FIRST REVISION TEST - 2024" aa Standard XII Reg.No. CHEMISTRY 7 ¥ Marks * shaban t : a “ 15x1=15 . Choose the correct answer: 1. Zinc is obtained from ZnO by . a) Carbon reduction b) Reduction using Silver c) ElectitS chemical process d) Acid Leaching 2. Math the following A) Pure Nitrogen i) Chorine A B) Haber Process ii) Sulphuric acid / C) Contact Process iii) Ammonia D) Deacons Process. iv). Sodium Azide or Barium Azide Which of the following is the correct option? : Ai ),BesS &D a) i i oii iv b i wv i iii c) ii wv ii i div ih i i 3 : ; 3. The.catalytic behaviour of transition metals’and their compounds is ascribed mainly due to a) their magnetic behaviour b) their unfilled d orbitals ) their ability to adopt variable oxidation’states 4) their chemical reactivity 4. Coordination number of [Co(en),Cl,] is a5 so. b)4 c)2 ds Half life for radioactive, 14C is 5760 years. In how many years, 200 mg of 14C.will be reduced to 25 mg? é a) 5760 years b) 11520 years c) 17280 years d) 23040 years The yellow colour of NaCl crystal is due to 7 a) Excitation of electrons in F centers. b) reflection of light from Cl-ion on the surface c) reflection of light from Na* ion d) Allthe above a 2 7. The aqueous solutions of anilinium chloride, sodiurm-acetate, and sodiim cyanide are respectively : a & a) acidic, basic, basic b) basic, acidic, basic ¢) basic, neutral, basic q ‘d) none of these 8. An example of basic buffer is Mi a)NH,OHandNH,Cl, “by NH,OH and NaOH * ; ) NaQH and NH,CI “" d) NaQH and KOH . © . Ina protein, various amino acids linked together by . a) peptide bond —_b) dative bond ©) a-glycosidic bond d) B-glycosidic bondXil Chemistry 2 10. fase Acetic acid does not give HVZ reaction. ‘eason: Acetic acid does not have u-hydrogen atom 4 a) if both assertion and reason are true and $2280 Is the correct explanation of assertion : ») iF both assertion and reason are true bul reason is not the correct explanation of assertion ©) Assertion is true but reason Is false _d) both assertion and reason are false 11, Which one of the following is used in the detection and estimation of -OH, -NH, groups in organic compounds? . a) Formic acid —_b) Benzoic acid —c) Acetyl chloride © 4) ety acetate 7 Br,/Nat 12. GH,CH,Br —2ak20H A KetinOve . —Mh ec op Dis a) bromomethane b) a-bromo sodium acetate c) methanamine . d) acetamide : 13. The reagent used to distinguish between acetaldehyde and benzaldehyde is a) Tollen's reagent b) Fehling’s solution - €) 2,4-dinitro phenyl hydrazine d) Semi carbazide 14, Secondary nitro alkanes react with nitrous acid to form a) red solution b) blue solution ~_c) green solution d) yellow solution 15. Which of the following base is not present in DNA? 2 a) Uracil b)Adenine c) Cytosine d) Guanine . Part-II i Il. Answer any 6 questions. (Q.No.24 is compulsory) 6x2=12 16. Which types of ores can be concentrated by froth floatation’ method? Give two examples. 17. How bleaching powder is prepared? 18. Which is more stable Fe®*'or Fe?*? Explain. 19. Whatis metal deficiency defect? Give example. 20. State Kohlrasuh’s Law. 21. Why are lyophilic colloidal sols are more stable than lyophobic colloidal sol? 22. How will malachite green is prepared from benzaldehyde? 23. Give two differences between Hormones and Vitamins. 24. A Copper electrode is dipped in 0.1 M copper sulphate Solution at 25°C. Calculate the electrode potential of copper (Given: E"¢,2"),70.34V) Part-II lll. Answer any 6 questions. (Q.No.33 is compulsory) 25. Give the uses of Silicones, 26. Mention the consequences of lanthanoid contraction. 27. In an Octahedral field, draw the figure to show splitting of d-orbitals, 28. Calculate the packing efficiency of FCC. 29. Define Equivalent Conductance. Give its unit. 6x3=1830. 31. 32. 35. 36. 37. 38. 3 Xil Chemistry Explain Tyndall effect. : write the Mechanism of Cannizaro reaction. Identify the enzyme catalyst in the following reactions: a) Oxidation of ethanol into acetic acid b) Hydrolysis of starch into maltose c) Hydrolysis of urea . An organic compound (A) - C3H,0, used as a sweetening agentwhich on oxidation with Fenton's reagent gives a mixture of compounds B and C. Identify A, B and C. Write possible reactions. Part -IV Answer all the questions. 5x5=25 . a) Explain the principle of electrolytic refining of metals with silver as an example. ‘ (5) (OR) b) i). . Whatis'inorganic benzene? How it is prepared? (3) ii) Write the structural formula for the following compounds (2) a) Nitric acid b) _Dinitrogen pentoxide *¢) Phosphoric acid d) — Phosphine ' ‘ a) i) © Describe the position of f block elements in the periodic table. (3) ii) Write the properties of interhalogen compounds. (2) ° (OR) . b) i) ~Based on the VB theory. Explain why [Ni(CN),]?- is diamagnetic. (3) ii) Write a short note on T1- back bonding in metal carbonyl (2) a) i) _ Derive Henderson equation. (3) ji) Write a note on sacrificial protection. (2) . (OR) b) i) Write-a note on electro osmosis? (3) « il) Write Arrenius equation and explain its terms. (2) a) i) Howphenolis prepared from a).Chloro benzene b) Isopropyl benzene. (3)° ii) Write a note on isoelectric point. (2) . (OR) b) Elucidate the structure of fructose. (5) a) Write a note on the reduction of nitro benzene under different conditions. (5) (OR) . b) Acompound ‘A’ of molecular formula C2HN on reduction with Na(Hg)/C,H,OH* gives 'B' of molecular formula C,H,N which undergoes carbylamine test. Compound ‘B' on reaction with nitrous acid gives compound ‘C’ of molecular formula C,H,O by liberating nitrogen. Identify A, B and C and write the reactions involved. (5) \ hens \