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Diffusion, Brownian Motion,

Solids/Liquids/Gases
Mark Scheme

Level IGCSE
Subject Chemistry
Exam Board CIE
Topic The Particulate nature of matter
Sub-Topic Diffusion, Brownian Motion,
Solids/Liquids/Gases
Paper Type Alternative to Practical
Booklet Mark Scheme

Time Allowed: 46 minutes

Score: /38

Percentage: /100
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1 (a volumes of hydrogen completed correctly (3)
0, 8, 34, 42, 46, 48, 48 [3]
guidance: 7 correct (3); 6 correct (2); 5 correct (1); 4 or fewer correct (0)

(b) points plotted correctly including origin (3)

guidance: 7 correct (3); 6 correct (2); 5 correct (1); 4 or fewer correct (0)

smooth curve missing anomalous point (1) [4]

(c)
c) point at 5 cm3 / 8 cm3 H2 / second point (1) [1]

(ii) leak / loss / escape of gas or wrong amount / too little HC l or zinc (1) [1]
allow: syringe sticking

(iii) reading from graph (1) ± half small square

indication on graph (1) [2]

(d) excess acid (1)

all zinc reacted (1) [2]

allow: used up

(e) sketch curve identical (2)

different curve levelling out at 48 cm3 (1)

1)
note: must be some indication of a second curve [2]
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60 f-H'---t-,--+
'+ ++-H�-r-+-r+,-+
rn ,--i--H' -,- '+
---t +
- + n H�
,....
+-
-,'
+
- ,-
H '-+-,-+
- ++"+- '
,-,- '7'- -�
- + -i-
...,.. -,- �r--i-- �
'-+ + - H -+
,....n Hl -,- ,-,.... H -r ,....n
-,- '+ ++- t- +- ++':1- -r'-t #,+++-H-r'-t-r-+,+,-+"+-H''-t-,-t ,-- ,--i--r-H
- + -i-- '-+I-
..,..,

40

volume of
hydrogen
gas/cm3

O _}1-'
'H....-I + .,_+-._.H_..H_..-+..,_+
....+ .....-+_._+_._+ ._.H
J-+-+....+,J- 1-+-,_J- .....-+_._+++..__+-._.H__,_H_..-++_._ _._+.,_+....,H- _J-1_-+..,_+
._+ ..__+-._.H......,-1 +--+- __,_H
_..-_._ + +.._+-
._.H _.. + '--'H_.--+_._+ __.H_..--+
_._+
-'-+
..__+-
._,H
....,_H
.....-+_._+_._+.,_+-._.H__,_H ....H_..+.....__
__::..__1--+-
- _._
_..+ +.... _._ .._:-+--
0 10 20 30 40
volume of hydrochloric acid/cm 3
[4]

[Total: 15)
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2 (a arrow under copper oxide (1) [1]

(b) black (1) to brown/red (1) [2]

(c) diagram of tube entering test-tube or similar in beaker of cold water/ice/Liebig [2]
condenser (1)

labelled water/ice/condenser (1)

(d) extinguished/goes out (1) not: no effect/no reaction [1]

3 (a flask (1)
tap/separating/dropping funnel (1) not burette
gas jar (1) accept measuring cylinder [3]

(b) gas should be collected downwards owtte (1) [1]

(c) to remove impurities/water (1) [1]

4 (a) volumes completed correctly

0, 60, 68, 95, 98, 99, 100 –1 for each incorrec [4]

(b) points plotted correctly (3) –1 for each incorrec

smooth curve (1) [4]

(c) point at 2 minutes (1) off curve owtte (1) [2]

(d) steeper curve (1)

levels out at same volume (1) [2]