra 6 thể tích CO2 (ở cù ng điều kiện nhiệt độ , á p
suấ t). Khi cho X tá c dụ ng vớ i Cl2 (theo tỉ lệ số mol 1:1), số dẫ n xuấ t monoclo tố i đa sinh ra là :
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Câ u 21: Ankan X có CTPT là C5H12. Clo hó a X, thu đượ c 4 dẫ n xuấ t monoclo. Tên gọ i củ a X là :
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Câ u 22: Khi cho metan tá c dụ ng vớ i clo (có á nh sá ng) theo tỉ lệ mol 1:2 tạ o thà nh sả n phẩ m chính là : 
CH2Cl2:
CH4 + 2Cl2  CH2Cl2 + 2HCl
Câ u 23: Dã y ankan nà o sau đâ y thỏ a mã n điều kiện: mỗ i cô ng thứ c phâ n tử có mộ t đồ ng pâ n khi tá c dụ ng
vớ i clo theo tỉ lệ mol 1:1 tạ o ra 1 dẫ n xuấ t monoankan duy nhấ t?
A. CH4 , C3H8 , C4H10 , C6H14
B. CH4 , C2H6 , C5H12 , C8H18
C. CH4 , C4H10 , C5H12 , C6H14
D. CH4 , C2H6 , C5H12 , C4H10
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Câ u 24: Khi brom hó a mộ t ankan chỉ thu đượ c mộ t dẫ n xuấ t monobrom duy nhấ t có tỉ khố i hơi đố i vớ i
hidro là 75,5. Tên củ a ankan đó là :
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Câ u 25: Khi clo hó a mộ t ankan X chỉ thu đượ c mộ t dẫ n xuấ t monoclo duy nhấ t có tỉ khố i hơi đố i vớ i hidro
là 53,25. Tên củ a ankan X là :
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Câ u 26: Khi co hó a hoà n toà n ankan X thu đượ c chấ t hữ u cơ Y có khố i lượ ng phâ n tử lớ n hơn khố i lượ ng
phâ n tử củ a X là 138. Ankan X là :
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Câ u 27: Mộ t ankan A có thà nh phầ n phầ n tră m C là 83,33%. Tìm CTPT và xá c định CTCT đú ng củ a A biết
rằ ng khi cho A tá c dụ ng vớ i Cl2 theo tỉ lệ mol 1:1 ta chỉ thu đượ c 1 sả n phẩ m thế monoclo?
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Câ u 28: Khi cho ankan X (trong phâ n tử có phầ n tră m khố i lượ ng C bằ ng 83,72%) tá c dụ ng vớ i clo theo tỉ
lệ số mol 1:1 (trong điều kiện chiếu sá ng) chỉ thu đượ c 2 dẫ n xuấ t monoclo đồ ng phâ n củ a nhau. Tên củ a
X là :
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Câ u 29: Khi tiến hà nh phả n ứ ng thế giữ a ankan X vớ i hơi brom có hiếu sá ng ngườ i ta thu đượ c hỗ n hợ p Y
chỉ chứ a 2 chấ t sả n phẩ m. Tỉ khố i hơi củ a Y so vớ i khô ng khí bằ ng 4. Tên củ a X là :
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Câ u 30: Khi tiến hà nh phả n ứ ng thế giữ a ankan X vớ i hơi brom có chiếu sá ng, ngườ i ta thu đượ c hỗ n hợ p
Y chỉ chứ a 2 chấ t sả n phẩ m. Tỉ khố i hơi cỉa Y so vớ i He bằ ng 29. Tên củ a X là :
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Câ u 31: Khi clo hó a mộ t ankan có CTPT C6H14 , ngườ i ta chỉ thu đượ c 2 sả n phẩ m thế monoclo. Danh phá p
IUPAC củ a ankan đó là :
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Câ u 32: Ankan X là chấ t khí ở điều kiện thườ ng. X phả n ứ ng vớ i clo (có á nh sá ng) tạ o 2 dẫ n xuấ t monoclo.
Có bao nhiêu chấ t thỏ a mã n điều kiện trên?
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Câ u 33: Ankan X có mộ t nguyên tử cacbon bậ c III, mộ t nguyên tử cacbon bậ c II, cò n lạ i là cá c nguyên tử
cacbon bậ c I. Khi cho X tá c dụ ng vớ i clo (á nh sá ng) thu đượ c bao nhiêu dẫ n xuấ t monoclo là đồ ng phâ n
cấ u tạ o củ a nhau?
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Câ u 34: Cho cá c ankan sau:
(a) CH3CH2CH3
(b) CH4
(c) CH3C(CH3)2CH3
(d) CH3CH3
(e) CH3CH(CH3)CH3
Ankan chỉ cho 1 sả n phẩ m thế duy nhấ t khi tá c dụ ng vớ i Cl2 (á nh sá ng) theo tỉ lệ mol 1:1 là :
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Câ u 35: Khi clo hó a metan thu đượ c mộ t sả n phâ m rthees chứ a 89,12% clo về khố i lượ ng. Cô ng thứ c củ a
sả n phẩ m là :
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Câ u 36: Phả n ứ ng củ a metan vớ i clo thuộ c loạ i phả n ứ ng nà o: CH4 + Cl2  CH3Cl + HCl
 Phả n ứ ng thế
Câ u 37: Cho 5,6 lít ankan thể tích đo ở 27,30C và 2,2 atm tá c dụ ng hết vớ i clo ngoà i á nh sá ng thu đượ c mộ t
dẫ n xuấ t clo duy nhấ t có khố i lượ ng 49,5 gam. Cô ng thứ c phâ n tử củ a ankan là :
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Câ u 38: Hidrocacbon Y mạ ch hở có 19 liên kết sigma trong phâ n tử (ngoà i ra khô ng cò n liên kết nà o
khá c). Khi đem Y tham gia phả n ứ ng thế vớ i clo thì thu đượ c 2 sả n phẩ m thế monoclo. Tên gọ i củ a Y là :
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