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FIITJEE Students From Classroom / Integrated School Programs have secured to 2 Zonal, 6 State & 18 City Topper Ranks.

33 in Top 100, 78 in Top 200 and 205 in Top 500 FIITJEE JEE(Advanced)-2016
ANSWERS, HINTS & SOLUTIONS
PART TEST - II
PAPER-1
Answer Key
All India Ranks bagged by FIITJEE Students from All Programs have qualified in JEE (Advanced), 2015.

Q. No. PHYSICS CHEMISTRY MATHEMATICS


B, C A, C A, C
1.
ALL INDIA TEST SERIES

B, C A, B, C, D A, C, D
2.
C B, C A, C, D
3.
B, D A, B, C, D B, D
4.
B, D A, C, D B, D
5.
A, D A, B, C A, B, C
6.
B, C B, C, D B, C, D
7.
A, D A, C A, C
8.
A, C, D B, C A, B, C, D
9.
B, D A, C A, C, D
10.
1 9 2
11.
3 6 9
12.
3 3 6
13.
6 4 4
14.
2 3 6
15.
2 1 2
16.
9 6 2
17.
5 4 6
18.
7 3 4
19.
4 2 5
20.

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2 AITS-PT-II-(Paper-1) –PCM(S)-JEE(Advanced)/16

Physics PART – I

1. W total = K
Normal and mg does no work and friction = 0
1
 (qE0) = mv 02
2

2. Initially, the circuit is


R1 = R

/R

/R

 R
Immediately after opening S, the circuit is as shown. L R1 = R
2
1    L2
Heat  L  2 
2  2R  4R2
L /2R

3. After collision, charged particle has speed v 0cos 30 along the v0
centre of the field.
mv
Radius =  2m = R deflection = 90
Bq

 Co-ordinates = 4 3  1,  4  3  3 m
30 60
1m

 5t 5 
4. VC  4 3 sin   
 3 6 
 3 2
net    1500 C/m
2 4
Where /2 is on the immediate left and 3/4 is on the immediate light.

5. In steady state, the circuit reduces to 1


 By KVL, A
VBA  3V
1A B
And power by 2 Volt battery = 2  1 = 2 W 1
2V

4V

6. Each surface carries the same flux, the net flux is (total charge/0).

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AITS-PT-II-(Paper-1) –PCM(S)-JEE(Advanced)/16 3

B0
7. If magnetic field at Q is B0, then magnetic field at P should be and direction of magnetic fields
2
at point P and Q are towards left.

 2dy  3
8. dF on each of the two symmetric elements = I    B0 y 
 3  2
3
a
2 dy
 2B 0Iydy   3 
= 
0


  
3   2
a  y


y

3
a
2
2  3  IB a3
 IB0   a  y ydy = 0

3 0  2  8
 mg a/2  mga
friction  2 
 a 0

xdx  
 4
For the frame to not rotate
IB0 a3 Mga

8 4
2mg
 B0 
Ia2

p2 p2 P 2
10.  cons tan t  i  2 so A is wrong;
 1 2
RT
By gas equation P 
M
2 T 2
  K  T 2  K so B is correct

 KP 2RT
P RT  P   PT  K so D is correct
M M

SECTION – C
1. No. of turns in thickness dx
dx
dN 
D
ba
 N
2D
 i 1 1   dx
 dB  4   0   
 4x  2 2  D
20i b
 B n
D a
20iA b
  n
d a
20 A b
 M n
D a

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4 AITS-PT-II-(Paper-1) –PCM(S)-JEE(Advanced)/16

2. Iiron  ibrass = 10 cm at all temperature


 iiron(1 + iron t)  ibrass(1+ brasst) = 10 cm
iiron iron = ibrass brass
iiron 1.8 3
 
ibrass 1.2 2
1
 ibrass  10 cm  ibrass = 20 cm
2
and iiron = 30 cm

3. dWdrag  dK  dU
L /2 V L /2
2KQq

L

2F0 dx  2mvdv 
0

L
x3
dx

4. From energy conservation


Ei = E f
 0 = UG + UE
 UG = UE
 Gm2 Gm2   kq2 Kq2 
 2    2  
   2  d2     2  d2 
1 1 1 d2
 1  1 
kq 2  2
 d 2
2 2
  = (using by using binomial)
Gm2 1  1 1 d2
 2  d2 2 2
kq2 4 2
  1
Gm2 d2
d kq2
  1
2 Gm2

5. The ratio of the emf is the ratio of flux of the fields in the two cases.

6. For sphere of radius r, every point on the shell is external  it behaves as a point charge. Now
 q / 4 R2 F
field due to shell at centre =  F2  q  1
40 40 2

 dx
7. E at the location of element =
20    x cos   x


 dF   (  dx)
20    x cos  
 2 dx Let cos  = a
 d  x sin 
20 (  x cos )  + ax = t
adx = dt
 
 d dx = dt/a
I t
 x=
 2 sin  xdx a
  

20   x cos 

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AITS-PT-II-(Paper-1) –PCM(S)-JEE(Advanced)/16 5

 2 sin  1  (1  a)   t    dt
=  2  1  a   (1  a)   ln   
(1  a)  xdx a a
20 a    = 
  x cos  t
 2 sin  1  1 a 
=
20 a2
 2a   ln 1  a  1 t
2
  = 2
a 
t
dt
  sin  1  1 a  1  dt 
=  2 2a  ln 1  a  = 2  dt  
20 a   a    t 
2
  sin  1  1  cos  
=   2cos   ln 1  cos  
20 cos 2  
 
2cos2 
 2  sin  1  2
=  2  sec   ln 
20 cos 2  sin 2  
 2 
 2
2    
= tan  2  sec  ln  cot  
20   2  

2     
= tan   2  2sec  ln  cot  
20   2 
2    
= tan  1  sec  ln  cot  
0   2 
 2  tan   
  1  sec ncot 
0I  2

3
2
8. Fourth capacitor has a potential difference of    27 V = 8V immediately after removing.
3
Capacity of the capacitor with
C C 3C
dielectric =  2  
2 2 2
 Circuit is (64C  q) q
3Q0
 q 1  e19t / 24RC 
19   64C  q +q
Where Q0 = 64 C
 q/3
EP  
0 (A / 2)0
 eEP = mg R

I y
9. Current in the element =  area of element
R(R cos ec)
   I 
dB  d  B    2r(sec d)  r 2  B0 
 R(R cos ec  )    cos 
h 2
B0IR

B  dB 
0
2 r

 For not to topple


mg  R  B P x
2mgh
 I
B0R

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6 AITS-PT-II-(Paper-1) –PCM(S)-JEE(Advanced)/16

10. The equation of P-V graph is


PV
P  3P0  0
V0
2
PV 3P0 V0 V  P0 V
 T 
nR nRV0
dT
For Tmax, 0
dV
3V0
V=
2
9P V
 Tmax  0 0
4nR

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AITS-PT-II-(Paper-1) –PCM(S)-JEE(Advanced)/16 7

Chemistry PART – II

SECTION – A
1. Compounds containing both N and S give blood red colouration in the Lassaigne’s test.

2. NH2 NH2
H2N H3C OH
C NH C NH
H2N H2N N
 pK a  13.6  12.4   4.72  10.95   4.62 
3. O
COOH
O CH3
H
and

CH3 O H
COOH O
are achiral and optically inactive.
4. Compound (A) is cellobiose. It is a disaccharide.
5.





N O N OH
H
Keto form Enol form 
Enol form is more stable than keto form because the enol form is aromatic.
6. H3C OH O
C N H2 SO4
  H3C
 C NH C6H5
H5C6 A LiAlH4

CH3  CH2  NH  C6H5


B 
7. H3C CH3
C C C can not exhibit geometrical isomerism
H H
8. H O
C
H C OH O O
|| ||
HIO4  excess 
C O  2H  C OH  CH3  C CH3  CO2

H3C C OH
CH3
9. (A) Anti hydroxylation
(D) Oxymercuration demercuration.
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8 AITS-PT-II-(Paper-1) –PCM(S)-JEE(Advanced)/16

10. (B) O O

 i  CH 
3 2 CuLi

 ii EtOH

CH3
(D) O O OH O
CH2 C OCH3 CH2 C OCH3
 i NaBH4
 ii H2 O 

SECTION – C
1. H3C CH3
CH3 CH3 H
CH3

, ,

H H H CH3

CH3 CH3 CH3 CH3

, H , CH3 , H
CH3

H H H H
H CH3 H CH3

 & enantiomers  & enantiomers 

2. The following compounds are aromatic.


H
N N
, , ,
N N ,
N ,
N
S
H

3. SO3H COOH HO O

, ,

CH3 NO2 HO O

4. H COOH
H2C COOH
&

H2C COOH
H COOH
Undergo dehydration on heating.
o
5. 1 amines give carbylamine reaction.

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AITS-PT-II-(Paper-1) –PCM(S)-JEE(Advanced)/16 9

6. CH3 CH3
H3C CH CH CH3  i CH3I
 H3C CH CH CH2
 ii AgOH,
N A
H3C CH3 H  1
Number of hyperconjugative structure of the compound (A) = 1

7. The following compounds give positive iodoform test.


O
H3C C CH2 CH3 , H3C CH CH2
OH O
O

H3C CH2 OH , I 2HC C CH3 , , H3C CH2 CH CH3

O Cl

8. Gauche form of the following compounds is more stable than anti form.
HO – CH2 – CH – OH, HO – CH2 – CH2 – F, HO – CH2 – CH2 – Cl, F – CH2 – CH2 – F

9. COOH COOH
O

H3C C OH , ,

CH3 OCH3
are less acidic than benzoic acid.
O
10. CH3COOH, C OH

Ketones, Aromatic aldehyde do not give positive Fehling test.

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10 AITS-PT-II-(Paper-1) –PCM(S)-JEE(Advanced)/16

Mathematics PART – III

SECTION – A

1. Shortest distance between these curves occur along common normal whose point of contact can
be taken as diameter of circle
9
 A1 
32
2
Let P(t, t + 1) is any point on parabola P1, then area of  formed by x-axis, tangent and normal at
P is
2


t 2
  4t
1 2
1  , d  0 maximum area is at t = 3
4t dt
925
 A2 
3
111
Similarly A 3 
4

2. If lines form a , then n = 4


If lines are concurrent or all the three parallel, n = 0
If two are parallel and third cuts, then n = 2

3. Let xn = tan n
 xn + 1 = tan(n + 45º), which means that the sequence {x n} is periodic with period 4
Thus x2016 = x0 = x2000 = x2004 = x2008 = 2015

sin3r 1  cos3r 1  1
4. Tr = sin 3r–1·sec 3r = 
cos3r  cos3r 1  2

 tan3r   tan3r 1 
n
1
 gn      Tr 
r 1 2

tan3n   tan  
tan  1
 fn     gn    
2
 tan3n 
2
 
5. Two tangent can be drawn to the two different branches of the y
2
hyperbola from any point on the curve y = x only if that point D C
lies on the portion AC (upto ) or BD (upto )
B A
x
O

2 2 2
6. (C A)(C T) = (C S) = b e
2
(P N)(P B) = b
(S1 Q)(S2 R) = a2
(S1 P)(S2 P) = (b + ey1)(b – ey1)

7. Orthocentre of PQR lies on hyperbola


=3
Incentre of ABC is orthocentre of PQR
26
Equation of AB is x  y  0
5
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AITS-PT-II-(Paper-1) –PCM(S)-JEE(Advanced)/16 11

Length of perpendicular from incentre on AB = r

8. Tangents at intersection point of line passing through P(3, 2)


(3, 2) with ellipse intersect at director circle Q
 h2 + k2 = 5 ….. (1)
hx ky
Equation of QR is   1 which passes through S(h, k)
3 2
(3, 2) R
h+k=1 ….. (2)
From equation (1) and (2), we get
(h, k) = (2, –1) or (–1, 2)
h

4 1
Slope of QR  3  or
k 3 3
2

9. Using cos(x + d) = cos x·cos d – sin x·sin d to express cos(x + d) for d = 1, 2, 3


We obtain a cos(x + 1) + b cos(x + 2) + c cos(x + 3) =  cos(x + ) for some  and 
If   0,  cos(x + ) = 0
 
 x +  = (2n + 1) , n  Z  x = (2n + 1) – 
2 2
 Two consecutive roots differ by 
 The equation cannot have two or more roots in (0, ) so we must have  = 0
In this case equation is satisfied for all x  R

10. sin( + ) =  sin 2


 sin ·cos  + cos ·sin  = 2 sin ·cos 

 sin ·t4 – (4 + 2 cos )t3 + (4 – 2 cos )t – sin  = 0 (where t  tan )
2
4  2cos 
 If t1, t2, t3 and t4 be the roots of equation  t1  ,  t1t 2  0
sin 
2cos   4
 t1t 2 t3  sin  , t1t2t3t4 = –1
   2  3  4  s1  s3 8 
tan  1    tan
 2  1  s2  s4 0 2
  2  3   4 
 1  n 
2 2
 1 + 2 + 3 + 4 = (2n + 1)

SECTION – C

1. cos(CDA) = –cos(CDB) C
AD2  DC2  AC2 BD2  DC2  BC2 r3 r3
 
2  AD  DC 2  BD  DC r1 r2
2 2 2 2
r22   r1  r2  r3    r1  r3  r12   r1  r2  r3   r2  r3  A D B

2r2  r1  r2  r3  2r1  r1  r2  r3 
C2
Now, r1, r2, r3 are in A.P. C1
 2r2 = r1 + r3
2 2 2 2 C3
r22   2r1  r2    2r2  r12   2r1  r2    3r2  r1 
 
2r2  2r1  r2  2r1  2r1  r2 

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12 AITS-PT-II-(Paper-1) –PCM(S)-JEE(Advanced)/16

3
r 
  1 2
 r2 

2. For lines to be chord of circle, its distance from the centre must be less than the radius
  24
For L1 : 2
13

   24  2 13, 24  2 13 
   {17, 18, ….., 31} (   z)
Similarly for L2:   {11, 12, ….., 25}

3. Let O be origin and P1, P2 be the initial and final position of P


Since OP1 and OP2 make equal angles with the y-axis
 P1P2 is parallel to OA

 Area of sector OP1P2 =
6

ax by
4. Equation of line   1  0 has two independent parameters. Now there must be one
c 3 c 3
a b
linear relation between and which is independent of a, b and c given relation can be
c3 c3
2a 3b   4c
expressed as  
c 3 c 3 c3
1 3
Now R.H.S is independent of  if  = 12 and for  = 12, line passes through a fixed point  , 
 2 4
 [] = 4

3
5. If sin2 x – sin x·sin y + sin2 y = x = y – /3
4
sin y 3 cos y  
 sin x    sin  y  
2 2  3
x = y + /3
O x = –y + 2/3

6. Let O be the circumcentre and I the incentre, then


A B C A B C
OI  R 1  8 sin  sin  sin  4R sin sin sin
2 2 2 2 2 2
A B C 2 1
 sin  sin  sin 
2 2 2 4
A B C
 cos A + cos B + cos C = 1  4 sin  sin  sin  2
2 2 2

7. B = 60º
Let h be the altitude from B
h h
 h = AB – BC = 
sin A sinC
 C  A  CA 3
 sin2    sin   0
 2   2  4
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AITS-PT-II-(Paper-1) –PCM(S)-JEE(Advanced)/16 13

CA 1
 sin  
 2  2

1 1  a C
8. AM 
2
AC 2a M
 
2 2
 AC = |a – 2| B
A(1, 1)
1 x+y=a
Now, area =  AC  AB
2
1 2 x + 3y = 4
 8    AC  [AC = AB]
2 x–y=0
2
 16 = (AC)
 (a – 2)2 = 16
 a – 2 = 4
 a = 6, –2

9. On adding and subtracting the equations, we get (x + 3)2 = 4(y – 1) and y2 – 20y + 59 = 0
respectively
Let points of intersection be(x1, y1),(x2, y1), (x3, y2) and (x4, y2)
 y1 + y2 = 20, and y1, y2 > 0
2 2
The required sum =   x1  3   y1  2
2
=  4  y1  1   y1  2 =  y1 = 2(y1 + y2) = 40

3 2 1  3 2 3 
10. y  tan  4 sin  sin  4 sin  cos 
11 11 3  11 11 11 
cos
11
3 3 2 3 2 3 3
 y 2 cos2  sin2  16 sin2  cos 2  8 sin  sin  cos
11 11 11 11 11 11 11
6 5 12
4cos  sin 2 sin
= 9  11cos
6
 11 11 = 9  11cos 6  11 = 11 1  cos 6 
11  11   11 
sin sin 
11 11
2
y = 11

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