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LAKSHYA JEE (2024)

Coordination Chemistry DPP-04

1. Select the CORRECT IUPAC name of 5. Find the correct match out of following
[Co(H2NCH2CH2NH2)3]2(SO4)3 is [Co(NH3)4(H2O) Tetraammineaquachlorido
1 :
(1) Tris(ethane-1, 2-diamine) cobalt (III) sulphate Cl]Cl2 cobalt(III) chloride
Potassium
(2) Tris(ethane-1, 2-diamine) cobaltate(III) 2 K2[Zn(OH)4] :
tetrahydroxidozincate(II)
sulphate
Potassium
(3) Tris(ethane-1, 2-diamine) cobaltate (II) 3 K3[Al(C2O4)3] :
trioxalatoaluminate(III)
sulphate Dichloridobis (ethane-1,
(4) None of the correct 4 [CoCl2(en)2]Cl : 2-diamine) cobalt (III)
chloride
2. Write the correct formula of the following
complex- 6. Write simplest ratio of Co3+ : NH3 : NO 2– in-
[Iron (III) hexacyanidoferrate (II)- Tetraamminedinitrito-Ncobalt(III)
tetradecahydrate] diamminetetranitrito-Ncobaltate(III)
(1) Fe4[Fe(CN)6]3
7. How many moles of ions (cation & anion) are
(2) Fe3[Fe(CN)6]2
present in 1 mole of
(3) Fe3[Fe(CN)6]2.4H2O Diamminediaquadipyridineiron(III) sulphate-
(4) Fe4[Fe(CN)6]3.14H2O
8. The IUPAC name of K4[Fe(CN)6] is:
3. Using IUPAC norms, the systematic name of the (1) Potassium hexacyanidoferrate(II)
complex [Co(NH3)4Cl(NO2)]Cl is: (2) Potassium hexacyanidoferrate(4–)
(3) Tetrapotassium hexacyanidoferrate
(1) Tetraminenitrito-O-chloridocobalt(III)
(4) All are correct
chloride
(2) Tetraamminenitrito-N-Chloridocobalt(III) 9. The IUPAC name of the coordination compound
chloride Ba[BrF4]2 is
(3) Tetraamminechloridonitrito-N-cobalt(III) (1) Barium tetrafluorobromate(V)
chloride (2) Barium tetrafluorobromate (III)
(4) Chloridonitrito-O-Tetraamminecobalt(III) (3) Barium bis (tetrafluorobromate((III)
chloride (4) None of these

10. The IUPAC name of [Ni(NH3)4]+2 [NiCl4]–2 is

4. Select the correct IUPAC name of
[Pt(-C2H4)Cl2(NH3)]
(1) Amminedichlorido (2-ethene)platinate(II)
(2) Amminedichlorido (1-ethene)platinate(II)
(3) Amminedichlorido (1-ethylene)platinum(1-)
(1) Tetrachloronickel (II)-tetraamminenickel (II)
(2) Tetraamminenickel (II)-tetrachloronickel (II)
(3) Tetraamminenickel (II)-tetrachloronickelate
(II)
(4) Tetrachloronickel (II)-tetraamminenickelate (0)

(4) Amminedichlorido (2-ethene)platinum(II)

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Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.
Answer Key
1. (1) 6. (1 : 3 : 3)
2. (4) 7. (5)
3. (3) 8. (4)
4. (4) 9. (2)
5. (1, 2, 3, 4) 10. (3)

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