Material Safety Data Sheet

Product: DALIA CRUDE OIL Page 1 / 8

FDS N° : 2011-001 Version: 3.0 Date : 12 / 01 / 2011

1. IDENTIFICATION OF THE SUBSTANCE AND COMPANY

Category: Crude Oil

Trade name: DALIA CRUDE OIL

Company
Name: TOTAL EXPLORATION & PRODUCTION ANGOLA
Address: Rua Rainha Ginga – CP2610 – Luanda – ANGOLA
Emergency Telephone N°: +244 - 222 - 673013

LABELLING

LABELLING Concerned EC No. 232-298-5 - PETROLEUM, CRUDE OIL

(standard or EU):
Symbol(s) :

Symbol(s) : T Toxic F+ Extremely Flammable

R-phrases : R-12 Extremely flammable.
R-26 Toxic for inhalation
R-45 May cause cancer.
R-65 Harmful: may cause lung damage if swallowed.
R-50/52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S-phrases : S-16 Keep away from sources of ignition - No Smoking. S-53 Avoid exposure - obtain
special instructions before use. S-45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where possible). S-61 Avoid release to
the environment. Refer to special instructions/Safety Data Sheets.

2. HAZARDS IDENTIFICATION

Health effects : Inhalation of vapours containing strong concentrations of hydrogen sulphide

(H2S) may cause immediate loss of consciousness and may be fatal (exposure
to concentrations of H2S above 700 ppm).
Prolonged or repeated exposure to strong concentrations of benzene in crude
oil vapours can have chronic effects, in particular on blood levels.
Prolonged or repeated contact with the skin may cause rashes or more serious
skin conditions.
In strong concentration the vapours and mist are irritating fot the eyes and the
respiratory system, they have an effect on the central nervous system, which
may be light (headache, dizziness, somnolence) or serious (fainting, at times
accompanied by convulsions) in which case first aid is required rapidly.
Environmental impact : This substance has been classified by the manufacturer R 52/53 : Harmful to
aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Physico-chemical hazards: Highly flammable or flammable, depending on the origin of the crude oil.
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FDS N° : 2011-001 Version: 3.0 Date : 12 / 01 / 2011

Product classification : Extremely flammable or Flammable.

Harmful : may cause lung damage if swallowed
Category 2 carcinogen.
Dangerous for the environment.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature : Crude oil is a natural substance. A complex combination of hydrocarbons,

composed mainly of aliphatic, alicyclic and aromatic hydrocarbons. May also
contain small amounts of nitrogen, oxygen and sulphur compounds.
The composition and properties vary significantly depending on the origin of
the crude oil

Substances presenting a health hazard EC No. CAS No. Content Symbol(s) R-phrases
Crude oil 232-298-5 8002-05-9 100% T ,F+ R-12, 45,
52/53, 65
H2S 231-977-3 7783-06-04 <3% F+,T+,N R12, 26,
50
Composition comments : Crude oil contains, hydrogen sulphide (H2S), a number of listed carcinogens,
notably benzene.

4. FIRST-AID MEASURES

General : IN CASE OF SERIOUS OR PERSISTENT CONDITIONS, CONSULT

A DOCTOR OR CALL FOR EMERGENCY MEDICAL AID.
Inhalation : In case of exposure to intense concentrations of vapours, fumes or
spray, transport the person away from the contaminated zone, keep
warm and allow to rest.
If breathing is difficult: call a doctor and apply mechanical ventilation
immediately.
Ingestion : Consult a doctor.
Do not induce vomiting to avoid the risk of aspiration into the
respiratory tract. Allow the person to rest.
Skin contact :. Immediately remove all soiled or stained clothing.
Wash immediately with plenty of water and soap
Eye contact : Wash immediately in copious amounts of water, keeping eyelids apart
for at least 15 minutes and consult a specialist.
Protective equipment for first-aiders : Personal breathing apparatus must be worn when operating in
confined premises.

5. FIRE-FIGHTING MEASURES

Extinguishing media : SUITABLE

Foam, CO2, powder, possibly water spray (preferably water containing a
wetting agent).

NOT RECOMMENDED
Solid water streams are prohibited as they could help to spread the
flames.

Product:
FDS N° : 2011-001
Specific fire-fighting methods :
Specific hazards :
Protective measures for fire
fighters :
6. ACCIDENTAL RELEASE MEASURES
Personal protection :
After spillage / leakage :
Spill cleanup methods :
Prevention of secondary
risks :
7. HANDLING AND STORAGE
HANDLING :
Prevention of user
exposure:
Material Safety Data Sheet
DALIA CRUDE OIL Page 3 / 8
Version: 3.0 Date : 12 / 01 / 2011
Simultaneous use of foam and water on the same surface is to be avoided
as water destroys the foam.
Arrange the machinery and equipment so as to prevent fire from
spreading (retention pits and basins, syphons in the drainage system).
Cool down any tanks and surfaces exposed to fire by spraying abundantly
with water.
Isolate the source of the combustible product; allow to burn out under
supervision or use appropriate fire extinguishers, as applicable.
Incomplete combustion and thermolysis may produce gases of varying
toxicity such as carbon monoxide, carbon dioxide, various hydrocarbons,
sulphur oxides, aldehydes etc., and soot. These are highly dangerous if
inhaled.
Special care must be taken to avoid the risk of explosion.
Use water curtains to protect the personnel.
An individual breathing apparatus and fire-protective clothing
Avoid skin contact with the poured product.
As applicable in view of the risk of exposure, wear hydrocarbon-proof protective
clothing, gloves, goggles, boots, and an insulated breathing apparatus (if vapour
inhalation is a risk)
Design installations so as to prevent water and ground pollution.
Protect drains, water systems and low-lying areas against possible release with
suitable absorbants and barriers to minimize the risk of pollution.
Protect environmentally sensitive areas and water resources.
In case of spillage, contact the competent authorities if the situation cannot be
brought under control rapidly and efficiently. and also if there has been
contamination of the ground or of the vegetation, and if the product has entered
the sewage system or streams, rivers or waterways.
Recovery:
Use mechanical means such as pumps, skimmers and absorbent materials.
Contain and collect the spilled product with sand or any other inert absorbent
material.
Preserve the waste in closed and sealed recipients.
Dispersant
Apply approved chemical dispersant product for offshore spill response.
Elimination:
Dispose of waste in compliance with regulations.
Hand over contaminated materials to an approved collector
Do not discard to sewers.
Warn all persons within proximity of the risk of fire and of explosion.
Remove all sources of ignition.
Cut off the electric power supply if this operation causes no sparks in the area
containing vapours from the product.
In general, never use a naked flame near the storage area without first
evaluating the risks and taking the necessary precautions. Never carry out
welding operations on empty tanks that have not been degassed.
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FDS N° : 2011-001 Version: 3.0 Date : 12 / 01 / 2011

Worker exposure must not be permanent and must be limited to a strict

minimum. Keep the product away from food and beverages. Operations
involving the inspection, cleaning and maintenance of storage containersrequire
the application of strict procedures and must be entrusted to qualified specialist
personnel only.
DO NOT SMOKE.
AVOID INHALING VAPOURS.
AVOID CONTACT WITH THE SKIN AND MUCOUS MEMBRANES.
Skin penetration of polycyclic aromatic hydrocarbons occurs mainly through
contact with product-stained clothing.
Wear safety boots and fully covering protective clothing GENERATING NO
STATIC ELECTRICITY
Prevention of fire and Design installations (machinery and equipment) to prevent burning product from
explosion : spreading (tanks, retention systems, interceptors (traps) in drainage systems).
Use explosion-proof material.
Handle away from any source of ignition (open flame and sparks) and heat (hot
manifolds or casings). Operate only on cold and degassed reservoirs in
ventilated premises (to avoid risk of explosion).
Precautions : WHILE MOVING THE PRODUCT: to prevent risks related to static electricity,
ensure that the machinery, equipment and tanks are properly earthed, prohibit
splash loading and ensure that the product is poured slowly, particularly at the
beginning of the operation.
To minimize the risk of fire, design installations so as to avoid: prevent
splashing and leaking of crude oil.
Avoid breathing in vapor, fumes or mists.
Do not eat or drink or smoke during use.
Avoid extended and repeated contact with the skin as this may cause skin
conditions, which may also be aggravated by minor injuries or by contact with
soiled clothing. Remove any soiled or splashed clothing immediately.
After contact with skin, wash immediately with plenty of water and soap.
Avoid contact with strong oxidizing agents. Use only hydrocarbon-resistant
containers, joints, pipes etc...

STORAGE :
Technical measures: Use anti-explosive materials conforming with the applicable regulations.
Storage precautions: Store away from all sources of ignition and heat. Installations should be
designed to avoid ground and water pollution. Electric installations must comply
with the applicable regulations.
Incompatible products : Dangerous reaction with strong oxidizing agents.
Packaging materials : Use only hydrocarbon-resistant containers, joints, pipes, etc.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Technical measures : Use this product in a well-ventilated atmosphere with explosion-proof

equipment. Worker exposure must not be permanent and must be limited to the
strict minimum for each individual. When working in confined spaces (tanks,
containers, etc.), ensure that there is a supply of air suitable for breathing and
wear the recommended equipment.
Occupational exposure France : C6-C12 hydrocarbon vapors : VLE: 1500 mg/m3 (8 hours), VME: 1000
limit : mg/m3
- Vapor aromatic hydrocarbon in France : C9-C12 (FRANCE) : VME = 150
mg/m3, sur 8 heures
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FDS N° : 2011-001 Version: 3.0 Date : 12 / 01 / 2011

- HYDROGEN SULPHIDE (France) : VME = 7 mg/m3 (or 5ppm) , VLE = 14

mg/m3 (or 10 ppm).
- For BENZENE in France, VME = 1 ppm (3.25 mg/m3) - For toluene in France
: VME=50ppm (192mg/m3), VLE=100ppm (384mg/m3) FRANCE, xylenes (any
isomers) : VME=50ppm (221mg/m3), VLE=100ppm (442mg/m3) n-hexane
(FRANCE & EU) : VME=20ppm (72mg/m³)
Respiratory protection : Protective engineering solutions should be implemented and in use before
personal protective equipment is considered. To enter tankers, tanks,
reservoirs where the oxygen content is too low, wear insulating respiratory
apparatus. In an emergency or for exceptional short-lasting jobs in an
atmosphere polluted by the product, it is necessary to wear self-contained
breathing apparatus. In event of exposure limits being exceeded (H2S) :
Mandatory to wear insulating breathing apparatus : A self-contained breathing
apparatus or supplied-air respiratory protection. The use of breathing apparatus
must comply strictly with the manufacturer’s instructions and the regulations
governing their choices and uses.
Hand protection : Hydrocarbon-proof gloves for aromatic hydrocarbons. Recommended materials
: PVA, Nitrile, Fluoro polymer. For more precise details about the choice of
appropriate protective glove, please contact the manufacturer.
Eye protection : Goggles, in case of risk of splashing.
Skin and body (other than Appropriate protective clothing. Boots or safety shoes.
the hands) protection :
Hygienic work practices : Avoid contact with the skin. If the product comes into contact with the skin,
wash the affected area immediately and copiously with soap and water. In case
of contact with eyes, wash immediately in copious amounts of water while
keeping eyelids spread apart for at least 15 minutes and consult a specialist.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Liquid Pour point: -9°C

Color: Dark brown color Boiling range: 1-800°C
Odor: Odor of petroleum Vapour Pressure 18.4 kPa
Flash Point < 100°F Vapour Density >1
Specific gravity (g/cm3) 0.91 Auto ignition temperature > 260°C
API 23 Kinematic viscosity 37.8 cP
Asphaltenes 2.9%
Explosive properties:
LEL 1.5 vol %
UEL 15 vol %

10. STABILITY AND REACTIVITY

Stability :
Conditions to avoid :
Materials to avoid :
Hazardous decomp. products :
The product is stable at normal storage, handling and use temperatures.
Heat, sparks, ignition points, flames, static electricity.
Strong oxidizing agents.
Incomplete combustion and thermolysis may produce gases of varying
toxicity such as carbon monoxide, carbon dioxide, various
hydrocarbons, sulphur oxides, aldehydes and soot.
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FDS N° : 2011-001 Version: 3.0 Date : 12 / 01 / 2011

11. TOXICOLOGICAL INFORMATION

ACUTE TOXICITY / LOCAL EFFECT :

Inhalation, comments: Vapors inhaled in strong concentration have a narcotic effect on the central
nervous system, which may be light headache, dizziness, somnolence or
serious fainting, in which case first aid is required rapidly. The inhalation of
vapors containing strong concentrations of hydrogen sulfide may cause
immediate loss of consciousness and may be fatal (exposure to
concentrations of H2S above 700 ppm). Strong concentrations of vapor and
spray may be irritating for the respiratory tract and mucous membranes.
Skin contact, comments: Not classified. Prolonged or repeated contact with the skin may cause rash
or more serious skin affections
Eye contact, comments: Strong irritation, burning feeling and temporary redness : eye tissue may
become damaged if the product is not removed rapidly
Ingestion, comments: Crude oil may be classified a harmful owing to the aspiration.
The product may enter the lungs and lead to the rapid development of very
serious pulmonary lesions.

CHRONIC TOXICITY OR LONG-TERM TOXICITY :

Skin contact : Prolonged or repeated contact with the skin may cause rash or more serious
skin conditions
Sensitization : Not classified as allergenic. Possibly allergic dermatitis.
Carcinogenicity : Carcinogen Category 2. Crude oils contain a number of listed carcinogens,
notably benzene, certain polycyclic aromatic hydrocarbons (PAH) and nickel
complexes.

12. ECOLOGICAL INFORMATION

Comments about ecotoxicity:
Mobility :
Bioaccumulation :
Persistence and
degradability :
This substance has been classified R52/53 by the manufacturer : harmful to
aquatic organisms, may cause long-term adverse effects to the aquatic
environment.
- Air: The product evaporates in the air and dissipates more or less
depending on local conditions. However, it may stagnate in pools in low-lying
areas, in an undisturbed or confined atmosphere.
- Soil: The product may infiltrate the ground.
- Water: The product spreads on the surface of the water. A small amount
may dissolve.
The potential for bioaccumulation of the product in the environment is very
low.
The product is intrinsically biodegradable (OECD 302).
However, certain components may persist in the environment.

13. DISPOSAL CONSIDERATIONS

Waste disposal : Waste is to be eliminated in compliance with applicable regulations.

Disposal of contaminated packaging : Crude petroleum is transported only by pipeline, in oil tankers or in
tanks
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FDS N° : 2011-001 Version: 3.0 Date : 12 / 01 / 2011

14. TRANSPORT INFORMATION

UN Number 1267
Proper shipping name (international) : PETROLEUM CRUDE OIL

Road (ADR) / Rail (RID) :

Class : 3
Code de classification : F1
Hazard Label(s) : 3
Hazard identification number : 30 or 33

Transport by barge (ADNR) :

Class : 3
Code de classification : F1
Hazard Label(s) : 3

Marine (IMO-IMDG) :
Class : 3
Hazard Label(s) : 3
Safety card : F-E, S-E
Marine pollutant : No

Air (ICAO/IATA) :
Class : 3
Hazard Label(s) : 3
Comments: Packing group : I , II, or III (according the flash point, the vapor
pressure and the initial boiling point).
Tunel restriction code : D/E

15. REGULATORY INFORMATION

EC No : 232-298-5 - CRUDE OIL

Symbol(s) :

Symbol(s) : T Toxic F+ Extremely Flammable

Risk phrases : R-12 Extremely flammable.
or R11 (F) or R10 (no symbol), depending on the nature of the crude oil.
R-45 May cause cancer.
R-65 Harmful: may cause lung damage if swallowed.
R-52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Safety phrases : S-16 Keep away from sources of ignition - No Smoking.
S-53 Avoid exposure - obtain special instructions before use.
S-45 In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
S-61 Avoid release to the environment.
EU directives : D. 67/548/EC modified by D. 94/69/EC (21th ATP)
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FDS N° : 2011-001 Version: 3.0 Date : 12 / 01 / 2011

16. Other information

- Recommended use/restrictions: Raw material for industry and refineries.
- Hazardous concentrations of hydrogen sulfide gas can accumulate in storage and rundown tanks,
marine vessels compartments or other confined spaces. When opening valves or dome covers, stand
upwind, keep as far from the opening as possible and avoid breathing any gases or vapors.
- H2S fatigues the sense of smell rapidly. The rotten egg odor of H2S disappears quickly, even though
high concentrations are still present.