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Organic & Everyday Chem PDF
Organic & Everyday Chem PDF
Organic & Everyday Chem PDF
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Organic Chemistry and Everyday Chemistry
Question- Answers
Q1. Two adjacent members of a homologous series have :
(a) a difference of –CH2 in their structure
(b) a difference of 14 a.m.u. in molecular mass
(c) same general methods of preparation
(d) all of the above
A homologous series can be defined as group of compounds in which the various members have
similar structural features & similar chemical properties & the successive members differ in their
molecular formula by ‘CH2’ . Individual member of series are called homologue.
Characteristics of Homologous Series –
1 ) All compounds in the series are composed of same elements and contain the same functional group.
2) All compounds in the series can be represented by one general formula .
Ex. Homologous series of alcohol-
General formula = Cn H2n+1 OH
3) The molecular mass of every two adjacent members differ by 14 or CH2 .
4) All members of series have similar chemical properties because of the presence of same functional group.
5) The members of series show a gradual gradation in their physical properties like solubility, density, melting point &
boiling points. The physical properties generally increases as the molecular mass increases.
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Q2. Alkenes are characterized by
(a) C –--- C bonds (b) C = C bonds
(c) C C bonds (d) cyclic structure
C2H6 (Ethane)
Vinegar is a liquid consisting of about 5–20% acetic acid (CH3COOH), water (H2O), and trace chemicals
that may include flavorings.
( --COOH)
Q9. How many different isomers are possible for a hydrocarbon with the molecular formula C4H10?
(a) 1 (b) 2
(c) 3 (d) 5
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Isomers of C5H12
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Q22. The aliphatic hydrocarbon which contain double covalent bonds are known as alkenes . Alkenes are
A] Saturated hydrocarbons
B] Unsaturated hydrocarbons
C] aromatic Hydrocarbons
D] none of the above
Unsaturated hydrocarbons have double or triple bond.
Methane is the simplest aliphatic compound and benzene is the simplest aromatic compound.
Q23. the compounds having same molecular formula but differ in their structures are called
A] isomers b] isotopes c] polymers d] allotropes
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Q24. the gas used for Artificial ripening of Green fruit is
A] acetylene b] ethylene c] ethane d] Carbon dioxide
Ethylene is a hydrocarbon which has the formula C ₂H ₄ or H₂C=CH₂. It is a colorless flammable gas
with a faint "sweet and musky" odour when pure. It is the simplest alkene.
Q26. The chloroform (CHCl3) if kept in the coloured bottle or container because it directly reacts with air and
light and forms a toxicated substance__
A] phosphine b] phosgene c] mustard gas d] CO
Phosgene : COCl2
Q27. Synthetic ethanol is produced by reacting ethene (in the presence of phosphoric acid) with
A) hydrogen
B) potassium dichromate
C) oxygen
D) water (steam)
Ethanol can also be manufactured by reacting ethene (from cracking crude oil fractions) with steam. A
catalyst of phosphoric acid is used to ensure a fast reaction. Ethanol is the only product. This is a
continuous reaction - as long as ethene and steam are fed into the reacting vessel, ethanol will be
produced.
The flavour of Apple is mainly because of the presence of Ethanol in it.
Q28. an organic compound is used in making picric acid (explosive), phenolphthalein (an indicator), bakelite
(first plastic made from synthetic components), salol (Phenyl salicylate), aspirin, salicylic acid etc. The organic
compound is
A] benzene b] phenol c] nitrobenzene d] aniline
Q29. Which of the following compounds does not contain a carboxylic acid group?
A] picric acid b] vinegar c] salicylic acid d] benzoic acid
Carboxylic acid group: -COOH
Picric acid formula (O₂N)₃C₆H₂OH. Its IUPAC name is 2,4,6-trinitrophenol.
Vinegar is a liquid consisting of about 5–20% acetic acid (CH3COOH), water (H2O)
Salicylic acid has the formula C₇H₆O₃.
Benzoic acid, C₇H₆O₂, is a colorless crystalline solid and a simple aromatic carboxylic acid.
The tracking of people by trained dogs is based on the recognition of carboxylic acid in the sweat from
feet.
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Oxalic acid (C2H2O4) is it dicarboxylic acid. Calcium oxalate is present in human urine, sometimes this
compound deposits in the Kidney and appears as kidney or prostate stone.
Everyday Chemistry
1. The hair dye available in the market contains two bottles, one containing dye and other containing hydrogen
peroxide. The bottles are mixed before applying the dye. The function of hydrogen peroxide is
A] to dilute the dye
B] to oxidise the dye to give desired colour
C] to reduce the dye to give desired colour
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D] to acidify the dye solution
2. Soaps cannot be used in acidic condition because they lose their cleansing effect due to the formation of
insoluble
A] esters
B] alcohols
C] hydrocarbons
D] long-chain fatty acids
4. Farmers are requested to mix lime with soil while farming their fields. This is because
A] lime is very helpful in maintaining the water content in the soil
B] lime decreases the acidity of soil
C] lime decreases the basicity of soil
D] high concentration of lime is necessary for the plant growth
5. The polymeric fibres used as a substitute for wool in making synthetic blankets, sweaters etc. is
A] nylon b] Teflon c] orlon d] bakelite
7. Cement, the most important building material at the present time, is used in the construction of buildings,
roads, dams etc. It does not contain
A] calcium silicate
B] calcium aluminate
C] calcium sulpho-aluminate
D] calcium phosphate
9. Which one of the following fibre is made from natural raw materials?
A] rayon b] nylon c] polyester d] polystyrene
Rayon is extracted from cellulose which is naturally found.
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14. Thermosetting Polymers can melt and take shape once after they have been solidified and they stay solid.
In thermosetting process a chemical process takes place that is Irreversible. Which of the following is
thermosetting polymer?
A] PVC b] vulcanised rubber c] polystyrene d] polyethylene
15. This plastic is heat and wear resistant. This plastic is used to build gears, plain bearing, valve seats and
seals. Which call of the following plastics is referred above?
A] rubber b] nylon c] PVC d] polystyrene
Nylon will melt around 400° F.
22. Which of the following is the residual product in the formation of soap?
a) Glyceraldehyde
b) Glycerol
c) Glycerine
d) Acrylonitrile
27. Which of the following chemical is added in washing powder for keeping the dirt suspended in water?
a) Sodium silicate
b) Inorganic phosphate
c) Carboxy-methyl cellulose
d) Sodium perborate
34. The major component used in preparation of different types of glasses is?
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a. Silica
b. sodium borate
c. calcium silicate
d. sodium silicate
36. Which one of the following will you put into pure water in order to pass electric current through it ?
a. Kerosene
b. mustard oil
c. lemon juice
d. Sugar
37. One of the occupational health hazards commonly faced by the workers of ceramics, pottery and glass
industry is
a. stone formation in gallbladder
b. Melanoma
c. silicosis
d. stone formation in kidney
Chemistry is linked with many aspects in our daily life. Such as-(1) Drugs (2) Food additives (3) Cosmetics &
cleaning agents (4) polymer industry (5) other uses
(1) DRUGS :-
(a) Antipyretic=To consume the normal body temperature in the presence of fever.
Example-Paracetamol.Analgin.Aspirin etc.
(b) Analgesic=uses for relieve pain
Example=Paracetamol.Analgin.Aspirin etc.
(c) Anaesthetics (also called painkiller) :cause a temporary loss of sensation with or without loss of
consciousness.
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Example= two types of pain killer uses (1) normal anaesthetics=it effected whole body loss of sensation
example=chloroform.cyclopropane. Nitrous oxide.
(2) Local anaesthetics= particular selective part loss of sensation. Example=Ethyl chloride(use as a spray).
(d) Tranquilizers (psychotherapeutic drug)= treatment of anxiety. Fear. Tension. Agitation.& disturbances of the
mind.
Example= Veronal. Luminal. Seconal
(e) Antiseptics & Disinfectants= uses to the prevent of growth of micro organisms. The main difference
between antiseptics & disinfectant. Antiseptic is applied to the human body but other applied to the non living
surfaces. Common example a doctor will apply an antiseptic to the surgical site on a persons body and use
disinfectant to sterilize the operating table.Example= Phenol.Cresol.Ethanol. Resorcinol.
(f) Antacid=Its neutralizes stomach acidity and is used to relieve heartburn .indigestion or an upset stomach.
Example= sodium bicarbonate. Calcium carbonate. Aluminium hydroxide. Most common antacid are Gelusil(
magnesium trisilicate + aluminium hydroxide) Digene. Diovol.
(g) Antibiotics= for bacterial infection
Example= penicillin. Gentamicin
(h) Antimicrobials (also known as sulfa drugs) = it is used for against bacteria & fungi. Example=
sulfadiazine.sulfathiazole.sulfacetamide.
(i) Antihistamine= to control the allergic in our human body.
Example= promethazine. Brompheniramine.
(2) The compound that causes general antidepressant action on the central nervous system belongs the class
of
(a) Analgesics
(b) Tranquilizers
(c) Narcotic analgesics
(d) Antihistamines
(7) equanil is
(a) artificial sweetener
(b) antihistamine
(c) tranquilizer
(d)antifertility drug
(11) Which of the following are antidepressants ** Bold phrases are all answers.
(a)iproniazid
(b)phenelzine
(c) equanil
(d)salvarsan *** a,b,c are answers
(15) which of the following will not enhance nutritional value of food
(a) artificial sweeteners
(b) minerals
(c) vitamins
(d)amino acids
(16)which chemicals can be added for sweetening of food items at cooking temperature and does not provide
calories
(a)sucrose
(b)aspartame
(c)glucose
(d)sucralose
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(17)which is not a target molecule for drug function in body
(a)carbohydrates
(b) vitamins
(c) lipids
(d) None
(18) polyethylene glycols are used in the preparation of which type of detergents
(a) cationic detergents
(b)anionic detergents
(c) non ionic detergents
(d)soaps
ALUM- double salts of potassium sulfate & aluminium sulfate is alum [k2 so4. Al2(so4)3.24H20]
USES-purify water. In medicine. Tanning. Dying. Cosmetics(deodorant & antitranspirants)
COPPER SULPHATE(CUSO4.5H2O)-Copper sulphate is known as blue vitriol. Blue stone. Roman vitriol.
Vitriol of copper.
USES- Bordeaux mixture- is used to control fungus. Horticulture. To treat aquarium fishes for parasitic
infection.
EPSOM SALT=Magnesium sulfate(MgSO4.7H2O) It is known as English salt. bitter salts. Bath salts
USES= Majority uses in agriculture. Polymer. Cosmetics.
BORIC ACID(H3BO3)-It is known as hydrogen borate. Orthoboric acid.
USES- cosmetics. Eye lotion. Food preservative. Pharmaceutical
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Polymer chemistry
Polymer-high molecular mass formed by the combination of a large no. of simple molecules is called polymers
& the simple molecules unit is its monomer.
Polymerisation-the process in which monomers get combined & transformed is known as polymerization.
Eg; n[monomer] to polymer
Classification of polymer:
(1) Natural polymers=starch. Cellulose. Proteins.natural rubber
(2) Synthetic polymers= (man made polymer) polythene. Synthetic rubber. PVC. Teflon. Nylon-66
(3) Semisynthetic polymers= some modification in natural polymers by artificial.eg; cellulose. Rayon.
Vulcanized rubber.
(4) Polythene=the monomer of ethylene or ethane
Uses= low density polythene:- insulation of electricity. Manufacture of squeeze bottles. Toys. Flexible pipes
High density polythene :- making containers. House wars. Toyes.
(5) Polystyrene=monomer of styrene
Uses= rain coats.toys. Radio & tv cabinets. It is hard & resistant to heat & chemicals.
(6)polypropylene= monomer of propylene
(7) polytetrafluoroethylene= Teflon
Uses=making oil seals. It is chemically inert & resistant to attack by corrosive reagent
(8) Nylon-66:- it is obtained by condensation of adipic acid & hexamethylenediamine with the elimination of
water molecule.
USES=nylon-66 is usually fabricated into sheets & textile.
(9) BUBBLE GUM contains styrene butadiene rubber.
(10) BUNA-N:- it is copolymer of buta 1,3 diene & acrylonitrile
Uses=making conveyor belt & printing rollers.
(11) polyesters= polymers contain an ester linkage. eg=decron.
(12) natural rubber= which is coiled linear 1,4 polymer of isoprene. It is not use very extensively for commercial
purpose.
(13) poly vinyl chloride (PVC)= monomer vinyl chloride.
(23) DDT was invented by Paul Muller. Dichlorodiphenyltrichloroethane, commonly known as DDT, is a
colorless, tasteless, and almost odorless crystalline chemical compound, an organochlorine, originally
developed as an insecticide, and ultimately becoming infamous for its environmental impacts.
(24) Heavy water discovered by H .C .Urey. Heavy water is water that contains heavy hydrogen or deuterium.
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